CN104371370A - Disperse dye composition and disperse dye, and preparation method and use thereof - Google Patents
Disperse dye composition and disperse dye, and preparation method and use thereof Download PDFInfo
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- CN104371370A CN104371370A CN201310753365.7A CN201310753365A CN104371370A CN 104371370 A CN104371370 A CN 104371370A CN 201310753365 A CN201310753365 A CN 201310753365A CN 104371370 A CN104371370 A CN 104371370A
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- component
- weight percent
- formula
- dye
- disperse dye
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- 0 *CC(*)*c(cc1)ccc1N1C(*c(cc2)ccc2[N+]([O-])=O)C1 Chemical compound *CC(*)*c(cc1)ccc1N1C(*c(cc2)ccc2[N+]([O-])=O)C1 0.000 description 4
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Abstract
The invention discloses a disperse dye composition and a disperse dye, and a preparation method and use thereof, and the disperse dye is suitable for dyeing and printing of fabrics, especially polyester and blended fabrics thereof.
Description
Technical field
The present invention relates to a kind of disperse dye composition, dispersed dye and preparation method and purposes.Described dispersed dye are applicable to fabric, particularly the dyeing of terylene and BLENDED FABRIC thereof and stamp.
Background technology
Along with people are to the pay attention to day by day of environmental protection, particularly some European countries have put into effect some regulation, policies etc. in succession.Same, in recent years, China it is also proposed higher requirement to environmental protection, and carry out control to some polluted enterprises, how dyestuff enterprise tries to achieve survival and development, is that pendulum is maximum in face of dye manufacturers, and is need the urgent difficult problem solved most.
Summary of the invention
The invention provides the economic environmental-friendly disperse dye that a kind of pH value range is wide, light fastness good, compatibleness is excellent, intensity is high, washing fastness is good.
The invention provides a kind of disperse dye composition, it is characterized in that composed of the following components:
Component A as the formula (1):
One or more B component as the formula (2):
In formula (2), X
1for bromine or chlorine; R
1, R
2respective is independently C
1~ C
4alkyl;
Component C such as formula shown in (3-1) and (3-2):
(EX-SF DISPERSE BLUE EX-SF 300 291:2)
(C.I. EX-SF DISPERSE BLUE EX-SF 300 291:1)
Optional one or more component D as the formula (4):
In formula (4), X
2, X
3respective is independently hydrogen, chlorine or bromine, R
3, R
4respective is independently C
2~ C
4alkyl, or C
1~ C
4the group that a hydrogen in alkyl is replaced by cyano group, phenyl, acetoxyl group or benzoyloxy; Wherein component D is not C.I. DISPERSE ORANGE 30 200 76;
Optional one or more component E as the formula (5):
In formula (5), X
4, X
5respective is independently hydrogen, chlorine or nitro, R
5for C
1~ C
4alkyl;
Optional one or more component F as the formula (6):
In formula (6), X
6, X
7respective is independently cyano group, bromine, chlorine or nitro, R
6for hydrogen or C
1~ C
4alkoxyl group, R
9for C
1~ C
4alkyl amido or C
1~ C
4alkyl, R
7, R
8respective is independently C
1~ C
4alkyl;
Optional component G as the formula (7):
(EX-SF DISPERSE BLUE EX-SF 300 2BLM).
According to disperse dye composition of the present invention, preferably, described B component is one or both in following compound:
(C.I. 63 ,DIS,PER,SE ,Vio,let, 63 93)
(63 DISPERSE Violet 63 93:1).
According to disperse dye composition of the present invention, preferably, described component D is one or more in following compound:
(DISPERSE ORANGE 30 200 288)
(C.I. DISPERSE ORANGE 30 200 73)
(C.I. DISPERSE ORANGE 30 200 61)
(C.I. DISPERSE ORANGE 30 200 30)
(DISPERSE ORANGE 30 200 278)
(DISPERSE ORANGE 30 200 30:2)
(C.I. disperse orange 25)
(C.I. DISPERSE ORANGE 30 200 33).
According to disperse dye composition of the present invention, preferably, described component E is one or more in following compound:
(C.I. DISPERSE YELLOW 119)
(C.I. DISPERSE Yellow 211).
According to disperse dye composition of the present invention, preferably, described component F is one or more in following compound:
(C.I. EX-SF DISPERSE BLUE EX-SF 300 165:1)
(C.I. EX-SF DISPERSE BLUE EX-SF 300 366)
(C.I. EX-SF DISPERSE BLUE EX-SF 300 165)
(C.I. EX-SF DISPERSE BLUE EX-SF 300 291)
Based on the gross weight of described disperse dye composition, the weight percent of component A is 2-73%, is preferably 2-72%, or is preferably 2-60%, or is preferably 2-51%, or is preferably 3-50%, or is preferably 3-6%.The weight percent of B component is 7-40%, is preferably 7-37%, or is preferably 12-39%, or is preferably 12-37%.The weight percent of component C is 20-58%, is preferably 38-58%, or is preferably 20-48%, or is preferably 30-55%, or is preferably 35-55%.The weight percent of component D is 0-70%, is preferably 2-50%, or is preferably 3-6%.The weight percent of component E is 0-10%, is preferably 2-6%.The weight percent of component F is 0-47%, is preferably 1-10%.The weight percent of component G is 0-47%, is preferably 1-10%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
Weight percent is the component A of 2 ~ 73%,
Weight percent is the B component of 7 ~ 40%,
Weight percent is the component C of 20 ~ 58%,
Optional weight percent is the component D of 0 ~ 70%,
Optional weight percent is the component E of 0 ~ 10%,
Optional weight percent is the component F of 0 ~ 47%, and
Optional weight percent is the component G of 0 ~ 47%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 3 ~ 50%,
The weight percent of B component is 12 ~ 39%,
The weight percent of component C is 38 ~ 58%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 60%,
The weight percent of B component is 7 ~ 37%,
The weight percent of component C is 30 ~ 55%,
The weight percent of component D is 3 ~ 6%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 3 ~ 6%,
The weight percent of B component is 12 ~ 37%,
The weight percent of component C is 35 ~ 55%,
The weight percent of component D is 2 ~ 50%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 51%,
The weight percent of B component is 12 ~ 37%,
The weight percent of component C is 35 ~ 55%,
The weight percent of component E is 2 ~ 6%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 72%,
The weight percent of B component is 7 ~ 40%,
The weight percent of component C is 20 ~ 48%,
The weight percent of component F is 1 ~ 10%.
According to disperse dye composition of the present invention, preferably, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 72%,
The weight percent of B component is 7 ~ 40%,
The weight percent of component C is 20 ~ 48%,
The weight percent of component G is 1 ~ 10%.
According to disperse dye composition of the present invention, preferably, in described component C, the weight percent of the compound shown in described formula (3-1) is 1 ~ 99%, be preferably 70 ~ 90%, the weight percent of the compound shown in described formula (3-2) is 1 ~ 99%, is preferably 10 ~ 30%, based on the weighing scale of described component C.
In actual production process, each dye component of the present invention usually may with some by products and other impurity, only otherwise affect of the present invention enforcement.
The present invention also provides a kind of dispersed dye, it is characterized in that, forms by according to disperse dye composition of the present invention and auxiliary material.
According to dispersed dye of the present invention, preferably, described auxiliary material comprises auxiliary agent and water.
According to dispersed dye of the present invention, preferably, described auxiliary agent comprises one or more following combination: naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin, sodium sulfate, tensio-active agent, sterilant, or other dye dispersants.
According to dispersed dye of the present invention, preferably, described auxiliary agent is 0.3 ~ 4:1 with the ratio of the weight of disperse dye composition.
The present invention also provides a kind of method prepared according to dispersed dye of the present invention, it is characterized in that, comprises the following steps:
After described each dye component mixing, under the existence of auxiliary material, carry out particlized process with sand mill or shredder; Or described each dye component is carried out particlized process with sand mill or shredder respectively under auxiliary material exists, then mixes.
Dispersed dye of the present invention, can be aqueous (usual solid content is 20 ~ 50%) with after sand mill or shredder grinding, can be powdery or particulate state (usual solid content is 87 ~ 96%) after spraying dry.
The present invention also provides a kind of according to the dyeing of dispersed dye of the present invention for fabric and/or the purposes of stamp.
The present invention also provides a kind of fabric, it is characterized in that, carries out dyeing and/or stamp prepares by using according to dispersed dye of the present invention.
The pH value range of dispersed dye of the present invention is wide, light fastness good, compatibleness is excellent, intensity is high, washing fastness is good.
Embodiment
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
In an embodiment, component A of the present invention, B, C and optional component D, E, F, G, after certain proportioning and auxiliary agent and water blending, carry out grinding distribution with sand mill and make slurry, or carry out spraying dry further, thus make dyestuff.
Described component A, B, C, D, E, F, G are known dye composition and can commercially buy, or can be prepared by existing method.
Embodiment 1:
By 41 grams of formula (1) dye components, 16 grams of formula (2-2) dye components, 30 grams of formula (3-1) dye components and the mixture of 13 grams of formula (3-2) dye components, 80 grams of Dispersant MFs and 80 grams of xylogen 85A, add water 390 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 1:
Repeat embodiment 1, except being replaced to except following formula (8) dye component by formula (1) dye component of embodiment 1, other is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 1 and comparative example 1 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008 to measure their intensity, measurement result is in table 1.
Table 1
| Title | Intensity |
| Embodiment 1 | 102% |
| Comparative example 1 | 100% |
Intensity is high to be meaned, the textiles of the same degree of depth can reduce dye dosage during printing and dyeing, reduces printing and dyeing cost.
Embodiment 2:
By 41 grams of formula (1) dye components, 16 grams of formula (2-1) dye components, 30 grams of formula (3-1) dye components and the mixture of 13 grams of formula (3-2) dye components, 80 grams of Dispersant MFs and 80 grams of xylogen 83A, add water 390 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 2:
Repeat embodiment 2, except being replaced to except following formula (9) dye component by formula (1) dye component of embodiment 2, other is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 2 and comparative example 2 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004 to measure their light fastness, the results are shown in Table 2.
Table 2
| Title | Light fastness (40h) |
| Embodiment 2 | 3 |
| Comparative example 2 | 2 |
Embodiment 3:
By the mixture of 41 grams of formula (1) dye components, 16 grams of formula (2-1) dye components, 30 grams of formula (3-1) dye components and 13 grams of formula (3-2) dye components, and 30 grams of Dispersant MFs, add water 200 grams and stir, grinding distribution makes pulp material finished product, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 3:
Repeat embodiment 3, except being replaced except an accepted way of doing sth (4-1) dye component by formula (1) dye component of embodiment 3, other is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 3 and comparative example 3 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, and with reference to intensity, light fastness and compatibleness that GB/T2400-2006 measures them, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibleness |
| Embodiment 3 | 105% | 2～3 | Ⅱ |
| Comparative example 3 | 100% | 2 | Ⅲ |
The method measuring compatibleness is: dye with reference to GB/T2394-2003, dye is entered from 60 DEG C, get a sample when temperature is raised to 80 DEG C at once, get a sample every 10 DEG C later, until 130 DEG C, further, sampling respectively when being incubated 10 minutes, 20 minutes, 30 minutes, 50 minutes for 130 DEG C, getting 10 pieces of cloth specimens altogether.Be incubated 50 minutes for standard specimen with 130 DEG C, each shelves cloth specimen that temperature is got is sample, whether synchronously observes its foxy.The Pyatyi system of being divided into I, II, III, IV, V (instrument: Computer color testing instrument datacolor600, colour difference formula CMC2:1).For black hues, calculate DC(gorgeous degree poor), DH(tonal difference) be all less than 0.6 cloth specimen block number.
I grade: five pieces and more than five pieces
II grade: four pieces
III grade: three pieces
IV grade: two pieces
V grade: one piece.
Embodiment 4:
By 41 grams of formula (1) dye components, 16 grams of formula (2-2) dye components, 30 grams of formula (3-1) dye components and the mixture of 13 grams of formula (3-2) dye components, 30 grams of Dispersant MFs and 30 grams of dispersing agent NNOs, add water 250 grams and stir, grinding distribution makes pulp material finished product, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 4:
Repeat embodiment 4, except being replaced to except following formula (10) dye component by formula (1) dye component of embodiment 4, other is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 4 and comparative example 4 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and with reference to intensity, pH value range that GB/T2403-2006 measures them, the results are shown in Table 4.
Table 4
| Title | Intensity | PH value stable range |
| Embodiment 4 | 107% | 3～9 |
| Comparative example 4 | 100% | 3～7 |
Note: pH value stable range: with the pH value range of intensity >=95% for pH value stable range.
Embodiment 5:
By 44 grams of formula (1) dye components, 22 grams of formula (2-2) dye components, 30.6 grams of formula (3-1) dye components and the mixture of 3.4 grams of formula (3-2) dye components, 31 grams of Dispersant MFs and 31 grams of dispersing agent NNOs, add water 200 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 5:
Repeat embodiment 5, except gram formula (1) dye component of 44 in embodiment 5 being replaced to 41.4 grams of formula (10) dye components and 2.6 grams of formula (11) dye components, other is constant.
The dyestuff finished product of embodiment 5 and comparative example 5 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 5 and comparative example 5 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and with reference to intensity, pH value range that GB/T2403-2006 measures them, the results are shown in Table 5.
Table 5
| Title | Intensity | PH value stable range |
| Embodiment 5 | 107% | 3～9 |
| Comparative example 5 | 100% | 3～7 |
Note: pH value stable range: with the pH value range of intensity >=95% for pH value stable range.
Embodiment 6:
By 7.8 grams of formula (1) dye components, 7.8 grams of formula (4-1) dye components, 6.0 grams of formula (2-1) dye components, 13.1 grams of formula (3-1) dye components and the mixture of 3.3 grams of formula (3-2) dye components, 31 grams of dispersing agent MFs and 31 grams of xylogen 85A, add water 200 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 6:
Repeat embodiment 6, except being replaced except an accepted way of doing sth (8) dye component by formula (1) dye component in embodiment 6, other is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 6 and comparative example 6 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008 to measure their intensity, the results are shown in Table 6.
Table 6
| Title | Intensity |
| Embodiment 6 | 102% |
| Comparative example 6 | 100% |
Embodiment 7:
By 9.5 grams of formula (1) dye components, 36.5 grams of formula (2-2) dye components, 27 grams of formula (3-1) dye components and the mixture of 27 grams of formula (3-2) dye components, 80 grams of Dispersant MFs and 80 grams of xylogen 83A, add water 390 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 7:
Repeat embodiment 7, except being replaced to except 54 grams of formula (3-1) dye components by the mixture of gram formula (3-1) dye component of 27 in embodiment 7 and 27 grams of formula (3-2) dye components, other is constant.
The dyestuff finished product of embodiment 7 and comparative example 7 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 7 and comparative example 7 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T3921-2008, measuring their washing fastness, the results are shown in Table 7.
Table 7
| Title | Washing fastness |
| Embodiment 7 | 4～5 |
| Comparative example 7 | 4 |
Embodiment 8:
By 12 grams of formula (1) dye components, 34 grams of formula (2-2) dye components, 10.8 grams of formula (3-1) dye components and the mixture of 43.2 grams of formula (3-2) dye components, 80 grams of Dispersant MFs and 80 grams of xylogen 83A, add water 390 grams and stir, grinding distribution is also dry, obtain dyestuff finished product, dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 8:
Repeat embodiment 8, except being replaced to except 54 grams of formula (3-2) dye components by the mixture of gram formula (3-1) dye component of 10.8 in embodiment 8 and 43.2 grams of formula (3-2) dye components, other is constant.
The dyestuff finished product of embodiment 8 and comparative example 8 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 8 and comparative example 8 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, measuring their intensity, light fastness, the results are shown in Table 8.
Table 8
| Title | Intensity | Light fastness (40h) |
| Embodiment 8 | 103.5% | 2～3 |
| Comparative example 8 | 100% | 2 |
Embodiment 9
According to the formula in table 9, make dyestuff finished product according to the method for embodiment 8.
Table 9 unit: gram
The dyestuff finished product of embodiment 9 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 9, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt the method for AATCC16-2004, measuring their light fastness, the results are shown in Table 10.
Table 10
| Embodiment | Light fastness |
| 9 | 3 |
Embodiment 10-17
According to the formula in table 11, make dyestuff finished product according to the method for embodiment 8.
Table 11 unit: gram
The dyestuff finished product of embodiment 10-17 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 10-17 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, and adopting the method for embodiment 3 to measure their light fastness, compatibleness, the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Compatibleness |
| 10 | 3 | Ⅱ |
| 11 | 2～3 | Ⅱ |
| 12 | 3 | Ⅱ |
| 13 | 2～3 | Ⅱ |
| 14 | 3 | Ⅱ |
| 15 | 2～3 | Ⅱ |
| 16 | 2～3 | Ⅱ |
| 17 | 3 | Ⅱ |
Embodiment 18 and 19
According to the formula in table 13, add appropriate amount of addition agent, make dyestuff finished product.
Table 13 unit: gram
The dyestuff finished product of embodiment 18 and 19 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 18 and 19 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt the method for AATCC16-2004, measuring their light fastness, the results are shown in Table 14.
Table 14
| Embodiment | Light fastness |
| 18 | 3 |
| 19 | 3 |
Embodiment 20-35
According to the formula in table 15, add appropriate amount of addition agent, make dyestuff finished product.
Table 15 unit: gram
The dyestuff finished product of embodiment 20-35 is carried out performance test.
Concrete testing method is as follows:
According to the method that GB/T2394-2003 is similar, the dyestuff finished product taking 0.5 gram of embodiment 20-35 respectively, in the water of 250ml, makes dispersed dye suspension.Draw 10ml dispersed dye suspension to mix with the water of 90ml, regulate dye bath pH to 5 with acetic acid, be then warmed up to 60 DEG C, put into 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, and adopting the method for embodiment 3 to measure their light fastness, compatibleness, the results are shown in Table 16.
Table 16
| Embodiment | Light fastness | Compatibleness |
| 20 | 2～3 | Ⅱ |
| 21 | 2～3 | Ⅱ |
| 22 | 2～3 | Ⅰ |
| 23 | 3 | Ⅱ |
| 24 | 3 | Ⅱ |
| 25 | 3 | Ⅰ |
| 26 | 2～3 | Ⅰ |
| 27 | 3 | Ⅰ |
| 28 | 2～3 | Ⅱ |
| 29 | 2～3 | Ⅱ |
| 30 | 2～3 | Ⅱ |
| 31 | 2～3 | Ⅱ |
| 32 | 3 | Ⅱ |
| 33 | 2～3 | Ⅱ |
| 34 | 3 | Ⅱ |
| 35 | 3 | Ⅱ |
Claims (21)
1. a disperse dye composition, is characterized in that composed of the following components:
Component A as the formula (1):
One or more B component as the formula (2):
In formula (2), X
1for bromine or chlorine; R
1, R
2respective is independently C
1~ C
4alkyl;
Component C such as formula shown in (3-1) and (3-2):
Optional one or more component D as the formula (4):
In formula (4), X
2, X
3respective is independently hydrogen, chlorine or bromine, R
3, R
4respective is independently C
2~ C
4alkyl, or C
1~ C
4the group that a hydrogen in alkyl is replaced by cyano group, phenyl, acetoxyl group or benzoyloxy; Wherein component D is not C.I. DISPERSE ORANGE 30 200 76;
Optional one or more component E as the formula (5):
In formula (5), X
4, X
5respective is independently hydrogen, chlorine or nitro, R
5for C
1~ C
4alkyl;
Optional one or more component F as the formula (6):
In formula (6), X
6, X
7respective is independently cyano group, bromine, chlorine or nitro, R
6for hydrogen or C
1~ C
4alkoxyl group, R
9for C
1~ C
4alkyl amido or C
1~ C
4alkyl, R
7, R
8respective is independently C
1~ C
4alkyl;
Optional component G as the formula (7):
2. disperse dye composition according to claim 1, is characterized in that, described B component is one or both in following compound:
3. disperse dye composition according to claim 1 and 2, is characterized in that, described component D is one or more in following compound:
4. the disperse dye composition according to any one of claims 1 to 3, is characterized in that, described component E is one or more in following compound:
5. the disperse dye composition according to any one of Claims 1 to 4, is characterized in that, described component F is one or more in following compound:
6. the disperse dye composition according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
Weight percent is the component A of 2 ~ 73%,
Weight percent is the B component of 7 ~ 40%,
Weight percent is the component C of 20 ~ 58%,
Optional weight percent is the component D of 0 ~ 70%,
Optional weight percent is the component E of 0 ~ 10%,
Optional weight percent is the component F of 0 ~ 47%, and
Optional weight percent is the component G of 0 ~ 47%.
7. the disperse dye composition according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 3 ~ 50%,
The weight percent of B component is 12 ~ 39%,
The weight percent of component C is 38 ~ 58%.
8. the disperse dye composition according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 60%,
The weight percent of B component is 7 ~ 37%,
The weight percent of component C is 30 ~ 55%,
The weight percent of component D is 3 ~ 6%.
9. the disperse dye composition according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 3 ~ 6%,
The weight percent of B component is 12 ~ 37%,
The weight percent of component C is 35 ~ 55%,
The weight percent of component D is 2 ~ 50%.
10. the disperse dye composition according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 51%,
The weight percent of B component is 12 ~ 37%,
The weight percent of component C is 35 ~ 55%,
The weight percent of component E is 2 ~ 6%.
11. disperse dye compositions according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 72%,
The weight percent of B component is 7 ~ 40%,
The weight percent of component C is 20 ~ 48%,
The weight percent of component F is 1 ~ 10%.
12. disperse dye compositions according to any one of Claims 1 to 5, is characterized in that, based on the gross weight of described composition, composed of the following components:
The weight percent of component A is 2 ~ 72%,
The weight percent of B component is 7 ~ 40%,
The weight percent of component C is 20 ~ 48%,
The weight percent of component G is 1 ~ 10%.
13. disperse dye compositions according to any one of claim 1 ~ 12, it is characterized in that, in described component C, the weight percent of the compound shown in described formula (3-1) is 1 ~ 99%, be preferably 70 ~ 90%, the weight percent of the compound shown in described formula (3-2) is 1 ~ 99%, is preferably 10 ~ 30%, based on the weighing scale of described component C.
14. 1 kinds of dispersed dye, is characterized in that, are made up of the disperse dye composition according to any one of claim 1 ~ 13 and auxiliary material.
15. dispersed dye according to claim 14, is characterized in that, described auxiliary material comprises auxiliary agent and water.
16. dispersed dye according to claim 15, it is characterized in that, described auxiliary agent comprises one or more following combination: naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin, sodium sulfate, tensio-active agent, sterilant, or other dye dispersants.
17. dispersed dye according to claim 15 or 16, it is characterized in that, described auxiliary agent is 0.3 ~ 4:1 with the ratio of the weight of disperse dye composition.
18. dispersed dye according to any one of claim 14 ~ 17, it is characterized in that, be aqueous after described dispersed dye sand mill or shredder grinding, solid content is 20 ~ 50%, or be powdery or particulate state after described dispersed dye spraying dry, solid content is 87 ~ 96%.
19. 1 kinds of methods preparing the dispersed dye according to any one of claim 14 ~ 18, is characterized in that, comprise the following steps:
After described each dye component mixing, under the existence of auxiliary material, carry out particlized process with sand mill or shredder; Or described each dye component is carried out particlized process with sand mill or shredder respectively under auxiliary material exists, then mixes.
20. 1 kinds of dispersed dye according to any one of claim 14 ~ 18 are used for the dyeing of fabric and the purposes of stamp.
21. 1 kinds of fabrics, is characterized in that, carry out dyeing and stamp prepares by using dispersed dye according to any one of claim 14 ~ 18.
Priority Applications (8)
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|---|---|---|---|
| CN201710189073.3A CN106928750B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310753365.7A CN104371370B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
| BR112016012058A BR112016012058B8 (en) | 2013-12-30 | 2014-12-30 | Composition of disperse dye and disperse dye |
| EP14876649.6A EP3147333B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| ES14876649.6T ES2653737T3 (en) | 2013-12-30 | 2014-12-30 | Composition of dispersed dye, dispersed dye and method of preparation and use thereof |
| PCT/CN2014/095585 WO2015101290A1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| KR1020167020366A KR101702513B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| US15/102,669 US10151062B2 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
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| CN201310753365.7A CN104371370B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
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Cited By (2)
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| CN105131648A (en) * | 2015-07-03 | 2015-12-09 | 浙江亿得化工有限公司 | Novel composite black disperse dye |
| CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
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| CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106928750B (en) | 2019-11-22 |
| CN104371370B (en) | 2017-02-15 |
| CN106928750A (en) | 2017-07-07 |
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Inventor after: Ruan Jingbo Inventor after: Zhao Guosheng Inventor after: Gu Weidi Inventor after: Ruan Haixing Inventor after: Ye Huaming Inventor after: Jing Xueping Inventor before: Chen Bailong |
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Effective date of registration: 20171018 Address after: Shangyu District of Zhejiang city in Shaoxing Province town road 312368 called mountain Patentee after: Zhejiang Runtu Co., Ltd. Address before: 312368 No. 231 village, Zhenjiang village, Shaoxing, Zhejiang Patentee before: Chen Bailong |