JP5645911B2 - 芳香族カルバメートの製造方法 - Google Patents

芳香族カルバメートの製造方法 Download PDF

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JP5645911B2
JP5645911B2 JP2012500118A JP2012500118A JP5645911B2 JP 5645911 B2 JP5645911 B2 JP 5645911B2 JP 2012500118 A JP2012500118 A JP 2012500118A JP 2012500118 A JP2012500118 A JP 2012500118A JP 5645911 B2 JP5645911 B2 JP 5645911B2
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Prior art keywords
carbonate
zinc
catalyst
aromatic
group
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JP2012500118A
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Japanese (ja)
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JP2012520333A (ja
JP2012520333A5 (enExample
Inventor
シュテファン・ヴェルスホーフェン
シュテファン・クライン
アントン・ビダル−フェラン
エリセンダ・レイサチ
フランセスク・ハビエル・リウス−ルイス
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Covestro Deutschland AG
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Bayer MaterialScience AG
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00Preparation of derivatives of isocyanic acid
    • C07C263/04Preparation of derivatives of isocyanic acid from or via carbamates or carbamoyl halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2012500118A 2009-03-16 2010-03-12 芳香族カルバメートの製造方法 Expired - Fee Related JP5645911B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09003729A EP2230228A1 (en) 2009-03-16 2009-03-16 Process for preparing aromatic carbamates
EP09003729.2 2009-03-16
PCT/EP2010/001563 WO2010105768A1 (en) 2009-03-16 2010-03-12 Process for perparing aromatic carbamates

Publications (3)

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JP2012520333A JP2012520333A (ja) 2012-09-06
JP2012520333A5 JP2012520333A5 (enExample) 2013-04-25
JP5645911B2 true JP5645911B2 (ja) 2014-12-24

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JP2012500118A Expired - Fee Related JP5645911B2 (ja) 2009-03-16 2010-03-12 芳香族カルバメートの製造方法

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US (1) US8513453B2 (enExample)
EP (2) EP2230228A1 (enExample)
JP (1) JP5645911B2 (enExample)
KR (1) KR20110139219A (enExample)
CN (1) CN102356062B (enExample)
HU (1) HUE025054T2 (enExample)
WO (1) WO2010105768A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014510714A (ja) 2011-01-18 2014-05-01 グラクソ グループ リミテッド レチガビンの製造方法
JP6466414B2 (ja) * 2013-05-22 2019-02-06 コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag 亜鉛クラスター化合物およびアミンと炭酸ジアルキルとの反応における触媒としてのそれらの使用
KR102016527B1 (ko) * 2013-06-20 2019-09-02 한국생산기술연구원 방향족 아민으로부터의 지방족 히드록시알킬 카바메이트의 제조방법
CN103980160B (zh) * 2014-05-08 2016-02-24 南京工业大学 一种合成异佛尔酮二氨基甲酸甲酯的方法
CN106349110A (zh) * 2015-07-17 2017-01-25 大东树脂化学股份有限公司 制备脂肪族二异氰酸酯的二步法及一锅化合成法
CN106543038A (zh) * 2015-09-16 2017-03-29 中国石油化工股份有限公司 一种4,4’-二苯甲烷二氨基甲酸甲酯合成工艺
WO2018210711A1 (en) * 2017-05-15 2018-11-22 Covestro Deutschland Ag Silica-based zinc catalysts. their preparation and use in the alkoxycarbonylation of amines
KR102132856B1 (ko) * 2018-08-27 2020-07-13 한국과학기술연구원 아연-이미다졸 복합체 혼합물 촉매 및 이를 이용한 메틸 n-페닐카바메이트의 제조방법
KR20220125214A (ko) * 2020-01-08 2022-09-14 스미토모 세이카 가부시키가이샤 유기 아연 촉매
CN111760451B (zh) * 2020-06-28 2023-03-28 上海应用技术大学 一种采用多金属氧酸盐在空气室温下催化分解甲醛的方法
JP7696562B2 (ja) * 2021-04-30 2025-06-23 国立研究開発法人産業技術総合研究所 一置換カーボネート塩を用いたカルバミン酸エステルの製造方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3763217A (en) 1970-12-03 1973-10-02 Halcon International Inc Preparation of carbamates
US4268683A (en) 1980-02-21 1981-05-19 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
US4404146A (en) * 1980-12-17 1983-09-13 Biosystems Research Inc. Metal oxyalkylates and method of making same
CA1193611A (en) 1980-10-07 1985-09-17 Joseph E. Lionele Anti viral, anti bacterial and/or anti fungal composition containing metal oxyalkylate
JPS5791948A (en) * 1980-10-07 1982-06-08 Bio Syst Res Inc Methaloxy alkylate and manufacture
EP0065026A1 (en) 1981-05-18 1982-11-24 The Dow Chemical Company Preparation of carbamates from aromatic amines and organic carbonates
JPS57188558A (en) * 1981-05-18 1982-11-19 Dow Chemical Co Manufacture of carbamate from aromatic amine and organic carbonate
DE4113156A1 (de) 1991-04-23 1993-01-14 Bayer Ag Verfahren zur herstellung von poly(o-alkylurethanen) der diphenylmethanreihe
DE4121211A1 (de) 1991-06-27 1993-01-14 Bayer Ag Verfahren zur herstellung von bis(ethoxycarbonylamino)toluolen und deren verwendung zur herstellung von diisocyanatotoluolen
IT1282023B1 (it) * 1995-07-06 1998-03-06 Mini Ricerca Scient Tecnolog Procedimento per la produzione di uretani aromatici
IT1282022B1 (it) * 1995-07-06 1998-03-06 Mini Ricerca Scient Tecnolog Procedimento per la produzione di carbammati aromatici
IT1317756B1 (it) 2000-02-03 2003-07-15 Eni Spa Procedimento integrato per la preparazione di isocianati aromatici eprocessi per la realizzazione delle relative fasi intermedie.
IT1318395B1 (it) 2000-03-17 2003-08-25 Enichem Spa Processo in continuo per la sintesi di uretani aromatici.
JP2004262835A (ja) * 2003-02-28 2004-09-24 Mitsui Chemicals Inc 芳香族イソシアネートの製造方法
JP5095415B2 (ja) 2005-12-05 2012-12-12 高砂香料工業株式会社 金属触媒による縮合反応

Also Published As

Publication number Publication date
US20120041223A1 (en) 2012-02-16
JP2012520333A (ja) 2012-09-06
EP2408737B1 (en) 2015-04-22
CN102356062B (zh) 2016-03-30
WO2010105768A1 (en) 2010-09-23
EP2230228A1 (en) 2010-09-22
EP2408737A1 (en) 2012-01-25
HUE025054T2 (en) 2016-01-28
WO2010105768A8 (en) 2011-08-25
KR20110139219A (ko) 2011-12-28
CN102356062A (zh) 2012-02-15
US8513453B2 (en) 2013-08-20

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