CN101760045B - Medium-low temperature environmental-friendly disperse dye composition - Google Patents

Medium-low temperature environmental-friendly disperse dye composition Download PDF

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CN101760045B
CN101760045B CN 200910156642 CN200910156642A CN101760045B CN 101760045 B CN101760045 B CN 101760045B CN 200910156642 CN200910156642 CN 200910156642 CN 200910156642 A CN200910156642 A CN 200910156642A CN 101760045 B CN101760045 B CN 101760045B
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dye composition
formula
alkyl
dye
fastness
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CN101760045A (en
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赵国生
高立江
顾伟娣
陈田木
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Zhejiang Runtu Co Ltd
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Zhejiang Runtu Co Ltd
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Abstract

The invention discloses a medium-low temperature environmental-friendly disperse dye composition, which comprises the following components in percentage by weight: 3-94 percent of dye compound A as shown in the formula (1), 3-55 percent of dye compound B as shown in the formula (2), 3-60 percent of dye compound C as shown in the formula (3) and 0-2 percent of dye compound D as shown in the formula (4). The dye composition has the advantages of bright color shade, good synchronism during dyeing, good reproducibility, and good leveling-dyeing property, coverage property and each fastness, and particularly has more remarkable advantages on compatibility among dyes and sublimation fastness; and moreover, the invention is environmental-friendly and overcomes the defect that environmental protection and good fastness property cannot be achieved at the same time in the prior art.

Description

Low-temperature environment-friendly type disperse dye composition in a kind of
Technical field
The present invention relates to a kind of middle low temperature disperse dye composition, be specially adapted to the dyeing and the stamp of the fine material of polyester material and vinegar.
Background technology
Along with the fast development of trevira in recent years and people to improving constantly that textiles requires, accordingly every dyeing behavior, fastness ability, the environmental-protecting performance of dyestuff itself are also had higher requirement.
Just yellow, orange disperse dye, the performance of general monogenetic dyestuff is more single, expect that Yellow disperse dye complete, better colour fastness must carry out composite by monogenetic dyestuff good with multiple compatibleness, that performance has his own strong points.Though composite dyestuff performance is better than homogencous dyes, the compatibleness between each monogenetic dyestuff is determining dyeing behavior and every fastness ability of composite dye.Seeking compatibleness Huang, orange disperse dye composition good and that every colour fastness is all good is that pendulum is badly in need of one of difficult problem that solves in face of everybody.
Summary of the invention
It is fabulous to the invention provides a kind of compatibleness, environment-friendly type yellow-orange disperse dye composition that sublimation fastness, washing fastness, crock fastness are all good.
Low-temperature environment-friendly type disperse dye composition in of the present invention, form by following component by weight percentage:
3%～94% as the formula (1) dye composition A:
Figure G200910156642XD00011
X 1, X 2It respectively is halogen;
3%～55% as the formula (2) dye composition B:
Figure G200910156642XD00021
X 3, X 4, X 5, X 6, X 7Separate is H or NO 2Or halogen or Or OR 3Or COOR 4OR 5OR 6Or Ph-R 7COO-or COOR 8COOR 9Or COOR 10-Ph; R 3, R 4, R 5, R 6, R 7, R 8, R 9, R 10Separate is C 1～C 4Alkyl;
R 1Be C 1～C 4Alkyl;
R 2Be H or C 1～C 4Alkyl or C 1～C 4Alkyl in a hydrogen replaced by oxyalkyl;
3%～60% as the formula (3) dye composition C:
Figure G200910156642XD00023
X 8, X 9Be H or halogen;
X 10Be H or halogen or C 1～C 4Alkyl;
R 11, R 12Be C 1～C 4Alkyl or C 1～C 4Alkyl in a hydrogen replaced or R by OH, CN or phenyl ring 13OCOR 14Or Or
Figure G200910156642XD00025
Or
Figure G200910156642XD00026
Or R 19OCOOR 20Or CH 2CH=CH 2Or R 21OR 22CN; R 13, R 14, R 15, R 16, R 17, R 18, R 19, R 20, R 21, R 22Separate is C 1～C 4Alkyl;
0～2% dye composition D as the formula (4):
Figure G200910156642XD00027
X 11, X 12Separate is H or NO 2Or CN or halogen;
X 13Be C 1～C 4Alkyl or NHCOR 25R 25Be C 1～C 4Alkyl;
X 14Be H or OCH 3Or OCH 2CH 3
R 23, R 24Separate is C 1～C 4Alkyl or C 1～C 4A hydrogen in the alkyl is replaced or CH by OH, CN or phenyl ring 2=CHCH 2Or R 26OCOR 27Or R 28COOR 29Or R 30OCO-Ph; R 26, R 27, R 28, R 29, R 30Separate is C 1～C 4Alkyl.
Described dye composition A is preferably suc as formula the dye composition shown in (1-1) and/or the formula (1-2):
Figure G200910156642XD00031
Described dye composition B is preferably suc as formula a kind of dye composition shown in (2-1)～(2-8) or the mixture of multiple dye composition:
Figure G200910156642XD00032
Figure G200910156642XD00041
Described dye composition C is preferably suc as formula a kind of dye composition shown in (3-1)～(3-5) or the mixture of multiple dye composition:
Described dye composition D is preferably suc as formula a kind of dye composition shown in (4-1)～(4-4) or the mixture of multiple dye composition::
Figure G200910156642XD00052
Figure G200910156642XD00061
Described dye composition D generally is added in and increases dark benefit in order to regulate coloured light, to play in orange.
Low-temperature environment-friendly type disperse dye composition in of the present invention generally needs to add auxiliary agent during application.Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.Usually, the ratio of auxiliary agent and former dyestuff weight is 0.8～5: 1.
Low-temperature environment-friendly type disperse dye composition can prepare with following method in of the present invention: after the former dyestuff of dye composition is mixed in proportion, in the presence of auxiliary agent, water or other tensio-active agent, carry out corpusculed with pulverizers such as sand mill or shredders, spraying drying then, of the present invention in low-temperature environment-friendly type disperse dye composition the proportioning adjustment can get yellow to orange coloured light between body compound, the auxiliary agent according to respectively dying.Above-mentioned dye composition all can adopt the commercially available prod.
Disperse dye composition of the present invention can be aqueous behind the corpusculed, can be powdery, particulate state after the spraying drying.This dye composite coloured light is gorgeous, on synchronism when dying good, heavy property in the third of the twelve Earthly Branches is good, level-dyeing property, opacifying property and every fastness are all good, especially compatibleness between dyestuff and sublimation fastness aspect advantage is more outstanding, and be environment-friendly type, remedied former environmental protection and the fastness ability shortcoming that can not get both well.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1～15
According to data shown in the table 1, with dye composition A, dye composition B, dye composition C, dye composition D, after adding water and piece together to mix with dispersion agent condensation compound of methyl naphthalene sulfonic acid and formaldehyde (MF), diffusant benzyl sulfonic formaldehyde condensation compound (CNF), diffusant naphthalene sulfonic acidformaldehyde condensation product (NNO), sodium lignosulfonate and other tensio-active agent by a certain percentage, grind dispersion with sand milling, carry out spraying drying then.
Wherein dye composition (1-1) can adopt the production DISPERSE YELLOW 1# of Zhejiang Province Runtu intercalated Co., Ltd, and dye composition (1-2) can adopt the production DISPERSE YELLOW 2# of Zhejiang Province Runtu intercalated Co., Ltd.
Dye composition (2-1) can adopt the production DISPERSE YELLOW 114# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (2-2) can adopt the production DISPERSE YELLOW 119# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (2-3) can adopt the production DISPERSE Yellow 211 # of Zhejiang Province Runtu intercalated Co., Ltd, and dye composition (2-4) can adopt the production DISPERSE YELLOW 241# of Zhejiang Province Runtu intercalated Co., Ltd.
Dye composition (3-1) can adopt the production DISPERSE ORANGE 30 200 25# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (3-2) can adopt the production DISPERSE YELLOW 288# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (3-3) can adopt the production DISPERSE YELLOW 298# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (3-4) can adopt the production DISPERSE YELLOW 278# of Zhejiang Province Runtu intercalated Co., Ltd, and dye composition (3-5) can adopt the production DISPERSE YELLOW 279# of Zhejiang Province Runtu intercalated Co., Ltd.
Dye composition (4-1) can adopt the production EX-SF DISPERSE BLUE EX-SF 300 183# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (4-2) can adopt the production EX-SF DISPERSE BLUE EX-SF 300 366# of Zhejiang Province Runtu intercalated Co., Ltd, dye composition (4-3) can adopt the production EX-SF DISPERSE BLUE EX-SF 300 291# of Zhejiang Province Runtu intercalated Co., Ltd, and dye composition (4-4) can adopt the production EX-SF DISPERSE BLUE EX-SF 300 291:1# of Zhejiang Province Runtu intercalated Co., Ltd.
Table 1:
Figure G200910156642XD00071
Figure G200910156642XD00081
The dye composite that Huang one orange disperse dye, auxiliary agent, the water that the foregoing description is made makes after mixing carries out performance test, and testing method is as follows:
Respectively get the dispersed dye of 0.5 gram embodiment 1～24, water is mixed with the dispersed dye suspension that concentration is 0.5g/500ml respectively, getting 20ml mixes with the water of 80ml, dye abundant PH to 5 with the acetic acid adjusting, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt similar GB/T2400-1980 and GB/T3921-1997 and GB/T3920-1997 and GB/T5178-1997 measure its dyefastness.Measurement result sees Table 2.
The embodiment title Compatibleness Washing fastness Crock fastness Sublimation fastness (180 ℃)
Embodiment 1 A 4-5 4-5 4-5
Embodiment 2 A-B 4-5 4-5 4-5
Embodiment 3 A 4-5 5 4-5
Embodiment 4 A 4-5 4-5 4-5
Embodiment 5 A 4-5 5 4-5
Embodiment 6 A 4-5 5 5
Embodiment 7 A 4-5 5 5
Embodiment 8 A 4-5 5 4-5
Embodiment 9 A 4-5 4-5 4-5
Embodiment 10 A-B 4-5 5 4-5
Embodiment 11 A 4-5 5 4-5
Embodiment 12 A 4-5 5 4-5
Embodiment 13 A 4-5 5 4-5
Embodiment 14 A 4-5 4-5 4-5
Embodiment 15 A 4-5 5 4-5
Embodiment 16 A 4-5 5 4-5
Embodiment 17 A 4-5 5 5
Embodiment 18 A 4-5 5 5
Embodiment 19 A 4-5 5 5
Embodiment 20 A 4-5 5 4-5
Embodiment 21 A-B 4-5 5 4-5
Embodiment 22 A 4-5 4-5 4-5
Embodiment 23 A 4-5 5 4-5
Embodiment 24 A 4-5 5 4-5

Claims (5)

1. low-temperature environment-friendly type disperse dye composition in a kind, by weight percentage, composed of the following components:
3%～94% as the formula (1) dye composition A:
Figure FDA00003016264900011
X 1, X 2It respectively is halogen;
3%～55% as the formula (2) dye composition B:
Figure FDA00003016264900012
X 3, X 4, X 5, X 6, X 7Separate is H or NO 2Or halogen or
Figure FDA00003016264900013
Or OR 3R 3Be C 1～C 4Alkyl;
R 1Be C 1～C 4Alkyl;
R 2Be H or C 1～C 4Alkyl;
3%～60% as the formula (3) dye composition C:
Figure FDA00003016264900014
X 8, X 9Be H or halogen;
X 10Be H;
R 11, R 12Be C 1～C 4Alkyl or C 1～C 4Alkyl in a hydrogen replaced by CN or phenyl ring;
0～2% dye composition D as the formula (4):
Figure FDA00003016264900021
X 11, X 12Separate is H or NO 2Or CN or halogen;
X 13Be C 1～C 4Alkyl or NHCOR 25R 25Be C 1～C 4Alkyl;
X 14Be H or OCH 3Or OCH 2CH 3
R 23, R 24Separate is C 1～C 4Alkyl or CH 2=CHCH 2
2. low-temperature environment-friendly type disperse dye composition in as claimed in claim 1 is characterized in that: described dye composition A is suc as formula the dye composition shown in (1-1) and/or the formula (1-2):
Figure FDA00003016264900022
Figure FDA00003016264900023
3. low-temperature environment-friendly type disperse dye composition in as claimed in claim 1, it is characterized in that: described dye composition B is preferably suc as formula a kind of dye composition shown in (2-1)～(2-8) or the mixture of multiple dye composition:
Figure FDA00003016264900024
Figure FDA00003016264900032
Figure FDA00003016264900034
Figure FDA00003016264900035
Figure FDA00003016264900041
4. low-temperature environment-friendly type disperse dye composition in as claimed in claim 1, it is characterized in that: described dye composition C is preferably suc as formula a kind of dye composition shown in (3-1)～(3-5) or the mixture of multiple dye composition:
Figure FDA00003016264900042
Figure FDA00003016264900043
Figure FDA00003016264900044
Figure FDA00003016264900045
Figure FDA00003016264900046
5. low-temperature environment-friendly type disperse dye composition in as claimed in claim 1, it is characterized in that: described dye composition D is preferably suc as formula a kind of dye composition shown in (4-1)～(4-4) or the mixture of multiple dye composition:
Figure FDA00003016264900051
Figure FDA00003016264900053
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CN104371370A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371360A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371365A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
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Cited By (8)

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CN104371370A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371360A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371365A (en) * 2013-12-30 2015-02-25 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371365B (en) * 2013-12-30 2017-02-15 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371370B (en) * 2013-12-30 2017-02-15 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN104371360B (en) * 2013-12-30 2017-02-15 陈百龙 Disperse dye composition and disperse dye, and preparation method and use thereof
CN106947286A (en) * 2013-12-30 2017-07-14 浙江闰土股份有限公司 A kind of disperse dye composition, disperse dyes and its preparation method and purposes
CN106947286B (en) * 2013-12-30 2019-11-22 浙江闰土股份有限公司 A kind of disperse dye composition, disperse dyes and its preparation method and purposes

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