CN102007160B - 连续生产生物降解聚酯的方法 - Google Patents
连续生产生物降解聚酯的方法 Download PDFInfo
- Publication number
- CN102007160B CN102007160B CN2009801131002A CN200980113100A CN102007160B CN 102007160 B CN102007160 B CN 102007160B CN 2009801131002 A CN2009801131002 A CN 2009801131002A CN 200980113100 A CN200980113100 A CN 200980113100A CN 102007160 B CN102007160 B CN 102007160B
- Authority
- CN
- China
- Prior art keywords
- acid
- mixture
- component
- stage
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/247—Suited for forming thin films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08154537.8 | 2008-04-15 | ||
| EP08154537 | 2008-04-15 | ||
| PCT/EP2009/054114 WO2009127555A1 (de) | 2008-04-15 | 2009-04-07 | Verfahren zur kontinuierlichen herstellung von biologisch abbaubaren polyestern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102007160A CN102007160A (zh) | 2011-04-06 |
| CN102007160B true CN102007160B (zh) | 2013-05-29 |
Family
ID=40707704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801131002A Active CN102007160B (zh) | 2008-04-15 | 2009-04-07 | 连续生产生物降解聚酯的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20110034662A1 (enExample) |
| EP (2) | EP2628758B1 (enExample) |
| JP (1) | JP5675586B2 (enExample) |
| KR (1) | KR20110007186A (enExample) |
| CN (1) | CN102007160B (enExample) |
| WO (1) | WO2009127555A1 (enExample) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2737582C (en) | 2008-09-29 | 2018-05-15 | Basf Se | Method for coating paper |
| WO2010034689A1 (de) | 2008-09-29 | 2010-04-01 | Basf Se | Biologisch abbaubare polymermischung |
| US20110313075A1 (en) | 2008-09-29 | 2011-12-22 | Basf Se | Aliphatic polyester |
| PL2331603T3 (pl) * | 2008-09-29 | 2019-05-31 | Basf Se | Poliestry alifatyczno-aromatyczne |
| EP2379301B1 (de) | 2008-12-19 | 2013-02-20 | Basf Se | Verfahren zur herstellung eines verbundbauteils durch mehrkomponentenspritzguss, solcher verbundbauteil und verwendung einer mischung zur herstellung des verbundbauteils |
| EP2488585B1 (de) | 2009-10-15 | 2014-06-18 | Basf Se | Verfahren zur kontinuierlichen herstellung von polyestermischungen |
| IT1399031B1 (it) * | 2009-11-05 | 2013-04-05 | Novamont Spa | Copoliestere alifatico-aromatico biodegradabile |
| WO2011054786A1 (de) | 2009-11-09 | 2011-05-12 | Basf Se | Verfahren zur herstellung von schrumpffolien |
| JP5886208B2 (ja) | 2010-01-14 | 2016-03-16 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 発泡性ポリ乳酸含有顆粒の製造法 |
| US20110237750A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for film production |
| US8604101B2 (en) | 2010-03-24 | 2013-12-10 | Basf Se | Process for producing aqueous dispersions of thermoplastic polyesters |
| EP2550090B1 (de) * | 2010-03-24 | 2016-10-05 | Basf Se | Verfahren zur herstellung wässriger dispersionen thermoplastischer polyester |
| CA2792699A1 (en) | 2010-03-24 | 2011-09-29 | Basf Se | Process for film production |
| AU2011231669A1 (en) | 2010-03-24 | 2012-10-25 | Basf Se | Process for producing cling films |
| US20110237743A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for producing clingfilms |
| AU2011322685A1 (en) | 2010-10-27 | 2013-05-23 | Basf Se | Use of polymer blends for producing slit film tapes |
| WO2012126921A1 (de) | 2011-03-23 | 2012-09-27 | Basf Se | Polyester auf basis von 2-methylbernsteinsaeure |
| US8546472B2 (en) | 2011-03-23 | 2013-10-01 | Basf Se | Polyesters based on 2-methylsuccinic acid |
| US9156943B2 (en) * | 2011-04-26 | 2015-10-13 | Taiwan Textile Research Institute | Modified polyesters and processes for manufacturing the same |
| US8933162B2 (en) * | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
| EP2573142A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Thermoplastische Formmasse mit verbesserter Kerbschlagzähigkeit |
| EP2573138A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Polyamid-Formmassen |
| DE102012003417A1 (de) * | 2012-02-17 | 2013-08-22 | Uhde Inventa-Fischer Gmbh | Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters |
| ES2537988T3 (es) | 2012-02-17 | 2015-06-16 | Sociedad Anónima Minera Catalano-Aragonesa | Poliestereteramida biodegradable |
| US9034983B2 (en) | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
| US9540661B2 (en) | 2012-07-09 | 2017-01-10 | Basf Se | Method for the complete anaerobic digestion of polymer mixtures |
| WO2014009176A1 (de) | 2012-07-10 | 2014-01-16 | Basf Se | Verfahren zum vollständigen anaeroben abbau von polymermischungen |
| EP2888322B1 (de) | 2012-08-24 | 2016-07-20 | Basf Se | Verwendung von polymermischungen zur herstellung von kartuschen, pipetten, cuvetten oder pipettenhalter |
| KR101992391B1 (ko) | 2012-09-04 | 2019-09-30 | (주)새한폴리머 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR20140031011A (ko) * | 2012-09-04 | 2014-03-12 | 삼성정밀화학 주식회사 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| EP2725048B1 (de) | 2012-10-29 | 2016-07-20 | Uhde Inventa-Fischer GmbH | Verfahren zur Herstellung eines hochmolekularen Polyesters oder Copolyesters sowie diese enthaltende Polymerblends |
| KR20140076354A (ko) | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR20140076355A (ko) | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR101992392B1 (ko) * | 2012-12-12 | 2019-09-30 | (주)새한폴리머 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| JP2014114417A (ja) * | 2012-12-12 | 2014-06-26 | Mitsubishi Chemicals Corp | 脂肪族ポリエステル |
| KR20140143045A (ko) * | 2013-06-05 | 2014-12-15 | 삼성정밀화학 주식회사 | 생분해성 폴리에스테르 수지 및 이를 포함하는 물품 |
| CN103408739B (zh) * | 2013-08-08 | 2016-01-06 | 山东汇盈新材料科技有限公司 | 低端羧基含量聚己二酸-对苯二甲酸丁二醇酯的制备方法 |
| US20160326305A1 (en) * | 2013-12-30 | 2016-11-10 | Lotte Fine Chemical Co., Ltd. | Composition for producing biodegradable polyester resin, and production method for biodegradable polyester resin |
| WO2017207827A1 (es) | 2016-05-30 | 2017-12-07 | Sociedad Anónima Minera Catalano-Aragonesa | Proceso de obtención de poliestereteramida biodegradable |
| TWI609919B (zh) * | 2016-11-24 | 2018-01-01 | 共聚彈性體之製備方法及其應用 | |
| DE102017128847A1 (de) | 2016-12-08 | 2018-06-14 | Basf Se | Biologisch abbaubare Fußbekleidung basierend auf Polymilchsäure |
| JP2018145413A (ja) * | 2017-03-02 | 2018-09-20 | 三菱ケミカル株式会社 | 脂肪族芳香族ポリエステルの製造方法 |
| EP3630869B2 (de) | 2017-05-31 | 2024-10-02 | Basf Se | Aliphatisch-aromatischer polyester mit erhöhtem weissgrad-index |
| ES2930754T3 (es) | 2017-07-06 | 2022-12-21 | T En Zimmer Gmbh | Proceso para preparar poliésteres utilizando un aditivo |
| ES2948234T3 (es) | 2017-11-20 | 2023-09-06 | Basf Se | Procedimiento continuo para la fabricación de un poliéster alifático |
| CN111372972A (zh) | 2017-11-20 | 2020-07-03 | 巴斯夫欧洲公司 | 纯化脂族聚酯的方法 |
| EP3941963B1 (en) * | 2019-03-19 | 2023-03-01 | Basf Se | A method for the combined production of at least two target products |
| KR101992393B1 (ko) * | 2019-04-03 | 2019-06-24 | (주)새한폴리머 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| US12371529B2 (en) | 2019-05-22 | 2025-07-29 | Basf Se | Process for purifying an aliphatic-aromatic polyester |
| WO2020234294A1 (en) | 2019-05-22 | 2020-11-26 | Basf Se | Continuous process for producing an aliphatic-aromatic polyester |
| CN114479039B (zh) * | 2020-10-26 | 2024-11-29 | 中国石油化工股份有限公司 | 一种耐水解聚酯催化剂及其制备方法和应用 |
| CN112280026B (zh) * | 2020-12-31 | 2021-03-09 | 江苏金发科技新材料有限公司 | 一种半芳香族聚酯及其制备方法和应用 |
| IT202100002135A1 (it) * | 2021-02-02 | 2022-08-02 | Novamont Spa | Poliesteri ramificati per extrusion coating |
| CN112940233B (zh) * | 2021-04-13 | 2021-12-07 | 四川大学 | 一种高熔点生物可降解共聚酯及其制备方法 |
| CN113354799B (zh) * | 2021-04-26 | 2022-07-05 | 浙江恒逸石化研究院有限公司 | 一种长链支化可降解聚酯及其制备方法 |
| CN113717356B (zh) * | 2021-09-14 | 2023-04-07 | 珠海万通化工有限公司 | 一种半芳香族聚酯及其制备方法和应用 |
| US20230124025A1 (en) | 2021-09-27 | 2023-04-20 | University Of Massachusetts | Compositions and methods for biodegradable, biomass-based polyesters |
| CN116023636B (zh) * | 2021-10-26 | 2025-03-25 | 江苏金发科技新材料有限公司 | 一种半芳香族聚酯及其制备方法和应用 |
| WO2023229215A1 (ko) * | 2022-05-21 | 2023-11-30 | 에코밴스 주식회사 | 생분해성 폴리에스테르 수지 조성물, 이를 포함하는 생분해성 폴리에스테르 필름 및 이를 포함하는 생분해성 성형품 |
| EP4598995A1 (en) | 2022-10-06 | 2025-08-13 | Basf Se | Thermoplastic polymer blend and use thereof |
| CN115926128B (zh) * | 2022-12-08 | 2025-07-11 | 金发科技股份有限公司 | 一种脂肪族-芳香族聚酯组合物、聚酯纤维及其制备方法和应用 |
| KR20240177276A (ko) * | 2023-06-19 | 2024-12-27 | 코오롱인더스트리 주식회사 | 생분해성 폴리에스테르 수지 및 이의 제조 방법 |
| CN117887048B (zh) * | 2023-12-29 | 2025-07-15 | 金发科技股份有限公司 | 一种可生物降解脂肪族聚酯及其制备方法和应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3211899A1 (de) * | 1982-03-31 | 1983-10-13 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zum kondensieren von poly(alkylenterephthalaten) |
| EP0244546B1 (de) * | 1986-04-29 | 1989-03-22 | Karl Fischer Industrieanlagen Gmbh | Verfahren und Vorrichtung zur Herstellung hochmolekularer Polyester |
| WO1992009654A2 (en) | 1990-11-30 | 1992-06-11 | Eastman Kodak Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| DE4430634A1 (de) * | 1994-08-29 | 1996-03-07 | Hoechst Ag | Verfahren zur Herstellung thermostabiler, farbneutraler, antimonfreier Polyester und die danach herstellbaren Produkte |
| DE4440858A1 (de) * | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| EP0719582B1 (de) | 1994-12-30 | 1999-03-03 | Karl Fischer Industrieanlagen Gmbh | Reaktorvorrichtung für fliessfähige und höherviskose Medien |
| DE19500757A1 (de) * | 1995-01-13 | 1996-07-18 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| JPH11236442A (ja) * | 1998-02-20 | 1999-08-31 | Nippon Ester Co Ltd | ポリエステルの製造方法 |
| ES2195465T3 (es) * | 1999-04-22 | 2003-12-01 | Zimmer Ag | Procedimiento para producir poli(tereftalato de trimetileno) (ptt). |
| JP2000309631A (ja) * | 1999-04-27 | 2000-11-07 | Toray Ind Inc | ポリエステルの製造方法 |
| DE19929790A1 (de) * | 1999-06-29 | 2001-01-04 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Polybutylenterephthalat aus Terephthalsäure und Butandiol |
| JP2003073466A (ja) * | 2001-06-19 | 2003-03-12 | Toray Ind Inc | ポリブチレンテレフタレートの製造法 |
| DE10155419B4 (de) | 2001-11-12 | 2005-06-16 | Inventa-Fischer Gmbh & Co. Kg | Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polyester sowie Vorrichtung zur Durchführung des Verfahrens |
| JP3996876B2 (ja) * | 2002-06-24 | 2007-10-24 | 三菱化学株式会社 | ポリエステル樹脂の製造方法 |
| DE10246251A1 (de) * | 2002-10-02 | 2004-04-15 | Zimmer Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polyestern |
| DE10351085A1 (de) | 2003-10-31 | 2005-06-16 | Inventa-Fischer Gmbh & Co. Kg | Turmreaktor sowie dessen Verwendung zur kontinuierlichen Herstellung von hochmolekularem Polyester |
| BRPI0517875A (pt) * | 2004-11-30 | 2008-10-28 | Asahi Kasei Chemicals Corp | resina de tereftalato de polietileno, gránulos, préforma, corpo oco de tereftalato de polietileno, métodos para produzir uma resina de poliéster, e, para produzir uma resina de tereftalato de polietileno |
| DE102005053068B4 (de) | 2005-11-04 | 2017-05-11 | Basf Se | Sebazinsäurehaltige Polyester und Polyestermischung, Verfahren zu deren Herstellung sowie ein Verzweigerbatch und die Verwendung der Polyestermischung |
| WO2007088074A1 (en) * | 2006-02-03 | 2007-08-09 | Saudi Basic Industries Corporation | Process for the preparation of polyethylene terephthalate |
| DE102006025942B4 (de) * | 2006-06-02 | 2011-07-07 | Uhde Inventa-Fischer GmbH & Co. KG, 13509 | Verfahren zur kontinuierlichen Herstellung von hochmolekularen Polyestern durch Veresterung von Dicarbonsäuren und/oder Umesterung von Dicarbonsäuren mit Diolen und/oder deren Mischungen sowie Vorrichtung hierzu |
| JP5176415B2 (ja) * | 2006-07-18 | 2013-04-03 | 三菱化学株式会社 | 脂肪族ポリエステルの製造方法 |
| JP5200531B2 (ja) * | 2007-12-27 | 2013-06-05 | 三菱化学株式会社 | 脂肪族ポリエステルの製造方法 |
-
2009
- 2009-04-07 WO PCT/EP2009/054114 patent/WO2009127555A1/de not_active Ceased
- 2009-04-07 US US12/988,102 patent/US20110034662A1/en not_active Abandoned
- 2009-04-07 KR KR1020107025424A patent/KR20110007186A/ko not_active Abandoned
- 2009-04-07 EP EP13167642.1A patent/EP2628758B1/de not_active Not-in-force
- 2009-04-07 EP EP09732629A patent/EP2268704A1/de not_active Withdrawn
- 2009-04-07 JP JP2011504419A patent/JP5675586B2/ja not_active Expired - Fee Related
- 2009-04-07 CN CN2009801131002A patent/CN102007160B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20110034662A1 (en) | 2011-02-10 |
| WO2009127555A1 (de) | 2009-10-22 |
| EP2268704A1 (de) | 2011-01-05 |
| EP2628758B1 (de) | 2014-10-08 |
| JP5675586B2 (ja) | 2015-02-25 |
| KR20110007186A (ko) | 2011-01-21 |
| EP2628758A1 (de) | 2013-08-21 |
| CN102007160A (zh) | 2011-04-06 |
| JP2011516708A (ja) | 2011-05-26 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |