CN101812248B - Blue disperse dye composition - Google Patents
Blue disperse dye composition Download PDFInfo
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- CN101812248B CN101812248B CN 201010152479 CN201010152479A CN101812248B CN 101812248 B CN101812248 B CN 101812248B CN 201010152479 CN201010152479 CN 201010152479 CN 201010152479 A CN201010152479 A CN 201010152479A CN 101812248 B CN101812248 B CN 101812248B
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- dye composition
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- 0 CCN(CC)C(C=C1)=CC(*)[C@]1N=Nc(c(C#N)cc([N+]([O-])=O)c1)c1C#N Chemical compound CCN(CC)C(C=C1)=CC(*)[C@]1N=Nc(c(C#N)cc([N+]([O-])=O)c1)c1C#N 0.000 description 3
- KYIVWHLRWARHRW-DQRAZIAOSA-N CN(Cc1ccccc1)c(cc1)ccc1/N=N\c(cc1)ccc1[N+]([O-])=O Chemical compound CN(Cc1ccccc1)c(cc1)ccc1/N=N\c(cc1)ccc1[N+]([O-])=O KYIVWHLRWARHRW-DQRAZIAOSA-N 0.000 description 1
Abstract
The invention discloses a blue disperse dye composition, which comprises the following components in percentage by weight: 28 to 70 percent of a component A which is a compound expressed as a formula (1), 28 to 70 percent of a component B which is one or more of compounds expressed as a formula (2), 0 to 1 percent of a component C which is one or more of compounds expressed as a formula (3), and 0 to 1 percent of a component D which is one or more of compounds expressed as a formula (4). The blue disperse dye composition has the advantages of environment friendliness, beautiful coloured light, high color yield, strong coverage, wide application range of pH value, strong alkali resistance, good rubbing fastness and light fastness, particularly prominent sublimation fastness and washing fastness, low price and strong practicability.
Description
Technical field
The invention belongs to the disperse dye composition preparation field, relate in particular to a kind of environment-friendly type of terylene and blended fabric dyeing and stamp that is applicable to and disperse blue composition.
Background technology
Blue color is one of indispensable coloured light during we live.With regard to dispersed dye, C.I.DISP BLUE 56# be one the most common, one of blue disperse dye of consumption maximum.But C.I.DISP.BLUE 56# sublimation fastness is relatively poor, and " three wastes " that produce when synthetic have greater environmental impacts, and easily are detected EX-SF DISPERSE BLUE EX-SF 300 35# or the EX-SF DISPERSE BLUE EX-SF 300 26# that Oeko-Tex Standard 100 is forbidden.But C.I.DISP.BLUE 56# coloured light is gorgeous, light fastness, alkali resistance are fabulous, level-dyeing property, hiding power are all fine.There are many substitutes to occur in the market, but no matter are the gorgeous degree of coloured light or all other fastness all do not reach requirement.Urgent need is sought an environment-friendly type now, and price comparison is rational, and coloured light is gorgeous, and every performance all can reach the blue disperse dye monochrome or the composition of C.I.DISP BLUE56# index.
Summary of the invention
It is good to the invention provides bright-coloured, the every fastness ability of a kind of coloured light, and environmental protection, economic blue disperse dye composition.
A kind of environment protecting blue disperse dye composition, weight percent consists of:
Component A 28～70%
B component 28～70%
Component C 0～1%
Component D 0～1%;
Described component A is as the formula (1):
Described B component is one or more in the compound as the formula (2):
Wherein, X
1Be cyano group or halogen; R
1Be C
1～C
4Alkyl;
Described component C is one or more in the compound as the formula (3):
Wherein, X
2, X
3, X
4, X
5, X
6Separate is H, NO
2, halogen ,-OSO
2-Ph ,-OR
4,-COOR
5,-COO-(CH
2) n
1-O-(CH
2) n
2-OR
6,-COO-(CH
2) n
3-Ph ,-COO--(CH
2) n
4-COOR
7Or-(CH
2) n
5-COO-Ph, wherein, R
2, R
3, R
4, R
5, R
6, R
7For separate be C
1～C
4Alkyl; n
1, n
2, n
3, n
4, n
5Value is respectively 1～4;
Described component D is one or more in the compound as the formula (4):
Wherein, X
7, X
8Separate is H or halogen; R
8, R
9Be separate C
1～C
4Alkyl, or C
1～C
4Alkyl in a H replaced by cyano group, phenyl ring, acetyl oxygen ethyl or benzoyl oxygen ethyl.
Preferably, the disperse dye composition weight percent consists of:
Component A 30～70%
B component 30～70%;
Or component A 30～69.5%
B component 30～69.5%
Component C 0.5%;
Or component A 30～69.5%
B component 30～69.5%
Component D 0.5%;
Or component A 30～69%
B component 30～69%
Component C and component D total amount 1%.
Add component C or component D, can regulate coloured light, promote the washing fastness of blue disperse dye composition, particularly to washing Buddhist nun's BLENDED FABRIC, washing fastness is obviously promoted.
Compound as the formula (2) can be preferably one of following compounds:
Compound as the formula (3) can be preferably one of following compounds:
Compound as the formula (4) is preferably one of following compounds:
Blue disperse dye composition of the present invention generally needs to add auxiliary agent during application, described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite;
Auxiliary agent is preferably: one or more of naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products;
Auxiliary agent is more preferably: one or more of condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, xylogen 83A).
Usually, auxiliary agent is 2～7.5: 1 with the ratio of the weight of dye composite.
A kind of preparation method of blue disperse dye: after above-claimed cpd mixed by weight percentage, in the presence of auxiliary agent, water or other tensio-active agent, carry out corpusculed with pulverizers such as sand mill or shredders, spraying drying makes dispersed dye then.
Above-mentioned compound all can adopt the commercially available prod.
Blue disperse dye of the present invention can be aqueous, paste behind the corpusculed, can be powdery, particulate state after the spraying drying.
Blue disperse dye of the present invention is an environment-friendly type, coloured light is gorgeous, dye yield is high, opacifying property strong, the scope of application of pH value is extremely wide, alkali resistance is strong, crock fastness, light fastness are all good, particularly sublimation fastness and washing fastness are particularly outstanding, and blue disperse dye composition low price of the present invention, and be practical.
Embodiment
Embodiment 1～18
Respectively according to the feed ratio of table 1, with component A, B component, component C, component D and auxiliary agent (Dispersant MF, dispersing agent NNO, xylogen 85A, xylogen 83A) and water piece together mix after, grind dispersion with sand milling, carry out spraying drying then, make blue disperse dye;
Wherein, the C.I.DISPBLUE 366# that can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce in the compd A;
Wherein, the formula in the compd B (2-1) can be selected the C.I.DISP BLUE 165# that Zhejiang Province Runtu intercalated Co., Ltd produces for use; The C.I.DISP BLUE 183:1# that formula (2-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce;
Wherein, the formula of Compound C (3-1) can be selected the C.I.DISP YELLOW 211# that Zhejiang Province Runtu intercalated Co., Ltd produces for use; The C.I.DISP YELLOW 119# that formula (3-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP YELLOW 114# that formula (3-3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP YELLOW 120# that formula (3-4) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP YELLOW 121# that formula (3-5) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP YELLOW 135# that formula (3-6) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP YELLOW 141# that formula (3-7) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce;
Wherein, the formula in the Compound D (4-1) can be selected the C.I.DISP ORANGE 288# that Zhejiang Province Runtu intercalated Co., Ltd produces for use; The C.I.DISP ORANGE 30:2# that formula (4-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP ORANGE 278# that formula (4-3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce; The C.I.DISP ORANGE 279# that formula (4-4) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce.
Table 1
The performance comparison test:
Blue disperse dye and C.I.DISP BLUE 56# that the foregoing description 1～18 is made carry out the performance comparison test, and testing method is as follows:
According to the GB/T2394-2003 similar methods, respectively get dispersed dye and C.I.DISP BLUE 56# that 0.5 gram embodiment 1～18 makes, water is mixed with the dispersed dye suspension that concentration is 0.5g/500ml respectively, getting 20ml suspension mixes with the water of 80ml, regulate dye bath pH=5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and dye, (pressure is 1.67 * 10 to be warmed up to 130 ℃ in 35 minutes
5Pa～1.76 * 10
5Pa), be incubated 30 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness.Measurement result sees Table 2.By measurement result as can be known, the every firm coefficient of EX-SF DISPERSE BLUE EX-SF 300 composition provided by the present invention is all excellent, especially crock fastness and sublimation fastness.
Table 2
| Blue disperse dye | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
| Embodiment 1 | 4 | 4-5 | 4-5 |
| Embodiment 2 | 4 | 4-5 | 4-5 |
| Embodiment 3 | 4-5 | 4-5 | 4-5 |
| Embodiment 4 | 4-5 | 4-5 | 4-5 |
| Embodiment 5 | 4-5 | 4-5 | 4-5 |
| Embodiment 6 | 4-5 | 4-5 | 4-5 |
| Embodiment 7 | 4-5 | 4-5 | 4-5 |
| Embodiment 8 | 4 | 4-5 | 4-5 |
| Embodiment 9 | 4-5 | 4-5 | 4-5 |
| Embodiment 10 | 4-5 | 4-5 | 4-5 |
| Embodiment 11 | 4-5 | 4-5 | 4-5 |
| Embodiment 12 | 4-5 | 4-5 | 4-5 |
| Embodiment 13 | 4-5 | 4-5 | 4-5 |
| Embodiment 14 | 4-5 | 4-5 | 4-5 |
| Embodiment 15 | 4-5 | 4-5 | 4-5 |
| Embodiment 16 | 4-5 | 4-5 | 4-5 |
| Embodiment 17 | 4-5 | 4-5 | 4-5 |
| Embodiment 18 | 4-5 | 4-5 | 4-5 |
| C.I.DISP BLUE 56# | 4 | 4-5 | 3-4 |
Claims (4)
1. blue disperse dye composition is characterized in that weight percent consists of:
Component A 30～69%
B component 30～69%
Component C and component D total amount 1%;
Described component A is as the formula (1):
Described B component is one or more in the compound as the formula (2):
Wherein, X
1Be cyano group or halogen; R
1Be C
1～C
4Alkyl;
Described component C is one or more in the compound as the formula (3):
Wherein, X
2, X
3, X
4, X
5, X
6Separate is H, NO
2, halogen ,-OSO
2-Ph ,-OR
4,-COOR
5,-COO-(CH
2) n
1-O-(CH
2) n
2-OR
6,-COO-(CH
2) n
3-Ph ,-COO-(CH
2) n
4-COOR
7Or-(CH
2) n
5-COO-Ph, wherein, R
2, R
3, R
4, R
5, R
6, R
7For separate be C
1～C
4Alkyl; n
1, n
2, n
3, n
4, n
5Value is respectively 1～4;
Described component D is one or more in the compound as the formula (4):
Wherein, X
7, X
8Separate is H or halogen; R
8, R
9Be separate C
1～C
4Alkyl, or C
1～C
4Alkyl in a H replaced by cyano group, phenyl ring, acetyl oxygen ethyl, benzoyl oxygen ethyl.
2. blue disperse dye composition according to claim 1 is characterized in that, described compound as the formula (2) is one of following compounds:
3. blue disperse dye composition according to claim 1 is characterized in that, described compound as the formula (3) is one of following compounds:
4. blue disperse dye composition according to claim 1 is characterized in that, described compound as the formula (4) is one of following compounds:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010152479 CN101812248B (en) | 2010-04-21 | 2010-04-21 | Blue disperse dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010152479 CN101812248B (en) | 2010-04-21 | 2010-04-21 | Blue disperse dye composition |
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| Publication Number | Publication Date |
|---|---|
| CN101812248A CN101812248A (en) | 2010-08-25 |
| CN101812248B true CN101812248B (en) | 2013-07-24 |
Family
ID=42619618
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010152479 Active CN101812248B (en) | 2010-04-21 | 2010-04-21 | Blue disperse dye composition |
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| Country | Link |
|---|---|
| CN (1) | CN101812248B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101982511B (en) * | 2010-09-18 | 2013-12-04 | 浙江万丰化工有限公司 | Blue disperse dye complex |
| CN102660143B (en) * | 2012-04-28 | 2015-06-10 | 浙江闰土股份有限公司 | Disperse blue dye composite |
| CN102993778B (en) * | 2012-11-12 | 2014-12-24 | 浙江闰土股份有限公司 | Disperse blue dye composition and disperse blue dye and preparation method and application thereof |
| CN102952417A (en) * | 2012-11-20 | 2013-03-06 | 浙江山川轻纺科技有限公司 | Dye for dyeing and printing of polyester textures and production process thereof |
| CN103881416B (en) * | 2014-03-26 | 2016-06-22 | 杭州福莱蒽特精细化工有限公司 | Dispers ozoic dyestuff compositions, dye preparations and its preparation method and application |
| CN105295440A (en) * | 2015-10-30 | 2016-02-03 | 无锡市长安曙光手套厂 | Disperse dye composition, disperse dye as well as preparation method and application thereof |
| CN105440734B (en) * | 2015-11-04 | 2017-09-12 | 浙江闰土股份有限公司 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN106317959A (en) * | 2016-08-22 | 2017-01-11 | 侯现曦 | Environment-friendly blue disperse dye with excellent color fastness |
| CN109486239B (en) * | 2018-11-12 | 2020-01-03 | 绍兴文理学院 | Disperse dye composition and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4750912A (en) * | 1985-08-24 | 1988-06-14 | Hoechst Aktiengesellschaft | Exhaust method for dyeing fine-denier polyester fibers in dark shades with disperse dye mixtures |
| US4872883A (en) * | 1987-02-02 | 1989-10-10 | Bayer Aktiengesellschaft | Mixtures of monoazo dyestuffs |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101412857A (en) * | 2008-11-26 | 2009-04-22 | 浙江闰土股份有限公司 | Environment-friendly yellow disperse dye composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2956799B2 (en) * | 1991-08-27 | 1999-10-04 | 日本化薬株式会社 | Dye composition and dyeing method using the same |
-
2010
- 2010-04-21 CN CN 201010152479 patent/CN101812248B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4750912A (en) * | 1985-08-24 | 1988-06-14 | Hoechst Aktiengesellschaft | Exhaust method for dyeing fine-denier polyester fibers in dark shades with disperse dye mixtures |
| US4872883A (en) * | 1987-02-02 | 1989-10-10 | Bayer Aktiengesellschaft | Mixtures of monoazo dyestuffs |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101412857A (en) * | 2008-11-26 | 2009-04-22 | 浙江闰土股份有限公司 | Environment-friendly yellow disperse dye composition |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平5-51538A 1993.03.02 |
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| CN101812248A (en) | 2010-08-25 |
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