CN106928749B - A kind of disperse dye composition, disperse dyes and its preparation method and purposes - Google Patents
A kind of disperse dye composition, disperse dyes and its preparation method and purposes Download PDFInfo
- Publication number
- CN106928749B CN106928749B CN201710188881.8A CN201710188881A CN106928749B CN 106928749 B CN106928749 B CN 106928749B CN 201710188881 A CN201710188881 A CN 201710188881A CN 106928749 B CN106928749 B CN 106928749B
- Authority
- CN
- China
- Prior art keywords
- component
- weight percent
- formula
- disperse
- dye composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
A kind of disperse dye composition, disperse dyes and its preparation method and purposes.The disperse dyes are suitable for dyeing and the stamp of fabric, especially terylene and its blended fabric.
Description
The application be the applying date be on December 30th, 2013, application No. is 201310751747.6, it is entitled " a kind of
Disperse dye composition, disperse dyes and its preparation method and purposes " application divisional application.
Technical field
The present invention relates to a kind of disperse dye composition, disperse dyes and its preparation method and purposes.The dispersion dye
Material is suitable for dyeing and the stamp of fabric, especially terylene and its blended fabric.
Background technique
As the environmental consciousness of today's society generally enhances, realize that low-carbon environment-friendly has been trend of the times, low-carbon economy has become
For the inexorable trend of economic development.Dye industry has realized that this opportunities and challenges, therefore gradually develops novel, environmental protection
Dyestuff.
Summary of the invention
The present invention provides the economic and environment-friendly type dispersion dye that a kind of pH value range is wide, light fastness is good, compatibility is excellent, intensity is high
Material.
The present invention provides a kind of disperse dye composition, it is characterised in that composed of the following components:
The component A as shown in formula (1):
One or more component B as shown in formula (2):
In formula (2), X1For bromine or chlorine；R1、R2Respectively stand alone as C1~C4Alkyl；
One or more component C as shown in formula (3):
In formula (3), X2For bromine or chlorine, R3、R4Respectively stand alone as C1~C4Alkyl or CH2CH=CH2, Y C1~C4Alkane
Base；
Optional one or more component D as shown in formula (4):
In formula (4), X3、X4Respectively stand alone as hydrogen, chlorine or bromine, R5、R6Respectively stand alone as C2~C4Alkyl or C1~C4Alkane
The group that a hydrogen in base is replaced by cyano, phenyl, acetoxyl group or benzoyloxy；Wherein component D is not C.I. dispersion
Orange 76；
Optional one or more component E as shown in formula (5):
In formula (5), X5、X6Respectively stand alone as hydrogen, chlorine or nitro, R7For C1~C4Alkyl；
Optional one or more component F as shown in formula (6):
In formula (6), X7For cyano or nitro, R8For C1~C4Alkyl amido or C1~C4Alkyl, R9、R10It is respectively independent
For C1~C4Alkyl；With
The optional component G as shown in formula (7):
(disperse blue 2BLM).
Disperse dye composition according to the present invention, it is preferable that the component B be one of following compound or
Two kinds:
(C.I. disperse violet 93)
(disperse violet 93:1).
Disperse dye composition according to the present invention, it is preferable that the component C be one of following compound or
It is two or more:
(C.I. disperse blue 291)
(disperse blue 291:2)
(C.I. disperse blue 291:1).
Disperse dye composition according to the present invention, it is preferable that the component D be one of following compound or
It is two or more:
(disperse orange 288)
(C.I. disperse orange 73)
(C.I. disperse orange 61)
(C.I. disperse orange 30)
(disperse orange 278)
(disperse orange 30:2)
(C.I. disperse orange 25)
(C.I. disperse orange 33).
Disperse dye composition according to the present invention, it is preferable that the component E be one of following compound or
It is two or more:
(C.I. disperse yellow 119)
(C.I. DISPERSE Yellow 211).
Disperse dye composition according to the present invention, it is preferable that the component F be one of following compound or
It is two or more:
(C.I. disperse blue 165:1)
(C.I. disperse blue 366)
(C.I. disperse blue 165).
Disperse dye composition according to the present invention, it is preferable that component B is such as formula (2-1) and formula (2-2) shownization
Close one or both of object:
Preferably, component C is one or more of compound as shown in following formula (3-1) to (3-4):
Based on the total weight of the disperse dye composition, the weight percent of component A is 2-73%, preferably 2-
72%, or preferably 2-60%, or preferably 2-51%, or preferably 3-50%, or preferably 3-6%.The weight hundred of component B
Divide than being 7-40%, preferably 7-37%, or preferably 12-39%, or preferably 12-37%.The weight percent of component C is
20-58%, preferably 38-58%, or preferably 20-48%, or preferably 30-55%, or preferably 35-55%.Component D's
Weight percent is 0-70%, preferably 2-50%, or preferably 3-6%.The weight percent of component E is 0-10%, preferably
For 2-6%.The weight percent of component F is 0-47%, preferably 1-10%.The weight percent of component G is 0-47%, preferably
For 1-10%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The component A that weight percent is 2~73%,
The component B that weight percent is 7~40%,
The component C that weight percent is 20~58%,
The component D that optional weight percent is 0~70%,
The component E that optional weight percent is 0~10%,
The component F that optional weight percent is 0~47%, and
The component G that optional weight percent is 0~47%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 3~50%,
The weight percent of component B is 12~39%,
The weight percent of component C is 38~58%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 2~60%,
The weight percent of component B is 7~37%,
The weight percent of component C is 30~55%,
The weight percent of component D is 3~6%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 3~6%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component D is 2~50%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 2~51%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component E is 2~6%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 2~72%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component F is 1~10%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, by with the following group
It is grouped as:
The weight percent of component A is 2~72%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component G is 1~10%.
In the actual production process, each dye component of the invention usually may be with some by-products and other miscellaneous
Matter, but as long as not influencing implementation of the invention.
The present invention also provides a kind of disperse dyes, which is characterized in that by disperse dye composition of the present invention and auxiliary
Material composition.
Disperse dyes according to the present invention, which is characterized in that the auxiliary material includes auxiliary agent and water.
Disperse dyes according to the present invention, which is characterized in that the auxiliary agent includes one or more below
Combination: naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulphate, surfactant, fungicide or other dyestuffs point
Powder.
Disperse dyes according to the present invention, which is characterized in that the weight of the auxiliary agent and disperse dye composition it
Than for 0.3~4:1.
The present invention also provides a kind of methods for preparing disperse dyes according to the present invention, which is characterized in that including with
Lower step:
After each dye component is mixed, particlized processing is carried out with sand mill or grinder in the presence of auxiliary material；
Or each dye component is subjected to particlized processing with sand mill or grinder in the presence of auxiliary material respectively, then mixed
It closes.
Disperse dyes of the present invention, with can be after sand mill or grinder grinding liquid (usual solid content for 20~
It 50%), can be powdery or graininess after spray drying (usual solid content is 87~96%).
The present invention also provides a kind of disperse dyes according to the present invention for the dyeing of fabric and the purposes of stamp.
The present invention also provides a kind of fabrics, which is characterized in that is carried out by using disperse dyes according to the present invention
Dyeing and stamp are prepared.
The pH value range of disperse dyes of the invention is wide, light fastness is good, compatibility is excellent, intensity is high.
Specific embodiment
Embodiment
Below with reference to embodiment, the invention will be further described, but the scope of protection of the present invention is not limited thereto.
In embodiment, component A, B, C of the invention and optional component D, E, F, G, by certain proportion and auxiliary agent and
After water blending, grinding distribution is carried out with sand mill, slurry or further progress spray drying is made, so that dyestuff be made.
Described component A, B, C, D, E, F, G are known dye composition and can buy on the market, Huo Zheke
It is prepared by existing method.
Embodiment 1:
By 15.6 grams of formula (1) dye components, 6.1 grams of formula (2-2) dye components, 16.3 grams of formula (3-3) dye components, 31 grams
Dispersant MF and 31 grams of lignin 85A add 200 grams of water to stir, and grinding distribution is simultaneously dry to get dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 1:
Embodiment 1 is repeated, other than the formula of embodiment 1 (1) dye component is substituted for following formula (8) dye component,
It is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 1 and comparative example 1 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the intensity that them are measured using GB/T6688-2008, measurement result are shown in Table 1.
Table 1
| Title | Intensity |
| Embodiment 1 | 102% |
| Comparative example 1 | 100% |
Intensity it is high it is meant that same depth textile, whens printing and dyeing can reduce dye dosage, reduce printing and dyeing cost.
Embodiment 2:
By 15.6 grams of formula (1) dye components, 6.1 grams of formula (2-1) dye components, 16.3 grams of formula (3-4) dye components, 31 grams
Dispersant MF and 31 grams of lignin 83A add 200 grams of water to stir, and grinding distribution is simultaneously dry to get dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 2:
Embodiment 2 is repeated, other than the formula of embodiment 2 (1) dye component is substituted for following formula (9) dye component,
It is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 2 and comparative example 2 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the light fastness that them are measured using AATCC16-2004, the results are shown in Table 2.
Table 2
| Title | Light fastness (40h) |
| Embodiment 2 | 2~3 |
| Comparative example 2 | 2 |
Embodiment 3:
By 15.6 grams of formula (1) dye components, 6.1 grams of formula (2-2) dye components, 11.4 grams of formula (3-3) dye components, 4.9
Gram formula (3-4) dye component and 11.4 grams of Dispersant MFs, add 100 grams of water to stir, liquid dyes are made in grinding distribution
Finished product, dyeing obtain the excellent black polyester of every fastness ability.
Comparative example 3:
Embodiment 3 is repeated, other than the formula of embodiment 3 (1) dye component is replaced an accepted way of doing sth (4-1) dye component,
It is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 3 and comparative example 3 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, AATCC16-2004, and surveyed referring to GB/T2400-2006
Intensity, light fastness and the compatibility for determining them, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibility |
| Embodiment 3 | 105% | 3 | Ⅱ |
| Comparative example 3 | 100% | 2 | III |
The method for measuring compatibility are as follows: dyed referring to GB/T2394-2003, enter dye from 60 DEG C, when temperature is raised to 80
DEG C when at once take a sample, a sample is taken every 10 DEG C later, until 130 DEG C, also, 130 DEG C keep the temperature 10 minutes, 20 points
It is separately sampled when clock, 30 minutes, 50 minutes, 10 pieces of cloth specimens are taken altogether.50 minutes are kept the temperature as standard specimen with 130 DEG C, and each shelves temperature is taken
Cloth specimen is sample, observes whether the variation of its form and aspect synchronizes.(the instrument: Computer color testing instrument of the Pyatyi system of being divided into I, II, III, IV, V
Datacolor 600, colour difference formula CMC 2:1).For black hues, DC (gorgeous degree is poor) is calculated, DH (hue difference) is respectively less than
0.6 cloth specimen block number.
I grade: five piece and five pieces or more
II grade: four piece
III grade: three piece
IV grade: two piece
V grade: one piece.
Embodiment 4:
By 15.6 grams of formula (1) dye components, 6.1 grams of formula (2-1) dye components, 16.4 grams of formula (3-1) dye components, 31 grams
Dispersant MF and 31 grams of dispersing agent NNOs add 200 grams of water to stir, and grinding distribution is simultaneously dry to get dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 4:
Embodiment 4 is repeated, other than the formula of embodiment 4 (1) dye component is substituted for following formula (10) dye component,
It is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 4 and comparative example 4 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, and measure their intensity, pH referring to GB/T2403-2006
It is worth range, the results are shown in Table 4.
Table 4
| Title | Intensity | PH stable range |
| Embodiment 4 | 107% | 3~9 |
| Comparative example 4 | 100% | 3~7 |
Note: pH stable range: using the pH value range of intensity >=95% as pH stable range.
Embodiment 5:
By 44 grams of formula (1) dye components, 22 grams of formula (2-2) dye components, 34 grams of formula (3-3) dye components, 31 grams of dispersions
Agent MF and 31 grams of dispersing agent NNOs add 200 grams of water to stir, and grinding distribution is simultaneously dry to get dyestuff finished product, dye
The black polyester excellent to every fastness ability.
Comparative example 5:
Embodiment 5 is repeated, in addition to 44 grams of formula (1) dye components in embodiment 5 are substituted for 41.4 grams of formula (10) dyestuffs
It is other constant except component and 2.6 grams of formula (11) dye components.
The dyestuff finished product of embodiment 5 and comparative example 5 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 5 and comparative example 5 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
It is worth range, the results are shown in Table 5.
Table 5
| Title | Intensity | PH value range |
| Embodiment 5 | 107% | 3~9 |
| Comparative example 5 | 100% | 3~7 |
Note: pH value range judges: using the pH value range of intensity >=95% as pH stable range.
Embodiment 6:
By 7.8 grams of formula (1) dye components, 7.8 grams of formula (4-1) dye components, 6.1 grams of formula (2-1) dye components, 16.4 grams
Formula (3-1) dye component, 31 grams of dispersing agent MFs and 31 grams of lignin 85A add 200 grams of water to stir, and grinding distribution is simultaneously
Drying obtains the excellent black polyester of every fastness ability to get dyestuff finished product, dyeing.
Comparative example 6:
Embodiment 6 is repeated, other than formula (1) dye component in embodiment 6 is replaced an accepted way of doing sth (8) dye component,
It is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 6 and comparative example 6 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the intensity that them are measured using GB/T6688-2008, the results are shown in Table 6.
Table 6
| Title | Intensity |
| Embodiment 6 | 102% |
| Comparative example 6 | 100% |
Embodiment 7-8
According to the compositing formula in table 7, dyestuff finished product is made similarly to Example 6.
7 unit of table: gram
The dyestuff finished product of embodiment 7 and embodiment 8 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 7 and embodiment 8 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the compatibility that them are measured using the method for embodiment 3, the results are shown in Table 8.
Table 8
| Embodiment | Compatibility |
| 7 | Ⅱ |
| 8 | Ⅱ |
Embodiment 9
According to the compositing formula in table 9, dyestuff finished product is made similarly to Example 6.
9 unit of table: gram
The dyestuff finished product of embodiment 9 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 9 is weighed into the water of 250ml,
Disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath pH to 5 with acetic acid,
Then 60 DEG C are warming up to, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, 130 DEG C are warming up in 35 minutes,
Heat preservation 45 minutes, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light simultaneously measures its light fastness using AATCC16-2004 method, the results are shown in Table 10.
Table 10
| Embodiment | Light fastness |
| 9 | 3 |
Embodiment 10-15
According to the compositing formula in table 11, dyestuff finished product is made similarly to Example 6.
11 unit of table: gram
The dyestuff finished product of embodiment 10-15 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 10-15 is weighed respectively to 250ml
Water in, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath with acetic acid
Then pH to 5 is warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, is warming up in 35 minutes
130 DEG C, 45 minutes are kept the temperature, 80 DEG C of samplings are cooled to.
Observe cloth specimen coloured light simultaneously use AATCC16-2004, and using embodiment 3 method measure they light fastness,
Compatibility the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Compatibility |
| 10 | 2~3 | Ⅱ |
| 11 | 2~3 | Ⅱ |
| 12 | 2~3 | Ⅱ |
| 13 | 2~3 | Ⅱ |
| 14 | 2~3 | Ⅱ |
| 15 | 3 | Ⅱ |
Embodiment 16-17
According to the compositing formula in table 13, appropriate amount of addition agent is added, dyestuff finished product is made.
13 unit of table: gram
The dyestuff finished product of embodiment 16-17 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 16 and 17 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the compatibility that them are measured using the method for embodiment 3, the results are shown in Table 14.
Table 14
| Embodiment | Compatibility |
| 16 | Ⅱ |
| 17 | Ⅰ |
Embodiment 18-38
According to the compositing formula in table 15, appropriate amount of addition agent is added, dyestuff finished product is made.
15 unit of table: gram
The dyestuff finished product of embodiment 18-38 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 18-38 is weighed respectively to 250ml
Water in, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath with acetic acid
Then pH to 5 is warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, is warming up in 35 minutes
130 DEG C, 45 minutes are kept the temperature, 80 DEG C of samplings are cooled to.
Observe cloth specimen coloured light simultaneously use AATCC16-2004, and using embodiment 3 method measure they light fastness,
Compatibility the results are shown in Table 16.
Table 16
| Embodiment | Light fastness | Compatibility |
| 18 | 2~3 | Ⅰ |
| 19 | 2~3 | Ⅰ |
| 20 | 3 | Ⅱ |
| 21 | 3 | Ⅰ |
| 22 | 3 | Ⅰ |
| 23 | 3 | Ⅰ |
| 24 | 2~3 | Ⅰ |
| 25 | 3 | Ⅰ |
| 26 | 2~3 | Ⅰ |
| 27 | 2~3 | Ⅰ |
| 28 | 3 | Ⅱ |
| 29 | 3 | Ⅱ |
| 30 | 2~3 | Ⅱ |
| 31 | 3 | Ⅱ |
| 32 | 3 | Ⅰ |
| 33 | 2~3 | Ⅰ |
| 34 | 2~3 | Ⅱ |
| 35 | 2~3 | Ⅱ |
| 36 | 3 | Ⅰ |
| 37 | 3 | Ⅰ |
| 38 | 3 | Ⅰ |
Embodiment 39-43
According to the compositing formula in table 17, appropriate amount of addition agent is added, dyestuff finished product is made.
17 unit of table: gram
The dyestuff finished product of embodiment 39-43 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 39-43 is weighed respectively to 250ml
Water in, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath with acetic acid
Then pH to 5 is warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, is warming up in 35 minutes
130 DEG C, 45 minutes are kept the temperature, 80 DEG C of samplings are cooled to.
Observe cloth specimen coloured light simultaneously use AATCC16-2004, and using embodiment 3 method measure they light fastness,
Compatibility the results are shown in Table 18.
Table 18
| Embodiment | Light fastness | Compatibility |
| 39 | 2~3 | Ⅱ |
| 40 | 3 | Ⅱ |
| 41 | 2~3 | Ⅱ |
| 42 | 3 | Ⅱ |
| 43 | 3 | Ⅱ |
Claims (21)
1. a kind of disperse dye composition, it is characterised in that composed of the following components:
The component A as shown in formula (1):
One or more component B as shown in formula (2):
In formula (2), X1For bromine or chlorine；R1、R2Respectively stand alone as C1~C4Alkyl；
One or more component C as shown in formula (3):
In formula (3), X2For bromine or chlorine, R3、R4Respectively stand alone as C1~C4Alkyl or CH2CH=CH2, Y C1~C4Alkyl；
Optional one or more component D as shown in formula (4):
In formula (4), X3、X4Respectively stand alone as hydrogen, chlorine or bromine, R5、R6Respectively stand alone as C2~C4Alkyl or C1~C4In alkyl
The group that is replaced by cyano, phenyl, acetoxyl group or benzoyloxy of a hydrogen；Wherein component D is not C.I. disperse orange 76；
Optional one or more component E as shown in formula (5):
In formula (5), X5、X6Respectively stand alone as hydrogen, chlorine or nitro, R7For C1~C4Alkyl；
Optional one or more component F as shown in formula (6):
In formula (6), X7For cyano or nitro, R8For C1~C4Alkyl amido or C1~C4Alkyl, R9、R10Respectively stand alone as C1
~C4Alkyl；With
The optional component G as shown in formula (7):
Wherein, the total weight based on the composition, the weight percent of the component A are 2~37%, the weight of the component B
Measuring percentage is 7~40%, and the weight percent of the component C is 20~58%, and the weight percent of optional component D is 0
The weight percent of~70%, optional component E are 0~10%, and the weight percent of optional component F is 0~47%, and is appointed
The weight percent of the component G of choosing is 0~47%.
2. disperse dye composition according to claim 1, which is characterized in that the component B is in following compound
It is one or two kinds of:
3. disperse dye composition according to claim 1 or 2, which is characterized in that the component C is in following compound
One or more:
4. disperse dye composition according to claim 1 or 2, which is characterized in that the component D is in following compound
One or more:
5. disperse dye composition according to claim 1 or 2, which is characterized in that the component E is in following compound
One or more:
6. disperse dye composition according to claim 1 or 2, which is characterized in that the component F is in following compound
One or more:
7. disperse dye composition according to claim 1 or 2, which is characterized in that component B is such as formula (2-1) and formula (2-
2) one or both of compound shown in:
Component C is one or more of compound as shown in following formula (3-1) to (3-4):
8. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
It is composed of the following components:
The weight percent of component A is 3~37%,
The weight percent of component B is 12~39%,
The weight percent of component C is 38~58%.
9. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
It is composed of the following components:
The weight percent of component A is 2~37%,
The weight percent of component B is 7~37%,
The weight percent of component C is 30~55%,
The weight percent of component D is 3~6%.
10. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount, composed of the following components:
The weight percent of component A is 3~6%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component D is 2~50%.
11. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount, composed of the following components:
The weight percent of component A is 2~37%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component E is 2~6%.
12. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount, composed of the following components:
The weight percent of component A is 2~37%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component F is 1~10%.
13. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount, composed of the following components:
The weight percent of component A is 2~37%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component G is 1~10%.
14. a kind of disperse dyes, which is characterized in that the disperse dye composition as described in any one of claim 1~13 and
Auxiliary material composition.
15. disperse dyes according to claim 14, which is characterized in that the auxiliary material includes auxiliary agent and water.
16. disperse dyes according to claim 15, which is characterized in that the auxiliary agent include it is below it is one or two kinds of with
On combination: naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulphate, surfactant, fungicide or other dyestuffs
Dispersing agent.
17. disperse dyes according to claim 15 or 16, which is characterized in that the auxiliary agent and disperse dye composition
Weight ratio is 0.3~4:1.
18. disperse dyes according to any one of claims 14-16, which is characterized in that the disperse dyes are sanded
Machine or grinder grinding after be liquid, solid content be 20~50% or the disperse dyes be spray-dried after be powdery or
Granular, solid content is 87~96%.
19. a kind of method for preparing disperse dyes described in any one of 4~18 according to claim 1, which is characterized in that including
Following steps:
After each dye component is mixed, particlized processing is carried out with sand mill or grinder in the presence of auxiliary material；Or
Each dye component is subjected to particlized processing with sand mill or grinder in the presence of auxiliary material respectively, then is mixed.
20. a kind of disperse dyes described in any one of 4~18 according to claim 1 are for the dyeing of fabric and the use of stamp
On the way.
21. a kind of fabric, which is characterized in that by using disperse dyes described according to claim 1 any one of 4~18 into
Row dyeing and stamp are prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188881.8A CN106928749B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188881.8A CN106928749B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310751747.6A CN104371360B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310751747.6A Division CN104371360B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106928749A CN106928749A (en) | 2017-07-07 |
| CN106928749B true CN106928749B (en) | 2019-11-22 |
Family
ID=52550569
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710188881.8A Active CN106928749B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310751747.6A Active CN104371360B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310751747.6A Active CN104371360B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN106928749B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788996B (en) * | 2015-04-29 | 2017-03-08 | 杭州福莱蒽特精细化工有限公司 | A kind of yellowish-brown dye composition |
| CN105062137A (en) * | 2015-07-31 | 2015-11-18 | 杭州福莱蒽特精细化工有限公司 | Disperse yellow brown dye composition with high dyeing degree |
| KR20220013364A (en) * | 2019-05-23 | 2022-02-04 | 닛뽄 가야쿠 가부시키가이샤 | Method for printing colored dispersions, recording media, and hydrophobic fibers |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058471A (en) * | 1983-09-09 | 1985-04-04 | Mitsui Toatsu Chem Inc | Water-insoluble disperse dye composition and dyeing of polyester fiber or polyester-cotton blended cloth using the same |
| JPH02225571A (en) * | 1990-01-26 | 1990-09-07 | Mitsui Toatsu Chem Inc | Water-insoluble disperse dye composition and dyeing or printing of polyester fiber therewith |
| CN101094895A (en) * | 2005-01-04 | 2007-12-26 | 克莱里安特财务(Bvi)有限公司 | Disperse azo dye mixtures |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101735663A (en) * | 2009-12-31 | 2010-06-16 | 上虞市金冠化工有限公司 | Composite black disperse dye |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN101792615A (en) * | 2010-03-09 | 2010-08-04 | 江苏吉华化工有限公司 | Environment-friendly dark blue and black series compound disperse dye and production method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN100354377C (en) * | 2005-06-07 | 2007-12-12 | 浙江闰土股份有限公司 | Composite environment-friendly disperse grey dye |
| CN101760045B (en) * | 2009-12-30 | 2013-07-24 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
-
2013
- 2013-12-30 CN CN201710188881.8A patent/CN106928749B/en active Active
- 2013-12-30 CN CN201310751747.6A patent/CN104371360B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058471A (en) * | 1983-09-09 | 1985-04-04 | Mitsui Toatsu Chem Inc | Water-insoluble disperse dye composition and dyeing of polyester fiber or polyester-cotton blended cloth using the same |
| JPH02225571A (en) * | 1990-01-26 | 1990-09-07 | Mitsui Toatsu Chem Inc | Water-insoluble disperse dye composition and dyeing or printing of polyester fiber therewith |
| CN101094895A (en) * | 2005-01-04 | 2007-12-26 | 克莱里安特财务(Bvi)有限公司 | Disperse azo dye mixtures |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN101735663A (en) * | 2009-12-31 | 2010-06-16 | 上虞市金冠化工有限公司 | Composite black disperse dye |
| CN101792615A (en) * | 2010-03-09 | 2010-08-04 | 江苏吉华化工有限公司 | Environment-friendly dark blue and black series compound disperse dye and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104371360B (en) | 2017-02-15 |
| CN104371360A (en) | 2015-02-25 |
| CN106928749A (en) | 2017-07-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104371358B (en) | Disperse dye composition and disperse dye and preparation method and use thereof | |
| CN104448928B (en) | Disperse blue dye composition, disperse dye, preparation method and application | |
| CN102344695B (en) | Composite dye composition, composite disperse dye and preparation method thereof | |
| CN104650621B (en) | Disperse dye composition, disperse dyes and its production and use | |
| CN105602284B (en) | A kind of blue disperse dye composition, blue disperse dye and its production and use | |
| CN104371361B (en) | Yellow disperse dye composition and disperse dye and preparation method and use thereof | |
| CN106928749B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| WO2015101290A1 (en) | Disperse dye composition, disperse dye and preparation method and use thereof | |
| CN106084886B (en) | A kind of blue disperse dye mixture and disperse dyes | |
| CN105670341B (en) | A kind of blue disperse dye composition, blue disperse dye and its preparation method and application | |
| CN106928750B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN106947286B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN105001672B (en) | A kind of orange disperse dye composition, disperse dyes and its production and use | |
| CN104194385A (en) | Azo 1:2 metal complex dye composition and application thereof in dyeing | |
| CN106947288B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN106700648A (en) | Black disperse dye composition | |
| CN104371363B (en) | A kind of Yellow disperse dye, its preparation method and purposes | |
| CN104371359B (en) | Disperse dye composition and disperse dye and preparation method and use thereof | |
| CN106046855B (en) | A kind of disperse dye composition | |
| CN106947287B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN104371364B (en) | Disperse dye composition and disperse dye, and preparation method and use thereof | |
| CN109735136B (en) | Yellow disperse dye composition, disperse dye, and preparation method and application thereof | |
| CN108841202B (en) | Disperse yellow dye mixture with improved sublimation fastness | |
| CN104497628B (en) | Disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN104327548B (en) | A kind of disperse yellow is to orange compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |