CN104371369B - Disperse dye composition and disperse dye, and preparation method and use thereof - Google Patents
Disperse dye composition and disperse dye, and preparation method and use thereof Download PDFInfo
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- CN104371369B CN104371369B CN201310751841.1A CN201310751841A CN104371369B CN 104371369 B CN104371369 B CN 104371369B CN 201310751841 A CN201310751841 A CN 201310751841A CN 104371369 B CN104371369 B CN 104371369B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a disperse dye composition and a disperse dye, and a preparation method and use thereof, and the disperse dye is suitable for dyeing and printing of fabrics, especially polyester and blended fabrics thereof.
Description
Technical field
The present invention relates to a kind of disperse dye composition, disperse dyes and its preparation method and purposes.Described dispersion dye
Material is applied to dyeing and the stamp of fabric, particularly terylene and its blend fabric.
Background technology
With the pay attention to day by day to environmental protection for the people, particularly some European countries have put into effect some regulations, policy etc. in succession.
Likewise, in recent years, China it is also proposed higher requirement to environmental protection, and some polluted enterprises are carried out with control, dyestuff enterprise
How to try to achieve survival and development, be that pendulum is maximum in face of dye manufacturers, and be the difficult problem needing most urgently to solve.
Content of the invention
A kind of pH value range of present invention offer is wide, light fastness is good, compatibility is excellent, intensity is high, washing fastness is good, Benzene Chloride
Phenol content meets Oeko-Tex Standard100（2013）The economic and environment-friendly type disperse dyes that I level requires.
The present invention provides a kind of disperse dye composition it is characterised in that including：
As formula（1）Shown component A：
As formula（2）Shown component B：
（C.I. disperse violet 93）
As formula（3）Shown component C：
（C.I. disperse blue 291:1）
Optional one or more are as formula（4）Shown component D：
Formula（4）In, X1、X2Each stand alone as hydrogen or bromine, R1、R2Each stand alone as C2～C4Alkyl, or C1～C4In alkyl
The group that replaced by cyano group, phenyl, acetoxyl group or benzoyloxy of a hydrogen；
Optional one or more are as formula（5）Shown component E：
Formula（5）In, X3、X4Each stand alone as hydrogen, chlorine or nitro, R3For C1～C4Alkyl；
Optional one or more are as formula（6）Shown component F：
Formula（6）In, X5、X6Each stand alone as cyano group, bromine or nitro, R4For hydrogen or C1～C4Alkoxyl, R7For C1～C4's
Alkyl amido or C1～C4Alkyl, R5、R6Each stand alone as C1～C4Alkyl；
Optional as formula（7）Shown component G：
（Disperse blue 2BLM）.
According to disperse dye composition of the present invention it is preferable that described component D be one of following compound or
Two or more：
（Disperse orange 288）
（C.I. disperse orange 73）
（C.I. disperse orange 61）
（C.I. disperse orange 25）
（C.I. disperse orange 33）.
According to disperse dye composition of the present invention it is preferable that described component E be one of following compound or
Two or more：
（C.I. disperse yellow 119）
（C.I. DISPERSE Yellow 211）.
According to disperse dye composition of the present invention it is preferable that described component F be one of following compound or
Two or more：
（C.I. disperse blue 165:1）
（C.I. disperse blue 366）
（C.I. disperse blue 165）
（C.I. disperse blue 291）.
Based on the gross weight of described disperse dye composition, the percentage by weight of component A is 2-73%, preferably 2-72%,
Or preferably 2-60%, or preferably 2-51%, or preferably 3-50%, or preferably 3-6%.The percentage by weight of component B is 7-
40%, preferably 7-37%, or preferably 12-39%, or preferably 12-37%.The percentage by weight of component C is 20-58%, preferably
For 38-58%, or preferably 20-48%, or preferably 30-55%, or preferably 35-55%.The percentage by weight of component D is 0-
70%, preferably 2-50%, or preferably 3-6%.The percentage by weight of component E is 0-10%, preferably 2-6%.The weight of component F
Percentage ratio is 0-47%, preferably 1-10%.The percentage by weight of component G is 0-47%, preferably 1-10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, including：
Percentage by weight is 2～73% component A,
Percentage by weight is 7～40% component B,
Percentage by weight is 20～58% component C,
Optional percentage by weight is 0～70% component D,
Optional percentage by weight is 0～10% component E,
Optional percentage by weight is 0～47% component F, and
Optional percentage by weight is 0～47% component G.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 3～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 3～6%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component D is 2～50%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
In actual production process, each dye component of the present invention generally may be miscellaneous with some by-products and other
Matter, as long as do not affect the enforcement of the present invention.
The present invention also provides a kind of disperse dyes it is characterised in that comprising to combine according to disperse dyes of the present invention
Thing and adjuvant.
According to disperse dyes of the present invention it is preferable that described adjuvant includes auxiliary agent and water.
According to disperse dyes of the present invention it is preferable that described auxiliary agent includes one or more following group
Close：Naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulfate, surfactant, antibacterial, or other dye dispersants.
According to disperse dyes of the present invention it is preferable that described auxiliary agent with the weight ratio of disperse dye composition is
0.3～4:1.
The present invention a kind of method prepared according to disperse dyes of the present invention is also provided it is characterised in that include with
Lower step：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；
Or described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed
Close.
Disperse dyes of the present invention, can be liquid after being ground with sand mill or grinder（Generally solid content be 20～
50%）, can be powdery or graininess after spray drying（Generally solid content is 87～96%）.
The present invention also provide a kind of according to disperse dyes of the present invention be used for the dyeing of fabric and the purposes of stamp.
The present invention also provides a kind of fabric it is characterised in that by using carrying out according to disperse dyes of the present invention
Dyeing and stamp prepare.
The light fastness of disperse dyes of the present invention is excellent, pH value is applied widely, the compatibility between each component is good,
Intensity is high, low cost of printing and dyeing, and washing fastness is good, and chlorinated phenol content meets Oeko-TexStandard100（2013）I level will
Ask.
Specific embodiment
Embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
In an embodiment, component A, B of the present invention, C and optional component D, E, F, G, by certain proportioning and auxiliary agent and
After water blending, it is ground dispersion with sand mill and makes slurry, or be spray-dried further, thus making dyestuff.
Described component A, B, C, D, E, F, G are known dye composition and can commercially buy, or can
Prepared by existing method.
Embodiment 1：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2）Dye component, 43 grams of formulas（3）Dye component, 80 grams of Dispersant MFs
With 80 grams of lignin 85A, add water 390 grams and stir, grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, and dyeing obtains each
The excellent black polyester of item fastness ability.
Comparative example 1：
Repeat embodiment 1, except by the formula of embodiment 1（1）Dye component is substituted for following formula（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 1 and comparative example 1 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and their intensity, washing fastness measured using GB/T6688-2008, GB/T3921-2008,
Measurement result is shown in Table 1.
Table 1
| Title | Intensity | Washing fastness |
| Embodiment 1 | 102% | 5 |
| Comparative example 1 | 100% | 4～5 |
Intensity is high can to reduce dye dosage it is meant that the textile of same depth during printing and dyeing, reduce printing and dyeing cost.
Embodiment 2：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2）Dye component, 43 grams of formulas（3）Dye component, 80 grams of Dispersant MFs
With 80 grams of lignin 83A, add water 390 grams and stir, grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, and dyeing obtains each
The excellent black polyester of item fastness ability.
Comparative example 2：
Repeat embodiment 2, except by the formula of embodiment 2（1）Dye component is substituted for following formula（9）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 2 and comparative example 2 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the light fastness that they are measured using AATCC16-2004, the results are shown in Table 2.
Table 2
| Title | Light fastness（40h） |
| Embodiment 2 | 2～3 |
| Comparative example 2 | 2 |
Embodiment 3：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2）Dye component, 43 grams of formulas（3）Dye component and 30 grams of dispersants
MF, adds water 200 grams and stirs, and grinding distribution makes pulp material finished product, and dyeing obtains excellent black of every fastness ability
Color polyester.
Comparative example 3：
Repeat embodiment 3, except by the formula of embodiment 3（1）Dye component replaces an accepted way of doing sth（4-1）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 3 and comparative example 3 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, and survey with reference to GB/T2400-2006
Determine their intensity, light fastness and compatibility, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibility |
| Embodiment 3 | 105% | 2～3 | Ⅱ |
| Comparative example 3 | 100% | 2 | Ⅲ |
Measure compatibility method be：Dyeed with reference to GB/T2394-2003, entered dye from 60 DEG C, when temperature is raised to 80
DEG C when horse back take a sample, take a sample every 10 DEG C later, until 130 DEG C, and, 130 DEG C be incubated 10 minutes, 20 points
Clock, 30 minutes, 50 minutes when separately sampled, take 10 pieces of cloth specimens altogether.It is incubated 50 minutes with 130 DEG C as standard specimen, each shelves temperature is taken
Cloth specimen is sample, whether synchronous observes its foxy.The Pyatyi system of being divided into I, II, III, IV, V（Instrument：Computer color testing instrument
Datacolor600, colour difference formula CMC2：1）.For black hues, calculate DC（Gorgeous degree is poor）、DH（Hue difference）It is respectively less than 0.6
Cloth specimen block number.
I grade：Five pieces and more than five pieces
II grade：Four pieces
III grade：Three pieces
IV grade：Two pieces
V grade：One piece.
Embodiment 4：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2）Dye component, 43 grams of formulas（3）Dye component, 30 grams of Dispersant MFs
With 30 grams of dispersing agent NNOs, add water 250 grams and stir, grinding distribution makes pulp material finished product, dyeing obtains every fastness
The black polyester of function admirable.
Comparative example 4：
Repeat embodiment 4, except by the formula of embodiment 4（1）Dye component is substituted for following formula（10）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 4 and comparative example 4 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 4.
Table 4
| Title | Intensity | PH stable scope |
| Embodiment 4 | 107% | 3～9 |
| Comparative example 4 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 5：
By 44 grams of formulas（1）Dye component, 22 grams of formulas（2）Dye component, 34 grams of formulas（3）Dye component, 31 grams of Dispersant MFs
With 31 grams of dispersing agent NNOs, add water 200 grams and stir, grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, and dyeing obtains each
The excellent black polyester of item fastness ability.
Comparative example 5：
Repeat embodiment 5, except by 44 grams of formulas in embodiment 5（1）Dye component is substituted for 41.4 grams of formulas（10）Dyestuff
Component and 2.6 grams of formulas（11）Outside dye component, other constant.
The dyestuff finished product of embodiment 5 and comparative example 5 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 5 and comparative example 5 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 5.
Table 5
| Title | Intensity | PH stable scope |
| Embodiment 5 | 107% | 3～9 |
| Comparative example 5 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 6：
By 7.8 grams of formulas（1）Dye component, 7.8 grams of formulas（4-1）Dye component, 6.0 grams of formulas（2）Dye component, 16.4 grams of formulas
（3）Dye component, 31 grams of dispersing agent MFs and 31 grams of lignin 85A, add water 200 grams and stir, and grinding distribution is simultaneously dried,
Obtain final product dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 6：
Repeat embodiment 6, except by the formula in embodiment 6（1）Dye component replaces an accepted way of doing sth（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 6 and comparative example 6 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and their intensity, washing fastness measured using GB/T6688-2008, GB/T3921-2008,
The results are shown in Table 6.
Table 6
| Title | Intensity | Washing fastness |
| Embodiment 6 | 102% | 5 |
| Comparative example 6 | 100% | 4～5 |
Embodiment 7：
By 9.5 grams of formulas（1）Dye component, 36.5 grams of formulas（2）Dye component, 54 grams of formulas（3）Dye component, 80 grams of dispersants
MF and 80 gram of lignin 83A, adds water 390 grams and stirs, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, dyeing obtains
The excellent blue polyester of every fastness ability.
Comparative example 7：
Repeat embodiment 7, except by the formula in embodiment 7（3）Dye component is substituted for following formula（12）Outside dye component,
Other constant.
The dyestuff finished product of embodiment 7 and comparative example 7 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 7 and comparative example 7 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and measure their washing fastness, chlorine using GB/T3921-2008, GB/T18414.1-2006
Phenol content, the results are shown in Table 7.
Table 7
| Title | Washing fastness | Chlorophenol content |
| Embodiment 7 | 5 | ＜ 0.05 |
| Comparative example 7 | 4～5 | ＞ 0.05 |
Embodiment 8：
By 12 grams of formulas（1）Dye component, 34 grams of formulas（2）Dye component, 54 grams of formulas（3）Dye component, 80 grams of Dispersant MFs
With 80 grams of lignin 83A, add water 390 grams and stir, grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, and dyeing obtains each
The excellent blue polyester of item fastness ability.
Comparative example 8：
Repeat embodiment 8, except by 54 grams of formulas in embodiment 8（3）Dye component is substituted for 27 grams of formulas（12）Dye set
Divide and 27 grams of formulas（3）Outside the mixture of dye component, other constant.
The dyestuff finished product of embodiment 8 and comparative example 8 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 8 and comparative example 8 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and using GB/T3921-2008, GB/T18414.1-2006, measure they washing fastness,
Chlorophenol content, the results are shown in Table 8.
Table 8
| Title | Washing fastness | Chlorophenol content |
| Embodiment 8 | 5 | ＜ 0.05 |
| Comparative example 8 | 4-5 | ＞ 0.05 |
Embodiment 9-10
According to the formula in table 9, the method according to embodiment 8 makes dyestuff finished product.
Table 9 unit：Gram
The dyestuff finished product of embodiment 9 and 10 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 9 and 10 respectively to 250ml
Water in, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and using GB/T3921-2008, the method for embodiment 3 and GB/T18414.1-2006, measure
Their washing fastness, compatibility, chlorophenol content, the results are shown in Table 10.
Table 10
| Embodiment | Washing fastness | Compatibility | Chlorophenol content |
| 9 | 5 | Ⅱ | ＜ 0.05 |
| 10 | 5 | Ⅱ | ＜ 0.05 |
Embodiment 11
According to the formula in table 11, the method according to embodiment 8 makes dyestuff finished product.
Table 11 unit：Gram
The dyestuff finished product of embodiment 11 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, the dyestuff finished product weighing 0.5 gram of embodiment 11 to the water of 250ml,
Make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjust dye bath pH to 5 with acetic acid,
Then it is warmed up to 60 DEG C, be respectively put into 2g polyester fiber simultaneously and carry out high-temperature pressure dyeing, be warmed up to 130 DEG C in 35 minutes,
Insulation 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, GB/T3921-2008, GB/T18414.1-2006, measure it
Light fastness, washing fastness, chlorophenol content, the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Washing fastness | Chlorophenol content |
| 11 | 3 | 5 | ＜ 0.05 |
Embodiment 12-14
According to the formula in table 13, the method according to embodiment 8 makes dyestuff finished product.
Table 13 unit：Gram
The dyestuff finished product of embodiment 12-14 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 12-14 respectively to 250ml
Water in, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, GB/T3921-2008, the method for embodiment 3, GB/
T18414.1-2006, measure they light fastness, washing fastness, compatibility, chlorophenol content, the results are shown in Table 14.
Table 14
| Embodiment | Light fastness | Washing fastness | Compatibility | Chlorophenol content |
| 12 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
| 13 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
| 14 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
Embodiment 15-25
According to the formula in table 15, add appropriate amount of addition agent, make dyestuff finished product.
Table 15 unit：Gram
The dyestuff finished product of embodiment 15-25 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 15-25 respectively to 250ml
Water in, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T3921-2008, the method for embodiment 3, GB/T18414.1-2006, measure it
Washing fastness, compatibility, chlorophenol content, the results are shown in Table 16.
Table 16
| Embodiment | Washing fastness | Compatibility | Chlorophenol content |
| 15 | 5 | Ⅱ | ＜ 0.05 |
| 16 | 5 | Ⅰ | ＜ 0.05 |
| 17 | 5 | Ⅰ | ＜ 0.05 |
| 18 | 5 | Ⅰ | ＜ 0.05 |
| 19 | 5 | Ⅰ | ＜ 0.05 |
| 20 | 5 | Ⅰ | ＜ 0.05 |
| 21 | 5 | Ⅰ | ＜ 0.05 |
| 22 | 5 | Ⅱ | ＜ 0.05 |
| 23 | 5 | Ⅱ | ＜ 0.05 |
| 24 | 5 | Ⅱ | ＜ 0.05 |
| 25 | 5 | Ⅱ | ＜ 0.05 |
Embodiment 26-27
According to the formula in table 17, add appropriate amount of addition agent, make dyestuff finished product.
Table 17 unit：Gram
The dyestuff finished product of embodiment 26 and 27 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 26 and 27 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, GB/T3921-2008, GB/T18414.1-2006, measure it
Light fastness, washing fastness, chlorophenol content, the results are shown in Table 18.
Table 18
| Embodiment | Light fastness | Washing fastness | Chlorophenol content |
| 26 | 3 | 5 | ＜ 0.05 |
| 27 | 3 | 5 | ＜ 0.05 |
Embodiment 28-36
According to the formula in table 19, add appropriate amount of addition agent, make dyestuff finished product.
Table 19 unit：Gram
The dyestuff finished product of embodiment 28-36 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 28-36 respectively to 250ml
Water in, make disperse dyes suspension.Draw 30ml disperse dyes suspension to mix with the water of 70ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt AATCC16-2004, GB/T3921-2008, the method for embodiment 3, GB/
T18414.1-2006, measure they light fastness, washing fastness, compatibility, chlorophenol content, the results are shown in Table 20.
Table 20
| Embodiment | Light fastness | Washing fastness | Compatibility | Chlorophenol content |
| 28 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
| 29 | 2～3 | 5 | Ⅰ | ＜ 0.05 |
| 30 | 3 | 5 | Ⅰ | ＜ 0.05 |
| 31 | 3 | 5 | Ⅰ | ＜ 0.05 |
| 32 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
| 33 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
| 24 | 2～3 | 5 | Ⅰ | ＜ 0.05 |
| 25 | 3 | 5 | Ⅱ | ＜ 0.05 |
| 36 | 2～3 | 5 | Ⅱ | ＜ 0.05 |
Claims (17)
1. a kind of disperse dye composition is it is characterised in that include：
Component A as shown in formula (1)：
Component B as shown in formula (2)：
Component C as shown in formula (3)：
One or more optional components D as shown in formula (4)：
In formula (4), X1、X2Each stand alone as hydrogen or bromine, R1、R2Each stand alone as C2～C4Alkyl, or C1～C4In alkyl one
The group that individual hydrogen is replaced by cyano group, phenyl, acetoxyl group or benzoyloxy；
One or more optional components E as shown in formula (5)：
In formula (5), X3、X4Each stand alone as hydrogen, chlorine or nitro, R3For C1～C4Alkyl；
One or more optional components F as shown in formula (6)：
In formula (6), X5、X6Each stand alone as cyano group, bromine or nitro, R4For hydrogen or C1～C4Alkoxyl, R7For C1～C4Alkane acyl
Amino or C1～C4Alkyl, R5、R6Each stand alone as C1～C4Alkyl；
Optional component G as shown in formula (7)：
Wherein, the gross weight based on described compositionss, the percentage by weight of described component A is 31～73%, the weight of described component B
Amount percentage ratio is 7～40%, and the percentage by weight of described component C is 20～58%, and the percentage by weight of optional component D is 0
～70%, the percentage by weight of optional component E is 0～10%, and the percentage by weight of optional component F is 0～47%, and appoints
The percentage by weight of component G of choosing is 0～47%.
2. disperse dye composition according to claim 1 is it is characterised in that described component D is in following compound
One or more：
3. disperse dye composition according to claim 1 and 2 is it is characterised in that described component E is in following compound
One or more：
4. disperse dye composition according to claim 1 and 2 is it is characterised in that described component F is in following compound
One or more：
5. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 31～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
6. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 31～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
7. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 31～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
8. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 31～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
9. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 31～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
10. a kind of disperse dyes are it is characterised in that comprise the disperse dyes combination according to any one of claim 1～9
Thing and adjuvant.
11. disperse dyes according to claim 10 are it is characterised in that described adjuvant includes auxiliary agent and water.
12. disperse dyes according to claim 11 it is characterised in that described auxiliary agent include following one or two with
On combination：Naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulfate, surfactant, antibacterial, or other dyestuffs
Dispersant.
13. disperse dyes according to claim 11 or 12 are it is characterised in that described auxiliary agent and disperse dye composition
Weight ratio is 0.3～4:1.
14. disperse dyes according to any one of claim 10～12 are it is characterised in that described disperse dyes sand milling
Machine or grinder are liquid after grinding, and solid content is 20～50%, or described disperse dyes be spray-dried after for powdery or
Granular, solid content is 87～96%.
A kind of 15. methods of the disperse dyes prepared according to any one of claim 10～14 are it is characterised in that include
Following steps：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；Or
Described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed.
A kind of 16. disperse dyes according to any one of claim 10～14 are used for the dyeing of fabric and the use of stamp
On the way.
A kind of 17. fabrics are it is characterised in that enter by using the disperse dyes according to any one of claim 10～14
Row dyeing and stamp prepare.
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| CN201710129051.8A CN106947286B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310751841.1A CN104371369B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
| PCT/CN2014/095585 WO2015101290A1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| US15/102,669 US10151062B2 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| ES14876649.6T ES2653737T3 (en) | 2013-12-30 | 2014-12-30 | Composition of dispersed dye, dispersed dye and method of preparation and use thereof |
| EP14876649.6A EP3147333B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| BR112016012058A BR112016012058B8 (en) | 2013-12-30 | 2014-12-30 | Composition of disperse dye and disperse dye |
| KR1020167020366A KR101702513B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
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Citations (5)
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|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
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| CN106947286A (en) | 2017-07-14 |
| CN104371369A (en) | 2015-02-25 |
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