CN101768376A - Environment-friendly disperse dye composition - Google Patents
Environment-friendly disperse dye composition Download PDFInfo
- Publication number
- CN101768376A CN101768376A CN200910156640A CN200910156640A CN101768376A CN 101768376 A CN101768376 A CN 101768376A CN 200910156640 A CN200910156640 A CN 200910156640A CN 200910156640 A CN200910156640 A CN 200910156640A CN 101768376 A CN101768376 A CN 101768376A
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- CN
- China
- Prior art keywords
- alkyl
- dye monomer
- dye
- formula
- disperse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000986 disperse dye Substances 0.000 title claims abstract description 19
- 239000000975 dye Substances 0.000 claims abstract description 95
- 239000000178 monomer Substances 0.000 claims abstract description 73
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- -1 R 13 Chemical compound 0.000 claims description 11
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000005429 oxyalkyl group Chemical group 0.000 claims description 4
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 10
- 239000010865 sewage Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- ROPYWXVRNREIQD-UHFFFAOYSA-N 2-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCC#N)CCOC(=O)C)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl ROPYWXVRNREIQD-UHFFFAOYSA-N 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000013543 active substance Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- CULIYQPRUGMRRT-UHFFFAOYSA-N 2-chloro-n-[2-[(2-cyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound ClCC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1C#N CULIYQPRUGMRRT-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 1
- KHZRTXVUEZJYNE-UHFFFAOYSA-N 3-[4-[(2,6-dichloro-4-nitrophenyl)diazenyl]-n-ethylanilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl KHZRTXVUEZJYNE-UHFFFAOYSA-N 0.000 description 1
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WFFKSTRPZWRBEW-UHFFFAOYSA-N n-[2-[(2-bromo-4,6-dinitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(Br)C=C([N+]([O-])=O)C=C1[N+]([O-])=O WFFKSTRPZWRBEW-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses an environment-friendly disperse dye composition which mainly comprises the following components in percentage by weight: 10-75% of dye monomer A shown as formula ; 2-35% of dye monomer B shown in formula (2); 8-50% of dye monomer C shown in formula (3); 1-10% of dye monomer D shown in formula (4). The disperse dye composition can be adjusted to obtain black, blue, gray, brown and other color lights, is an environment-friendly dye, has wide pH value application range during dyeing, good deep dyeing property, strong covering property, lifting power, color yield, level dyeing property and good fastness, and can greatly improve the dyeThe utilization rate and the dyeing sewage are reduced.
Description
Technical field
The present invention relates to a kind of environmental-friendly disperse dye composition, be specially adapted to the dyeing and the stamp of terylene and BLENDED FABRIC thereof.
Background technology
In dispersed dye, C.I.Disperse Orange 76# (76# orange) is because of its equalization is good, and fastness is good, and colorant match is good, usually compound with C.I.Disperse Blue 291:1#, C.I.Disperse Violet93#, piece together high-intensity black, the blue serial dispersed dye of system.This is black, not only intensity height but also depth are fabulous for dispersed dye of blue series, and be very extensive in the application of dyeing polyester materials.But owing to the 76# orange can cracking produce harmful arylamine under given conditions, it is irritated that human body is produced, therefore the high strength that has 76# orange dispersed dye black, blue series are classified as the forbidding dyestuff by European Union member countries such as Germany, though black, the blue serial substitute products of many environment-friendly types are arranged on the market, and its depth and lid screening dynamics all do not reach previous level.Seek environment-friendly type, black, the blue serial disperse dye composition of depth, opacifying property all good high strength is that pendulum is badly in need of the difficult problem that solves in face of everybody at present.
Summary of the invention
The invention provides a kind of environmental protection, depth, opacifying property fabulous high strength is disperseed the dye composite of black blue series, this disperse dye composition belongs to intensity height, depth is good, dye yield is high, homogeneity is good high strength disperse dye composition.
A kind of disperse dye composition of environment-friendly type, by weight percentage, mainly form by following component:
10%~75% dye monomer A as the formula (1):
X wherein
1Be H or CN or NO
2
X
2Be H or halogen, and X
1And X
2Be not H simultaneously;
X
3Be H or C
1~C
4Alkyl or NHCOR
3Or OH; R
3Be C
1~C
4Alkyl;
X
4Be H or OH or OR
4Or R
5OR
6R
4, R
5, R
6Independent separately is C
1~C
4Alkyl;
R
1, R
2Independent separately is H or C
1~C
4Alkyl or CH
2CH=CH
2Or R
7OR
8Or R
9OR
10OH or R
11OCOR
12Or R
13COOR
14Or
Or R
16COOR
17OR
18Or C
1~C
4A hydrogen in the alkyl is replaced by OH, CN or benzene; R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
15, R
16, R
17, R
18Independent separately is C
1~C
4Alkyl;
2%~35% dye monomer B as the formula (2):
X
5Be H or NO
2Or halogen or OR
21Or SO
2R
22R
21, R
22Independent separately is C
1~C
4Alkyl;
X
6Be H or C
1~C
4Alkyl or OR
23Or NHCOR
24R
23, R
24Independent separately is C
1~C
4Alkyl;
R
19, R
20Independent separately is C
1~C
4Alkyl or C
1~C
4Alcoxyl alkyloyloxyethyl alkyl (as CH
2CH
2OCOOCH
3) or C
1~C
4Alkanoic acid alkane ester or C
1~C
4Alkyl in a hydrogen replaced by CN, OH, benzene, oxyalkyl, alkyloyl or benzoyl group;
8%~50% dye monomer C as the formula (3):
X
7, X
8Independent separately is H or halogen;
X
9Be H or C
1~C
4Alkyl or halogen;
R
25, R
26Independent separately is H or C
1~C
4Alkyl or R
27OCOR
28Or
Or
Or
Or R
33OCOOR
34Or CH
2CH=CH
2Or R
35OR
36CN or C
1~C
4Alkanoic acid alkane ester or C
1~C
4Alkyl in a hydrogen replaced by OH, CN or benzene; R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36Independent separately is C
1~C
4Alkyl;
1%~10% dye monomer D as the formula (4):
X
10, X
11, X
12, X
13, X
14Independent separately is H or NO
2Or halogen or
Or OR
39Or COOR
40OR
41OR
42Or Ph-R
43COO-or COOR
44COOR
45Or COOR
46-Ph; R
39, R
40, R
41, R
42, R
43, R
44, R
45, R
46Independent separately is C
1~C
4Alkyl; R
37Be C
1~C
4Alkyl;
R
38Be H or C
1~C
4Alkyl or C
1~C
4Alkyl in a hydrogen replaced by oxyalkyl.
Described dye monomer A is preferably suc as formula a kind of dye monomer shown in (1-1)~(1-24) or the mixture of multiple dye monomer:
Dye monomer B is preferably suc as formula a kind of dye monomer shown in (2-1)~(2-11) or the mixture of multiple dye monomer:
Dye monomer C is preferably suc as formula a kind of dye monomer shown in (3-1)~(3-18) or the mixture of multiple dye monomer:
Dye monomer D is preferably suc as formula a kind of dye monomer shown in (4-1)~(4-13) or the mixture of multiple dye monomer:
Dyestuff of the present invention needs to add auxiliary agent usually when composite.Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.Usually, auxiliary agent is 0.7~4.5 with the ratio of former dyestuff weight: 1.
Environmental-friendly disperse dye composition of the present invention can be used by the below method and prepare:
After dye monomer mixed by said ratio, in the presence of auxiliary agent, water or other tensio-active agent, carry out corpusculed with pulverizers such as sand mill or shredders; Also the former dyestuff of dye monomer carries out corpusculed with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other tensio-active agent, mixes by said ratio again.
Described dye monomer A, dye monomer B, dye monomer C, dye monomer D can adopt the commercially available prod.
It is aqueous that environmental-friendly disperse dye composition of the present invention grinds the back with sand mill or shredder, is powdery, particulate state after the spraying drying.Environmental-friendly disperse dye composition of the present invention can be according to dye monomer A, B, C, D and the adjustment of auxiliary agent ratio are deceived, blue, ash, coloured light such as palm fibre, the gained dye composite is the environmental protection dyestuff, meet environmental protection and the ecological requirement of the Oeko-Tex standard of the European Community 100, and the subject range of pH value is broad when dyeing, depth is good, opacifying property strong, lifting force, dye yield, level-dyeing property, every fastness is all good, can improve dye utilization rate greatly, reduce dyeing waste, and be that every performance approaches one of orange disperse dye composition of piecing together the black blue series of making of 76# most when at present each grade Polyester Fibers being dyeed.
Embodiment
The invention will be further described below in conjunction with embodiment and Comparative Examples, but protection scope of the present invention is not limited to this.
Embodiment 1~48
According to data shown in the table 1, after dye monomer A, dye monomer B, dye monomer C, dye monomer D and dispersion agent condensation compound of methyl naphthalene sulfonic acid and formaldehyde (MF), diffusant benzyl sulfonic formaldehyde condensation compound (CNF), diffusant naphthalene sulfonic acidformaldehyde condensation product (NNO), sodium lignosulfonate and other tensio-active agent added water and piece together to mix, grind dispersion with sand milling, carry out spraying drying then.
The EX-SF DISPERSE BLUE EX-SF 300 291:2 that dye monomer shown in its Chinese style (1-1) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the EX-SF DISPERSE BLUE EX-SF 300 291:1 that dye monomer shown in the formula (1-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the EX-SF DISPERSE BLUE EX-SF 300 291 that dye monomer shown in the formula (1-3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the EX-SF DISPERSE BLUE EX-SF 300 291 that dye monomer shown in the formula (1-4) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the EX-SF DISPERSE BLUE EX-SF 300 291:4 that dye monomer shown in the formula (1-5) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the 63 DISPERSE Violet 63 93# that dye monomer shown in the formula (1-6) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the 63 DISPERSE Violet 63 93:1# that dye monomer shown in the formula (1-7) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the Disperse Blue-79 # that dye monomer shown in the formula (1-8) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (1-9) can select the EX-SF DISPERSE BLUE EX-SF 300 183:1# of Zhejiang Province Runtu intercalated Co., Ltd's production etc. for use.
The Red-1 200 45# that dye monomer shown in its Chinese style (2-1) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the Red-1 200 79# that dye monomer shown in the formula (2-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the Disperse Red 58# that dye monomer shown in the formula (2-3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the Red-1 200 56# that dye monomer shown in the formula (2-4) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (2-5) can select the Red-1 200 77 of Zhejiang Province Runtu intercalated Co., Ltd's production etc. for use.
The DISPERSE ORANGE 30 200 278# that dye monomer shown in its Chinese style (3-1) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 288# that dye monomer shown in the formula (3-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 298# that dye monomer shown in the formula (3-3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 279# that dye monomer shown in the formula (3-4) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 30:2 that dye monomer shown in the formula (3-5) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 30# that dye monomer shown in the formula (3-6) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (3-7) can select the DISPERSE ORANGE 30 200 61# of Zhejiang Province Runtu intercalated Co., Ltd's production etc. for use.
The DISPERSE YELLOW 114# that dye monomer shown in its Chinese style (4-1) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE YELLOW 119# that dye monomer shown in the formula (4-2) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE Yellow 211 # that dye monomer shown in the formula (4-3) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE YELLOW 241# that dye monomer shown in the formula (4-4) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce, the dye monomer shown in the formula (4-5) can adopt the DISPERSE YELLOW 126# of Zhejiang Province Runtu intercalated Co., Ltd's production etc.
Table 1:
Comparative Examples is DISPERSE ORANGE 30 200 288#10g, EX-SF DISPERSE BLUE EX-SF 300 291:350g and the composite dye composite of 63 DISPERSE Violet 63 93:140g that adopts Zhejiang Province Runtu intercalated Co., Ltd to produce.
With the dispersed dye that the foregoing description makes, auxiliary agent, the dye composite that water makes after mixing and the disperse dye composition of Comparative Examples carry out performance test, and testing method is as follows:
Respectively get the dispersed dye of 1.0 gram embodiment 1~48, water is mixed with the dispersed dye suspension that concentration is 1g/500ml respectively, gets 10ml, 50ml, 80ml and 90ml, 50ml, the water of 20ml mixes, dye abundant pH to 5 with the acetic acid adjusting, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt GB/T2397-2003, GB/T3921-1997, GB/T3920-1997, GB/T5178-1997 measure its dyefastness.Measurement result sees Table 2.
Embodiment | Lifting force | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
Embodiment 1 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 2 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 3 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 4 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 5 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 6 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 7 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 8 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment | Lifting force | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
Embodiment 9 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 10 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 11 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 12 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 13 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 14 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 15 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 16 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 17 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 18 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 19 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 20 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 21 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 22 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 23 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 24 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 25 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 26 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 27 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 28 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 29 | ??A | ??4-5 | ??5 | ??4 |
Embodiment 30 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment | Lifting force | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
Embodiment 31 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 32 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 33 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 34 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 35 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 36 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 37 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 38 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 39 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 40 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 41 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 42 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 43 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 44 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 45 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 46 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 47 | ??A | ??4-5 | ??5 | ??4-5 |
Embodiment 48 | ??A | ??4-5 | ??5 | ??4-5 |
Comparative Examples | ??A-B | ??4 | ??4 | ??4-5 |
Claims (5)
1. the disperse dye composition of an environment-friendly type, by weight percentage, mainly form by following component:
10%~75% dye monomer A as the formula (1):
X wherein
1Be H or CN or NO
2
X
2Be H or halogen, and X
1And X
2Be not H simultaneously;
X
3Be H or C
1~C
4Alkyl or NHCOR
3Or OH; R
3Be C
1~C
4Alkyl;
X
4Be H or OH or OR
4Or R
5OR
6R
4, R
5, R
6Independent separately is C
1~C
4Alkyl;
R
1, R
2Independent separately is H or C
1~C
4Alkyl or CH
2CH=CH
2Or R
7OR
8Or R
9OR
10OH or R
11OCOR
12Or R
13COOR
14Or R
15OCO
Or R
16COOR
17OR
18Or C
1~C
4A hydrogen in the alkyl is replaced by OH, CN or benzene; R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
15, R
16, R
17, R
18Independent separately is C
1~C
4Alkyl;
2%~35% dye monomer B as the formula (2):
X
5Be H or NO
2Or halogen or OR
21Or SO
2R
22R
21, R
22Independent separately is C
1~C
4Alkyl;
X
6Be H or C
1~C
4Alkyl or OR
23Or NHCOR
24R
23, R
24Independent separately is C
1~C
4Alkyl;
R
19, R
20Independent separately is C
1~C
4Alkyl or C
1~C
4Alcoxyl alkyloyloxyethyl alkyl (as CH
2CH
2OCOOCH
3) or C
1~C
4Alkanoic acid alkane ester or C
1~C
4Alkyl in a hydrogen replaced by CN, OH, benzene, oxyalkyl, alkyloyl or benzoyl group;
8%~50% dye monomer C as the formula (3):
X
7, X
8Independent separately is H or halogen;
X
9Be H or C
1~C
4Alkyl or halogen;
R
25, R
26Independent separately is H or C
1~C
4Alkyl or R
27OCOR
28Or R
29OCONH
Or R
30OCO
Or R
31OCOR
32 Or R
33OCOOR
34Or CH
2CH=CH
2Or R
35OR
36CN or C
1~C
4Alkanoic acid alkane ester or C
1~C
4Alkyl in a hydrogen replaced by OH, CN or benzene; R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36Independent separately is C
1~C
4Alkyl;
1%~10% dye monomer D as the formula (4):
X
10, X
11, X
12, X
13, X
14Independent separately is H or NO
2Or halogen or
Or OR
39Or COOR
40OR
41OR
42Or Ph-R
43COO-or COOR
44COOR
45Or COOR
46-Ph;
R
39, R
40, R
41, R
42, R
43, R
44, R
45, R
46Independent separately is C
1~C
4Alkyl;
R
37Be C
1~C
4Alkyl;
R
38Be H or C
1~C
4Alkyl or C
1~C
4Alkyl in a hydrogen replaced by oxyalkyl.
Priority Applications (1)
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Applications Claiming Priority (1)
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---|---|---|---|
CN 200910156640 CN101768376B (en) | 2009-12-30 | 2009-12-30 | Environment-friendly disperse dye composition |
Publications (2)
Publication Number | Publication Date |
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CN101768376A true CN101768376A (en) | 2010-07-07 |
CN101768376B CN101768376B (en) | 2013-10-23 |
Family
ID=42501484
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