CN101835785A - 混合的氟代烷基-烷基表面活性剂 - Google Patents
混合的氟代烷基-烷基表面活性剂 Download PDFInfo
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- CN101835785A CN101835785A CN200880102130A CN200880102130A CN101835785A CN 101835785 A CN101835785 A CN 101835785A CN 200880102130 A CN200880102130 A CN 200880102130A CN 200880102130 A CN200880102130 A CN 200880102130A CN 101835785 A CN101835785 A CN 101835785A
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- 239000004094 surface-active agent Substances 0.000 title abstract description 28
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 5
- 239000013543 active substance Substances 0.000 claims description 59
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- 239000000758 substrate Substances 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 27
- 125000003118 aryl group Chemical group 0.000 abstract description 3
- 229910006067 SO3−M Inorganic materials 0.000 abstract 2
- 101100277337 Arabidopsis thaliana DDM1 gene Proteins 0.000 abstract 1
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- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- CNTIXUGILVWVHR-UHFFFAOYSA-N diphosphoryl chloride Chemical compound ClP(Cl)(=O)OP(Cl)(Cl)=O CNTIXUGILVWVHR-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
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- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
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- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
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- 239000004579 marble Substances 0.000 description 1
- OKKJLVBELUTLKV-VMNATFBRSA-N methanol-d1 Chemical compound [2H]OC OKKJLVBELUTLKV-VMNATFBRSA-N 0.000 description 1
- JPQBRSQJGWOTGC-UHFFFAOYSA-N methyl(silyloxysilyloxy)silane Chemical class C[SiH2]O[SiH2]O[SiH3] JPQBRSQJGWOTGC-UHFFFAOYSA-N 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
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- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000005211 surface analysis Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 150000003527 tetrahydropyrans Chemical class 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- RQNVJDSEWRGEQR-UHFFFAOYSA-N tris(prop-2-enyl) borate Chemical compound C=CCOB(OCC=C)OCC=C RQNVJDSEWRGEQR-UHFFFAOYSA-N 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
- C07C43/137—Saturated ethers containing hydroxy or O-metal groups containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
- Fire-Extinguishing Compositions (AREA)
- Polyethers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
Description
打分 | 描述 |
1 | 不平的薄膜表面覆盖,显著的条痕和表面缺陷 |
2 | 许多表面缺陷和条痕是明显的,但是一般来讲,薄膜覆盖整个地板砖表面 |
3 | 可见的条痕和表面缺陷,薄膜沿地板砖的边缘缩退 |
4 | 较少的表面不规则或条痕 |
5 | 无可见的表面缺陷或条痕 |
抗粘连性数字等级 | 分离的描述 | 性能描述 |
10 | 无粘着 | 完美 |
9 | 痕量粘着 | 优异 |
8 | 非常轻度的粘着 | 很好 |
7 | 轻度粘着 | 良好/很好 |
6 | 中等至轻度粘着 | 良好 |
5 | 中等粘着 | 一般 |
4 | 非常粘,无密封 | 较差至一般 |
3 | 5-25%密封 | 较差 |
2 | 25-50%密封 | 较差 |
1 | 50-75%密封 | 非常差 |
0 | 75-100%密封 | 非常差 |
试剂(g): | 比较实施例C | 实施例7 |
柠檬酸 | 10 | 10 |
全氟烷基乙氧基化物* | 76 | 38 |
BRIJ 56** | 0 | 36.5 |
甲苯 | 90 | 90 |
实施例 | 氟% | 0.5* | 0.1* | 0.05* | 0.01* |
比较实施例D | 50.3±3.8 | 20.9±1.8 | 24.6±1.0 | 24.8±0.4 | 25.3±0.9 |
比较实施例E | 0.0 | 22.5±0.2 | 31.8±1.2 | 36.2±1.3 | 36.9±2.0 |
11 | 34.8±3.3 | 16.5±2.1 | 24.2±6.8 | 29.9±8.9 | 38.7±2.3 |
12 | 35.1±6.6 | 15.9±0.1 | 21.2±3.1 | 27.4±5.2 | 36.0±2.8 |
10 | 34.2±2.9 | 16.2±0.8 | 18.9±1.3 | 24.2±3.0 | 36.1±3.7 |
13 | 32.1±1.4 | 16.5±1.0 | 17.4±1.1 | 21.6±1.9 | 30.9±2.8 |
9 | 37.1±6.7 | 17.8±0.0 | 18.4±0.1 | 19.7±0.5 | 29.2±1.8 |
14 | 30.9±0.9 | 19.5±1.0 | 20.6±0.6 | 22.0±1.0 | 29.5±1.8 |
15 | 30.1±2.3 | 19.9±1.3 | 21.6±0.7 | 22.5±0.8 | 27.5±2.6 |
16 | 34.0±2.6 | 15.9±0.7 | 17.7±1.1 | 20.9±1.8 | 24.5±1.0 |
17 | 26.7±1.6 | 16.5±0.4 | 17.9±0.7 | 19.4±0.6 | 26.8±1.7 |
18 | 22.8±1.9 | 16.1±0.5 | 17.4±1.1 | 19.3±1.9 | 28.4±2.2 |
19 | 16.8±1.5 | 16.6±0.1 | 16.4±0.3 | 17.3±0.1 | 28.9±1.9 |
20 | 35.7±1.9 | 17.9±0.1 | 21.4±0.8 | 24.1±0.9 | 24.0±0.9 |
实施例 | 涂料 | 重量剂量 | 氟剂量 | 平均抗粘连性得分 |
比较实施例D | Vista 6400 | 0.28g | 70ppm | 5.0 |
实施例18 | Vista 6400 | 0.61g | 70ppm | 5.3 |
实施例15 | Vista 6400 | 0.46g | 70ppm | 8.0 |
实施例 | 涂料 | 重量剂量 | 氟剂量 | 平均抗粘连性得分 |
比较实施例D | Vista 6400 | 0.28g | 70ppm | 5.0 |
实施例18 | Vista 6400 | 0.28g | 32ppm | 6.0 |
实施例15 | Vista 6400 | 0.28g | 42ppm | 7.0 |
Claims (12)
Priority Applications (1)
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CN201510154799.4A CN104860985B (zh) | 2007-08-06 | 2008-08-04 | 混合的氟代烷基‑烷基表面活性剂 |
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Application Number | Priority Date | Filing Date | Title |
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US11/890395 | 2007-08-06 | ||
US11/890,395 US7728163B2 (en) | 2007-08-06 | 2007-08-06 | Mixed fluoroalkyl-alkyl surfactants |
PCT/US2008/072082 WO2009020906A2 (en) | 2007-08-06 | 2008-08-04 | Mixed fluoroalkyl-alkyl surfactants |
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CN201510154799.4A Expired - Fee Related CN104860985B (zh) | 2007-08-06 | 2008-08-04 | 混合的氟代烷基‑烷基表面活性剂 |
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Country Status (9)
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US (2) | US7728163B2 (zh) |
EP (1) | EP2173758A2 (zh) |
JP (3) | JP5697980B2 (zh) |
KR (1) | KR101506753B1 (zh) |
CN (2) | CN101835785B (zh) |
AU (3) | AU2008283998B2 (zh) |
CA (1) | CA2693788A1 (zh) |
HK (2) | HK1148289A1 (zh) |
WO (1) | WO2009020906A2 (zh) |
Cited By (3)
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CN102643253A (zh) * | 2012-04-13 | 2012-08-22 | 阜新恒通氟化学有限公司 | 一种全氟烷基环氧丙烷的制备方法 |
CN110922957A (zh) * | 2019-11-26 | 2020-03-27 | 陕西科技大学 | 一种孪尾粘弹性表活剂凝胶体压裂液及其制备方法和胶体解除方法 |
CN111234200A (zh) * | 2020-03-23 | 2020-06-05 | 东北石油大学 | 一种改性全氟醇聚氧乙烯醚稠油破乳剂的制备方法 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8263670B2 (en) * | 2007-08-06 | 2012-09-11 | E.I. Du Pont De Nemours And Company | Mixed fluoroalkyl-alkyl surfactants |
US7728163B2 (en) * | 2007-08-06 | 2010-06-01 | E.I. Du Pont De Nemours And Company | Mixed fluoroalkyl-alkyl surfactants |
US8022238B2 (en) | 2009-03-20 | 2011-09-20 | E. I. Du Pont De Nemours And Company | Phosphate surfactants |
US8258341B2 (en) * | 2009-07-10 | 2012-09-04 | E.I. Du Pont De Nemours And Company | Polyfluorosulfonamido amine and intermediate |
KR101319085B1 (ko) | 2009-09-08 | 2013-10-17 | 다이킨 고교 가부시키가이샤 | 신규 비이온계 계면 활성제 및 방무제 |
EA201290220A1 (ru) * | 2009-12-11 | 2013-01-30 | Родиа Оперейшнс | Способы и системы для улучшения времени открытой выдержки и времени высыхания латексных связующих и покрытий на водной основе |
US8729138B2 (en) * | 2010-03-25 | 2014-05-20 | E I Du Pont De Nemours And Company | Mixture of polyfluoroalkylsulfonamido alkyl amines |
US9920219B2 (en) * | 2015-06-22 | 2018-03-20 | Awi Licensing Llc | Soil and dirt repellent powder coatings |
CN109880173B (zh) * | 2018-11-30 | 2021-02-26 | 杭州捷尔思阻燃化工有限公司 | 磷氮型无卤膨胀阻燃剂的表面改性方法及其应用 |
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EP0150942A2 (en) * | 1984-01-12 | 1985-08-07 | Mitsubishi Petrochemical Co., Ltd. | Composite heat-insulating material containing a cellular urethane |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102643253A (zh) * | 2012-04-13 | 2012-08-22 | 阜新恒通氟化学有限公司 | 一种全氟烷基环氧丙烷的制备方法 |
CN110922957A (zh) * | 2019-11-26 | 2020-03-27 | 陕西科技大学 | 一种孪尾粘弹性表活剂凝胶体压裂液及其制备方法和胶体解除方法 |
CN110922957B (zh) * | 2019-11-26 | 2021-10-01 | 陕西铭锐石油科技有限公司 | 一种孪尾粘弹性表活剂凝胶体压裂液及其制备方法和胶体解除方法 |
CN111234200A (zh) * | 2020-03-23 | 2020-06-05 | 东北石油大学 | 一种改性全氟醇聚氧乙烯醚稠油破乳剂的制备方法 |
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AU2014224091B2 (en) | 2016-02-04 |
AU2008283998A1 (en) | 2009-02-12 |
US20100267843A1 (en) | 2010-10-21 |
KR101506753B1 (ko) | 2015-04-23 |
CA2693788A1 (en) | 2009-02-12 |
AU2014224090A1 (en) | 2014-10-02 |
CN104860985A (zh) | 2015-08-26 |
AU2014224091A1 (en) | 2014-10-02 |
CN104860985B (zh) | 2017-08-04 |
CN101835785B (zh) | 2015-05-06 |
WO2009020906A3 (en) | 2009-05-28 |
US8242301B2 (en) | 2012-08-14 |
WO2009020906A2 (en) | 2009-02-12 |
JP2014169453A (ja) | 2014-09-18 |
JP2014167130A (ja) | 2014-09-11 |
AU2008283998B2 (en) | 2014-07-03 |
AU2014224090B2 (en) | 2016-02-04 |
US7728163B2 (en) | 2010-06-01 |
KR20100057027A (ko) | 2010-05-28 |
JP2010535791A (ja) | 2010-11-25 |
EP2173758A2 (en) | 2010-04-14 |
JP5976724B2 (ja) | 2016-08-24 |
HK1148289A1 (zh) | 2011-09-02 |
US20090042996A1 (en) | 2009-02-12 |
HK1213902A1 (zh) | 2016-07-15 |
JP5697980B2 (ja) | 2015-04-08 |
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