CN101974254B - Black and blue series disperse dye composition - Google Patents
Black and blue series disperse dye composition Download PDFInfo
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- CN101974254B CN101974254B CN 201010519396 CN201010519396A CN101974254B CN 101974254 B CN101974254 B CN 101974254B CN 201010519396 CN201010519396 CN 201010519396 CN 201010519396 A CN201010519396 A CN 201010519396A CN 101974254 B CN101974254 B CN 101974254B
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- disperse dye
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- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 239000000986 disperse dye Substances 0.000 title claims abstract description 27
- 239000000975 dye Substances 0.000 claims abstract description 54
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229910052736 halogen Chemical group 0.000 claims description 10
- 150000002367 halogens Chemical group 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 150000002431 hydrogen Chemical group 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 15
- 230000008878 coupling Effects 0.000 description 13
- 238000010168 coupling process Methods 0.000 description 13
- 238000005859 coupling reaction Methods 0.000 description 13
- 238000006193 diazotization reaction Methods 0.000 description 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000002270 dispersing agent Substances 0.000 description 7
- ROPYWXVRNREIQD-UHFFFAOYSA-N 2-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCC#N)CCOC(=O)C)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl ROPYWXVRNREIQD-UHFFFAOYSA-N 0.000 description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- CULIYQPRUGMRRT-UHFFFAOYSA-N 2-chloro-n-[2-[(2-cyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound ClCC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1C#N CULIYQPRUGMRRT-UHFFFAOYSA-N 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LXQOQPGNCGEELI-UHFFFAOYSA-N 2,4-dinitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O LXQOQPGNCGEELI-UHFFFAOYSA-N 0.000 description 1
- AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical compound NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 1
- PNPCRKVUWYDDST-UHFFFAOYSA-N 3-chloroaniline Chemical compound NC1=CC=CC(Cl)=C1 PNPCRKVUWYDDST-UHFFFAOYSA-N 0.000 description 1
- PBGKNXWGYQPUJK-UHFFFAOYSA-N 4-chloro-2-nitroaniline Chemical compound NC1=CC=C(Cl)C=C1[N+]([O-])=O PBGKNXWGYQPUJK-UHFFFAOYSA-N 0.000 description 1
- QSNSCYSYFYORTR-UHFFFAOYSA-N 4-chloroaniline Chemical compound NC1=CC=C(Cl)C=C1 QSNSCYSYFYORTR-UHFFFAOYSA-N 0.000 description 1
- SRDOTWUOTQTGAK-UHFFFAOYSA-N C=O.C1(=CC=CC2=CC=CC=C12)S(=O)(=O)OCC1=CC=CC=C1 Chemical compound C=O.C1(=CC=CC2=CC=CC=C12)S(=O)(=O)OCC1=CC=CC=C1 SRDOTWUOTQTGAK-UHFFFAOYSA-N 0.000 description 1
- 0 CC([C@](C=C1*)N=Cc(c(N=O)c2)c(*)cc2N)C=C1N Chemical compound CC([C@](C=C1*)N=Cc(c(N=O)c2)c(*)cc2N)C=C1N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- JLXXLCJERIYMQG-UHFFFAOYSA-N phenylcyanamide Chemical group N#CNC1=CC=CC=C1 JLXXLCJERIYMQG-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Coloring (AREA)
Abstract
The invention discloses a black and blue series disperse dye composition which contains at least one dye monomer A shown as formula (I) and at least one dye monomer B shown as formula (II). The disperse dye composition of the invention has the advantages of extremely good compatibility, wide application range of the pH value while dyeing, strong deep dyeing property, high color yield, good fastness, low production cost, low price and high environmental protection performance, thus being the disperse dye composition with excellent comprehensive properties, wherein, formula (I) and formula (II) are shown in description.
Description
Technical field
The present invention relates to a kind of black blue series disperse dye composition, especially a kind of environment-friendly type is deceived blue series disperse dye composition, is specially adapted to dyeing and the stamp of terylene and BLENDED FABRIC thereof.
Background technology
In the printing and dyeing of polyester material, the black blue series of dispersed dye is to use one of wider dyestuff.The serial dispersed dye of black indigo plant of environment-friendly type are generally by EX-SF DISPERSE BLUE EX-SF 300 291:1,63 DISPERSE Violet 63 93#, DISPERSE ORANGE 30 200 76# or formed by EX-SF DISPERSE BLUE EX-SF 300 291#, 63 DISPERSE Violet 63 93:1, DISPERSE ORANGE 30 200 288# blending in the market.But DISPERSE ORANGE 30 200 76# under given conditions can cracking and produce harmful arylamine, human body is produced irritated, is classified as the forbidding dyestuff by European Union member countries such as Germany.
Although DISPERSE ORANGE 30 200 288# is the environmental protection dyestuff, it remains further to be improved at compatibleness, depth, the aspect such as opacifying property, and particularly the third of the twelve Earthly Branches, look more serious, is subject to certain limitation to the printing and dyeing of the higher high-grade import trevira of look requirement in the third of the twelve Earthly Branches time.Therefore, dyeing is badly in need of seeking an environment-friendly type, high-performance, is deceived blue series disperse dye composition cheaply, to satisfy the needs of outlet.
Summary of the invention
The invention provides a kind of black blue series disperse dye composition, solved a difficult problem of being brought by DISPERSE ORANGE 30 200 76# and DISPERSE ORANGE 30 200 288#.Composition of the present invention when dyeing the pH value applied widely, depth is strong, dye yield is high, every fastness is all good.
A kind of black blue series disperse dye composition contains at least a suc as formula the dye monomer A shown in (I) and at least a suc as formula the dye monomer B shown in (II);
Wherein, formula (I) is:
In formula, X is cyano group or halogen; R
1Be hydrogen or C
1～C
4Alkoxyl group; R
2Be C
1～C
4Alkyl; R
3, R
4Independent separately is hydrogen, C
1～C
4Alkyl, C
2～C
4Alkenyl or C
1～C
4Alkyl on a hydrogen quilt-OH ,-CN ,-OCOR
5,-OCOOR
5,-COOR
5,-C
6H
5,-OC
6H
5Or C
1～C
4Alkoxyl group replaces, R
5Be hydrogen or C
1～C
4Alkyl.
Formula (II):
X in formula
1, X
2, X
3Separately independent be H ,-CN ,-NO
2, halogen or C
1～C
4Alkyl, and work as X
1For-NO
2, X
2During for H, X
3For-CN ,-NO
2Or C
1～C
4Alkyl; X
4For H ,-CN, halogen, C
1～C
4Alkyl or C
1～C
4Alkoxyl group; R
6Be C
1～C
4Alkyl, C
2～C
4Alkenyl, or C
1～C
4Alkyl a hydrogen quilt-CN ,-COOR
8,-OCOR
8,-OCOOR
8Or C
1～C
4Alkoxyl group replace, R wherein
8Be C
1～C
4Alkyl; R
7Be H or C
1～C
4Alkyl, n is 1 or 2.
In production, selecting formula (I) dye monomer is weight 50%～85%, and the dye monomer of formula (II) is weight 15%～50%.
Preferably, described black blue series disperse dye composition contains at least a suc as formula the dye monomer A shown in (I) and at least a suc as formula the dye monomer B shown in (II) and suc as formula the dye monomer C shown in (III):
Wherein: X is-CN, Br, Cl, R1 is C
1～C
4Alkoxyl group, R
2Be C
1～C
4Alkyl, R
3, R
4Independent separately is C
1～C
4Alkyl ,-CH
2CH=CH
2,-CH
2CH
2OCOCH
3,
Wherein: X
1, X
2, X
3Separately independent be H ,-CN ,-NO
2, halogen or C
1～C
4Alkyl and X
1For-NO
2, X
2During for H, X
3Be not H or halogen; X
1, X
2, X
3Be not H simultaneously;
Wherein: Y is Br or Cl.
The dye monomer B of through type (II) adds separately, and the crock fastness after dye composite is used is excellent especially; Adding of the dye monomer of through type (III) can be regulated coloured light, satisfies the requirement of different occasions.
In production, selecting formula (I) dye monomer is weight 27%～66%, and the dye monomer of formula (II) is weight 14%～40%, and the dye monomer of formula (III) is weight 20%～43%.
More preferred, described (I) formula dye monomer is one or more of following compounds:
Described (II) formula dye monomer is one or more of following compounds:
Dye monomer A and dye monomer B are mixture state when producing.
Disperse dye composition of the present invention generally need to add auxiliary agent to disperse during application.Described auxiliary agent is dispersed dye dispersion agent commonly used, diffusants etc. when composite, is preferably one of following or any one mixture wherein: the anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl sulfonic formaldehyde condensation compound, sulfonated lignin.
More preferred, described auxiliary agent is one of following or any one mixture wherein: dispersing agent NNO (sodium methylene bis-naphthalene sulfonate), Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl naphthalenesulfonate formaldehyde condensation compound), sodium lignosulfonate (as commercial dispersants Reax83A, Reax 85A) etc.Usually, auxiliary agent and dye monomer weight and ratio be 0.8～5: 1.
Disperse dye composition of the present invention can prepare by the following method: after the former dyestuff of dye monomer is mixed by a certain percentage, under existing, auxiliary agent, water or other tensio-active agent carry out particlized with pulverizers such as sand mill or shredders, then spraying drying.Above-mentioned dye monomer all can adopt commercially available prod or preparation voluntarily.
Black blue series disperse dye composition of the present invention can be aqueously after corpusculed, can be powdery, particulate state after spraying drying.Disperse dye composition compatibleness of the present invention is fabulous, when dyeing the pH value applied widely, depth is strong, dye yield is high, every fastness is all good, and low, the low price that manufactures a finished product, environmental-protecting performance is high, is a black blue series disperse dye composition that over-all properties is superior.
Embodiment
The invention will be further described below in conjunction with implementation column, but protection scope of the present invention is not limited to this.
Embodiment 1～18
According to data shown in table 1, with dye monomer A, dye monomer B and condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), sodium lignosulfonate (xylogen 83A, 85A), after adding the water blending, carry out grinding distribution, then spraying drying with sand mill.
Dye monomer wherein all can adopt commercially available prod or preparation voluntarily.
The EX-SF DISPERSE BLUE EX-SF 300 291:1 that structural formula (I-1) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The EX-SF DISPERSE BLUE EX-SF 300 291:2 that structural formula (I-2) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The EX-SF DISPERSE BLUE EX-SF 300 291# that structural formula (I-3) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The EX-SF DISPERSE BLUE EX-SF 300 modification 291# that structural formula (I-4) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The Disperse Blue-79 that structural formula (I-5) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce: 1;
The Disperse Blue-79 # that structural formula (I-6) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The Disperse Blue-79 that structural formula (I-7) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce: 2;
The EX-SF DISPERSE BLUE EX-SF 300 165:1 that structural formula (I-8) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The 63 DISPERSE Violet 63 93# that structural formula (I-9) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The 63 DISPERSE Violet 63 93:1 that structural formula (I-10) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The EX-SF DISPERSE BLUE EX-SF 300 316:1 that structural formula (I-11) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The EX-SF DISPERSE BLUE EX-SF 300 291:4 that structural formula (I-12) can adopt Zhejiang Province Runtu intercalated Co., Ltd to produce;
The preparation method of structural formula (II-1) is: after adjacent cyano-aniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-2) is: after 2-nitro-4-chloroaniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-3) is: after 3-chloroaniline diazotization, then form with 3-methyl-N-ethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-4) is: after 2-N-methyl-p-nitroaniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-5) is: after 2-cyano group-4-dinitraniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-6) is: after 3-N-methyl-p-nitroaniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-7) is: after 2-chloroaniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-8) is: after 2,4-dinitraniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-9) is: after aniline diazotization, then form with N-cyanoethyl-Phenhenzamine coupling;
The preparation method of structural formula (II-10) is: after 3-N-methyl-p-nitroaniline diazotization, then form with 3-oxyethyl group-N-propenyl-Phenhenzamine coupling;
The preparation method of structural formula (II-11) is: after 2-N-methyl-p-nitroaniline diazotization, then form with 3-methyl-N-ethyl-N-styroyl aniline coupling;
The preparation method of structural formula (II-12) is: after 4-chloroaniline diazotization, then form with N-methyl-Phenhenzamine coupling;
The preparation method of structural formula (II-13) is: after aniline diazotization, then form with N-methyl-Phenhenzamine coupling.
Table 1
Annotate: all added the dye monomer of formula (III) in embodiment, wherein embodiment 1,2,3,5,9,10,12,16 has added preferably the dye monomer suc as formula (II).
Performance test
The dye mixture that above-described embodiment 1～18 is made carries out performance test, and testing method is as follows:
According to the similar method of GB/T2394-2003, respectively get the dispersed dye that 0.5 gram embodiment 1～18 makes, water is mixed with respectively the dispersed dye suspension that concentration is 0.5g/500ml, get 20ml and mix with the water of 80ml, regulate dye bath pH to 5 with acetic acid, then be warmed up to 60 ℃, put into respectively simultaneously 2 gram trevira and carry out high-temperature pressure dyeing, be warmed up to 130 ℃ in 35 minutes, be incubated 30 minutes, be cooled to 80 ℃ of samplings.
Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness, measurement result sees Table 2.
Table 2
By the test result of table 2 as can be known, dye composite dyeing compatibleness of the present invention is splendid, and every fastness such as light fastness, crock fastness, sublimation fastness, washing fastness are all excellent.Have wide market outlook.
Claims (7)
1. a black blue series disperse dye composition, contain at least a suc as formula the dye monomer A shown in (I) and at least a suc as formula the dye monomer B shown in (II);
Wherein, formula (I) is:
In formula, X is cyano group or halogen; R
1Be hydrogen or C
1～C
4Alkoxyl group; R
2Be C
1～C
4Alkyl; R
3, R
4Independent separately is hydrogen, C
1～C
4Alkyl, C
2～C
4Alkenyl or C
1～C
4Alkyl on a hydrogen quilt-OH ,-CN ,-OCOR
5,-OCOOR
5,-COOR
5,-C
6H
5,-OC
6H
5Or C
1～C
4Alkoxyl group replaces, R
5Be hydrogen or C
1～C
4Alkyl;
Formula (II) is:
X in formula
1, X
2, X
3Separately independent be H ,-CN ,-NO
2, halogen or C
1～C
4Alkyl, and work as X
1For-NO
2, X
2During for H, X
3For-CN ,-NO
2Or C
1～C
4Alkyl; X
4For H ,-CN, halogen, C
1～C
4Alkyl or C
1～C
4Alkoxyl group; R
6Be C
1～C
4Alkyl, C
2～C
4Alkenyl or C
1～C
4Alkyl a hydrogen quilt-CN ,-COOR
8,-OCOR
8,-OCOOR
8Or C
1～C
4Alkoxyl group replace, R wherein
8Be C
1～C
4Alkyl; R
7Be H or C
1～C
4Alkyl, n is 1 or 2.
2. black blue series disperse dye composition according to claim 1, it is characterized in that: described black blue series disperse dye composition contains at least a suc as formula the dye monomer A shown in (I) and at least a suc as formula the dye monomer B shown in (II) and at least a suc as formula the dye monomer C shown in (III):
Wherein: X is-CN, Br or Cl, R
1Be C
1～C
4Alkoxyl group, R
2Be C
1～C
4Alkyl, R
3, R
4Independent separately is C
1～C
4Alkyl ,-CH
2CH=CH
2,-CH
2CH
2OCOCH
3,
Wherein: X
1, X
2, X
3Separately independent be H ,-CN ,-NO
2, halogen or C
1～C
4Alkyl and X
1For-NO
2, X
2During for H, X
3Be not H or halogen; X
1, X
2, X
3Be not H simultaneously;
Wherein: Y is Br or Cl.
3. black blue series disperse dye composition according to claim 1, it is characterized in that: described (I) formula dye monomer is one or more of following compounds:
4. black blue series disperse dye composition according to claim 1, it is characterized in that: described (II) formula dye monomer is one or more of following compounds:
5. black blue series disperse dye composition according to claim 1, it is characterized in that: it is weight 50%～85% that described black blue series disperse dye composition is selected formula (I) dye monomer, and the dye monomer of formula (II) is weight 15%～50%.
6. black blue series disperse dye composition according to claim 2, it is characterized in that: it is weight 27%～66% that described black blue series disperse dye composition is selected formula (I) dye monomer, the dye monomer of formula (II) is weight 14%～40%, and the dye monomer of formula (III) is weight 20%～43%.
7. the described black blue series disperse dye composition of according to claim 1～6 arbitrary claims, it is characterized in that: in described black blue series disperse dye composition, dye monomer with the ratio of auxiliary agent weight is: 1: 0.8～5.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010519396 CN101974254B (en) | 2010-10-26 | 2010-10-26 | Black and blue series disperse dye composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010519396 CN101974254B (en) | 2010-10-26 | 2010-10-26 | Black and blue series disperse dye composition |
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| Publication Number | Publication Date |
|---|---|
| CN101974254A CN101974254A (en) | 2011-02-16 |
| CN101974254B true CN101974254B (en) | 2013-05-15 |
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ID=43574166
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|---|---|---|---|
| CN 201010519396 Expired - Fee Related CN101974254B (en) | 2010-10-26 | 2010-10-26 | Black and blue series disperse dye composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153888A (en) * | 2011-02-24 | 2011-08-17 | 浙江万丰化工有限公司 | Disperse dye compound |
| CN102344694B (en) * | 2011-11-14 | 2012-07-04 | 浙江闰土股份有限公司 | Composite dye composition, composite disperse dye and preparation method thereof |
| CN102344695B (en) * | 2011-11-14 | 2012-07-04 | 浙江闰土股份有限公司 | Composite dye composition, composite disperse dye and preparation method thereof |
| CN102660145B (en) * | 2012-04-28 | 2014-06-25 | 浙江万丰化工有限公司 | Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof |
| CN102702790B (en) * | 2012-06-07 | 2014-06-18 | 江苏之江化工有限公司 | Disperse black azo dye mixture |
| CN102775809B (en) * | 2012-08-09 | 2014-07-02 | 江苏之江化工有限公司 | Cyano-containing azo disperse dye |
| CN103275512A (en) * | 2013-05-28 | 2013-09-04 | 江苏之江化工有限公司 | Blue monoazo dye |
| CN111500088B (en) * | 2020-04-24 | 2021-08-17 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
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| CN1887971A (en) * | 2006-07-12 | 2007-01-03 | 浙江龙盛集团股份有限公司 | Composite disperse dye |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101307191A (en) * | 2008-06-28 | 2008-11-19 | 浙江龙盛集团股份有限公司 | Disperse dye composition and disperse dye |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1887971A (en) * | 2006-07-12 | 2007-01-03 | 浙江龙盛集团股份有限公司 | Composite disperse dye |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101307191A (en) * | 2008-06-28 | 2008-11-19 | 浙江龙盛集团股份有限公司 | Disperse dye composition and disperse dye |
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