CN104629492B - A kind of disperse violet composite dye composition - Google Patents
A kind of disperse violet composite dye composition Download PDFInfo
- Publication number
- CN104629492B CN104629492B CN201510057367.1A CN201510057367A CN104629492B CN 104629492 B CN104629492 B CN 104629492B CN 201510057367 A CN201510057367 A CN 201510057367A CN 104629492 B CN104629492 B CN 104629492B
- Authority
- CN
- China
- Prior art keywords
- component
- formula
- disperse violet
- dye composition
- composite dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 CCSC(*)C(C*1)C(*(C)N)*(C)(C)*CC1N Chemical compound CCSC(*)C(C*1)C(*(C)N)*(C)(C)*CC1N 0.000 description 4
Abstract
The present invention relates to a kind of disperse violet composite dye composition, be made up of component A as the formula (1) and component B as the formula (2), in formula (1): R1For H or NHCOCH3, R2、R3Independently for C1‑C4Alkyl, CH2CH2COOCH3Or CH2CH2OCH3；In formula (2): X3For H, NHCOCH2CH3Or NHCOCH3, R2For CH2CH2OCOCH3Or CH2CH2CN.Instant component is simple, bright in luster, and every fastness such as sunlight fastness, washing fastness, fastness to rubbing is the most excellent, and especially sublimation reliability is significantly improved.(1)
Description
Technical field
The present invention relates to a kind of disperse dye composition, be specifically related to a kind of disperse violet composite dye composition, be suitable for
In terylene and blended fabric dyeing thereof and stamp.
Background technology
Disperse dyes are broadly divided into disperse orange, disperse blue, disperse yellow, disperse red etc., it is also possible to several different dispersion dyes
Material is arranged in pairs or groups according to a certain percentage, obtains disperseing the disperse dyes such as black, Disperse Green, disperse violet.
In China market, the disperse purple dye compositions of mixture is more at present, and quality is all preferable, but exists on domestic market
Disperse dyes in the content of impurity, salt and heavy metal etc. the highest, and form complexity, fusing point is relatively low, identical
Under the conditions of certainly will affect the dye-uptake of dyestuff, coloured light and colorfastness.And more serious to the contamination ratio of other fiber, Bu Shaopin
Sublimation reliability, thermal migration and the fastness to wet rubbing etc. planted can not meet needs.Therefore, seek a kind of component simply, and respectively
The most excellent disperse violet composite dye composition of application performance is the heat subject of dyeing industry.
Summary of the invention
For the above-mentioned technical problem of prior art, it is an object of the invention to provide a kind of disperse violet composite dye combination
Thing, this dye composite component is simple, bright in luster, and every fastness such as sunlight fastness, washing fastness, fastness to rubbing
The most excellent, particularly fastness to sublimation has and improves significantly.
For reaching above-mentioned purpose, the present invention is achieved by the following technical solutions:
A kind of disperse violet composite dye composition, is made up of component A and component B,
Described component A is one or more in compound shown in formula (1):
(1)
In formula (1): R1For H or-NHCOCH3, R2、R3Independently for C1-C4Alkyl ,-CH2CH2COOCH3Or-
CH2CH2OCH3；
Described component B is one or more in compound shown in formula (2):
(2)
In formula (2): X3For H, NHCOCH2CH3Or NHCOCH3, R2For CH2CH2OCOCH3Or CH2CH2CN。
Described component A is one or both mixture in the compound shown in formula (1-1) and formula (1-2):
(1-1)
(1-2).
Described component B is one or both mixture in the compound shown in formula (2-1) and formula (2-2):
(2-1)
(2-2).
As preferably, described component A and the percentage by weight of component B consist of:
Component A:45%-86%
Component B:14%-55%.
Being more highly preferred to, described component A and the percentage by weight of component B consist of:
Component A:60%-75%
Component B:25%-40%.
The application in terylene and the dyeing of blend fabric and stamp thereof of a kind of disperse violet composite dye composition.
Described disperse violet composite dye composition needs to add auxiliary agent, described auxiliary agent and component A and group when application
The ratio dividing the gross weight of B is 0.9-3.2:1.
Described auxiliary agent is dispersant, the diffusant etc. that disperse dyes are conventional when compounding, one of the most following or its
In the most several mixture: naphthalene sulfonic acid-formaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl sulfonic formaldehyde condensation compound,
The anionic dispersing agents such as lignosulfonates.Being more highly preferred to, described auxiliary agent is one of following or the most several mixed
Compound: dispersing agent NNO (sodium methylene bis-naphthalene sulfonate), Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl
Base naphthalenesulfonate formaldehyde condensation compound), sodium lignin sulfonate (such as commercial dispersants Reax 83A, Reax 85A) etc..
Disperse violet composite dye composition of the present invention can be prepared by the following method: by dye component by certain
After ratio mixing, in the presence of auxiliary agent, water, carry out particlized with the pulverizer such as sand mill or grinder, be then spray-dried.On
State dye monomer all to use commercially available prod or prepare voluntarily.
Disperse violet composite dye composition of the present invention, can be aqueous after corpusculed, can be powder after spray drying
Shape, graininess.
Disperse violet composite dye composition component of the present invention is simple, bright in luster, sunlight fastness, water-fastness jail
Every fastness such as degree, fastness to rubbing are the most excellent, and especially sublimation reliability is significantly improved.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to
This.
Embodiment 1-8
According to data shown in table 1, by dye component A, component B and auxiliary agent dispersing agent NNO (sodium methylene bis-naphthalene sulfonate), divide
Powder MF(condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl naphthalenesulfonate formaldehyde condensation compound), sodium lignin sulfonate
(such as commercial dispersants Reax 83A, Reax 85A) etc., after the blending that adds water, are ground dispersion, then spray dried with sand mill
Dry.Dye component therein and auxiliary agent all can be prepared by mode well known in the art, it would however also be possible to employ commercially available prod.
Table 1
Performance test
The disperse violet composite dye composition that above-described embodiment 1-8 prepares is carried out performance test, and method of testing is as follows: press
According to the method that GB/T2394-2003 is similar, respectively take 0.5 gram of disperse violet composite dye composition prepared by embodiment 1-8, use water
Being configured to the disperse dyes suspension that concentration is 0.5g/500ml respectively, the water taking 20ml with 80ml mixes, by acetic acid regulation dye
Bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, heats up in 35 minutes
To 130 DEG C, it is incubated 30 minutes, is cooled to 80 DEG C of samplings.
GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 is used to measure its dyefastness, measurement result
It is shown in Table 2.
Table 2
Known to upper table, the every fastness of disperse violet composite dye composition of the present invention is the most excellent, especially fastness to wet rubbing
Raising further is had with sublimation reliability.
Above-described embodiment is only used for illustrating the inventive concept of the present invention, rather than the restriction to rights protection of the present invention,
All changes utilizing this design that the present invention carries out unsubstantiality, all should fall into protection scope of the present invention.
Claims (6)
1. a disperse violet composite dye composition, it is characterised in that be made up of component A and component B,
Described component A is one or more in compound shown in formula (1):
(1)
In formula (1): R1For H or-NHCOCH3, R2、R3Independently for C1-C4Alkyl ,-CH2CH2COOCH3Or-
CH2CH2OCH3；
Described component B is one or more in compound shown in formula (2):
(2)
In formula (2): X3For H, NHCOCH2CH3Or NHCOCH3, R2For CH2CH2OCOCH3Or CH2CH2CN；
Described component A and the percentage by weight of component B consist of:
Component A:45%-86%
Component B:14%-55%.
2. disperse violet composite dye composition as claimed in claim 1, it is characterised in that described component A be formula (1-1) and
One or both mixture in compound shown in formula (1-2):
(1-1)
(1-2).
3. disperse violet composite dye composition as claimed in claim 1, it is characterised in that described component B be formula (2-1) and
One or both mixture in compound shown in formula (2-2):
(2-1)
(2-2).
4. disperse violet composite dye composition as claimed in claim 1, it is characterised in that described component A and the weight of component B
Amount percentage ratio consists of:
Component A:60%-75%
Component B:25%-40%.
5. a disperse violet composite dye composition as claimed in claim 1 is at terylene and the dyeing of blend fabric thereof and stamp
In application.
6. the application of disperse violet composite dye composition as claimed in claim 5, it is characterised in that: described disperse violet is combined
Dye composite needs to add auxiliary agent when application, and described auxiliary agent is 0.9-3.2 with the ratio of the gross weight of component A and component B:
1。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510057367.1A CN104629492B (en) | 2015-02-04 | 2015-02-04 | A kind of disperse violet composite dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510057367.1A CN104629492B (en) | 2015-02-04 | 2015-02-04 | A kind of disperse violet composite dye composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104629492A CN104629492A (en) | 2015-05-20 |
| CN104629492B true CN104629492B (en) | 2016-08-24 |
Family
ID=53208753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510057367.1A Expired - Fee Related CN104629492B (en) | 2015-02-04 | 2015-02-04 | A kind of disperse violet composite dye composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104629492B (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2820787B2 (en) * | 1990-10-30 | 1998-11-05 | 日本化薬株式会社 | Dyeing method for disperse dye composition and hydrophobic fiber |
| CN101602896B (en) * | 2009-07-20 | 2012-07-25 | 浙江闰土股份有限公司 | Brown disperse dye composition |
| CN102504596A (en) * | 2011-11-15 | 2012-06-20 | 东营安诺其纺织材料有限公司 | Bi-component monoazo disperse blue dye composition |
| CN104087016B (en) * | 2014-06-05 | 2016-05-04 | 浙江龙盛集团股份有限公司 | A kind of disperse dye composition, disperse dyes goods and application thereof |
-
2015
- 2015-02-04 CN CN201510057367.1A patent/CN104629492B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104629492A (en) | 2015-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100543087C (en) | A kind of disperse azo dye composition | |
| CN101338081B (en) | Dispersed deep blue dye composition | |
| CN1995154B (en) | Dispersing orange dye composition and dispersing dye | |
| CN102002259B (en) | High-fastness black and blue disperse dye composite | |
| CN101760045B (en) | Medium-low temperature environmental-friendly disperse dye composition | |
| CN100558822C (en) | A kind of disperse dye composition | |
| CN102391680B (en) | Disperse dye composite for dyeing and printing polyester spandex fiber | |
| CN103073918B (en) | Medium temperature type three-primary-color disperse dyes | |
| CN102558908B (en) | Compound high-strength disperse dye | |
| CN104448928B (en) | Disperse blue dye composition, disperse dye, preparation method and application | |
| CN106479221B (en) | It is a kind of dark blue to black disperse dye mixture | |
| CN104371358B (en) | Disperse dye composition and disperse dye and preparation method and use thereof | |
| CN102924975B (en) | Disperse dye composition and disperse dyes, and preparation method and purpose thereof | |
| WO2015101290A1 (en) | Disperse dye composition, disperse dye and preparation method and use thereof | |
| CN102277012B (en) | Disperse purplish-red dye composition | |
| CN106084886A (en) | A kind of blue disperse dye mixture and disperse dyes | |
| CN102229756B (en) | Mesothermal disperse blue dye composition | |
| CN106700648A (en) | Black disperse dye composition | |
| CN104371360B (en) | Disperse dye composition and disperse dye, and preparation method and use thereof | |
| CN102532941B (en) | Composite brilliant blue disperse dye | |
| CN104629492B (en) | A kind of disperse violet composite dye composition | |
| CN101948633B (en) | Environment-friendly quick dyeing disperse dye composition | |
| CN104371370B (en) | Disperse dye composition and disperse dye, and preparation method and use thereof | |
| CN106833020A (en) | A kind of disperse dye composition and its application | |
| CN102585550A (en) | Blue disperse dye |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 Termination date: 20170204 |