CN104371370B - Disperse dye composition and disperse dye, and preparation method and use thereof - Google Patents
Disperse dye composition and disperse dye, and preparation method and use thereof Download PDFInfo
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- CN104371370B CN104371370B CN201310753365.7A CN201310753365A CN104371370B CN 104371370 B CN104371370 B CN 104371370B CN 201310753365 A CN201310753365 A CN 201310753365A CN 104371370 B CN104371370 B CN 104371370B
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- 0 *C(C=C1)=C(*CC=*)C(*)=CC1[N+]([O-])=O Chemical compound *C(C=C1)=C(*CC=*)C(*)=CC1[N+]([O-])=O 0.000 description 3
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Abstract
The invention discloses a disperse dye composition and a disperse dye, and a preparation method and use thereof, and the disperse dye is suitable for dyeing and printing of fabrics, especially polyester and blended fabrics thereof.
Description
Technical field
The present invention relates to a kind of disperse dye composition, disperse dyes and its preparation method and purposes.Described dispersion dye
Material is applied to dyeing and the stamp of fabric, particularly terylene and its blend fabric.
Background technology
With the pay attention to day by day to environmental protection for the people, particularly some European countries have put into effect some regulations, policy etc. in succession.
Likewise, in recent years, China it is also proposed higher requirement to environmental protection, and some polluted enterprises are carried out with control, dyestuff enterprise
How to try to achieve survival and development, be that pendulum is maximum in face of dye manufacturers, and be the difficult problem needing most urgently to solve.
Content of the invention
The present invention provides the economy that a kind of pH value range is wide, light fastness is good, compatibility is excellent, intensity is high, washing fastness is good
Environmental-friendly disperse dye.
The present invention provides a kind of disperse dye composition it is characterised in that composed of the following components：
As formula（1）Shown component A：
One or more are as formula（2）Shown component B：
Formula（2）In, X1For bromine or chlorine；R1、R2Each stand alone as C1～C4Alkyl；
As formula（3-1）With（3-2）Shown component C：
（Disperse blue 291:2）
（C.I. disperse blue 291:1）
Optional one or more are as formula（4）Shown component D：
Formula（4）In, X2、X3Each stand alone as hydrogen, chlorine or bromine, R3、R4Each stand alone as C2～C4Alkyl, or C1～C4Alkane
The group that one of base hydrogen is replaced by cyano group, phenyl, acetoxyl group or benzoyloxy；Wherein component D is not C.I. dispersion
Orange 76；
Optional one or more are as formula（5）Shown component E：
Formula（5）In, X4、X5Each stand alone as hydrogen, chlorine or nitro, R5For C1～C4Alkyl；
Optional one or more are as formula（6）Shown component F：
Formula（6）In, X6、X7Each stand alone as cyano group, bromine, chlorine or nitro, R6For hydrogen or C1～C4Alkoxyl, R9For C1~
C4Alkyl amido or C1～C4Alkyl, R7、R8Each stand alone as C1～C4Alkyl；
Optional as formula（7）Shown component G：
（Disperse blue 2BLM）.
According to disperse dye composition of the present invention it is preferable that described component B be one of following compound or
Two kinds：
（C.I. disperse violet 93）
（Disperse violet 93:1）.
According to disperse dye composition of the present invention it is preferable that described component D be one of following compound or
Two or more：
（Disperse orange 288）
（C.I. disperse orange 73）
（C.I. disperse orange 61）
（C.I. disperse orange 30）
（Disperse orange 278）
（Disperse orange 30:2）
（C.I. disperse orange 25）
（C.I. disperse orange 33）.
According to disperse dye composition of the present invention it is preferable that described component E be one of following compound or
Two or more：
（C.I. disperse yellow 119）
（C.I. DISPERSE Yellow 211）.
According to disperse dye composition of the present invention it is preferable that described component F be one of following compound or
Two or more：
（C.I. disperse blue 165:1）
（C.I. disperse blue 366）
（C.I. disperse blue 165）
（C.I. disperse blue 291）
Based on the gross weight of described disperse dye composition, the percentage by weight of component A is 2-73%, preferably 2-72%,
Or preferably 2-60%, or preferably 2-51%, or preferably 3-50%, or preferably 3-6%.The percentage by weight of component B is 7-
40%, preferably 7-37%, or preferably 12-39%, or preferably 12-37%.The percentage by weight of component C is 20-58%, preferably
For 38-58%, or preferably 20-48%, or preferably 30-55%, or preferably 35-55%.The percentage by weight of component D is 0-
70%, preferably 2-50%, or preferably 3-6%.The percentage by weight of component E is 0-10%, preferably 2-6%.The weight of component F
Percentage ratio is 0-47%, preferably 1-10%.The percentage by weight of component G is 0-47%, preferably 1-10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
Percentage by weight is 2～73% component A,
Percentage by weight is 7～40% component B,
Percentage by weight is 20～58% component C,
Optional percentage by weight is 0～70% component D,
Optional percentage by weight is 0～10% component E,
Optional percentage by weight is 0～47% component F, and
Optional percentage by weight is 0～47% component G.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 3～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 2～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 3～6%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component D is 2～50%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 2～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, by with the following group
It is grouped into：
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
According to disperse dye composition of the present invention it is preferable that in described component C, described formula（3-1）Shown change
The percentage by weight of compound is 1～99%, preferably 70～90%, described formula（3-2）The percentage by weight of shown compound is 1
～99%, preferably 10～30%, the weight meter based on described component C.
In actual production process, each dye component of the present invention generally may be miscellaneous with some by-products and other
Matter, as long as do not affect the enforcement of the present invention.
The present invention also provides a kind of disperse dyes it is characterised in that by according to disperse dye composition of the present invention
With adjuvant composition.
According to disperse dyes of the present invention it is preferable that described adjuvant includes auxiliary agent and water.
According to disperse dyes of the present invention it is preferable that described auxiliary agent includes one or more following group
Close：Naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulfate, surfactant, antibacterial, or other dye dispersants.
According to disperse dyes of the present invention it is preferable that described auxiliary agent with the weight ratio of disperse dye composition is
0.3～4:1.
The present invention a kind of method prepared according to disperse dyes of the present invention is also provided it is characterised in that include with
Lower step：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；
Or described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed
Close.
Disperse dyes of the present invention, can be liquid after being ground with sand mill or grinder（Generally solid content be 20～
50%）, can be powdery or graininess after spray drying（Generally solid content is 87～96%）.
The present invention also provide a kind of according to disperse dyes of the present invention be used for the dyeing of fabric and/or the use of stamp
On the way.
The present invention also provides a kind of fabric it is characterised in that by using carrying out according to disperse dyes of the present invention
Dyeing and/or stamp prepare.
The pH value range of the disperse dyes of the present invention is wide, light fastness is good, compatibility is excellent, intensity is high, washing fastness is good.
Specific embodiment
Embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
In an embodiment, component A, B of the present invention, C and optional component D, E, F, G, by certain proportioning and auxiliary agent and
After water blending, it is ground dispersion with sand mill and makes slurry, or be spray-dried further, thus making dyestuff.
Described component A, B, C, D, E, F, G are known dye composition and can commercially buy, or can
Prepared by existing method.
Embodiment 1：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2-2）Dye component, 30 grams of formulas（3-1）Dye component and 13 grams of formulas
（3-2）The mixture of dye component, 80 grams of Dispersant MFs and 80 grams of lignin 85A, add water 390 grams and stir, and grind
Disperse and be dried, obtain final product dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 1：
Repeat embodiment 1, except by the formula of embodiment 1（1）Dye component is substituted for following formula（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 1 and comparative example 1 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and measure their intensity using GB/T6688-2008, measurement result is shown in Table 1.
Table 1
| Title | Intensity |
| Embodiment 1 | 102% |
| Comparative example 1 | 100% |
Intensity is high can to reduce dye dosage it is meant that the textile of same depth during printing and dyeing, reduce printing and dyeing cost.
Embodiment 2：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2-1）Dye component, 30 grams of formulas（3-1）Dye component and 13 grams of formulas
（3-2）The mixture of dye component, 80 grams of Dispersant MFs and 80 grams of lignin 83A, add water 390 grams and stir, and grind
Disperse and be dried, obtain final product dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 2：
Repeat embodiment 2, except by the formula of embodiment 2（1）Dye component is substituted for following formula（9）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 2 and comparative example 2 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the light fastness that they are measured using AATCC16-2004, the results are shown in Table 2.
Table 2
| Title | Light fastness（40h） |
| Embodiment 2 | 3 |
| Comparative example 2 | 2 |
Embodiment 3：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2-1）Dye component, 30 grams of formulas（3-1）Dye component and 13 grams of formulas
（3-2）The mixture of dye component, and 30 grams of Dispersant MFs, add water 200 grams and stir, grinding distribution makes pulp
Material finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 3：
Repeat embodiment 3, except by the formula of embodiment 3（1）Dye component replaces an accepted way of doing sth（4-1）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 3 and comparative example 3 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, and survey with reference to GB/T2400-2006
Determine their intensity, light fastness and compatibility, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibility |
| Embodiment 3 | 105% | 2～3 | Ⅱ |
| Comparative example 3 | 100% | 2 | Ⅲ |
Measure compatibility method be：Dyeed with reference to GB/T2394-2003, entered dye from 60 DEG C, when temperature is raised to 80
DEG C when horse back take a sample, take a sample every 10 DEG C later, until 130 DEG C, and, 130 DEG C be incubated 10 minutes, 20 points
Clock, 30 minutes, 50 minutes when separately sampled, take 10 pieces of cloth specimens altogether.It is incubated 50 minutes with 130 DEG C as standard specimen, each shelves temperature is taken
Cloth specimen is sample, whether synchronous observes its foxy.The Pyatyi system of being divided into I, II, III, IV, V（Instrument：Computer color testing instrument
Datacolor600, colour difference formula CMC2：1）.For black hues, calculate DC（Gorgeous degree is poor）、DH（Hue difference）It is respectively less than 0.6
Cloth specimen block number.
I grade：Five pieces and more than five pieces
II grade：Four pieces
III grade：Three pieces
IV grade：Two pieces
V grade：One piece.
Embodiment 4：
By 41 grams of formulas（1）Dye component, 16 grams of formulas（2-2）Dye component, 30 grams of formulas（3-1）Dye component and 13 grams of formulas
（3-2）The mixture of dye component, 30 grams of Dispersant MFs and 30 grams of dispersing agent NNOs, add water 250 grams and stir, and grind
Pulp material finished product is made in dispersion, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 4：
Repeat embodiment 4, except by the formula of embodiment 4（1）Dye component is substituted for following formula（10）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 4 and comparative example 4 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 4.
Table 4
| Title | Intensity | PH stable scope |
| Embodiment 4 | 107% | 3～9 |
| Comparative example 4 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 5：
By 44 grams of formulas（1）Dye component, 22 grams of formulas（2-2）Dye component, 30.6 grams of formulas（3-1）Dye component and 3.4 grams
Formula（3-2）The mixture of dye component, 31 grams of Dispersant MFs and 31 grams of dispersing agent NNOs, add water 200 grams and stir, grind
Mill disperses and is dried, and obtains final product dyestuff finished product, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 5：
Repeat embodiment 5, except by 44 grams of formulas in embodiment 5（1）Dye component is substituted for 41.4 grams of formulas（10）Dyestuff
Component and 2.6 grams of formulas（11）Outside dye component, other constant.
The dyestuff finished product of embodiment 5 and comparative example 5 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 5 and comparative example 5 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 5.
Table 5
| Title | Intensity | PH stable scope |
| Embodiment 5 | 107% | 3～9 |
| Comparative example 5 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 6：
By 7.8 grams of formulas（1）Dye component, 7.8 grams of formulas（4-1）Dye component, 6.0 grams of formulas（2-1）Dye component, 13.1 grams
Formula（3-1）Dye component and 3.3 grams of formulas（3-2）The mixture of dye component, 31 grams of dispersing agent MFs and 31 grams of lignin 85A, plus
200 grams of water stirs, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, and dyeing obtains excellent black of every fastness ability
Color polyester.
Comparative example 6：
Repeat embodiment 6, except by the formula in embodiment 6（1）Dye component replaces an accepted way of doing sth（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 6 and comparative example 6 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the intensity that they are measured using GB/T6688-2008, the results are shown in Table 6.
Table 6
| Title | Intensity |
| Embodiment 6 | 102% |
| Comparative example 6 | 100% |
Embodiment 7：
By 9.5 grams of formulas（1）Dye component, 36.5 grams of formulas（2-2）Dye component, 27 grams of formulas（3-1）Dye component and 27 grams
Formula（3-2）The mixture of dye component, 80 grams of Dispersant MFs and 80 grams of lignin 83A, add water 390 grams and stir, grind
Mill disperses and is dried, and obtains final product dyestuff finished product, and dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 7：
Repeat embodiment 7, except by 27 grams of formulas in embodiment 7（3-1）Dye component and 27 grams of formulas（3-2）Dye component
Mixture be substituted for 54 grams of formulas（3-1）Outside dye component, other constant.
The dyestuff finished product of embodiment 7 and comparative example 7 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 7 and comparative example 7 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T3921-2008, measure their washing fastness, the results are shown in Table 7.
Table 7
| Title | Washing fastness |
| Embodiment 7 | 4～5 |
| Comparative example 7 | 4 |
Embodiment 8：
By 12 grams of formulas（1）Dye component, 34 grams of formulas（2-2）Dye component, 10.8 grams of formulas（3-1）Dye component and 43.2 grams
Formula（3-2）The mixture of dye component, 80 grams of Dispersant MFs and 80 grams of lignin 83A, add water 390 grams and stir, grind
Mill disperses and is dried, and obtains final product dyestuff finished product, and dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 8：
Repeat embodiment 8, except by 10.8 grams of formulas in embodiment 8（3-1）Dye component and 43.2 grams of formulas（3-2）Dyestuff
The mixture of component is substituted for 54 grams of formulas（3-2）Outside dye component, other constant.
The dyestuff finished product of embodiment 8 and comparative example 8 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 8 and comparative example 8 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, measure their intensity, light fastness,
The results are shown in Table 8.
Table 8
| Title | Intensity | Light fastness（40h） |
| Embodiment 8 | 103.5% | 2～3 |
| Comparative example 8 | 100% | 2 |
Embodiment 9
According to the formula in table 9, the method according to embodiment 8 makes dyestuff finished product.
Table 9 unit：Gram
The dyestuff finished product of embodiment 9 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, the dyestuff finished product weighing 0.5 gram of embodiment 9 to the water of 250ml,
Make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath pH to 5 with acetic acid,
Then it is warmed up to 60 DEG C, be respectively put into 2g polyester fiber simultaneously and carry out high-temperature pressure dyeing, be warmed up to 130 DEG C in 35 minutes,
Insulation 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the method using AATCC16-2004, measure their light fastness, the results are shown in Table 10.
Table 10
| Embodiment | Light fastness |
| 9 | 3 |
Embodiment 10-17
According to the formula in table 11, the method according to embodiment 8 makes dyestuff finished product.
Table 11 unit：Gram
The dyestuff finished product of embodiment 10-17 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 10-17 respectively to 250ml
Water in, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and simultaneously adopt AATCC16-2004, and using the method for embodiment 3 measure they light fastness,
Compatibility, the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Compatibility |
| 10 | 3 | Ⅱ |
| 11 | 2～3 | Ⅱ |
| 12 | 3 | Ⅱ |
| 13 | 2～3 | Ⅱ |
| 14 | 3 | Ⅱ |
| 15 | 2～3 | Ⅱ |
| 16 | 2～3 | Ⅱ |
| 17 | 3 | Ⅱ |
Embodiment 18 and 19
According to the formula in table 13, add appropriate amount of addition agent, make dyestuff finished product.
Table 13 unit：Gram
The dyestuff finished product of embodiment 18 and 19 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 18 and 19 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the method using AATCC16-2004, measure their light fastness, the results are shown in Table 14.
Table 14
| Embodiment | Light fastness |
| 18 | 3 |
| 19 | 3 |
Embodiment 20-35
According to the formula in table 15, add appropriate amount of addition agent, make dyestuff finished product.
Table 15 unit：Gram
The dyestuff finished product of embodiment 20-35 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 20-35 respectively to 250ml
Water in, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and simultaneously adopt AATCC16-2004, and using the method for embodiment 3 measure they light fastness,
Compatibility, the results are shown in Table 16.
Table 16
| Embodiment | Light fastness | Compatibility |
| 20 | 2～3 | Ⅱ |
| 21 | 2～3 | Ⅱ |
| 22 | 2～3 | Ⅰ |
| 23 | 3 | Ⅱ |
| 24 | 3 | Ⅱ |
| 25 | 3 | Ⅰ |
| 26 | 2～3 | Ⅰ |
| 27 | 3 | Ⅰ |
| 28 | 2～3 | Ⅱ |
| 29 | 2～3 | Ⅱ |
| 30 | 2～3 | Ⅱ |
| 31 | 2～3 | Ⅱ |
| 32 | 3 | Ⅱ |
| 33 | 2～3 | Ⅱ |
| 34 | 3 | Ⅱ |
| 35 | 3 | Ⅱ |
Claims (20)
1. a kind of disperse dye composition is it is characterised in that composed of the following components：
Component A as shown in formula (1)：
One or more components B as shown in formula (2)：
In formula (2), X1For bromine or chlorine；R1、R2Each stand alone as C1～C4Alkyl；
Component C as shown in formula (3-1) and (3-2)：
One or more optional components D as shown in formula (4)：
In formula (4), X2、X3Each stand alone as hydrogen, chlorine or bromine, R3、R4Each stand alone as C2～C4Alkyl, or C1～C4In alkyl
The group that replaced by cyano group, phenyl, acetoxyl group or benzoyloxy of a hydrogen；Wherein component D is not C.I. disperse orange 76；
One or more optional components E as shown in formula (5)：
In formula (5), X4、X5Each stand alone as hydrogen, chlorine or nitro, R5For C1～C4Alkyl；
One or more optional components F as shown in formula (6)：
In formula (6), X6、X7Each stand alone as cyano group, bromine, chlorine or nitro, R6For hydrogen or C1～C4Alkoxyl, R9For C1～C4's
Alkyl amido or C1～C4Alkyl, R7、R8Each stand alone as C1～C4Alkyl；
Optional component G as shown in formula (7)：
Wherein, the gross weight based on described compositionss, the percentage by weight of described component A is 39/190～73%, described component B
Percentage by weight be 7～40%, the percentage by weight of described component C is 20～58%, the percentage by weight of optional component D
For 0～70%, the percentage by weight of optional component E is 0～10%, and the percentage by weight of optional component F is 0～47%,
Percentage by weight with optional component G is 0～47%.
2. disperse dye composition according to claim 1 is it is characterised in that described component B is in following compound
One or two：
3. disperse dye composition according to claim 1 and 2 is it is characterised in that described component D is in following compound
One or more：
4. disperse dye composition according to claim 1 and 2 is it is characterised in that described component E is in following compound
One or more：
5. disperse dye composition according to claim 1 and 2 is it is characterised in that described component F is in following compound
One or more：
6. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
Composed of the following components：
The percentage by weight of component A is 39/190～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
7. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
Composed of the following components：
The percentage by weight of component A is 39/190～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
8. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
Composed of the following components：
The percentage by weight of component A is 39/190～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
9. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
Composed of the following components：
The percentage by weight of component A is 39/190～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
10. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss
Amount, composed of the following components：
The percentage by weight of component A is 39/190～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
11. disperse dye compositions according to claim 1 and 2 it is characterised in that in described component C, described formula (3-
1) percentage by weight of the compound shown in is 1～99%, the percentage by weight of the compound shown in described formula (3-2) is 1～
99%, the weight meter based on described component C.
12. disperse dye compositions according to claim 11 it is characterised in that in described component C, described formula (3-1)
The percentage by weight of shown compound is 70～90%, the percentage by weight of the compound shown in described formula (3-2) is 10～
30%, the weight meter based on described component C.
A kind of 13. disperse dyes are it is characterised in that combined by the disperse dyes according to any one of claim 1～12
Thing and adjuvant composition.
14. disperse dyes according to claim 13 are it is characterised in that described adjuvant includes auxiliary agent and water.
15. disperse dyes according to claim 14 it is characterised in that described auxiliary agent include following one or two with
On combination：Naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulfate, surfactant, antibacterial, or other dyestuffs
Dispersant.
16. disperse dyes according to claims 14 or 15 are it is characterised in that described auxiliary agent and disperse dye composition
Weight ratio is 0.3～4:1.
17. disperse dyes according to any one of claim 13～15 are it is characterised in that described disperse dyes sand milling
Machine or grinder are liquid after grinding, and solid content is 20～50%, or described disperse dyes be spray-dried after for powdery or
Granular, solid content is 87～96%.
A kind of 18. methods of the disperse dyes prepared according to any one of claim 13～17 are it is characterised in that include
Following steps：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；Or
Described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed.
A kind of 19. disperse dyes according to any one of claim 13～17 are used for the dyeing of fabric and the use of stamp
On the way.
A kind of 20. fabrics are it is characterised in that enter by using the disperse dyes according to any one of claim 13～17
Row dyeing and stamp prepare.
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| CN201710189073.3A CN106928750B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310753365.7A CN104371370B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
| BR112016012058A BR112016012058B8 (en) | 2013-12-30 | 2014-12-30 | Composition of disperse dye and disperse dye |
| ES14876649.6T ES2653737T3 (en) | 2013-12-30 | 2014-12-30 | Composition of dispersed dye, dispersed dye and method of preparation and use thereof |
| EP14876649.6A EP3147333B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| PCT/CN2014/095585 WO2015101290A1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| US15/102,669 US10151062B2 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| KR1020167020366A KR101702513B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
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| CN105131648A (en) * | 2015-07-03 | 2015-12-09 | 浙江亿得化工有限公司 | Novel composite black disperse dye |
| CN106349753A (en) * | 2016-08-22 | 2017-01-25 | 九江富达实业有限公司 | Novel disperse dye composition |
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| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN101760045B (en) * | 2009-12-30 | 2013-07-24 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
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| JPH0244338B2 (en) * | 1983-07-27 | 1990-10-03 | Mitsui Toatsu Chemicals | HORIESUTERUSENIYOBUNSANSENRYOSOSEIBUTSUOYOBISENSHOKUMATAHANATSUSENHOHO |
| JPS62156367A (en) * | 1985-12-26 | 1987-07-11 | 合成染料技術研究組合 | Dyeing of hydrophobic fiber |
| CN100341953C (en) * | 2005-05-20 | 2007-10-10 | 浙江闰土股份有限公司 | Composite environmental protection type disperse dyes |
| CN100503740C (en) * | 2007-01-05 | 2009-06-24 | 浙江龙盛染料化工有限公司 | Dispersed black dye composition |
| CN101054477B (en) * | 2007-05-18 | 2010-05-26 | 浙江龙盛染料化工有限公司 | Dispersion dyes composition |
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|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN101760045B (en) * | 2009-12-30 | 2013-07-24 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
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| CN104371370A (en) | 2015-02-25 |
| CN106928750A (en) | 2017-07-07 |
| CN106928750B (en) | 2019-11-22 |
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Inventor after: Ruan Jingbo Inventor after: Zhao Guosheng Inventor after: Gu Weidi Inventor after: Ruan Haixing Inventor after: Ye Huaming Inventor after: Jing Xueping Inventor before: Chen Bailong |
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Effective date of registration: 20171018 Address after: Shangyu District of Zhejiang city in Shaoxing Province town road 312368 called mountain Patentee after: Zhejiang Runtu Co., Ltd. Address before: 312368 No. 231 village, Zhenjiang village, Shaoxing, Zhejiang Patentee before: Chen Bailong |