CN102220031B - Black-and-blue series disperse dye composition - Google Patents
Black-and-blue series disperse dye composition Download PDFInfo
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- CN102220031B CN102220031B CN2011100956670A CN201110095667A CN102220031B CN 102220031 B CN102220031 B CN 102220031B CN 2011100956670 A CN2011100956670 A CN 2011100956670A CN 201110095667 A CN201110095667 A CN 201110095667A CN 102220031 B CN102220031 B CN 102220031B
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- 0 *C([C@](C=C1)N=Nc(c(*)c2)c(*)cc2[N+]([O-])=O)C=C1N(*)* Chemical compound *C([C@](C=C1)N=Nc(c(*)c2)c(*)cc2[N+]([O-])=O)C=C1N(*)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
- C09B67/0082—Preparations of disperse dyes or solvent dyes in liquid form
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a black-and-blue series disperse dye composition, comprising the following components of: 30-85 wt% of Component A, 5-40 wt% of Component B, 9.5-50 wt% of Component C, 0.5-10 wt% of Component D, 0-10 wt% of Component E, and 0-5 wt% of Component F, wherein the Component A contains one or more compounds in Formula (I), the Component B contains one or more compounds in Formula (II), the Component C contains one or more compounds in Formula (III), the Component D is the compound in Formula (IV), the Component E is the compound in Formula (V) and the Component F is the compound in Formula (VI). The black-and-blue series disperse dye composition provided by the invention has advantages of good contaminated resistance for spandex, great compatibleness, high dye uptake, excellent fastness in each aspect such as color fastness to sunlight, rubbing fastness and sublimation fastness when dyeing on polyster/spandex fabrics, and especially great color fastness to washing.
Description
Technical field
The present invention relates to a kind of disperse dye composition, particularly a kind of black blue series disperse dye composition that is applicable to the hydrophobic fibre printing and dyeing.
Background technology
Along with growth in the living standard, people start to pursue the stability of the comfortableness of clothes and form, size, also naturally require fabric that suitable elasticity is arranged.Wash/spandex because of its have excellent rebound performance, soft, wear comfortablely, more and more be subject to people's favor.And the main dispersed dye that adopt of wash/SPANDEX STRETCH FABRIC dyeing, but the General Decentralized dyestuff is heavier to the contamination of spandex, and be to be attached to surface, therefore once washing, be easy to fade, research and development is less or can to dye and have the dispersed dye of fastness preferably on spandex be the research and development problem of the current dyestuff circle most important thing to the spandex contamination.
Summary of the invention
The invention provides a kind of black blue series disperse dye composition of can be washing, dyeing on the ammonia fabric, compare with general black blue serial dispersed dye, have the advantages such as little to the spandex contamination, that sublimation fastness good, and light fastness is good, particularly washing fastness is more excellent.
A kind of black blue series disperse dye composition, by weight percentage, component comprises:
Described component A is one or more in compound shown in formula (I):
In formula (I), X
1for Cl, Br or CN; R
1, R
2, R
3, R
4independent separately is C
1～C
4alkyl; M, n are 1 or 2;
Described B component is one or more in compound shown in formula (II):
In formula (II), X
2for Phenylsulfonic acid ester group, nitro, methoxyl group or
R
5for C
1～C
4alkyl;
Described component C is one or more in compound shown in formula (III)
In formula (III), X
3, X
4independent separately is hydrogen, halogen, cyano group, nitro; R
6for C
1～C
4alkyl; R
7, R
8independent separately is C
1～C
4alkyl ,-CH
2cOOCH
3,-CH
2cOOC
2h
5,-C
2h
4cOOCH
3or-C
2h
4cOOC
2h
5;
Described component D is the compound shown in formula (IV):
Described component E is the compound shown in formula V:
Described component F is the compound shown in formula (VI):
When the dye composite of selecting mainly is comprised of component A, B component, component C and component D, preferably the weight percent of black blue series disperse dye composition composition comprises:
For ease of regulating coloured light, be applicable to the needs of multiple occasion, available dye composite mainly is comprised of component A, B component, component C, component D and component E, now deceives blue series disperse dye composition, and by weight percentage, component comprises:
Same, available dye composite also can be comprised of component A, B component, component C, component D, component E and component F, now deceives blue series disperse dye composition, and by weight percentage, component comprises:
In addition, when the every fastness ability of needs is all more excellent, preferably deceive blue series disperse dye composition, by weight percentage, component comprises:
Consider being easy to get property of raw material and dyeing behavior, described component A is preferably the mixture of one or more in compound shown in formula (I-1) to (I-5):
Described B component is preferably one or more mixtures in compound shown in formula (II-1) to (II-4):
Described component C is preferably one or more mixtures in compound shown in formula (III-1) to (III-5):
Dye composite of the present invention, when reality is used, need to add auxiliary agent, and described auxiliary agent is dispersed dye dispersion agent, diffusant and other tensio-active agents etc. commonly used when composite.Preferred auxiliary agent comprises one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 83A, 85A) etc.The ratio of the weight that the weight that usually, adds auxiliary agent and dye component A～F are total is 0.6～4.5:1.
Can prepare with following methods by black blue series disperse dye composition of the present invention:
By component A, B component and component C and component D, component E, component F, after mixing by said ratio, under existing, auxiliary agent, water or other tensio-active agent carry out the particlized processing with pulverizers such as sand mill or shredders; Also can, by the former dyestuff of component A, B component, component C, component D, component E, component F, under existing, auxiliary agent, water or other tensio-active agent carry out micropartical with pulverizers such as sand mill or shredders respectively, then be mixed by said ratio.
Black blue series disperse dye composition of the present invention, aqueous with can be after sand mill or shredder grinding, can be powdery, particulate state after spraying drying.
Described component A, B component, component C, component D, component E, component F all can adopt commercially available prod.
Black blue series disperse dye composition of the present invention, little to the spandex contamination, compatibleness is splendid, dye uptake is high, be mainly used in the dyeing of wash/spandex, and every fastness excellences such as the sunlight fastness dyeed on wash/spandex fabric, fastness to rubbing, fastness to sublimation, particularly have extraordinary washing fastness, is referred to as " extra-high-speed washing fastness product ".
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to this.
According to the data in table 1, component A, B component, component C, component D, component E, component F, auxiliary agent and water mixture are carried out to grinding distribution with sand mill, then carry out spraying drying.Component A wherein, B component, component C, component D, component E, component F all can adopt the dispersed dye of Zhejiang Province Runtu intercalated Co., Ltd's production or be prepared voluntarily by existing method.
Structural formula (I-1) preparation method is: after 2,4-dinitrobenzene-6-chloroaniline diazotization, then with 2-methoxyl group-5-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
Structural formula (I-2) preparation method is: after 2,4-dinitrobenzene-6-chloroaniline diazotization, then with 2-oxyethyl group-5-acetylaminohydroxyphenylarsonic acid N, the coupling of N-dipropyl acyl-oxygen monomethylaniline forms;
Structural formula (I-3) preparation method is: after 2,4 dinitro 6 bromo aniline diazotization, then with 2-methoxyl group-5-propionamido-N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
Structural formula (I-4) preparation method is: after 2,4 dinitro 6 bromo aniline diazotization, then with 2-methoxyl group-5-acetylaminohydroxyphenylarsonic acid N, the coupling of N-dipropyl acyl-oxygen ethylaniline forms;
Structural formula (I-5) preparation method is: after 2,4 dinitro 6 bromo aniline diazotization, then with 2-methoxyl group-5-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
The DISPERSE YELLOW 119# that structural formula (II-1) can select Zhejiang Province Runtu intercalated Co., Ltd to produce;
The DISPERSE YELLOW 126# that structural formula (II-2) can select Zhejiang Province Runtu intercalated Co., Ltd to produce;
Structural formula (II-3) by P-nethoxyaniline diazotization after, then form with the coupling of N-ethylpyridine ketone;
The DISPERSE YELLOW 114# that structural formula (II-4) can select Zhejiang Province Runtu intercalated Co., Ltd to produce;
Structural formula (III-1) preparation method is: after 2,6-Dichloro-4-nitroaniline diazotization, then with 3-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
Structural formula (III-2) by 2,6-Dichloro-4-nitroaniline diazotization after, then with 3-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diacetyl oxy ethyl aniline forms;
Structural formula (III-3) by 2 cyano 4 nitro aniline diazotization after, then with 3-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
Structural formula (III-4) by 2,4-dinitrobenzene-6-chloroaniline diazotization after, then with 3-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
Structural formula (III-5) by 2,4-dinitraniline diazotization after, then with 3-acetylaminohydroxyphenylarsonic acid N, the coupling of N-diethyl acyl-oxygen monomethylaniline forms;
The Disperse Blue-60 # that structural formula (IV) can select Zhejiang Province Runtu intercalated Co., Ltd to produce;
The structure formula V by 2,6-Dichloro-4-nitroaniline diazotization after, then form with N-methyl-Phenhenzamine coupling;
Structural formula (VI) by 3-amino-5-nitro benzisothiazole diazotization after, then with the 3-hydroxy-n, the coupling of N-dipropyl acyl-oxygen monomethylaniline forms;
Table 1
Performance test
The dye mixture that above-described embodiment 1～15 is made carries out performance test, and testing method is as follows:
The similar method according to GB/T2394-2003, the disperse dye composition that will be made by embodiment 1～15, water is mixed with respectively the dispersed dye suspension that mass percent concentration is 1%, draw 20ml dispersed dye suspension and mix with the water of 80m, with acetic acid, regulate dye bath pH to 5, then be warmed up to 60 ℃, put into respectively wash/spandex of 2g trevira simultaneously and carry out high-temperature pressure dyeing, be warmed up to 130 ℃ in 35 minutes, be incubated 30 minutes, be cooled to 80 ℃ of samplings.
Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T8427-1998, GB/T5718-1997, GB/T3920-1997 to measure its dyefastness, measurement result is in Table 2.
Table 2(unit: level)
As seen from the above table, every fastness that this black blue series disperse dye composition dyes on wash/spandex is all very excellent, and particularly washing fastness is significantly improved.
Claims (8)
1. deceive blue series disperse dye composition for one kind, by weight percentage, component comprises:
Described component A is one or more in compound shown in formula (I):
In formula (I), X
1for Cl, Br or CN; R
1, R
2, R
3, R
4independent separately is C
1～C
4alkyl; M, n are 1 or 2;
Described B component is one or more in compound shown in formula (II):
In formula (II), X
2for Phenylsulfonic acid ester group, nitro, methoxyl group or
R
5for C
1～C
4alkyl;
Described component C is one or more in compound shown in formula (III)
In formula (III), X
3, X
4independent separately is hydrogen, halogen, cyano group, nitro; R
6for C
1～C
4alkyl; R
7, R
8independent separately is C
1～C
4alkyl ,-CH
2cOOCH
3,-CH
2cOOC
2h
5,-C
2h
4cOOCH
3or-C
2h
4cOOC
2h
5;
Described component D is the compound shown in formula (IV):
Described component E is the compound shown in formula V:
2. a black blue series disperse dye composition, is characterized in that, described component comprises:
Described component A is one or more in compound shown in formula (I):
In formula (I), X
1for Cl, Br or CN; R
1, R
2, R
3, R
4independent separately is C
1～C
4alkyl; M, n are 1 or 2;
Described B component is one or more in compound shown in formula (II):
In formula (II), X
2for Phenylsulfonic acid ester group, nitro, methoxyl group or
R
5for C
1～C
4alkyl;
Described component C is one or more in compound shown in formula (III)
In formula (III), X
3, X
4independent separately is hydrogen, halogen, cyano group, nitro; R
6for C
1～C
4alkyl; R
7, R
8independent separately is C
1～C
4alkyl ,-CH
2cOOCH
3,-CH
2cOOC
2h
5,-C
2h
4cOOCH
3or-C
2h
4cOOC
2h
5;
Described component D is the compound shown in formula (IV):
Described component E is the compound shown in formula V:
Described component F is the compound shown in formula (VI):
3. black blue series disperse dye composition according to claim 1 and 2, is characterized in that, described component A is one or more mixtures in compound shown in formula (I-1) to (I-5):
4. black blue series disperse dye composition according to claim 1 and 2, is characterized in that, described B component is one or more mixtures in compound shown in formula (II-1) to (II-4):
5. black blue series disperse dye composition according to claim 1 and 2, is characterized in that, described component C is one or more mixtures in compound shown in formula (III-1) to (III-5):
6. black blue series disperse dye composition according to claim 1, is characterized in that, described black blue series disperse dye composition need to add auxiliary agent while using, and the weight that auxiliary agent adds is 0.6～4.5 times of dye component A～E gross weight.
7. black blue series disperse dye composition according to claim 2, is characterized in that, described black blue series disperse dye composition need to add auxiliary agent while using, and the weight that auxiliary agent adds is 0.6～4.5 times of dye component A～F gross weight.
8. according to the described black blue series disperse dye composition of claim 6 or 7, it is characterized in that, described auxiliary agent comprises one or more in naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100956670A CN102220031B (en) | 2011-04-15 | 2011-04-15 | Black-and-blue series disperse dye composition |
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| CN103421347B (en) * | 2013-09-02 | 2014-08-27 | 杭州福莱蒽特精细化工有限公司 | High washing fastness dispersed dark blue dye composition |
| CN103965651B (en) * | 2014-05-23 | 2016-04-20 | 约克夏染料（中山）有限公司 | A kind of high washing fastness admixture of disperse dyes and application thereof |
| CN104559316A (en) * | 2014-12-18 | 2015-04-29 | 浙江龙盛集团股份有限公司 | High-fastness blue-to-black disperse dye composition and dye product |
| CN106317959A (en) * | 2016-08-22 | 2017-01-11 | 侯现曦 | Environment-friendly blue disperse dye with excellent color fastness |
| CN106833018B (en) * | 2016-12-21 | 2019-09-10 | 杭州吉华江东化工有限公司 | A kind of dispersed black dye mixture and its dye preparations |
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| CN101735663A (en) * | 2009-12-31 | 2010-06-16 | 上虞市金冠化工有限公司 | Composite black disperse dye |
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| CN100412139C (en) * | 2006-08-23 | 2008-08-20 | 浙江龙盛集团股份有限公司 | Dispersion dye composition |
| CN100543087C (en) * | 2007-02-14 | 2009-09-23 | 浙江龙盛染料化工有限公司 | A kind of disperse azo dye composition |
| CN101338081B (en) * | 2008-07-11 | 2011-10-05 | 浙江龙盛集团股份有限公司 | Dispersed deep blue dye composition |
| CN101768375B (en) * | 2009-12-31 | 2014-03-12 | 上虞市金冠化工有限公司 | Black disperse dye composition |
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| CN101735663A (en) * | 2009-12-31 | 2010-06-16 | 上虞市金冠化工有限公司 | Composite black disperse dye |
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