CN100577744C - Black-blue series environment-friendly disperse dyes composition - Google Patents
Black-blue series environment-friendly disperse dyes composition Download PDFInfo
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- CN100577744C CN100577744C CN200810061729A CN200810061729A CN100577744C CN 100577744 C CN100577744 C CN 100577744C CN 200810061729 A CN200810061729 A CN 200810061729A CN 200810061729 A CN200810061729 A CN 200810061729A CN 100577744 C CN100577744 C CN 100577744C
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Abstract
The invention discloses a black and blue-series environmental-friendly disperse dye compound, which has the following components based on weight proportion: 5 to 50 portions of mixture of dye monomers A and dye monomers B, 20 to 50 portions of dye monomers C, 1 to12 portions of dye monomers D and 5 to 50 portions of dye monomers E, and also may comprise 1 to 15 portions of dye monomers F. The dye compound has excellent compatibility, wide application range of pH value in dyeing, high color yield, good level dyeing property and good color fastness; particularly in the aspect of washing fastness, the compound has more prominent advantages and is a black and blue-series environmental-friendly disperse dye compound with excellent comprehensive performances.
Description
Technical field
The dispersion that the present invention relates to a kind of environmental protection is black, the dye composite of blue series, particularly is applicable to terylene and blended fabric dyeing and stamp.
Background technology
In the printing and dyeing of polyester material, piece together mixed that black, blue series dyes is most widely used by C.I.DISP.BLUE 291: 1, C.I.DISP.VIOLET93#, C.I.DISP.ORANGE 76#, but owing to a dyestuff is arranged in its compound dyestuff is that C.I.DISP.ORANGE 76# can cracking produce harmful arylamine under given conditions, it is irritated that human body is produced, classified as the forbidding dyestuff by European Union member countries such as Germany, so can't satisfy the outlet needs of dyeing textile product.Seek the substitute that substitutes this dyestuff, and must satisfy environmental requirement, having preferably with other dyestuff, compatibleness is the difficult problem of the required solution of present printing and dyeing mill.
Summary of the invention
The invention provides a kind of dispersed dye of black, blue series of environmental protection, solved an above-mentioned environmental protection difficult problem, and compatibleness and every fastness are all good, washing fastness aspect is particularly compared with above-mentioned dyestuff and to be significantly improved.
A kind of black, blue serial environment-friendly disperse dye composition in weight part, comprising:
5~50 parts suc as formula the dye monomer A shown in (1-1) with suc as formula the mixture of the dye monomer B shown in (1-2):
20~50 parts suc as formula the dye monomer C shown in (2-1) and/or the formula (2-2):
1~12 part suc as formula the dye monomer D shown in (3-1):
5~50 parts suc as formula the dye monomer E shown in (3-2):
Described disperse dye composition can also comprise 1~15 part suc as formula the dye monomer F shown in (4-1) and/or the formula (4-2):
Help to improve the sublimation fastness of dyestuff, washing fastness.
Preferably counting by weight of described disperse dye composition comprises: the mixture of 25-45 part dye monomer A and B, 25-38 part dye monomer C, 5-10 part dye monomer D, 10-40 part dye monomer E, 3-10 part dye monomer F.
Dye monomer A and dye monomer B are mixture state when producing.
Disperse dye composition of the present invention generally needs to add auxiliary agent during application.Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.Usually, auxiliary agent is 0.8~5: 1 with the ratio of former dyestuff weight.
Disperse dye composition of the present invention can be with the preparation of following method: after the former dyestuff of dye monomer is mixed in proportion, carry out corpusculed with pulverizers such as sand mill or shredders in the presence of auxiliary agent, water or other tensio-active agent, then spraying drying.Above-mentioned dye monomer all can adopt the commercially available prod.
Disperse dye composition of the present invention can be aqueously behind the corpusculed, can be powdery, particulate state after the spraying drying.The compatibleness of this dye composition is fabulous, and wide accommodation, dye yield height, good level-dyeing property, every fastness of pH value are all good when dyeing, especially the advantage of washing fastness aspect is more outstanding, is that a superior environment-friendly type of over-all properties is disperseed dye composite black, blue series.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1~12
According to data shown in the table 1, after dye monomer A, dye monomer B, dye monomer C, dye monomer D, dye monomer E, dye monomer F and condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), sodium lignosulfonate (xylogen 85A, 83A) added water and piece together to mix, grind dispersion with sand milling, carry out spraying drying then.
Wherein dye monomer A and dye monomer B can select the C.I.DISP BLUE 291 that Zhejiang Province Runtu intercalated Co., Ltd produces: 3# for use, C.I.DISP VIOLET 93# and C.I.DISP VIOLET 93:1# that dye monomer C can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the DISPERSE ORANGE 30 200 30:2# that dye monomer D can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the C.I.DISP BLUE 291# that the DISPERSE ORANGE 30 200 288# that dye monomer E can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, dye monomer F can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce.
Table 1
The dye composition that dispersed dye, auxiliary agent, the water that the foregoing description is made makes after mixing carries out performance test, and testing method is as follows:
Respectively get the dispersed dye that 0.5 gram embodiment 1~12 makes, water is mixed with the dispersed dye suspension that concentration is 0.5g/500ml respectively, getting 20ml mixes with the water of 80ml, regulate dye bath pH to 5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness.Measurement result sees Table 2.
Table 2 unit: level
The embodiment title | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
Embodiment 1 | 4-5 | 4-5 | 4-5 |
Embodiment 2 | 5 | 4-5 | 4-5 |
Embodiment 3 | 4-5 | 4-5 | 4-5 |
Embodiment 4 | 5 | 4-5 | 4-5 |
Embodiment 5 | 4-5 | 4-5 | 4-5 |
Embodiment 6 | 5 | 4-5 | 4-5 |
Embodiment 7 | 5 | 4-5 | 4-5 |
Embodiment 8 | 4-5 | 4-5 | 4-5 |
Embodiment 9 | 5 | 4-5 | 4-5 |
Embodiment 10 | 4-5 | 4-5 | 4-5 |
Embodiment 11 | 4-5 | 4-5 | 4-5 |
Embodiment 12 | 4-5 | 4-5 | 4-5 |
Claims (3)
1, a kind of black, blue serial environment-friendly disperse dye composition in weight part, comprising:
5~50 parts suc as formula the dye monomer A shown in (1-1) with suc as formula the mixture of the dye monomer B shown in (1-2):
20~50 parts suc as formula the dye monomer C shown in (2-1) and/or the formula (2-2):
1~12 part suc as formula the dye monomer D shown in (3-1):
5~50 parts suc as formula the dye monomer E shown in (3-2):
2, environment-friendly disperse dye composition as claimed in claim 1, it is characterized in that: comprise 5~50 parts suc as formula the dye monomer A shown in (1-1) with suc as formula the mixture of the dye monomer B shown in (1-2), 20~50 parts one or both are suc as formula the dye monomer C shown in (2-1) and/or the formula (2-2), 1~12 part suc as formula the dye monomer D shown in (3-1), 5~50 parts suc as formula the dye monomer E shown in (3-2), and 1~15 part suc as formula the dye monomer F shown in (4-1) and/or the formula (4-2):
3, disperse dye composition as claimed in claim 2, it is characterized in that: comprise that 25-45 part is suc as formula the dye monomer A shown in (1-1) with suc as formula the mixture of the dye monomer B shown in (1-2), 25-38 part one or both suc as formula the dye monomer C shown in (2-1) and/or the formula (2-2), 5~10 parts suc as formula the dye monomer D shown in (3-1), 10~40 parts suc as formula the dye monomer E shown in (3-2), and 3~10 parts suc as formula the dye monomer F shown in (4-1) and/or the formula (4-2).
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CN200810061729A CN100577744C (en) | 2008-05-16 | 2008-05-16 | Black-blue series environment-friendly disperse dyes composition |
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CN100577744C true CN100577744C (en) | 2010-01-06 |
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Families Citing this family (19)
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CN101798472B (en) * | 2010-03-26 | 2014-01-15 | 浙江闰土股份有限公司 | Black and blue disperse dye composition |
CN101974254B (en) * | 2010-10-26 | 2013-05-15 | 浙江闰土股份有限公司 | Black and blue series disperse dye composition |
CN102153888A (en) * | 2011-02-24 | 2011-08-17 | 浙江万丰化工有限公司 | Disperse dye compound |
CN102344695B (en) * | 2011-11-14 | 2012-07-04 | 浙江闰土股份有限公司 | Composite dye composition, composite disperse dye and preparation method thereof |
CN102344694B (en) * | 2011-11-14 | 2012-07-04 | 浙江闰土股份有限公司 | Composite dye composition, composite disperse dye and preparation method thereof |
CN102653635A (en) * | 2012-03-15 | 2012-09-05 | 江苏之江化工有限公司 | Printing black disperse dyes |
CN103194095B (en) * | 2013-03-29 | 2014-08-13 | 浙江龙盛集团股份有限公司 | Dispersed blue-to-black dye composition |
CN103275512A (en) * | 2013-05-28 | 2013-09-04 | 江苏之江化工有限公司 | Blue monoazo dye |
CN103627207B (en) * | 2013-11-19 | 2015-04-15 | 江苏盛吉化工有限公司 | Deep blue disperse dye mixture |
CN104371369B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye, and preparation method and use thereof |
CN106928749B (en) * | 2013-12-30 | 2019-11-22 | 浙江闰土股份有限公司 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
CN104371359B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye and preparation method and use thereof |
CN104371358B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye and preparation method and use thereof |
CN106928750B (en) * | 2013-12-30 | 2019-11-22 | 浙江闰土股份有限公司 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
CN104371365B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye, and preparation method and use thereof |
CN104371364B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye, and preparation method and use thereof |
CN104371362B (en) * | 2013-12-30 | 2017-04-12 | 陈百龙 | Disperse dye composition and disperse dye, and preparation method and use thereof |
CN105131648A (en) * | 2015-07-03 | 2015-12-09 | 浙江亿得化工有限公司 | Novel composite black disperse dye |
CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
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