CN102356062B - 制备芳族氨基甲酸酯的方法 - Google Patents

制备芳族氨基甲酸酯的方法 Download PDF

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Publication number
CN102356062B
CN102356062B CN201080012312.4A CN201080012312A CN102356062B CN 102356062 B CN102356062 B CN 102356062B CN 201080012312 A CN201080012312 A CN 201080012312A CN 102356062 B CN102356062 B CN 102356062B
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Prior art keywords
carbonate
zinc
oac
aromatic
reaction
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Chinese (zh)
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CN102356062A (zh
Inventor
S.沃肖芬
S.克莱因
A.维达尔-弗兰
E.赖克萨赫
F.X.里厄斯-鲁伊斯
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Covestro Deutschland AG
Bayer Intellectual Property GmbH
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Bayer MaterialScience AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C07C263/04—Preparation of derivatives of isocyanic acid from or via carbamates or carbamoyl halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201080012312.4A 2009-03-16 2010-03-12 制备芳族氨基甲酸酯的方法 Active CN102356062B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09003729A EP2230228A1 (en) 2009-03-16 2009-03-16 Process for preparing aromatic carbamates
EP09003729.2 2009-03-16
PCT/EP2010/001563 WO2010105768A1 (en) 2009-03-16 2010-03-12 Process for perparing aromatic carbamates

Publications (2)

Publication Number Publication Date
CN102356062A CN102356062A (zh) 2012-02-15
CN102356062B true CN102356062B (zh) 2016-03-30

Family

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CN201080012312.4A Active CN102356062B (zh) 2009-03-16 2010-03-12 制备芳族氨基甲酸酯的方法

Country Status (7)

Country Link
US (1) US8513453B2 (enExample)
EP (2) EP2230228A1 (enExample)
JP (1) JP5645911B2 (enExample)
KR (1) KR20110139219A (enExample)
CN (1) CN102356062B (enExample)
HU (1) HUE025054T2 (enExample)
WO (1) WO2010105768A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014510714A (ja) 2011-01-18 2014-05-01 グラクソ グループ リミテッド レチガビンの製造方法
JP6466414B2 (ja) * 2013-05-22 2019-02-06 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ 亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用
KR102016527B1 (ko) * 2013-06-20 2019-09-02 한국생산기술연구원 방향족 아민으로부터의 지방족 히드록시알킬 카바메이트의 제조방법
CN103980160B (zh) * 2014-05-08 2016-02-24 南京工业大学 一种合成异佛尔酮二氨基甲酸甲酯的方法
CN106349110A (zh) * 2015-07-17 2017-01-25 大东树脂化学股份有限公司 制备脂肪族二异氰酸酯的二步法及一锅化合成法
CN106543038A (zh) * 2015-09-16 2017-03-29 中国石油化工股份有限公司 一种4,4’-二苯甲烷二氨基甲酸甲酯合成工艺
WO2018210711A1 (en) * 2017-05-15 2018-11-22 Covestro Deutschland Ag Silica-based zinc catalysts. their preparation and use in the alkoxycarbonylation of amines
KR102132856B1 (ko) * 2018-08-27 2020-07-13 한국과학기술연구원 아연-이미다졸 복합체 혼합물 촉매 및 이를 이용한 메틸 n-페닐카바메이트의 제조방법
KR20220125214A (ko) * 2020-01-08 2022-09-14 스미토모 세이카 가부시키가이샤 유기 아연 촉매
CN111760451B (zh) * 2020-06-28 2023-03-28 上海应用技术大学 一种采用多金属氧酸盐在空气室温下催化分解甲醛的方法
JP7696562B2 (ja) * 2021-04-30 2025-06-23 国立研究開発法人産業技術総合研究所 一置換カーボネート塩を用いたカルバミン酸エステルの製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0752413A1 (en) * 1995-07-06 1997-01-08 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for the production of aromatic carbamates
EP0752414A1 (en) * 1995-07-06 1997-01-08 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for the production of aromatic urethanes
WO2001068590A1 (en) * 2000-03-17 2001-09-20 Enichem S.P.A. Continuous process for the synthesis of aromatic urethanes
CN1419538A (zh) * 2000-02-03 2003-05-21 恩尼化学有限公司 制备芳烃异氰酸酯的综合方法及实施相关中间阶段的程序
EP1958940A1 (en) * 2005-12-05 2008-08-20 Takasago International Corporation Condensation reaction by metal catalyst

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Publication number Priority date Publication date Assignee Title
US3763217A (en) 1970-12-03 1973-10-02 Halcon International Inc Preparation of carbamates
US4268683A (en) 1980-02-21 1981-05-19 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
US4404146A (en) * 1980-12-17 1983-09-13 Biosystems Research Inc. Metal oxyalkylates and method of making same
CA1193611A (en) 1980-10-07 1985-09-17 Joseph E. Lionele Anti viral, anti bacterial and/or anti fungal composition containing metal oxyalkylate
JPS5791948A (en) * 1980-10-07 1982-06-08 Bio Syst Res Inc Methaloxy alkylate and manufacture
EP0065026A1 (en) 1981-05-18 1982-11-24 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
JPS57188558A (en) * 1981-05-18 1982-11-19 Dow Chemical Co Manufacture of carbamate from aromatic amine and organic carbonate
DE4113156A1 (de) 1991-04-23 1993-01-14 Bayer Ag Verfahren zur herstellung von poly(o-alkylurethanen) der diphenylmethanreihe
DE4121211A1 (de) 1991-06-27 1993-01-14 Bayer Ag Verfahren zur herstellung von bis(ethoxycarbonylamino)toluolen und deren verwendung zur herstellung von diisocyanatotoluolen
JP2004262835A (ja) * 2003-02-28 2004-09-24 Mitsui Chemicals Inc 芳香族イソシアネートの製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0752413A1 (en) * 1995-07-06 1997-01-08 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for the production of aromatic carbamates
EP0752414A1 (en) * 1995-07-06 1997-01-08 Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica Process for the production of aromatic urethanes
CN1419538A (zh) * 2000-02-03 2003-05-21 恩尼化学有限公司 制备芳烃异氰酸酯的综合方法及实施相关中间阶段的程序
WO2001068590A1 (en) * 2000-03-17 2001-09-20 Enichem S.P.A. Continuous process for the synthesis of aromatic urethanes
EP1958940A1 (en) * 2005-12-05 2008-08-20 Takasago International Corporation Condensation reaction by metal catalyst

Also Published As

Publication number Publication date
JP5645911B2 (ja) 2014-12-24
US20120041223A1 (en) 2012-02-16
JP2012520333A (ja) 2012-09-06
EP2408737B1 (en) 2015-04-22
WO2010105768A1 (en) 2010-09-23
EP2230228A1 (en) 2010-09-22
EP2408737A1 (en) 2012-01-25
HUE025054T2 (en) 2016-01-28
WO2010105768A8 (en) 2011-08-25
KR20110139219A (ko) 2011-12-28
CN102356062A (zh) 2012-02-15
US8513453B2 (en) 2013-08-20

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Effective date of registration: 20160623

Address after: Leverkusen, Germany

Patentee after: COVESTRO DEUTSCHLAND AG

Address before: German Monheim

Patentee before: BAYER INTELLECTUAL PROPERTY GmbH

Effective date of registration: 20160623

Address after: German Monheim

Patentee after: BAYER INTELLECTUAL PROPERTY GmbH

Address before: Germany Leverkusen

Patentee before: BAYER MATERIALSCIENCE AG