CN104371359B - Disperse dye composition and disperse dye and preparation method and use thereof - Google Patents
Disperse dye composition and disperse dye and preparation method and use thereof Download PDFInfo
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- CN104371359B CN104371359B CN201310751296.6A CN201310751296A CN104371359B CN 104371359 B CN104371359 B CN 104371359B CN 201310751296 A CN201310751296 A CN 201310751296A CN 104371359 B CN104371359 B CN 104371359B
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- 239000000986 disperse dye Substances 0.000 title claims abstract description 84
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 239000004744 fabric Substances 0.000 claims abstract description 23
- 238000004043 dyeing Methods 0.000 claims abstract description 22
- 239000000975 dye Substances 0.000 claims description 100
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000002270 dispersing agent Substances 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- 239000002671 adjuvant Substances 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052794 bromium Inorganic materials 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- -1 acetoxyl group Chemical group 0.000 claims description 2
- RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- KHZRTXVUEZJYNE-UHFFFAOYSA-N 3-[4-[(2,6-dichloro-4-nitrophenyl)diazenyl]-n-ethylanilino]propanenitrile Chemical compound C1=CC(N(CCC#N)CC)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl KHZRTXVUEZJYNE-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 229920000728 polyester Polymers 0.000 abstract description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 36
- 239000000047 product Substances 0.000 description 36
- 230000000052 comparative effect Effects 0.000 description 24
- 239000000725 suspension Substances 0.000 description 24
- 239000000835 fiber Substances 0.000 description 12
- 238000011056 performance test Methods 0.000 description 12
- 238000005070 sampling Methods 0.000 description 12
- 238000010998 test method Methods 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 11
- 0 CCC(C1C(CC2)CC22C=*(C)C2)C1*=C Chemical compound CCC(C1C(CC2)CC22C=*(C)C2)C1*=C 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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Abstract
The invention discloses a disperse dye composition and a disperse dye, and a preparation method and use thereof, and the disperse dye is suitable for dyeing and printing of fabrics, especially polyester and blended fabrics thereof.
Description
Technical field
The present invention relates to a kind of disperse dye composition, disperse dyes and its preparation method and purposes.Described dispersion dye
Material is applied to dyeing and the stamp of fabric, particularly terylene and its blend fabric.
Background technology
Environmental consciousness with today's society generally strengthens, and realizing low-carbon environment-friendly has been trend of the times, and low-carbon economy becomes
Inexorable trend for economic development.Dye industry has realized that this opportunities and challenges, therefore gradually develops novelty, environmental protection
Dyestuff.
Content of the invention
The present invention provides the economic and environment-friendly type dispersion dye that a kind of pH value range is wide, light fastness is good, compatibility is excellent, intensity is high
Material.
The present invention provides a kind of disperse dye composition it is characterised in that including：
As formula（1）Shown component A：
One or more are as formula（2）Shown component B：
Formula（2）In, X1For bromine or chlorine；R1、R2Each stand alone as C1～C4Alkyl；
One or more are as formula（3）Shown component C：
Formula（3）In, X2For bromine or chlorine, R3、R4Each stand alone as C1～C4Alkyl or CH2CH=CH2, Y is C1～C4Alkane
Base；
Optional one or more are as formula（4）Shown component D：
Formula（4）In, X3、X4Each stand alone as hydrogen, chlorine or bromine, R5、R6Each stand alone as C2～C4Alkyl, or C1～C4Alkane
The group that one of base hydrogen is replaced by cyano group, phenyl, acetoxyl group or benzoyloxy；Wherein component D is not C.I. dispersion
Orange 76；
Optional one or more are as formula（5）Shown component E：
Formula（5）In, X5、X6Each stand alone as hydrogen, chlorine or nitro, R7For C1～C4Alkyl；
Optional one or more are as formula（6）Shown component F：
Formula（6）In, X7For cyano group or nitro, R8For C1～C4Alkyl amido or C1～C4Alkyl, R9、R10Each independent
For C1～C4Alkyl；With
Optional as formula（7）Shown component G：
According to disperse dye composition of the present invention it is preferable that described component B be one of following compound or
Two kinds：
According to disperse dye composition of the present invention it is preferable that described component C be one of following compound or
Two or more：
According to disperse dye composition of the present invention it is preferable that described component D be one of following compound or
Two or more：
According to disperse dye composition of the present invention it is preferable that described component E be one of following compound or
Two or more：
According to disperse dye composition of the present invention it is preferable that described component F be one of following compound or
Two or more：
According to disperse dye composition of the present invention it is preferable that component B is as formula（2-1）And formula（2-2）Shownization
One of compound or two kinds：
Component C is as following formula（3-1）Extremely（3-4）One of shown compound or two or more：
Based on the gross weight of described disperse dye composition, the percentage by weight of component A is 2-73%, preferably 2-72%,
Or preferably 2-60%, or preferably 2-51%, or preferably 3-50%, or preferably 3-6%.The percentage by weight of component B is 7-
40%, preferably 7-37%, or preferably 12-39%, or preferably 12-37%.The percentage by weight of component C is 20-58%, preferably
For 38-58%, or preferably 20-48%, or preferably 30-55%, or preferably 35-55%.The percentage by weight of component D is 0-
70%, preferably 2-50%, or preferably 3-6%.The percentage by weight of component E is 0-10%, preferably 2-6%.The weight of component F
Percentage ratio is 0-47%, preferably 1-10%.The percentage by weight of component G is 0-47%, preferably 1-10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss, including：
Percentage by weight is 2～73% component A,
Percentage by weight is 7～40% component B,
Percentage by weight is 20～58% component C,
Optional percentage by weight is 0～70% component D,
Optional percentage by weight is 0～10% component E,
Optional percentage by weight is 0～47% component F, and
Optional percentage by weight is 0～47% component G.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 3～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 3～6%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component D is 2～50%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
According to disperse dye composition of the present invention it is preferable that gross weight based on described compositionss,
The percentage by weight of component A is 2～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
In actual production process, each dye component of the present invention generally may be miscellaneous with some by-products and other
Matter, but as long as do not affect the enforcement of the present invention.
The present invention also provides a kind of disperse dyes it is characterised in that comprising to combine according to disperse dyes of the present invention
Thing and adjuvant.
According to disperse dyes of the present invention it is characterised in that described adjuvant includes auxiliary agent and water.
According to disperse dyes of the present invention it is characterised in that described auxiliary agent includes following one or more
Combination：Naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulfate, surfactant, antibacterial, or other dyestuffs divide
Powder.
According to disperse dyes of the present invention it is characterised in that the weight of described auxiliary agent and disperse dye composition it
Than for 0.3～4:1.
The present invention also provides a kind of method prepared according to disperse dyes of the present invention, is characterised by, including following
Step：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；
Or described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed
Close.
Disperse dyes of the present invention, can be liquid after being ground with sand mill or grinder（Generally solid content be 20～
50%）, can be powdery or graininess after spray drying（Generally solid content is 87～96%）.
The present invention also provide a kind of according to disperse dyes of the present invention be used for the dyeing of fabric and the purposes of stamp.
The present invention also provides a kind of fabric it is characterised in that by using carrying out according to disperse dyes of the present invention
Dyeing and stamp prepare.
The pH value range of the disperse dyes of the present invention is wide, light fastness is good, compatibility is excellent, intensity is high.
Specific embodiment
Embodiment
With reference to embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
In an embodiment, component A, B of the present invention, C and optional component D, E, F, G, by certain proportioning and auxiliary agent and
After water blending, it is ground dispersion with sand mill and makes slurry, or be spray-dried further, thus making dyestuff.
Described component A, B, C, D, E, F, G are known dye composition and can commercially buy, or can
Prepared by existing method.
Embodiment 1：
By 15.6 grams of formulas（1）Dye component, 6.1 grams of formulas（2-2）Dye component, 16.3 grams of formulas（3-3）Dye component, 31 grams
Dispersant MF and 31 grams of lignin 85A, add water 200 grams and stir, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 1：
Repeat embodiment 1, except by the formula of embodiment 1（1）Dye component is substituted for following formula（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 1 and comparative example 1 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and measure their intensity using GB/T6688-2008, measurement result is shown in Table 1.
Table 1
| Title | Intensity |
| Embodiment 1 | 102% |
| Comparative example 1 | 100% |
Intensity is high can to reduce dye dosage it is meant that the textile of same depth during printing and dyeing, reduce printing and dyeing cost.
Embodiment 2：
By 15.6 grams of formulas（1）Dye component, 6.1 grams of formulas（2-1）Dye component, 16.3 grams of formulas（3-4）Dye component, 31 grams
Dispersant MF and 31 grams of lignin 83A, add water 200 grams and stir, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 2：
Repeat embodiment 2, except by the formula of embodiment 2（1）Dye component is substituted for following formula（9）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 2 and comparative example 2 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the light fastness that they are measured using AATCC16-2004, the results are shown in Table 2.
Table 2
| Title | Light fastness（40h） |
| Embodiment 2 | 2～3 |
| Comparative example 2 | 2 |
Embodiment 3：
By 15.6 grams of formulas（1）Dye component, 6.1 grams of formulas（2-2）Dye component, 11.4 grams of formulas（3-3）Dye component, 4.9
Gram formula（3-4）Dye component and 11.4 grams of Dispersant MFs, add water 100 grams and stir, and grinding distribution makes liquid dyes
Finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 3：
Repeat embodiment 3, except by the formula of embodiment 3（1）Dye component replaces an accepted way of doing sth（4-1）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 3 and comparative example 3 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, AATCC16-2004, and survey with reference to GB/T2400-2006
Determine their intensity, light fastness and compatibility, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibility |
| Embodiment 3 | 105% | 3 | Ⅱ |
| Comparative example 3 | 100% | 2 | Ⅲ |
Measure compatibility method be：Dyeed with reference to GB/T2394-2003, entered dye from 60 DEG C, when temperature is raised to 80
DEG C when horse back take a sample, take a sample every 10 DEG C later, until 130 DEG C, and, 130 DEG C be incubated 10 minutes, 20 points
Clock, 30 minutes, 50 minutes when separately sampled, take 10 pieces of cloth specimens altogether.It is incubated 50 minutes with 130 DEG C as standard specimen, each shelves temperature is taken
Cloth specimen is sample, whether synchronous observes its foxy.The Pyatyi system of being divided into I, II, III, IV, V（Instrument：Computer color testing instrument
Datacolor600, colour difference formula CMC2：1）.For black hues, calculate DC（Gorgeous degree is poor）、DH（Hue difference）It is respectively less than 0.6
Cloth specimen block number.
I grade：Five pieces and more than five pieces
II grade：Four pieces
III grade：Three pieces
IV grade：Two pieces
V grade：One piece.
Embodiment 4：
By 15.6 grams of formulas（1）Dye component, 6.1 grams of formulas（2-1）Dye component, 16.4 grams of formulas（3-1）Dye component, 31 grams
Dispersant MF and 31 grams of dispersing agent NNOs, add water 200 grams and stir, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, dye
Color obtains the excellent black polyester of every fastness ability.
Comparative example 4：
Repeat embodiment 4, except by the formula of embodiment 4（1）Dye component is substituted for following formula（10）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 4 and comparative example 4 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 4.
Table 4
| Title | Intensity | PH stable scope |
| Embodiment 4 | 107% | 3～9 |
| Comparative example 4 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 5：
By 44 grams of formulas（1）Dye component, 22 grams of formulas（2-2）Dye component, 34 grams of formulas（3-3）Dye component, 31 grams of dispersions
Agent MF and 31 grams of dispersing agent NNOs, add water 200 grams and stir, and grinding distribution is simultaneously dried, and obtains final product dyestuff finished product, dyes
To the excellent black polyester of every fastness ability.
Comparative example 5：
Repeat embodiment 5, except by 44 grams of formulas in embodiment 5（1）Dye component is substituted for 41.4 grams of formulas（10）Dyestuff
Component and 2.6 grams of formulas（11）Outside dye component, other constant.
The dyestuff finished product of embodiment 5 and comparative example 5 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 5 and comparative example 5 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and adopt GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
Value scope, the results are shown in Table 5.
Table 5
| Title | Intensity | PH stable scope |
| Embodiment 5 | 107% | 3～9 |
| Comparative example 5 | 100% | 3～7 |
Note：PH stable scope：With the pH value range of intensity >=95% for pH stable scope.
Embodiment 6：
By 7.8 grams of formulas（1）Dye component, 7.8 grams of formulas（4-1）Dye component, 6.1 grams of formulas（2-1）Dye component, 16.4 grams
Formula（3-1）Dye component, 31 grams of dispersing agent MFs and 31 grams of lignin 85A, add water 200 grams and stir, grinding distribution is simultaneously
It is dried, obtains final product dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 6：
Repeat embodiment 6, except by the formula in embodiment 6（1）Dye component replaces an accepted way of doing sth（8）Outside dye component, its
It is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 6 and comparative example 6 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light the intensity that they are measured using GB/T6688-2008, the results are shown in Table 6.
Table 6
| Title | Intensity |
| Embodiment 6 | 102% |
| Comparative example 6 | 100% |
Embodiment 7 and 8
According to the compositing formula in table 7, dyestuff finished product is obtained similarly to Example 6.
Table 7 unit：Gram
The dyestuff finished product of embodiment 7 and embodiment 8 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 7 and embodiment 8 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and their compatibility is measured using the method for embodiment 3, the results are shown in Table 8.
Table 8
| Embodiment | Compatibility |
| 7 | Ⅱ |
| 8 | Ⅱ |
Embodiment 9
According to the compositing formula in table 9, dyestuff finished product is obtained similarly to Example 6.
Table 9 unit：Gram
The dyestuff finished product of embodiment 9 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, the dyestuff finished product weighing 0.5 gram of embodiment 9 to the water of 250ml,
Make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath pH to 5 with acetic acid,
Then it is warmed up to 60 DEG C, be respectively put into 2g polyester fiber simultaneously and carry out high-temperature pressure dyeing, be warmed up to 130 DEG C in 35 minutes,
Insulation 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and its light fastness is measured using AATCC16-2004 method, the results are shown in Table 10.
Table 10
| Embodiment | Light fastness |
| 9 | 3 |
Embodiment 10-15
According to the compositing formula in table 11, dyestuff finished product is obtained similarly to Example 6.
Table 11 unit：Gram
The dyestuff finished product of embodiment 10-15 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 10-15 respectively to 250ml
Water in, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and simultaneously adopt AATCC16-2004, and using the method for embodiment 3 measure they light fastness,
Compatibility, the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Compatibility |
| 10 | 2～3 | Ⅱ |
| 11 | 2～3 | Ⅱ |
| 12 | 2～3 | Ⅱ |
| 13 | 2～3 | Ⅱ |
| 14 | 2～3 | Ⅱ |
| 15 | 3 | Ⅱ |
Embodiment 16-17
According to the compositing formula in table 13, add appropriate amount of addition agent, make dyestuff finished product.
Table 13 unit：Gram
The dyestuff finished product of embodiment 16-17 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 16 and 17 respectively extremely
In the water of 250ml, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjusted with acetic acid
Section dye bath pH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, in 35 minutes
It is warmed up to 130 DEG C, be incubated 45 minutes, be cooled to 80 DEG C of samplings.Observe cloth specimen coloured light and they are measured using the method for embodiment 3
Compatibility, the results are shown in Table 14.
Table 14
| Embodiment | Compatibility |
| 16 | Ⅱ |
| 17 | Ⅰ |
Embodiment 18-38
According to the compositing formula in table 15, add appropriate amount of addition agent, make dyestuff finished product.
Table 15 unit：Gram
The dyestuff finished product of embodiment 18-38 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 18-38 respectively to 250ml
Water in, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and simultaneously adopt AATCC16-2004, and using the method for embodiment 3 measure they light fastness,
Compatibility, the results are shown in Table 16.
Table 16
| Embodiment | Light fastness | Compatibility |
| 18 | 2～3 | Ⅰ |
| 19 | 2～3 | Ⅰ |
| 20 | 3 | Ⅱ |
| 21 | 3 | Ⅰ |
| 22 | 3 | Ⅰ |
| 23 | 3 | Ⅰ |
| 24 | 2～3 | Ⅰ |
| 25 | 3 | Ⅰ |
| 26 | 2～3 | Ⅰ |
| 27 | 2～3 | Ⅰ |
| 28 | 3 | Ⅱ |
| 29 | 3 | Ⅱ |
| 30 | 2～3 | Ⅱ |
| 31 | 3 | Ⅱ |
| 32 | 3 | Ⅰ |
| 33 | 2～3 | Ⅰ |
| 34 | 2～3 | Ⅱ |
| 35 | 2～3 | Ⅱ |
| 36 | 3 | Ⅰ |
| 37 | 3 | Ⅰ |
| 38 | 3 | Ⅰ |
Embodiment 39-43
According to the compositing formula in table 17, add appropriate amount of addition agent, make dyestuff finished product.
Table 17 unit：Gram
The dyestuff finished product of embodiment 39-43 is carried out performance test.
Concrete method of testing is as follows：
According to the similar method of GB/T2394-2003, weigh the dyestuff finished product of 0.5 gram of embodiment 39-43 respectively to 250ml
Water in, make disperse dyes suspension.Draw 10ml disperse dyes suspension to mix with the water of 90ml, adjust dye bath with acetic acid
PH to 5, is then warmed up to 60 DEG C, is respectively put into 2g polyester fiber simultaneously and carries out high-temperature pressure dyeing, was warmed up in 35 minutes
130 DEG C, it is incubated 45 minutes, is cooled to 80 DEG C of samplings.
Observe cloth specimen coloured light and simultaneously adopt AATCC16-2004, and using the method for embodiment 3 measure they light fastness,
Compatibility, the results are shown in Table 18.
Table 18
| Embodiment | Light fastness | Compatibility |
| 39 | 2～3 | Ⅱ |
| 40 | 3 | Ⅱ |
| 41 | 2～3 | Ⅱ |
| 42 | 3 | Ⅱ |
| 43 | 3 | Ⅱ |
Claims (21)
1. a kind of disperse dye composition is it is characterised in that include：
Component A as shown in formula (1)：
One or more components B as shown in formula (2)：
In formula (2), X1For bromine or chlorine；R1、R2Each stand alone as C1～C4Alkyl；
One or more components C as shown in formula (3)：
In formula (3), X2For bromine or chlorine, R3、R4Each stand alone as C1～C4Alkyl or CH2CH=CH2, Y is C1～C4Alkyl；
One or more optional components D as shown in formula (4) or formula (4-5)：
In formula (4), X3、X4Each stand alone as hydrogen, chlorine or bromine, R5、R6Each stand alone as C2～C4Alkyl, or C1～C4In alkyl
The group that replaced by cyano group, phenyl, acetoxyl group or benzoyloxy of a hydrogen；Wherein component D is not C.I. disperse orange 76；
One or more optional components E as shown in formula (5)：
In formula (5), X5、X6Each stand alone as hydrogen, chlorine or nitro, R7For C1～C4Alkyl；
One or more optional components F as shown in formula (6)：
In formula (6), X7For cyano group or nitro, R8For C1～C4Alkyl amido or C1～C4Alkyl, R9、R10Each stand alone as C1
～C4Alkyl；With
Optional component G as shown in formula (7)：
Wherein, the gross weight based on described compositionss, the percentage by weight of described component A is 24.5～73%, described component B
Percentage by weight is 7～40%, and the percentage by weight of described component C is 20～58%, and the percentage by weight of optional component D is
0～70%, the percentage by weight of optional component E is 0～10%, and the percentage by weight of optional component F is 0～47%, and
The percentage by weight of optional component G is 0～47%.
2. disperse dye composition according to claim 1 is it is characterised in that described component B is in following compound
One or two：
3. disperse dye composition according to claim 1 and 2 is it is characterised in that described component C is in following compound
One or more：
4. disperse dye composition according to claim 1 and 2 is it is characterised in that described component D is in following compound
One or more：
5. disperse dye composition according to claim 1 and 2 is it is characterised in that described component E is in following compound
One or more：
6. disperse dye composition according to claim 1 and 2 is it is characterised in that described component F is in following compound
One or more：
7. disperse dye composition according to claim 1 and 2 is it is characterised in that component B is as formula (2-1) and formula (2-
2) one of compound shown in or two kinds：
Component C is one of compound or two or more as shown in following formula (3-1) is to (3-4)：
8. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 24.5～50%,
The percentage by weight of component B is 12～39%,
The percentage by weight of component C is 38～58%.
9. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss,
The percentage by weight of component A is 24.5～60%,
The percentage by weight of component B is 7～37%,
The percentage by weight of component C is 30～55%,
The percentage by weight of component D is 3～6%.
10. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss
Amount,
The percentage by weight of component A is 24.5～51%,
The percentage by weight of component B is 12～37%,
The percentage by weight of component C is 35～55%,
The percentage by weight of component E is 2～6%.
11. disperse dye compositions according to claim 1 and 2 are it is characterised in that gross weight based on described compositionss
Amount,
The percentage by weight of component A is 24.5～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component F is 1～10%.
12. disperse dye composition according to claim 1 and 2 is it is characterised in that gross weight based on described compositionss
Amount,
The percentage by weight of component A is 24.5～72%,
The percentage by weight of component B is 7～40%,
The percentage by weight of component C is 20～48%,
The percentage by weight of component G is 1～10%.
A kind of 13. disperse dyes are it is characterised in that comprise the disperse dyes group according to any one of claim 1～12
Compound and adjuvant.
14. disperse dyes according to claim 13 are it is characterised in that described adjuvant includes auxiliary agent and water.
15. disperse dyes according to claim 14 it is characterised in that described auxiliary agent include following one or two with
On combination：Sodium sulfate, surfactant, antibacterial or dye dispersant.
16. disperse dyes according to claim 15 it is characterised in that described dye dispersant include following one kind or
Two kinds of combination：Naphthalene sulfonic formaldehyde condensation compound or lignosulfonates.
17. disperse dyes according to any one of claim 14～16 are it is characterised in that described auxiliary agent and disperse dyes
The weight ratio of compositionss is 0.3～4:1.
18. disperse dyes according to any one of claim 13～16 are it is characterised in that described disperse dyes sand milling
Machine or grinder are liquid after grinding, and solid content is 20～50%, or described disperse dyes be spray-dried after for powdery or
Granular, solid content is 87～96%.
A kind of 19. methods of the disperse dyes prepared according to any one of claim 13～18 are it is characterised in that include
Following steps：
After described each dye component is mixed, in the presence of adjuvant, carry out particlized process with sand mill or grinder；Or
Described each dye component is carried out particlized process with sand mill or grinder respectively in the presence of adjuvant, then is mixed.
A kind of 20. disperse dyes according to any one of claim 13～18 are used for the dyeing of fabric and the use of stamp
On the way.
A kind of 21. fabrics are it is characterised in that enter by using the disperse dyes according to any one of claim 13～18
Row dyeing and stamp prepare.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310751296.6A CN104371359B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye and preparation method and use thereof |
| US15/102,669 US10151062B2 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| PCT/CN2014/095585 WO2015101290A1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| ES14876649.6T ES2653737T3 (en) | 2013-12-30 | 2014-12-30 | Composition of dispersed dye, dispersed dye and method of preparation and use thereof |
| KR1020167020366A KR101702513B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
| BR112016012058A BR112016012058B8 (en) | 2013-12-30 | 2014-12-30 | Composition of disperse dye and disperse dye |
| EP14876649.6A EP3147333B1 (en) | 2013-12-30 | 2014-12-30 | Disperse dye composition, disperse dye and preparation method and use thereof |
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| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environment-friendly disperse grey dye |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
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|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environment-friendly disperse grey dye |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black and blue series environment-friendly disperse dye composition |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
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Inventor after: Ruan Jingbo Inventor after: Zhao Guosheng Inventor after: Gu Weidi Inventor after: Ruan Haixing Inventor after: Ye Huaming Inventor after: Jing Xueping Inventor before: Chen Bailong |
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Effective date of registration: 20171018 Address after: Shangyu District of Zhejiang city in Shaoxing Province town road 312368 called mountain Patentee after: Zhejiang Runtu Co., Ltd. Address before: 312368 No. 231 village, Zhenjiang village, Shaoxing, Zhejiang Patentee before: Chen Bailong |