CN102532941B - Composite brilliant blue disperse dye - Google Patents
Composite brilliant blue disperse dye Download PDFInfo
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- CN102532941B CN102532941B CN2011104573403A CN201110457340A CN102532941B CN 102532941 B CN102532941 B CN 102532941B CN 2011104573403 A CN2011104573403 A CN 2011104573403A CN 201110457340 A CN201110457340 A CN 201110457340A CN 102532941 B CN102532941 B CN 102532941B
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Abstract
The invention discloses a composite brilliant blue disperse dye, which mainly comprises the components in parts by weight as follows: 5-25 parts of dye monomer A shown as formula (I) and 0.05-2 parts of dye monomer B shown as formula (II). The composite brilliant blue disperse dye can be further added with an accessory ingredient. The composite brilliant blue disperse dye is suitable for dyeing polyester materials, coloration and printing. The composite brilliant blue disperse dye has extremely excellent high temperature hot melting dyeing property, excellent fastness, and good insolation fastness, sublimation fastness and washing fastness.
Description
(1) technical field
The present invention relates to a kind of composite brilliant blue disperse dye.
(2) background technology
From the textile fabric present situation, the shared ratio of the fabric that has multiple fiber combinations to form increases year by year, and some the medium-to-high grade fabrics as domestic, comprise polyester blended fabric etc.The dispersed dye of supply in the market, can't well meet the printing and dyeing needs of such textiles: its thermal migration and washing fastness are not ideal enough, have affected the various wet fastness of dope dyeing, and peripheral environment is also brought to more pollution.
(3) summary of the invention
For overcoming the deficiency of existing dispersed dye, the object of the invention is to provide the composite brilliant blue disperse dye that a kind of dye uptake is high, washing fastness good, fastness is good, heat-resisting transport property is little, is suitable for the dyeing of multifilament fabric as the polyester blended fabric.
The technical solution used in the present invention is:
A kind of composite brilliant blue disperse dye mainly forms by following mass parts by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II):
The 5-25 mass parts suc as formula the dye monomer A shown in (I)
0.05-2 mass parts suc as formula the dye monomer B shown in (II)
Preferred described composite brilliant blue disperse dye mainly forms by following mass parts by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II):
The 5-15 mass parts suc as formula the dye monomer A shown in (I)
0.05-0.15 mass parts suc as formula the dye monomer B shown in (II).
The implication of above-mentioned " mainly " refers to that the active coloring component of described composite brilliant blue disperse dye is chromatid A and the chromatid B combination with above-mentioned mass fraction, in dyestuff, can also add other on color not impact but dyeing other auxiliary agents commonly used.
Composite brilliant blue disperse dye of the present invention, can be composed of the following components: the 5-25 mass parts suc as formula the dye monomer A shown in (I), the 0.05-2 mass parts suc as formula the dye monomer B shown in (II).This is the former dyestuff that does not add auxiliary agent.
Further, described composite reactive blue dye can also comprise auxiliary agent, and described composite brilliant blue disperse dye is comprised of following component and auxiliary agent:
The 5-25 mass parts suc as formula the dye monomer A shown in (I), 0.05-2 mass parts suc as formula the dye monomer B shown in (II).
Described auxiliary agent quality consumption is generally 2.7～18.8 times of total mass of dye monomer A and dye monomer B, is preferably 5.6～～18.8 times of total mass of dye monomer A and dye monomer B.
Preferred, described composite reactive blue dye forms by following mass fraction by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II) and auxiliary agent: suc as formula the dye monomer A 5-25 mass parts shown in (I), suc as formula the dye monomer B 0.05-2 mass parts shown in (II), 2.7～18.8 times of the total mass that auxiliary agent quality consumption is dye monomer A and dye monomer B, preferred, the total mass of dye monomer A, dye monomer B and auxiliary agent is 100 mass parts.
Preferred, described composite reactive blue dye forms by following mass fraction by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II) and auxiliary agent: suc as formula the dye monomer A 5-15 mass parts shown in (I), suc as formula the dye monomer B 0.05-0.15 mass parts shown in (II), 5.6～18.8 times of the total mass that auxiliary agent quality consumption is dye monomer A and dye monomer B, preferred, the total mass of dye monomer A, dye monomer B and auxiliary agent is 100 mass parts.
Most preferred, described composite reactive blue dye forms by following mass fraction by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II) and auxiliary agent: suc as formula the dye monomer A 5-11 mass parts shown in (I), suc as formula the dye monomer B 0.05-0.13 mass parts shown in (II), 8～18.8 times of the total mass that auxiliary agent quality consumption is dye monomer A and dye monomer B, preferred, the total mass of dye monomer A, dye monomer B and auxiliary agent is 100 mass parts.
Due to the singularity of dye industry, be difficult to also there is no need to make sterling, usually generally can be with a small amount of impurity in some making processes.
Auxiliary agent of the present invention is the dyestuff usual auxiliaries.Usually can be one of following or the mixture of two or more arbitrary proportions: naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, sulfonated lignin or benzyl naphthalenesulfonate formaldehyde condensation compound.Described naphthalene sulfonic acidformaldehyde condensation product is as dispersing agent NNO (naphthalene sulfonic acidformaldehyde condensation product); The alkyl naphthalene sulfonic acid formaldehyde condensation products is as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde); The benzyl naphthalenesulfonate formaldehyde condensation compound is as dispersing agent CNF (benzyl naphthalenesulfonate formaldehyde condensation compound); Sulfonated lignin are as sodium lignosulfonate (as dispersion agent Reax83A, the Reax85A sold on market) etc.This is auxiliary agent commonly used as well known to those skilled in the art.
The preparation method of composite brilliant blue disperse dye provided by the invention is: dye monomer A, dye monomer B, the auxiliary agent that will measure ratio add in water or other wetting agent, carry out grinding distribution with shredder, then spraying drying makes described composite brilliant blue disperse dye.This is to well known to a person skilled in the art the preparation method.Above-mentioned dye monomer A, dye monomer B, can adopt respectively commercially available prod C.I. EX-SF DISPERSE BLUE EX-SF 300 354 former dyestuffs, the former dyestuff of C.I. DISPERSE YELLOW 184:1.
Also can prepare as follows by composite brilliant blue disperse dye of the present invention: first by dye monomer A and auxiliary agent 1, make finished product dyestuff C.I. EX-SF DISPERSE BLUE EX-SF 300 354, by dye monomer B and auxiliary agent 2, make finished product dyestuff C.I. DISPERSE YELLOW 184:1.By above-mentioned finished product dyestuff C.I. EX-SF DISPERSE BLUE EX-SF 300 354, finished product dyestuff C.I. DISPERSE YELLOW 184:1 and auxiliary agent 3 by metering than after adding the water blending, grinding distribution, and then spraying drying makes described composite brilliant blue disperse dye; Or directly buy finished product dyestuff C.I. EX-SF DISPERSE BLUE EX-SF 300 354 and finished product C.I. DISPERSE YELLOW 184:1, then with auxiliary agent 4 by metering than after adding the water blending, grinding distribution, and then spraying drying makes described composite brilliant blue disperse dye.The consumption of described finished product dyestuff C.I. EX-SF DISPERSE BLUE EX-SF 300 354 with the quality of dye monomer A wherein measure, the consumption of finished product dyestuff C.I. DISPERSE YELLOW 184:1 measures with the quality of dye monomer B wherein.Described auxiliary agent 1, auxiliary agent 2, auxiliary agent 3 or auxiliary agent 4 mean the step of using in different step, and can mean identical can be also different auxiliary agents, and those skilled in the art should choose suitable auxiliary agent and prepare dyestuff.
The consumption of described water is generally 1～2 times of total mass of all raw materials.
Composite brilliant blue disperse dye provided by the invention, a kind of dispersed dye of bright blue coloured silk are provided, blueness is very gorgeous, be highly suitable for dying polyester material, yarn dyeing and stamp, high temperature pad-dry-cure dyeing performance is splendid, the fastness excellent property, as sunlight fastness, fastness to sublimation, wash resistant fastness all show well.
(4) accompanying drawing explanation
The dyeing photo of the composite brilliant blue disperse dye that Fig. 1 commercial dye C.I. EX-SF DISPERSE BLUE EX-SF 300 354, C.I. DISPERSE YELLOW 184:1 and embodiment 1 make.
(5) embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1-8
According to continuous data shown in table 1, by dye monomer A (the former dyestuff of C.I. EX-SF DISPERSE BLUE EX-SF 300 354, purchased from Zhejiang rich Australia dyestuffs industries company limited), dye monomer B (the former dyestuff of C.I. DISPERSE YELLOW 184:1, purchased from Zhejiang rich Australia dyestuffs industries company limited), after auxiliary agent (Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl naphthalenesulfonate formaldehyde condensation compound), dispersing agent NNO (naphthalene sulfonic acidformaldehyde condensation product), sodium lignosulfonate) adds the water blending, carry out grinding distribution with shredder, spraying drying gets final product.
Table 1
Example 9-16
According to continuous data shown in table 2, by C.I. EX-SF DISPERSE BLUE EX-SF 300 354 (commercial dyes, monomer A content is 50%, all the other are auxiliary agent, purchased from Zhejiang rich Australia dyestuffs industries company limited), C.I. DISPERSE YELLOW 184:1 (commercial dye, monomers B content is 10%, all the other are auxiliary agent, purchased from Zhejiang rich Australia dyestuffs industries company limited), auxiliary agent (Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl naphthalenesulfonate formaldehyde condensation compound), dispersing agent NNO (naphthalene sulfonic acidformaldehyde condensation product), sodium lignosulfonate) after adding the water blending, carry out grinding distribution with shredder, spraying drying.
Table 2
Embodiment 17
Respectively get the composite brilliant blue disperse dye that 0.5 gram embodiment 1-16 makes, be dispersed in the water of 500 milliliters, mix with 60 ml waters after drawing 20 milliliters.Adjust dye bath pH=5 with acetic acid, be warming up to 70 ℃ and put into wash/cotton of 2 grams simultaneously and dyeed, in 30 minutes, temperature rises to 130 ℃ (2 normal atmosphere) by 70 ℃, is incubated 30 minutes, starts the sampling to the cloth after dyeing while being cooled to 90 ℃ and is detected.Adopt that GB GB/T3921-1997, GB/T3920-1997, GB/T8427-1998, GB/T5718-1997. test respectively that it is water-fastness, rub resistance, colour fastness to light and sub limation fastness.Test result is in Table 3.And the cloth after the composite brilliant blue disperse dye that embodiment 1 is made dyeing takes pictures, accompanying drawing 1 is shown in by photo.
Table 3
| The embodiment title | Water-fastness | Rub resistance | Fast light | Sublimation fastness (90 ℃) |
| Embodiment 1 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 2 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 3 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 4 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 5 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 6 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 7 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 8 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 9 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 10 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 11 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 12 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 13 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 14 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 15 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
| Embodiment 16 | 4 grades | 4～5 grades | 6 grades | 4～5 grades |
Comparative example 1-2
Respectively get 0.5 gram C.I. EX-SF DISPERSE BLUE EX-SF 300 354 (commercial dyes, monomer A content is 50%, all the other are auxiliary agent, purchased from Zhejiang rich Australia dyestuffs industries company limited), C.I. DISPERSE YELLOW 184:1 (commercial dye, monomers B content is 10%, and all the other are auxiliary agent, purchased from Zhejiang rich Australia dyestuffs industries company limited), be dispersed in the water of 500 milliliters, mix with 60 ml waters after drawing 20 milliliters.Adjust dye bath pH=5 with acetic acid, be warming up to 70 ℃ and put into wash/cotton of 2 grams simultaneously and dyeed, in 30 minutes, temperature rises to 130 ℃ (2 normal atmosphere) by 70 ℃, be incubated 30 minutes, take out while being cooled to 90 ℃, after drying, the cloth after dyeing is taken pictures, accompanying drawing 1 is shown in by photo.
From accompanying drawing 1, can find out, the blueness that 354 dyeing of C.I. EX-SF DISPERSE BLUE EX-SF 300 obtain is darker, partially red, and after C.I. DISPERSE YELLOW 184:1 dyeing, is the yellow with fluorescence, and what composite brilliant blue disperse dye dyeing obtained is more gorgeous blueness, slightly partially greenish blue.
Embodiment 18
Get the composite brilliant blue disperse dye that embodiment 1～3 makes, take the commercial dye Disperse Blue-60 as standard specimen, after equal conditions dyeing, test its color scale, acquired results is in Table 4.Can find out both difference.
Table 4
Claims (10)
1. a composite brilliant blue disperse dye is characterized in that described composite brilliant blue disperse dye mainly forms by following mass parts by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II):
The 5-25 mass parts suc as formula the dye monomer A shown in (I)
0.05-2 mass parts suc as formula the dye monomer B shown in (II)
2. composite brilliant blue disperse dye according to claim 1 is characterized in that described composite brilliant blue disperse dye mainly forms by following mass parts by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II):
The 5-15 mass parts suc as formula the dye monomer A shown in (I)
0.05-0.15 mass parts suc as formula the dye monomer B shown in (II).
3. composite brilliant blue disperse dye according to claim 1 is characterized in that described composite brilliant blue disperse dye is composed of the following components:
The 5-25 mass parts suc as formula the dye monomer A shown in (I), 0.05-2 mass parts suc as formula the dye monomer B shown in (II).
4. composite brilliant blue disperse dye according to claim 1 is characterized in that described composite brilliant blue disperse dye is comprised of following component and auxiliary agent:
The 5-25 mass parts suc as formula the dye monomer A shown in (I), 0.05-2 mass parts suc as formula the dye monomer B shown in (II).
5. composite brilliant blue disperse dye according to claim 4,2.7～18.8 times of the total mass that the quality consumption that it is characterized in that described auxiliary agent is dye monomer A and dye monomer B.
6. composite brilliant blue disperse dye according to claim 5,5.6～18.8 times of the total mass that the quality consumption that it is characterized in that described auxiliary agent is dye monomer A and dye monomer B.
7. composite brilliant blue disperse dye according to claim 6, it is characterized in that described composite brilliant blue disperse dye forms by following mass fraction by the dye monomer A suc as formula shown in (I) with suc as formula the dye monomer B shown in (II) and auxiliary agent: the 5-15 mass parts suc as formula the dye monomer A shown in (I), 0.05-0.15 mass parts suc as formula the dye monomer B shown in (II), 5.6～18.8 times of the total mass that the quality consumption of auxiliary agent is dye monomer A and dye monomer B.
8. according to the described composite brilliant blue disperse dye of one of claim 4～7, it is characterized in that described auxiliary agent is one of following or the mixture of two or more arbitrary proportions: naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, sulfonated lignin or benzyl naphthalenesulfonate formaldehyde condensation compound.
9. composite brilliant blue disperse dye according to claim 8, is characterized in that described alkyl naphthalene sulfonic acid formaldehyde condensation products is condensation compound of methyl naphthalene sulfonic acid and formaldehyde.
10. composite brilliant blue disperse dye according to claim 8, is characterized in that described sulfonated lignin are sodium lignosulfonate.
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| CN2011104573403A CN102532941B (en) | 2011-12-31 | 2011-12-31 | Composite brilliant blue disperse dye |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103740136B (en) * | 2013-12-29 | 2016-01-06 | 浙江龙盛集团股份有限公司 | A kind of high fastness disperses bright blue dye composite |
| CN107418249B (en) * | 2017-06-23 | 2019-08-16 | 浙江博澳染料工业有限公司 | A kind of bright blue dyestuff of economy composite type dispersion |
| CN114262526A (en) * | 2021-12-30 | 2022-04-01 | 江苏德旺数码科技有限公司 | Disperse dye composition and disperse brilliant blue dye |
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| WO2006068823A1 (en) * | 2004-12-20 | 2006-06-29 | Eastman Kodak Company | Thermal donor for high-speed printing |
| WO2007123825A3 (en) * | 2006-04-18 | 2008-01-17 | Eastman Kodak Co | Slipping layer for dye-donor element |
| CN102206430A (en) * | 2011-04-06 | 2011-10-05 | 浙江闰土股份有限公司 | Environment-friendly type yellow disperse dyestuff composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JPH073179A (en) * | 1993-06-15 | 1995-01-06 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JP2952134B2 (en) * | 1993-07-09 | 1999-09-20 | キヤノン株式会社 | Ink jet printing method and printed matter |
| JP3880151B2 (en) * | 1996-10-11 | 2007-02-14 | キヤノン株式会社 | Water-soluble addition polymer, water-based ink using the same, ink-jet recording method and ink-jet printing method using the water-based ink |
| US7582121B2 (en) * | 2005-05-31 | 2009-09-01 | L'oreal S.A. | Composition for dyeing keratin fibers, comprising at least one diamino-N,N-dihydropyrazolone derivative, at least one coupler, and at least one heterocyclic direct dye |
| KR20080094954A (en) * | 2006-02-17 | 2008-10-27 | 훈츠만 어드밴스트 머티리얼스(스위처랜드) 게엠베하 | Process for dyeing polyester |
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| US5166236A (en) * | 1990-12-05 | 1992-11-24 | E. I. Du Pont De Nemours And Company | Crosslinkable fluoro elastomer composition |
| WO2006068823A1 (en) * | 2004-12-20 | 2006-06-29 | Eastman Kodak Company | Thermal donor for high-speed printing |
| WO2007123825A3 (en) * | 2006-04-18 | 2008-01-17 | Eastman Kodak Co | Slipping layer for dye-donor element |
| CN102206430A (en) * | 2011-04-06 | 2011-10-05 | 浙江闰土股份有限公司 | Environment-friendly type yellow disperse dyestuff composition |
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Address after: 312300, No. three, No. 3, Shangyu economic and Technological Development Zone, Hangzhou Bay, Shangyu District, Zhejiang, Shaoxing Patentee after: Zhejiang Bo'ao new materials Co., Ltd Address before: 312369 No.3, Weisan Road, Hangzhou Bay Fine Chemical Park, Shangyu City, Shaoxing City, Zhejiang Province Patentee before: ZHEJIANG BOAO DYESTUFF INDUSTRY Co.,Ltd. |