CN101830740A - Efficient, fast and fractional fermentation method of organic fertilizer - Google Patents

Efficient, fast and fractional fermentation method of organic fertilizer Download PDF

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Publication number
CN101830740A
CN101830740A CN201010162097A CN201010162097A CN101830740A CN 101830740 A CN101830740 A CN 101830740A CN 201010162097 A CN201010162097 A CN 201010162097A CN 201010162097 A CN201010162097 A CN 201010162097A CN 101830740 A CN101830740 A CN 101830740A
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fermentation
stalk
fertilizer
controlled
raw material
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吴国军
麻清丽
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INNER MONGOLIA LINYUAN DEER INDUSTRIAL Co Ltd
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INNER MONGOLIA LINYUAN DEER INDUSTRIAL Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The invention discloses an efficient, fast and fractional fermentation method of the organic fertilizer. The method comprises the following steps: firstly screening raw materials such as excrement and stalk, removing impurities, grinding for standby, wherein the water contents of excrement and stalk are adjusted to 65-70wt% and the raw materials per ton comprises 80-85% of animal waste and 15-20% of stalk; stirring the raw materials evenly to convey to a solar greenhouse fermentation plant, performing sterilization and fermentation, wherein the fermentation temperature is controlled to 55-65 DEG C and the fermentation time is controlled to 48-72 hours; when the decomposed fertilizer is tested to be qualified, adding 2-3 kilometers of the biological agent--Bacillus laterosporus per ton of the fertilizer, stirring evenly for fermentation, wherein the temperature is controlled to 30-45 DEG C, the fermentation time of beneficial bacterium is controlled to 48-72 hours; and pelletizing the fermented raw materials, drying, polishing, screening, packaging quantitatively and warehousing the finished product. The fermentation method of the invention can be used in the continuous production of the organic fertilizer.

Description

Efficient, fast and fractional fermentation method of organic fertilizer
Technical field
The present invention relates to a kind of production method of fertilizer, relate to a kind of microbial fermentation processes of fertilizer specifically.
Background technology
According to investigations, the most areas of China have been subjected to destruction in various degree because of long-term application chemical fertilizer has made ecological environment of soil, soil physical and chemical property and soil microflora, especially too much use simple substance chemical fertilizer, made nutritive element serious disproportion in the soil, the fertility supply capacity descends, the soil compaction aggravation, and the rhizosphere soil microorganism dominant population reduces in a large number, and to a certain extent quality of agricultural product has been caused pollution, make product be difficult to reach the requirement of green organic food.Along with the microorganism field progress of science and technology, the various countries scientist generally believes that fertilizer will develop to efficient, compound direction, promptly should seek a kind of new bio compound fertilizer that organic and inorganic and microbial fertilizer global advantage can be integrated in one.
In the north; industry area based on the husbandry breed; along with agricultural industry is constantly adjusted; aquaculture development is rapid; breeding production management state and development trend are good; formed mass-producing; overstocking of the waste of feces of livestock and poultry and fodder grass brought a difficult problem for breed factory and culture zone; a large amount of culture zone peripheries that are deposited in; become the breeding site, regeneration ground of worm fly through rotting for a long time, make the ambient air environmental degradation, phenomenon such as the smell is awful; also can cause the generation of the various eqpidemic diseases of livestock, have a strong impact on people's living environment and health.
In the past, in vast husbandry area, the treatment process that solves this Litter, rubbish and excrement of animals is that the nature stacking is converted into farm manure.This method is in the process of making, using and have a series of problems: the one, and content of microorganisms is less, helps the harmful microorganism growth and breeding; The 2nd, open-air long-time the stacking, particularly the nitrogen nutrient loss is more for nutrient; The 3rd, spontaneous fermentation is not subjected to the control of human factor, includes the deleterious sick worm of plant growth; The 4th, it is not thorough to become thoroughly decomposed, and consumption is big slightly, root will occur burning and burn seedling, causes the underproduction.It has stench, use inconvenience, be not suitable for mechanized operation, phenomenon such as inhomogeneous.
Fertilizer processing enterprise in the past carries out scale production, because of being subjected to seasonal restriction, for reaching the effect of becoming thoroughly decomposed, heats to adopting steam in the proving room, and energy consumption is big, because of a large amount of so of boiler emission 2Flue dust causes atmospheric pollution.My company cultures and a tame emphasis leading enterprise of deer product deep processing based on red deer, in order to develop new market, is starting point with the national policy recycling economy, the living environment of solution culture zone, improves the quality product of farm crop.
Summary of the invention
The objective of the invention is: a kind of efficient, fast and fractional fermentation method of organic fertilizer is provided.Be combined on the basis of traditional farm manure, underground heat, steam fermentation process, adopt fertilizer luminous energy quick fermentation manufacture craft to produce fertilizer, nutrient is complete, the energy chessom, increases fertility, and objectionable impurities is handled thoroughly, improves quality product.But suitability for industrialized production, stdn quality, be convenient to pollution-free green-efficient organic fertilizer of storing, transport, selling.This techniques save energy is pollution-free simultaneously.Solution makes the organic famine in soil because of soil life-time service chemical fertilizer, nutritive element serious disproportion in the soil, and the fertility supply capacity descends, the problem that soil compaction is serious; Solution is because of original fermentation process, cost height, boiler emission volume of smoke and SO 2Solve the problem that original farm manure can not mechanize be implemented; Improve fertilizer quality.
Technical scheme of the present invention is:
1. raw material is prepared and allotment
Earlier raw materials such as ight soil, stalk are screened, remove impurity and pulverize standby; , the water content of stalk and ight soil should be adjusted to weight percent 65%--70%; Raw material per ton is thrown in ratio: weight percent excrement of animals 80%---85%, stalk 15%---20%;
2, sterilization fermentation
Raw material stirring evenly back is carried out sterilization fermentation with being transported to the solar energy greenhouse fermentation plant, and leavening temperature is controlled at 55-65 ℃, fermentation time 48--72 hour;
3, probiotics fermentation
To become thoroughly decomposed good fertilizer after the assay was approved, add bacteria agent one bacillus laterosporus 2-3 kg/ton, and stir, controlled temperature is at 30-45 ℃, probiotics fermentation time 48-72 hour;
4, back arrangement
Raw material input granulation workshop by fermentation is processed into particle, dry control moisture weight percent≤20%, through polishing, screening, metering packing, and the finished product warehouse-in.
Advantage of the present invention is:
1, reduces the smoke contamination that uses boiler to cause, save energy, the characteristics that cost is low.
2, fertilizer can provide full nutrition, and fertilizer efficiency is long, can increase and upgrade the soil organism, promotes microbial reproduction, improves the physico-chemical property and the biological activity of soil, is the main nutrient source of pollution-free food production.
3, yeast phase is short, does not limit season limit, meets large-scale production.
4, become thoroughly decomposed thoroughly and contain a large amount of probioticss.
5, improve geology, have heat retaining property and drought resistance.
6, can improve the quality of products.Can make base manure and topdress.
Through≤1000 of per 100 grams of fertilizer nitrogen+phosphorus+potassium content 〉=12%, organic content 46%, the induced worm egg death rate 〉=95% coliform value of this explained hereafter.Living bacteria count (cfu) hundred million/g 〉=0.20.
Sequence number Interventions Requested Standard-required Measured data The individual event conclusion Remarks
??1 Total nutrient (N+P 2O 5+K 2O)(%)≥ ??4 ??12.6 Qualified
??2 Nitrogenous (N) (%) 〉= ??—— ??4.0 Qualified
??3 Available phosphorus (P 2O 5)(%)≥ ??—— ??5.4 Qualified
??4 Contain potassium (K 2O)(%)≥ ??—— ??3.2 Qualified
??5 Organic (%) 〉= ??30 ??46 Qualified
??6 Humic acids (%) 〉= ??10 ??12 Qualified
??7 Induced worm egg death rate ??—— ??≥95% Qualified
??8 Per 100 grams of coliform value ??—— ??≤1000 Qualified
Sequence number Interventions Requested Standard-required Measured data The individual event conclusion Remarks
??9 Living bacteria count (cfu), hundred million/g ??≥ ??0.20 Qualified
Entrusted Balin Left Banner flag husbandry office clay fertilizer station in 2009, through answering the wide contrast experiment of hand push, same plot, same kind, execute the fertilizer of the same price, execute fertilizer of the present invention than other fertile tomato increase production 21.2%.Eggplant volume increase 16.8% (vegetables amount of increase in production 15-26%, average out to 20%), corn yield increasing 16.4%, sorghum high yield 12.4% (Cereals class amount of increase in production 10-15%, average out to 12%).Fruit on average increases production about 10%, compares the drought resisting degree with its chemical fertilizer and prolongs 15 days---and 20 days.
The experiment proved that the efficient organic fertilizer that adopts efficient, fast and fractional fermentation method of organic fertilizer production is safe and reliable, fertilizer efficiency long, to improve the soil, culture fertility, increase soil organism effect be obvious.The present invention meets large-scale production and cultures waste pollution to reducing, and strengthens water conservation, improves agroecological environment and plays a significant role.Have good economic benefit and social benefit.
Description of drawings
Fig. 1 is a process flow sheet of the present invention.
Embodiment
Embodiment 1
1. preparation work
1. earlier raw materials such as ight soil, stalk are screened, remove impurity and pulverize standby;
2. want water to regulate argol humidity, reach and hold agglomerating, loose promptly loosing.Excrement is fresh more good more;
3. the stalk of required fermentation is soaked with liquid dung in advance.Preferably use the stalk of pulverizing, stalk is short more, and it is fast more to become thoroughly decomposed, and the effect of becoming thoroughly decomposed is good more;
4. raw material per ton is thrown in ratio: by weight percentage, and excrement of animals 80% stalk 20%, bacillus laterosporus 2 kg/ton;
Bacterial classification is a bacillus laterosporus, belongs to bacillus, and Gram-positive can be changed into feminine gender, and gemma is oval, adnation, middle life or nearly middle giving birth to, and sporangiocyst expands, and free gemma is on one side than the other side thick (canoe shape);
Bacillus laterosporus is a kind of natural bacterial classification that uses through the microorganism detection center approval of the national Ministry of Agriculture.Can be used for soil microorganisms fertilizer and production cultures.
The bacterial classification that we use is the product that open-minded biotechnology company limited produces, Ministry of Agriculture's registration card number: the accurate word of microorganism fertilizer (2007) (0663) number.
2, order of operation
1), getting a wetted stalk tiles on the fermentation platform; Be sprinkling upon required ight soil on the stalk uniformly; The water content of stalk and ight soil should be adjusted to weight percent 65%, promptly holds can drip less water and be advisable;
2), raw material stirring is evenly gone in the fermentation vat back employing turnover throwing machine A.T.C, the process of carrying out microbiological deterioration, decomposition with being transported to the solar energy greenhouse fermentation plant.Leavening temperature is controlled at 55 ℃, and fermentation time 48 hours is finished the sterilization fermentation process, and the bacterium of will mixing, harmful bacterium kill ratio reach more than 98%, and temperature is too high influential to nutrient.This process makes full use luminous energy, with solar energy collecting between fermentation vat, be illuminate luminous energy 4-5 doubly, be not subjected to seasonal restriction, cost is low, can produce throughout the year, this technology rate height that becomes thoroughly decomposed, sterilising effect is good.
The judgement of rotten degree:
1. color and smell: grog presents Vandyke brown, reaches no stink.
2. physical behavior: grog is loose soft, holds with a firm grip one to let go again and does not touch with one's hand.The stalk hand rubbing can be rubbed with the hands mashed, can killing pathogenic bacteria, virus, weed seed, reach innoxious standard.
3) after, the sterilization fermentation technology finishes, carry out probiotics nursery stage: will become thoroughly decomposed good fertilizer after the assay was approved, add bacteria agent, stir and enter biological fermentation and breed the phase, controlled temperature is the end 48 hours nursery stages of 30 ℃ of probioticss (the bacillus laterosporus breeding is when optimum temps is 40 ℃).This process: improve ecological environment of soil, the quality of improving the soil, the permeability of increase soil, heat retaining property, nutrient preserving capability; Stimulate the root of the crop growth, promote plant growth, increase output, improve crop quality; Reduce disease and pest, reduce pesticide residue; Strengthen photosynthesis, improve fertilizer efficiency.
4), finish the organic-biological reproductive process, test once more, after the assay was approved, the input granulation workshop is processed into particle, dry weight in wet base per-cent 15%, polishing, screening, metering packing, finished product warehouse-in.
Heaterless solar energy condensation board can be adopted in the solar energy greenhouse workshop, also can adopt solar water heater to carry out pipeline and heat.When cloudy day or nocturnal temperature do not reach, can adopt biogas pipeline that heat is provided.
Embodiment 2
1. preparation work
1. earlier raw materials such as ight soil, stalk are screened, remove impurity and pulverize standby;
2. want water to regulate argol humidity, reach and hold agglomerating, loose promptly loosing.Excrement is fresh more good more;
3. the stalk of required fermentation is soaked with liquid dung in advance.Preferably use the stalk of pulverizing, stalk is short more, and it is fast more to become thoroughly decomposed, and the effect of becoming thoroughly decomposed is good more;
4. raw material per ton is thrown in ratio: by weight percentage, and excrement of animals 85% stalk 15%, bacillus laterosporus 3 kg/ton;
Bacterial classification is a bacillus laterosporus, belongs to bacillus, and Gram-positive can be changed into feminine gender, and gemma is oval, adnation, middle life or nearly middle giving birth to, and sporangiocyst expands, and free gemma is on one side than the other side thick (canoe shape);
Bacillus laterosporus is a kind of natural bacterial classification that uses through the microorganism detection center approval of the national Ministry of Agriculture.Can be used for soil microorganisms fertilizer and production cultures.
The bacterial classification that we use is the product that open-minded biotechnology company limited produces, Ministry of Agriculture's registration card number: the accurate word of microorganism fertilizer (2007) (0663) number.
2, order of operation
1), getting a wetted stalk tiles on the fermentation platform; Be sprinkling upon required ight soil on the stalk uniformly; The water content of stalk and ight soil should be adjusted to weight percent 70%, promptly holds can drip less water and be advisable;
2), raw material stirring is evenly gone in the fermentation vat back employing turnover throwing machine A.T.C, the process of carrying out microbiological deterioration, decomposition with being transported to the solar energy greenhouse fermentation plant.Leavening temperature is controlled at 65 ℃, and fermentation time 72 hours is finished the sterilization fermentation process, and the bacterium of will mixing, harmful bacterium kill ratio reach more than 98%, and temperature is too high influential to nutrient.This process makes full use luminous energy, with solar energy collecting between fermentation vat, be illuminate luminous energy 4-5 doubly, be not subjected to seasonal restriction, cost is low, can produce throughout the year, this technology rate height that becomes thoroughly decomposed, sterilising effect is good.
The judgement of rotten degree:
1. color and smell: grog presents Vandyke brown, reaches no stink.
2. physical behavior: grog is loose soft, holds with a firm grip one to let go again and does not touch with one's hand.The stalk hand rubbing can be rubbed with the hands mashed, can killing pathogenic bacteria, virus, weed seed, reach innoxious standard.
3) after, the sterilization fermentation technology finishes, carry out probiotics nursery stage: will become thoroughly decomposed good fertilizer after the assay was approved, add bacteria agent, stir and enter biological fermentation and breed the phase, controlled temperature is the end 72 hours nursery stages of 45 ℃ of probioticss (the bacillus laterosporus breeding is when optimum temps is 40 ℃).This process: improve ecological environment of soil, the quality of improving the soil, the permeability of increase soil, heat retaining property, nutrient preserving capability; Stimulate the root of the crop growth, promote plant growth, increase output, improve crop quality; Reduce disease and pest, reduce pesticide residue; Strengthen photosynthesis, improve fertilizer efficiency.
4), finish the organic-biological reproductive process, test once more, after the assay was approved, the input granulation workshop is processed into particle, dry weight in wet base per-cent 20%, polishing, screening, metering packing, finished product warehouse-in.
Heaterless solar energy condensation board can be adopted in the solar energy greenhouse workshop, also can adopt solar water heater to carry out pipeline and heat.When cloudy day or nocturnal temperature do not reach, can adopt biogas pipeline that heat is provided.
Embodiment 3
1. preparation work
1. earlier raw materials such as ight soil, stalk are screened, remove impurity and pulverize standby;
2. want water to regulate argol humidity, reach and hold agglomerating, loose promptly loosing.Excrement is fresh more good more;
3. the stalk of required fermentation is soaked with liquid dung in advance.Preferably use the stalk of pulverizing, stalk is short more, and it is fast more to become thoroughly decomposed, and the effect of becoming thoroughly decomposed is good more;
4. raw material per ton is thrown in ratio: by weight percentage, and excrement of animals 82% stalk 18%, bacillus laterosporus 2.5 kg/ton;
Bacterial classification is a bacillus laterosporus, belongs to bacillus, and Gram-positive can be changed into feminine gender, and gemma is oval, adnation, middle life or nearly middle giving birth to, and sporangiocyst expands, and free gemma is on one side than the other side thick (canoe shape);
Bacillus laterosporus is a kind of natural bacterial classification that uses through the microorganism detection center approval of the national Ministry of Agriculture.Can be used for soil microorganisms fertilizer and production cultures.
The bacterial classification that we use is the product that open-minded biotechnology company limited produces, Ministry of Agriculture's registration card number: the accurate word of microorganism fertilizer (2007) (0663) number.
2, order of operation
1), getting a wetted stalk tiles on the fermentation platform; Be sprinkling upon required ight soil on the stalk uniformly; The water content of stalk and ight soil should be adjusted to weight percent 68%, promptly holds can drip less water and be advisable;
2), raw material stirring is evenly gone in the fermentation vat back employing turnover throwing machine A.T.C, the process of carrying out microbiological deterioration, decomposition with being transported to the solar energy greenhouse fermentation plant.Leavening temperature is controlled at 60 ℃, and fermentation time 60 hours is finished the sterilization fermentation process, and the bacterium of will mixing, harmful bacterium kill ratio reach more than 98%, and temperature is too high influential to nutrient.This process makes full use luminous energy, with solar energy collecting between fermentation vat, be illuminate luminous energy 4-5 doubly, be not subjected to seasonal restriction, cost is low, can produce throughout the year, this technology rate height that becomes thoroughly decomposed, sterilising effect is good.
The judgement of rotten degree:
1. color and smell: grog presents Vandyke brown, reaches no stink.
2. physical behavior: grog is loose soft, holds with a firm grip one to let go again and does not touch with one's hand.The stalk hand rubbing can be rubbed with the hands mashed, can killing pathogenic bacteria, virus, weed seed, reach innoxious standard.
3) after, the sterilization fermentation technology finishes, carry out probiotics nursery stage: will become thoroughly decomposed good fertilizer after the assay was approved, add bacteria agent, stir and enter biological fermentation and breed the phase, controlled temperature is the end 60 hours nursery stages of 40 ℃ of probioticss (the bacillus laterosporus breeding is when optimum temps is 40 ℃).This process: improve ecological environment of soil, the quality of improving the soil, the permeability of increase soil, heat retaining property, nutrient preserving capability; Stimulate the root of the crop growth, promote plant growth, increase output, improve crop quality; Reduce disease and pest, reduce pesticide residue; Strengthen photosynthesis, improve fertilizer efficiency.
4), finish the organic-biological reproductive process, test once more, after the assay was approved, the input granulation workshop is processed into particle, dry weight in wet base per-cent 18%, polishing, screening, metering packing, finished product warehouse-in.
Heaterless solar energy condensation board can be adopted in the solar energy greenhouse workshop, also can adopt solar water heater to carry out pipeline and heat.When cloudy day or nocturnal temperature do not reach, can adopt biogas pipeline that heat is provided.

Claims (1)

1. efficient, fast and fractional fermentation method of organic fertilizer is characterized in that:
(1), raw material is prepared and allotment
Earlier raw materials such as ight soil, stalk are screened, remove impurity and pulverize standbyly, the water content of stalk and ight soil should be adjusted to weight percent 65%--70%, raw material input ratio per ton: weight percent excrement of animals 80%-85%, stalk 15%-20%;
(2), sterilization fermentation
Raw material stirring evenly back is carried out sterilization fermentation with being transported to the solar energy greenhouse fermentation plant, and leavening temperature is controlled at 55-65 ℃, fermentation time 48--72 hour;
(3), probiotics fermentation
To become thoroughly decomposed good fertilizer after the assay was approved, add bacteria agent one bacillus laterosporus 2-3 kg/ton, and stir, controlled temperature is at 30-45 ℃, probiotics fermentation time 48-72 hour;
(4), back arrangement
Raw material input granulation workshop by fermentation is processed into particle, dry control moisture weight percent≤20%, through polishing, screening, metering packing, and the finished product warehouse-in.
CN201010162097A 2010-04-10 2010-04-10 Efficient, fast and fractional fermentation method of organic fertilizer Pending CN101830740A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102603376A (en) * 2012-04-11 2012-07-25 柳图固 Biological organic fertilizer and production method thereof
CN102617202A (en) * 2012-04-13 2012-08-01 贵州省现代中药材研究所 Process for preparing organic fertilizer by bagged fermentation of corn stalks and cow dung
CN102674915A (en) * 2012-06-07 2012-09-19 宁国市明华农林综合开发有限公司 Process method for preparing biological fertilizer by utilizing hickory hulls
CN104230416A (en) * 2014-08-21 2014-12-24 福建省诏安县绿洲生化有限公司 Method of producing solid organic carbon fertilizer
CN109265207A (en) * 2018-10-22 2019-01-25 汪添法 A method of it is fermented using cellar underground heat to organic fertilizer
CN110467485A (en) * 2019-08-28 2019-11-19 张涵旭 A kind of biological method handling excrement
CN111620729A (en) * 2020-05-20 2020-09-04 西藏珠峰华绿生态农业科技有限公司 Fermentation method of animal excrement
CN115215696A (en) * 2022-07-13 2022-10-21 辽宁创强农业科技有限公司 Carbon-based fertilizer processing equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0609865A1 (en) * 1993-02-02 1994-08-10 Günter Grube Process for obtaining an organic or organic-mineral fertiliser
CN1316404A (en) * 2000-04-06 2001-10-10 张兴权 Process for preparing compound biologic organic fertilizer from solid waste

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0609865A1 (en) * 1993-02-02 1994-08-10 Günter Grube Process for obtaining an organic or organic-mineral fertiliser
CN1316404A (en) * 2000-04-06 2001-10-10 张兴权 Process for preparing compound biologic organic fertilizer from solid waste

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102603376A (en) * 2012-04-11 2012-07-25 柳图固 Biological organic fertilizer and production method thereof
CN102617202A (en) * 2012-04-13 2012-08-01 贵州省现代中药材研究所 Process for preparing organic fertilizer by bagged fermentation of corn stalks and cow dung
CN102674915A (en) * 2012-06-07 2012-09-19 宁国市明华农林综合开发有限公司 Process method for preparing biological fertilizer by utilizing hickory hulls
CN102674915B (en) * 2012-06-07 2014-07-16 宁国市明华农林综合开发有限公司 Process method for preparing biological fertilizer by utilizing hickory hulls
CN104230416A (en) * 2014-08-21 2014-12-24 福建省诏安县绿洲生化有限公司 Method of producing solid organic carbon fertilizer
CN109265207A (en) * 2018-10-22 2019-01-25 汪添法 A method of it is fermented using cellar underground heat to organic fertilizer
CN110467485A (en) * 2019-08-28 2019-11-19 张涵旭 A kind of biological method handling excrement
CN111620729A (en) * 2020-05-20 2020-09-04 西藏珠峰华绿生态农业科技有限公司 Fermentation method of animal excrement
CN115215696A (en) * 2022-07-13 2022-10-21 辽宁创强农业科技有限公司 Carbon-based fertilizer processing equipment

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