CN102007160B - 连续生产生物降解聚酯的方法 - Google Patents

连续生产生物降解聚酯的方法 Download PDF

Info

Publication number
CN102007160B
CN102007160B CN2009801131002A CN200980113100A CN102007160B CN 102007160 B CN102007160 B CN 102007160B CN 2009801131002 A CN2009801131002 A CN 2009801131002A CN 200980113100 A CN200980113100 A CN 200980113100A CN 102007160 B CN102007160 B CN 102007160B
Authority
CN
China
Prior art keywords
acid
mixture
component
stage
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2009801131002A
Other languages
English (en)
Chinese (zh)
Other versions
CN102007160A (zh
Inventor
U·威特
山本基仪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102007160A publication Critical patent/CN102007160A/zh
Application granted granted Critical
Publication of CN102007160B publication Critical patent/CN102007160B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/785Preparation processes characterised by the apparatus used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/247Suited for forming thin films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN2009801131002A 2008-04-15 2009-04-07 连续生产生物降解聚酯的方法 Active CN102007160B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08154537.8 2008-04-15
EP08154537 2008-04-15
PCT/EP2009/054114 WO2009127555A1 (de) 2008-04-15 2009-04-07 Verfahren zur kontinuierlichen herstellung von biologisch abbaubaren polyestern

Publications (2)

Publication Number Publication Date
CN102007160A CN102007160A (zh) 2011-04-06
CN102007160B true CN102007160B (zh) 2013-05-29

Family

ID=40707704

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009801131002A Active CN102007160B (zh) 2008-04-15 2009-04-07 连续生产生物降解聚酯的方法

Country Status (6)

Country Link
US (1) US20110034662A1 (https=)
EP (2) EP2628758B1 (https=)
JP (1) JP5675586B2 (https=)
KR (1) KR20110007186A (https=)
CN (1) CN102007160B (https=)
WO (1) WO2009127555A1 (https=)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102165013B (zh) 2008-09-29 2013-04-24 巴斯夫欧洲公司 可生物降解的聚合物混合物
AU2009295911B2 (en) 2008-09-29 2014-03-27 Basf Se Method for coating paper
KR101731123B1 (ko) 2008-09-29 2017-04-27 바스프 에스이 지방족 폴리에스테르
WO2010034710A1 (de) * 2008-09-29 2010-04-01 Basf Se Aliphatisch-aromatischer polyester
WO2010069804A1 (de) 2008-12-19 2010-06-24 Basf Se Verfahren zur herstellung eines verbundbauteils durch mehrkomponentenspritzguss
US8754173B2 (en) 2009-10-15 2014-06-17 Basf Se Method for continuously producing polyester mixtures
IT1399031B1 (it) * 2009-11-05 2013-04-05 Novamont Spa Copoliestere alifatico-aromatico biodegradabile
MX2012005237A (es) 2009-11-09 2012-06-13 Basf Se Proceso para la obtencion de peliculas de contraccion.
EP2617771B1 (de) 2010-01-14 2016-04-06 Basf Se Verfahren zur Herstellung von expandierbaren Polymilchsäure-haltigen Granulaten
US8604101B2 (en) 2010-03-24 2013-12-10 Basf Se Process for producing aqueous dispersions of thermoplastic polyesters
US20110237743A1 (en) * 2010-03-24 2011-09-29 Basf Se Process for producing clingfilms
CN102869723A (zh) 2010-03-24 2013-01-09 巴斯夫欧洲公司 制备保鲜膜的方法
US20110237750A1 (en) * 2010-03-24 2011-09-29 Basf Se Process for film production
WO2011117308A1 (de) * 2010-03-24 2011-09-29 Basf Se Verfahren zur herstellung wässriger dispersionen thermoplastischer polyester
CA2792699A1 (en) 2010-03-24 2011-09-29 Basf Se Process for film production
JP2013542292A (ja) 2010-10-27 2013-11-21 ビーエーエスエフ ソシエタス・ヨーロピア スリットフィルムテープを製造するためのポリマー混合物の使用
US8546472B2 (en) 2011-03-23 2013-10-01 Basf Se Polyesters based on 2-methylsuccinic acid
WO2012126921A1 (de) 2011-03-23 2012-09-27 Basf Se Polyester auf basis von 2-methylbernsteinsaeure
US9156943B2 (en) * 2011-04-26 2015-10-13 Taiwan Textile Research Institute Modified polyesters and processes for manufacturing the same
US8933162B2 (en) * 2011-07-15 2015-01-13 Saudi Basic Industries Corporation Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
EP2573138A1 (de) 2011-09-21 2013-03-27 Basf Se Polyamid-Formmassen
EP2573142A1 (de) 2011-09-21 2013-03-27 Basf Se Thermoplastische Formmasse mit verbesserter Kerbschlagzähigkeit
PT2628761E (pt) 2012-02-17 2015-07-02 Anónima Minera Catalano Aragonesa Soc Poliestereteramida biodegradável
DE102012003417A1 (de) * 2012-02-17 2013-08-22 Uhde Inventa-Fischer Gmbh Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters
US9034983B2 (en) 2012-03-01 2015-05-19 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
US9540661B2 (en) 2012-07-09 2017-01-10 Basf Se Method for the complete anaerobic digestion of polymer mixtures
WO2014009176A1 (de) 2012-07-10 2014-01-16 Basf Se Verfahren zum vollständigen anaeroben abbau von polymermischungen
WO2014029645A2 (de) 2012-08-24 2014-02-27 Basf Se Verwendung von polymermischungen zur herstellung von kartuschen, pipetten, cuvetten oder pipettenhalter
KR20140031011A (ko) * 2012-09-04 2014-03-12 삼성정밀화학 주식회사 생분해성 지방족 폴리에스테르의 연속 제조방법
KR101992391B1 (ko) 2012-09-04 2019-09-30 (주)새한폴리머 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법
EP2725048B1 (de) 2012-10-29 2016-07-20 Uhde Inventa-Fischer GmbH Verfahren zur Herstellung eines hochmolekularen Polyesters oder Copolyesters sowie diese enthaltende Polymerblends
KR20140076355A (ko) * 2012-12-12 2014-06-20 삼성정밀화학 주식회사 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법
JP2014114417A (ja) * 2012-12-12 2014-06-26 Mitsubishi Chemicals Corp 脂肪族ポリエステル
KR101992392B1 (ko) * 2012-12-12 2019-09-30 (주)새한폴리머 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법
KR20140076354A (ko) 2012-12-12 2014-06-20 삼성정밀화학 주식회사 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법
KR20140143045A (ko) * 2013-06-05 2014-12-15 삼성정밀화학 주식회사 생분해성 폴리에스테르 수지 및 이를 포함하는 물품
CN103408739B (zh) * 2013-08-08 2016-01-06 山东汇盈新材料科技有限公司 低端羧基含量聚己二酸-对苯二甲酸丁二醇酯的制备方法
CN105849150A (zh) * 2013-12-30 2016-08-10 乐天精密化学株式会社 制备生物可降解的聚酯树脂的组合物和生物可降解的聚酯树脂的制备方法
PT3467005T (pt) 2016-05-30 2020-10-15 Sa Minera Catalano Aragonesa Método para obter poliestereteramida biodegradável
TWI609919B (zh) * 2016-11-24 2018-01-01 共聚彈性體之製備方法及其應用
DE102017128847A1 (de) 2016-12-08 2018-06-14 Basf Se Biologisch abbaubare Fußbekleidung basierend auf Polymilchsäure
JP2018145413A (ja) * 2017-03-02 2018-09-20 三菱ケミカル株式会社 脂肪族芳香族ポリエステルの製造方法
WO2018219708A1 (de) 2017-05-31 2018-12-06 Basf Se ALIPHATISCH-AROMATISCHER POLYESTER MIT ERHÖHTEM WEIßGRAD-INDEX
MY199834A (en) 2017-07-06 2023-11-24 Technip Zimmer Gmbh Process for preparing polyesters by using an additive
KR20200080320A (ko) 2017-11-20 2020-07-06 바스프 에스이 지방족 폴리에스테르의 연속식 제조 방법
CN111372972A (zh) 2017-11-20 2020-07-03 巴斯夫欧洲公司 纯化脂族聚酯的方法
EP3941963B1 (en) * 2019-03-19 2023-03-01 Basf Se A method for the combined production of at least two target products
KR101992393B1 (ko) * 2019-04-03 2019-06-24 (주)새한폴리머 생분해성 지방족 폴리에스테르의 연속 제조방법
WO2020234294A1 (en) 2019-05-22 2020-11-26 Basf Se Continuous process for producing an aliphatic-aromatic polyester
WO2020234293A1 (en) 2019-05-22 2020-11-26 Basf Se Process for purifying an aliphatic-aromatic polyester
CN114479039B (zh) * 2020-10-26 2024-11-29 中国石油化工股份有限公司 一种耐水解聚酯催化剂及其制备方法和应用
CN112280026B (zh) * 2020-12-31 2021-03-09 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用
IT202100002135A1 (it) * 2021-02-02 2022-08-02 Novamont Spa Poliesteri ramificati per extrusion coating
CN112940233B (zh) * 2021-04-13 2021-12-07 四川大学 一种高熔点生物可降解共聚酯及其制备方法
CN113354799B (zh) * 2021-04-26 2022-07-05 浙江恒逸石化研究院有限公司 一种长链支化可降解聚酯及其制备方法
CN113717356B (zh) * 2021-09-14 2023-04-07 珠海万通化工有限公司 一种半芳香族聚酯及其制备方法和应用
US20230124025A1 (en) 2021-09-27 2023-04-20 University Of Massachusetts Compositions and methods for biodegradable, biomass-based polyesters
CN116023636B (zh) * 2021-10-26 2025-03-25 江苏金发科技新材料有限公司 一种半芳香族聚酯及其制备方法和应用
WO2023229215A1 (ko) * 2022-05-21 2023-11-30 에코밴스 주식회사 생분해성 폴리에스테르 수지 조성물, 이를 포함하는 생분해성 폴리에스테르 필름 및 이를 포함하는 생분해성 성형품
CN119998384A (zh) 2022-10-06 2025-05-13 巴斯夫欧洲公司 热塑性聚合物共混物及其用途
CN115926128B (zh) * 2022-12-08 2025-07-11 金发科技股份有限公司 一种脂肪族-芳香族聚酯组合物、聚酯纤维及其制备方法和应用
KR20240177276A (ko) * 2023-06-19 2024-12-27 코오롱인더스트리 주식회사 생분해성 폴리에스테르 수지 및 이의 제조 방법
CN117887048B (zh) * 2023-12-29 2025-07-15 金发科技股份有限公司 一种可生物降解脂肪族聚酯及其制备方法和应用
DE102024208998A1 (de) * 2024-09-19 2026-03-19 Benecke-Kaliko Aktiengesellschaft Vernetzte und kettenverlängerte Filme und Schaumstoffe auf der Basis von biologisch abbaubaren Polyestern für verbesserte Hydrolyse

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3211899A1 (de) * 1982-03-31 1983-10-13 Chemische Werke Hüls AG, 4370 Marl Verfahren zum kondensieren von poly(alkylenterephthalaten)
DE3662526D1 (en) * 1986-04-29 1989-04-27 Fischer Karl Ind Gmbh Process and device for the fabrication of high molecular weight polyester
EP0559785B1 (en) 1990-11-30 1997-03-12 Eastman Chemical Company Blends of aliphatic-aromatic copolyesters with cellulose ester polymers
DE4430634A1 (de) * 1994-08-29 1996-03-07 Hoechst Ag Verfahren zur Herstellung thermostabiler, farbneutraler, antimonfreier Polyester und die danach herstellbaren Produkte
DE4440858A1 (de) * 1994-11-15 1996-05-23 Basf Ag Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper
DE59505196D1 (de) * 1994-12-30 1999-04-08 Fischer Karl Ind Gmbh Reaktorvorrichtung für fliessfähige und höherviskose Medien
DE19500757A1 (de) * 1995-01-13 1996-07-18 Basf Ag Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper
JPH11236442A (ja) * 1998-02-20 1999-08-31 Nippon Ester Co Ltd ポリエステルの製造方法
ES2195465T3 (es) * 1999-04-22 2003-12-01 Zimmer Ag Procedimiento para producir poli(tereftalato de trimetileno) (ptt).
JP2000309631A (ja) * 1999-04-27 2000-11-07 Toray Ind Inc ポリエステルの製造方法
DE19929790A1 (de) * 1999-06-29 2001-01-04 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polybutylenterephthalat aus Terephthalsäure und Butandiol
JP2003073466A (ja) * 2001-06-19 2003-03-12 Toray Ind Inc ポリブチレンテレフタレートの製造法
DE10155419B4 (de) * 2001-11-12 2005-06-16 Inventa-Fischer Gmbh & Co. Kg Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polyester sowie Vorrichtung zur Durchführung des Verfahrens
JP3996876B2 (ja) * 2002-06-24 2007-10-24 三菱化学株式会社 ポリエステル樹脂の製造方法
DE10246251A1 (de) * 2002-10-02 2004-04-15 Zimmer Ag Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polyestern
DE10351085A1 (de) 2003-10-31 2005-06-16 Inventa-Fischer Gmbh & Co. Kg Turmreaktor sowie dessen Verwendung zur kontinuierlichen Herstellung von hochmolekularem Polyester
JP4744450B2 (ja) * 2004-11-30 2011-08-10 旭化成ケミカルズ株式会社 ポリエステル樹脂、その成形体及びそれらの製造方法
DE102005053068B4 (de) 2005-11-04 2017-05-11 Basf Se Sebazinsäurehaltige Polyester und Polyestermischung, Verfahren zu deren Herstellung sowie ein Verzweigerbatch und die Verwendung der Polyestermischung
WO2007088074A1 (en) * 2006-02-03 2007-08-09 Saudi Basic Industries Corporation Process for the preparation of polyethylene terephthalate
DE102006025942B4 (de) * 2006-06-02 2011-07-07 Uhde Inventa-Fischer GmbH & Co. KG, 13509 Verfahren zur kontinuierlichen Herstellung von hochmolekularen Polyestern durch Veresterung von Dicarbonsäuren und/oder Umesterung von Dicarbonsäuren mit Diolen und/oder deren Mischungen sowie Vorrichtung hierzu
JP5176415B2 (ja) * 2006-07-18 2013-04-03 三菱化学株式会社 脂肪族ポリエステルの製造方法
JP5200531B2 (ja) * 2007-12-27 2013-06-05 三菱化学株式会社 脂肪族ポリエステルの製造方法

Also Published As

Publication number Publication date
EP2628758A1 (de) 2013-08-21
EP2268704A1 (de) 2011-01-05
WO2009127555A1 (de) 2009-10-22
US20110034662A1 (en) 2011-02-10
CN102007160A (zh) 2011-04-06
KR20110007186A (ko) 2011-01-21
JP2011516708A (ja) 2011-05-26
EP2628758B1 (de) 2014-10-08
JP5675586B2 (ja) 2015-02-25

Similar Documents

Publication Publication Date Title
CN102007160B (zh) 连续生产生物降解聚酯的方法
CN102549072B (zh) 连续生产聚酯混合物的方法
US9040639B2 (en) Method for the continuous production of biodegradable polyesters
KR102945918B1 (ko) 지방족-방향족 폴리에스테르의 정제 방법
FI117510B (fi) Biologisesti hajoavia polymeereja, menetelmä niiden valmistamiseksi, sekä niiden käyttö biologisesti hajoavien muotokappaleiden valmistukseen
EP4206257B1 (en) Semiaromatic polyester, and preparation method and application thereof
KR20200080320A (ko) 지방족 폴리에스테르의 연속식 제조 방법
KR20200085337A (ko) 지방족 폴리에스테르의 정제 방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant