CN100558822C - Disperse blue dye composition - Google Patents
Disperse blue dye composition Download PDFInfo
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- CN100558822C CN100558822C CNB2006101549153A CN200610154915A CN100558822C CN 100558822 C CN100558822 C CN 100558822C CN B2006101549153 A CNB2006101549153 A CN B2006101549153A CN 200610154915 A CN200610154915 A CN 200610154915A CN 100558822 C CN100558822 C CN 100558822C
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- dye composition
- disperse dye
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- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 239000001045 blue dye Substances 0.000 title abstract description 5
- 239000000986 disperse dye Substances 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims description 11
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 5
- -1 methoxy ethyl Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
- ODFJOVXVLFUVNQ-UHFFFAOYSA-N acetarsol Chemical compound CC(=O)NC1=CC([As](O)(O)=O)=CC=C1O ODFJOVXVLFUVNQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 10
- 239000004744 fabric Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 238000001694 spray drying Methods 0.000 abstract description 2
- 239000006071 cream Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 210000004243 sweat Anatomy 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 22
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 235000019357 lignosulphonate Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002895 hyperchromatic effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
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- Coloring (AREA)
Abstract
The invention provides a disperse blue dye composition which basically comprises one or more components A with a structure shown in a formula and one or more components B with a structure shown in a formula (II), wherein based on the components A and the components B, the weight fraction of the components A is 1-99%, and the weight fraction of the components B is 1-99%; the disperse dye obtained by the disperse blue dye composition can be used for dyeing in a liquid state or a cream state after microparticulation or in a powdery or granular state after being dried by a spray drying method and the like. When the polyester fiber material is dyed by the disperse dye prepared from the disperse dye composition, dark blue dyed fabrics with bright color, good dispersibility, sun resistance, washing resistance, sweat resistance and other excellent performances can be obtained by adjusting the proportion of different components.
Description
(1) technical field
The present invention relates to a kind of disperse dye composition, relate in particular to a kind of disperse dye composition of trevira printing and dyeing usefulness.
(2) background technology
In dispersed dye, EX-SF DISPERSE BLUE EX-SF 300 C.I.56 is acknowledged as important blue disperse dye in the world wide, and the fabric that obtains with its dyeing can produce bright especially high fastness ruddiness blueness.But then, also as all anthraquinone dyes, the outstanding shortcoming of existence is that staining power is low to this dyestuff, and the cost that causes dyeing increases, and especially hyperchromatic the time, cost is higher.
In order to overcome the shortcoming of anthraquinone dye to greatest extent, searching can replace the dyestuff that also can reach its excellent dyeing behavior equally of EX-SF DISPERSE BLUE EX-SF 300 C.I.56, trial of being done such as U.S. Pat 5160348, wherein the technical scheme of Cai Yonging is the composite of one group of azoic dyestuff, although dyeing behavior makes moderate progress, also reduced the dyeing cost, but in actual dyeing course, the synchronous colouring of this composite dyestuff, circulation ratio still can not be satisfactory.
(3) summary of the invention
Be to solve the above-mentioned deficiency of dispersed blue dye in the prior art, the invention provides a kind of piece together mix that back colouring property synchronously is good, compatibleness is good, favorable reproducibility and the low disperse dye composition of cost.
For reaching goal of the invention the technical solution used in the present invention be:
A kind of disperse dye composition, basically form suc as formula the B component shown in (II) suc as formula the component A shown in (I) and one or more structures by one or more structures, based on described component A and B component, described component A weight fraction is 1～99%, and described B component weight fraction is 1～99%;
In the formula (I), X, Y independently are nitro, cyano group or halogen separately;
Z is-NHCOR
3Or-OR
4, R wherein
3, R
4Be C
1～C
4Alkyl;
W is hydrogen or C
1～C
4Alkoxyl group;
R
1, R
2Separate is C
1～C
4Alkyl or C
1～C
4Substituted substituted alkyl of H in the alkyl, in the described substituted alkyl substituting group be hydroxyl or cyano group or-OCOR
5, or C
1～C
4Alkoxyl group, R wherein
5Be C
1～C
4Alkyl;
In the formula (II), R
6Be nitro or halogen;
R
7Be C
1～C
3Alkoxyl group;
R
8For hydrogen or-NHCOR
11, or C
1～C
4Alkyl; R
11Be C
1～C
4Alkyl;
R
9, R
10Be C
1～C
4Alkyl or C
1～C
4Substituted substituted alkyl of H in the alkyl, substituting group is alkoxyl group or alkoxycarbonyl in the described substituted alkyl.
Preferably, described disperse dye composition is made up of the component A of weight fraction 60～95% and the B component of weight fraction 5～40%.
Also can contain one or more structures in the described disperse dye composition suc as formula the component C shown in (III), based on described component A, B component and component C, described component A weight fraction is 60～95%, and described B component weight fraction is 1～30%, and described component C weight fraction is 1～15%;
In the formula (III),
V is cyano group or nitro;
R
12Be methyl or kharophen;
R
13, R
14Independent separately is ethyl or cyanoethyl or methoxy ethyl or allyl group or hydroxyethyl or butyl.
Preferably, described disperse dye composition is made up of the component A of weight fraction 60～95%, the B component of weight fraction 1～30% and the component C of weight fraction 1～15%.
Preferred, described disperse dye composition is made up of the component A of weight fraction 65～95%, the B component of weight fraction 1～25% and the component C of weight fraction 1～10%.
Described component A is preferably one of following or two or more composition wherein:
Described B component is preferably one of following or two or more composition wherein:
Described component C is preferably one of following or two or more composition wherein:
Preferred, described disperse dye composition is the mixture of the compound (II-1) of the compound (I-1) of weight fraction 60～95% and weight fraction 5～40%; Perhaps, described disperse dye composition is the compound (I-1) of weight fraction 65～95%, the compound (II-1) of weight fraction 1～25% and compound (III-1) mixture of weight fraction 1～10%.
Because the singularity of dye industry is difficult to also there is no need to make pure product, can have the impurity in some preparation process usually, also allows to contain the physics impurity of a spot of moisture content and trace when dye composite of the present invention is made finished product.
When preparing disperse dye composition of the present invention, it is synthetic that employed component A, B component and component C can know the ground mode by those skilled in the art easily, wherein monomer A, B also can also can purchase the commercial goods with reference to the method preparation of introducing among patent JP58040360 and the GB2030163.
Disperse dye composition of the present invention generally needs to add auxiliary agent and disperses, to obtain dispersed dye during application.For example that structural formula (I), (II) and structural formula (III) is represented former dyestuff carries out corpusculed with pulverizers such as sand mill or shredders after mixing by above-mentioned proportioning in the presence of auxiliary agent, water or other wetting agent, obtain dispersed dye; Former dyestuff that also can structural formula (I), (II) and structural formula (III) is represented carries out mixing with above-mentioned ratio after corpusculed is handled with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other wetting agent in addition, obtains dispersed dye.Usually, auxiliary agent is 0.8～5: 1 with the ratio of former dyestuff weight.
Described auxiliary agent is dispersed dye dispersion agent commonly used, diffusants etc. when composite, one of preferred following or its several mixture arbitrarily: anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Particularly, naphthalene sulfonic acidformaldehyde condensation product such as dispersing agent NNO, alkyl naphthalene sulfonic acid formaldehyde condensation products such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic formaldehyde condensation compound such as dispersing agent CNF etc., sulfonated lignin such as sodium lignosulfonate (as commercial dispersants Reax 83A, Reax 85A) etc.
The dispersed dye that adopt disperse dye composition of the present invention to obtain, the liquid state after can corpusculed, emulsifiable paste attitude or with spray-drying process etc. carry out dried powdery, graininess is supplied with dyeing.When the dispersed dye made from disperse dye composition of the present invention dye Polyester Fibers,, can obtain to have that coloured light is gorgeous by adjusting proportion among different, the mazarine dyeing and weaving thing of premium propertiess such as good dispersity, sun-proof, washable, perspiration resistance.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
With the B component of the component A of 89 gram formulas (I-1), 11 gram formulas (II-1), the sodium lignosulfonates of 195 grams, add water piece together mix after, grind with shredder and to disperse, spraying drying gets product.This dyestuff can offer the good mazarine of the every fastness ability of fabric.
Embodiment 2:
With the B component of the component A of 84 gram formulas (I-1), 10 gram formulas (II-1), the component C of 6 gram formulas (III-1), the sodium lignosulfonates of 195 grams, add water piece together mix after, grind with shredder and to disperse, spraying drying gets product.This dyestuff can offer the good mazarine of the every fastness ability of fabric.
Embodiment 3～12:
According to data shown in the table 1, with component A, B component, component C, auxiliary agent, add water and piece together to mix after, grind dispersion with shredder, spraying drying makes finished product then.
Table 1
Embodiment 24:
Respectively getting 0.5 dispersed dye that make of gram embodiment 1～23 is dispersed in 500 ml waters, mix with 60 milliliters water after drawing 20 milliliters, transferring dye bath PH with acetic acid is 5, be warming up to 70 ℃ put into simultaneously 2 the gram trevira dye, in 30 minutes, be warmed up to 130 ℃ by 70 ℃, be incubated 30 minutes, begin sampling when being cooled to 90 ℃.Observe sample cloth coloured light, adopt that GB GB/T3921-1997, GB/T3920-1997, GB/T3922-1997, GB/T8427-1998 test respectively that it is washable, rub resistance, perspiration resistance, sun-resistant fastness, the results are shown in Table 2.
Table 2
Test result shows: the every fastness excellent property of dispersed blue dye provided by the invention, composite effect is remarkable.
Claims (6)
1. disperse dye composition, basically form suc as formula the component C shown in (III) suc as formula the component A shown in (I), B component and one or more structures by one or more structures, based on described component A, B component and component C, described component A weight fraction is 60～95%, described B component weight fraction is 1～30%, and described component C weight fraction is 1～15%;
In the formula (I), X, Y independently are nitro, cyano group or halogen separately;
Z is-NHCOR
3Or-OR
4, R wherein
3, R
4Be C
1～C
4Alkyl;
W is hydrogen or C
1～C
4Alkoxyl group;
R
1, R
2Separate is C
1～C
4Alkyl or C
1～C
4Substituted substituted alkyl of H in the alkyl, in the described substituted alkyl substituting group be hydroxyl or cyano group or-OCOR
5, or C
1～C
4Alkoxyl group, R wherein
5Be C
1～C
4Alkyl;
In the formula (III),
V is cyano group or nitro;
R
12Be methyl or kharophen;
R
13, R
14Independent separately is ethyl or cyanoethyl or methoxy ethyl or allyl group or hydroxyethyl or butyl;
Described B component is one of following or two or more mixture wherein:
2. disperse dye composition as claimed in claim 1 is characterized in that described disperse dye composition is made up of the component A of weight fraction 60～95%, the B component of weight fraction 1～30% and the component C of weight fraction 1～15%.
3. disperse dye composition as claimed in claim 2 is characterized in that described disperse dye composition is made up of the component A of weight fraction 65～95%, the B component of weight fraction 1～25% and the component C of weight fraction 1～10%.
4. as the described disperse dye composition of one of claim 1～3, it is characterized in that described component A is one of following or two or more composition wherein:
5. as the described disperse dye composition of one of claim 1～3, it is characterized in that described component C is one of following or two or more composition wherein:
6. disperse dye composition as claimed in claim 1 is characterized in that described disperse dye composition is the mixture of the compound (III-1) of the compound (II-1) of compound (I-1), weight fraction 1～25% of weight fraction 65～95% and weight fraction 1～10%:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101549153A CN100558822C (en) | 2006-11-29 | 2006-11-29 | Disperse blue dye composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101549153A CN100558822C (en) | 2006-11-29 | 2006-11-29 | Disperse blue dye composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1974679A CN1974679A (en) | 2007-06-06 |
| CN100558822C true CN100558822C (en) | 2009-11-11 |
Family
ID=38125046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101549153A Active CN100558822C (en) | 2006-11-29 | 2006-11-29 | Disperse blue dye composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100558822C (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100560B (en) * | 2007-07-24 | 2010-08-11 | 浙江龙盛染料化工有限公司 | Deep color dispersion dyes composition |
| CN101982511B (en) * | 2010-09-18 | 2013-12-04 | 浙江万丰化工有限公司 | Blue disperse dye complex |
| CN102229756B (en) * | 2011-04-29 | 2013-12-25 | 浙江闰土股份有限公司 | Mesothermal disperse blue dye composition |
| CN104710837A (en) * | 2013-12-31 | 2015-06-17 | 江苏吉华化工有限公司 | Disperse blue dye composition |
| CN104559321B (en) * | 2015-01-29 | 2017-01-18 | 浙江昱泰染化科技有限公司 | Disperse black dye composition, dye product and application |
| CN106479219B (en) * | 2015-08-24 | 2018-06-29 | 杭州福莱蒽特精细化工有限公司 | A kind of high dye uptake it is dark blue to black disperse dye composition |
| CN105602284B (en) * | 2015-12-31 | 2017-12-12 | 浙江闰土股份有限公司 | A kind of blue disperse dye composition, blue disperse dye and its production and use |
| CN105670341B (en) * | 2015-12-31 | 2018-04-20 | 浙江闰土股份有限公司 | A kind of blue disperse dye composition, blue disperse dye and its preparation method and application |
| CN105585876B (en) * | 2015-12-31 | 2018-05-25 | 浙江闰土股份有限公司 | A kind of disperse dye composition, disperse dyes and its preparation method and application |
| CN106084886B (en) * | 2016-06-12 | 2017-08-29 | 沈金火 | A kind of blue disperse dye mixture and disperse dyes |
| CN109880401A (en) * | 2019-03-02 | 2019-06-14 | 浙江欧亚数码科技有限公司 | A kind of dispersed blue dye and its preparation process |
| CN110305500B (en) * | 2019-06-20 | 2021-03-19 | 杭州吉华江东化工有限公司 | Dye composition, disperse dye product containing dye composition and application of disperse dye product |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096523A (en) * | 1993-02-17 | 1994-12-21 | Basf公司 | The azo-dye mixer of navy to black hues |
| CN1075142C (en) * | 1994-04-19 | 2001-11-21 | 日本化药株式会社 | Disperse dye composition and method for dyeing hydrophobic fiber material therewith |
-
2006
- 2006-11-29 CN CNB2006101549153A patent/CN100558822C/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096523A (en) * | 1993-02-17 | 1994-12-21 | Basf公司 | The azo-dye mixer of navy to black hues |
| CN1075142C (en) * | 1994-04-19 | 2001-11-21 | 日本化药株式会社 | Disperse dye composition and method for dyeing hydrophobic fiber material therewith |
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| Publication number | Publication date |
|---|---|
| CN1974679A (en) | 2007-06-06 |
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