CN102186777A - 含锂的过渡金属硫化物化合物 - Google Patents
含锂的过渡金属硫化物化合物 Download PDFInfo
- Publication number
- CN102186777A CN102186777A CN2009801407811A CN200980140781A CN102186777A CN 102186777 A CN102186777 A CN 102186777A CN 2009801407811 A CN2009801407811 A CN 2009801407811A CN 200980140781 A CN200980140781 A CN 200980140781A CN 102186777 A CN102186777 A CN 102186777A
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- Prior art keywords
- lithium
- transition metal
- metal sulfide
- containing transition
- producing
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/20—Methods for preparing sulfides or polysulfides, in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/24—Preparation by reduction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/24—Preparation by reduction
- C01B17/26—Preparation by reduction with carbon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/24—Preparation by reduction
- C01B17/28—Preparation by reduction with reducing gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/12—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/20—Compounds containing manganese, with or without oxygen or hydrogen, and containing one or more other elements
- C01G45/22—Compounds containing manganese, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/12—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/80—Compounds containing cobalt, with or without oxygen or hydrogen, and containing one or more other elements
- C01G51/82—Compounds containing cobalt, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/11—Sulfides; Oxysulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/08—Sulfides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Iron (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0818758.5 | 2008-10-14 | ||
| GB0818758A GB2464455B (en) | 2008-10-14 | 2008-10-14 | Lithium-containing transition metal sulfide compounds |
| GB0906601A GB2464357B (en) | 2008-10-14 | 2009-04-17 | Lithium containing transition metal sulfide compounds |
| GB0906601.0 | 2009-04-17 | ||
| PCT/GB2009/051314 WO2010043886A2 (en) | 2008-10-14 | 2009-10-06 | Lithium containing transition metal sulfide compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102186777A true CN102186777A (zh) | 2011-09-14 |
Family
ID=40083955
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801407811A Pending CN102186777A (zh) | 2008-10-14 | 2009-10-06 | 含锂的过渡金属硫化物化合物 |
| CN2009801402822A Pending CN102177607A (zh) | 2008-10-14 | 2009-10-06 | 含锂的过渡金属硫化物化合物 |
| CN2009801398507A Pending CN102177094A (zh) | 2008-10-14 | 2009-10-06 | 含锂的过渡金属硫化物化合物 |
| CN2009801403670A Pending CN102177090A (zh) | 2008-10-14 | 2009-10-06 | 硫化锂的制备 |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801402822A Pending CN102177607A (zh) | 2008-10-14 | 2009-10-06 | 含锂的过渡金属硫化物化合物 |
| CN2009801398507A Pending CN102177094A (zh) | 2008-10-14 | 2009-10-06 | 含锂的过渡金属硫化物化合物 |
| CN2009801403670A Pending CN102177090A (zh) | 2008-10-14 | 2009-10-06 | 硫化锂的制备 |
Country Status (9)
| Country | Link |
|---|---|
| US (4) | US20110200878A1 (enExample) |
| EP (4) | EP2337764A1 (enExample) |
| JP (4) | JP2012505143A (enExample) |
| KR (4) | KR20110122092A (enExample) |
| CN (4) | CN102186777A (enExample) |
| AR (4) | AR073866A1 (enExample) |
| GB (2) | GB2464455B (enExample) |
| TW (4) | TW201022154A (enExample) |
| WO (4) | WO2010043886A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117977044A (zh) * | 2024-04-01 | 2024-05-03 | 四川新能源汽车创新中心有限公司 | 一种硫化物基全固态电池物料的回收方法 |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8097967B2 (en) | 2008-06-30 | 2012-01-17 | Demand Energy Networks, Inc. | Energy systems, energy devices, energy utilization methods, and energy transfer methods |
| GB2464455B (en) * | 2008-10-14 | 2010-09-15 | Iti Scotland Ltd | Lithium-containing transition metal sulfide compounds |
| CN103329319B (zh) * | 2011-01-27 | 2017-08-29 | 出光兴产株式会社 | 碱金属硫化物和导电剂的复合材料 |
| JP4948659B1 (ja) * | 2011-04-12 | 2012-06-06 | 三井金属鉱業株式会社 | リチウムイオン電池固体電解質材料用硫化リチウムの製造方法 |
| JP5423725B2 (ja) * | 2011-05-17 | 2014-02-19 | トヨタ自動車株式会社 | 正極活物質粒子及びその製造方法 |
| JP2015503837A (ja) * | 2012-01-10 | 2015-02-02 | ザ リージェンツ オブ ザ ユニバーシティ オブ コロラド,ア ボディー コーポレイトTHE REGENTS OF THE UNIVERSITY OF COLORADO,a body corporate | リチウム全固体電池 |
| JP6059449B2 (ja) * | 2012-04-26 | 2017-01-11 | 古河機械金属株式会社 | 二次電池用正極材料の製造方法、二次電池用正極の製造方法および二次電池の製造方法 |
| FR2997941B1 (fr) | 2012-11-15 | 2023-03-03 | Arkema France | Procede de preparation de sulfure de metal alcalin |
| JP2014169196A (ja) * | 2013-03-01 | 2014-09-18 | Nippon Chem Ind Co Ltd | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP6162981B2 (ja) * | 2013-03-01 | 2017-07-12 | 日本化学工業株式会社 | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP6150229B2 (ja) * | 2013-09-12 | 2017-06-21 | 東レ・ファインケミカル株式会社 | 硫化リチウムの製造方法 |
| JP6254413B2 (ja) * | 2013-10-07 | 2017-12-27 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
| DE102013018350A1 (de) * | 2013-10-31 | 2015-05-13 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung | Verfahren zur Herstellung eines partikulären Lithiumsulfid-Kohlenstoff-Komposits |
| CN104609376A (zh) * | 2015-01-30 | 2015-05-13 | 浙江工业大学 | 一种硫化锂粉体的制备方法 |
| JP6602258B2 (ja) * | 2015-05-22 | 2019-11-06 | 日本化学工業株式会社 | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP6499513B2 (ja) * | 2015-05-22 | 2019-04-10 | 日本化学工業株式会社 | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| CN106299261B (zh) * | 2015-06-01 | 2019-01-15 | 中国科学院苏州纳米技术与纳米仿生研究所 | 硫化锂/碳复合纳米材料及其制备方法与应用 |
| CN105016310A (zh) * | 2015-07-30 | 2015-11-04 | 广东先导稀材股份有限公司 | 一种高纯硫化锂的制备方法及装置 |
| WO2017027831A1 (en) * | 2015-08-13 | 2017-02-16 | The Regents Of The University Of California | Lithium sulfide electrode and method |
| JP7014496B2 (ja) * | 2016-06-14 | 2022-02-01 | 出光興産株式会社 | 硫化リチウム、及びその製造方法 |
| TWI748052B (zh) * | 2017-02-03 | 2021-12-01 | 德商亞比馬利德國有限公司 | 高反應性、無塵且自由流動的硫化鋰及其生產方法 |
| CN106986392B (zh) * | 2017-04-13 | 2018-05-04 | 环境保护部南京环境科学研究所 | 一种陨硫铁的合成方法及合成装置 |
| CN108400327A (zh) * | 2018-01-11 | 2018-08-14 | 北京天工新材科技发展有限公司 | 一种硫化锂的制备方法 |
| CN108767234B (zh) * | 2018-06-05 | 2021-06-08 | 天津巴莫科技有限责任公司 | 一种富锂固溶体硫氧化物正极材料及其制备方法 |
| KR101944518B1 (ko) * | 2018-07-23 | 2019-02-01 | 한국지질자원연구원 | 탄산리튬으로부터 고농도 리튬 수용액 제조방법 |
| CN110526219A (zh) * | 2019-08-26 | 2019-12-03 | 浙江工业大学 | 一种硫化锂粉体的合成方法 |
| CN110790239B (zh) * | 2019-08-26 | 2022-01-28 | 浙江工业大学 | 一种硫化锂粉体的机械球磨合成方法 |
| EP3800708A1 (en) * | 2019-10-01 | 2021-04-07 | Centre National de la Recherche Scientifique | Use of a transition metal sulphide compound in a positive electrode for solid state batteries |
| CN110931783B (zh) * | 2019-12-06 | 2021-05-28 | 华南师范大学 | 一种硫化锂/纳米金属正极复合材料及其制备方法与应用 |
| JP7005693B2 (ja) * | 2020-06-24 | 2022-01-21 | 古河機械金属株式会社 | リチウムイオン電池用正極活物質、正極材料、正極、およびリチウムイオン電池 |
| WO2022009810A1 (ja) * | 2020-07-09 | 2022-01-13 | 三井金属鉱業株式会社 | 硫化リチウムの製造方法 |
| CN112520763B (zh) * | 2020-08-03 | 2022-04-15 | 浙江工业大学 | 一种利用硫酸锂制备硫化锂的方法 |
| KR102580338B1 (ko) * | 2021-01-28 | 2023-09-20 | (주)솔리드아이오닉스 | 황화리튬 제조 방법 |
| CN113401878B (zh) * | 2021-06-16 | 2022-11-11 | 高能时代(珠海)新能源科技有限公司 | 一种硫化锂的制备方法 |
| WO2023091521A1 (en) | 2021-11-16 | 2023-05-25 | Solid Power Operating, Inc. | Lithium sulfide production method |
| EP4527792A1 (en) * | 2022-05-20 | 2025-03-26 | Solid Ionics Co., Ltd | Method for producing lithium sulfide |
| EP4590630A1 (en) * | 2022-09-19 | 2025-07-30 | California Institute of Technology | Lithium-rich aluminum iron sulfide li-ion battery cathodes |
| KR20240072554A (ko) | 2022-11-17 | 2024-05-24 | 현대자동차주식회사 | 황화수소 가스를 사용하지 않는 황화리튬의 제조방법 |
| CN116969422B (zh) * | 2023-07-31 | 2024-12-06 | 武汉中科先进材料科技有限公司 | 一种硫化锂的制备方法、硫化物固态电解质及全固态电池 |
| KR20250054892A (ko) | 2023-10-16 | 2025-04-24 | 조이운 | 네일아트 부산물 흡입 겸용 공기 정화기 |
| CN117985660A (zh) * | 2023-12-27 | 2024-05-07 | 宜宾市天宜锂业科创有限公司 | 一种使用黄铁矿制备电池级硫化锂的方法 |
| KR20250158268A (ko) * | 2024-04-30 | 2025-11-06 | 에스케이온 주식회사 | 고체 전해질용 황화 리튬 및 이의 제조방법 |
| CN118289807B (zh) * | 2024-06-05 | 2024-09-10 | 北京紫越知新科技有限公司 | 硫化电解质及其制备方法、复合电解质膜用组合物、制备复合电解质膜的方法、锂离子电池 |
| KR102807909B1 (ko) | 2024-10-30 | 2025-05-14 | 주식회사 에코프로이노베이션 | 탄소열환원 공정으로 제조된 황화 리튬의 정제 방법 |
| CN120463158B (zh) * | 2025-07-11 | 2025-10-14 | 紫金矿业新能源新材料科技(长沙)有限公司 | 一种制备硫化锂的方法 |
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| US4731307A (en) * | 1986-06-10 | 1988-03-15 | The United States Of America As Represented By The United States Department Of Energy | Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2 |
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| JP3816141B2 (ja) * | 1996-04-16 | 2006-08-30 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
| JP3510420B2 (ja) * | 1996-04-16 | 2004-03-29 | 松下電器産業株式会社 | リチウムイオン伝導性固体電解質およびその製造方法 |
| GB2351075A (en) * | 1999-06-17 | 2000-12-20 | Secr Defence | Producing lithiated transition metal sulphides |
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2008
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- 2009-10-06 US US13/124,051 patent/US20110200882A1/en not_active Abandoned
- 2009-10-06 KR KR1020117010845A patent/KR20110132311A/ko not_active Withdrawn
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- 2009-10-06 CN CN2009801403670A patent/CN102177090A/zh active Pending
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117977044A (zh) * | 2024-04-01 | 2024-05-03 | 四川新能源汽车创新中心有限公司 | 一种硫化物基全固态电池物料的回收方法 |
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