CN106893358B - It is a kind of blue to black disperse dye composition, dye preparations and application - Google Patents
It is a kind of blue to black disperse dye composition, dye preparations and application Download PDFInfo
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- CN106893358B CN106893358B CN201710061604.0A CN201710061604A CN106893358B CN 106893358 B CN106893358 B CN 106893358B CN 201710061604 A CN201710061604 A CN 201710061604A CN 106893358 B CN106893358 B CN 106893358B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
Abstract
The invention discloses a kind of blue to black disperse dye composition, dye preparations and application.It is described blue to black disperse dye composition, including component A, component B, component C and component D, wherein component A is selected from one of compound shown in formula (I) or a variety of, component B is selected from one of compound shown in formula (II) or a variety of, the component C is selected from least one of compound shown in formula (III), and the component D is selected from least one of compound shown in formula (IV).It is described it is blue contain to black disperse dye product described in claim 1 blue to black disperse dye composition and auxiliary agent, the weight ratio of auxiliary agent and disperse dye composition is 0.2~5:1.Indigo plant provided by the invention has the characteristics that every fastness is excellent, lifting force is good when being applied to hydrophobic fiber material dyeing or stamp to black disperse dye composition and dye preparations.
Description
One, technical field
The present invention relates to a kind of indigo plants to black disperse dye composition and dye preparations and its in hydrophobic fiber material
Application in dyeing or stamp.
Two, technical background
Nowadays, all the fashion in the market at home and abroad containing spandex stretch fabric.This kind of product is with higher elastic and excellent
Good resilience performance, soft, comfortable and easy to wear, easy absorbing sweat and the advantages that electrostatic will not be generated.Wash/ammonia stockinette dyeing master
Disperse dyes are used, since affinity of many disperse dyes to spandex is high, stainability is good, disperse dyes are to spandex
Contamination is serious.In fastness test, the disperse dyes being infected on spandex are easy to migrate out from fiber, influence terylene/ammonia
The wet colour fastness of synthetic fibre textile.Many disperse dyes have good rub resistance, washable and color fastness to light on terylene, but
Fastness on spandex can only achieve medium level so as to the demanding product of color fastness in dyeing process exist compared with
Big problem.
Three, summary of the invention
To solve the above problems, the present invention provides a kind of indigo plants to black disperse dye composition and dye preparations and its to answer
With being applied to hydrophobic fiber material dyeing or when stamp, have the characteristics that every fastness is excellent, lifting force is good.
The technical solution adopted by the present invention is that:
A kind of blue to black disperse dye composition, including component A, component B, component C and component D, wherein component A is selected from
One of compound shown in formula (I) is a variety of, and component B is selected from one of compound shown in formula (II) or a variety of, described
Component C is selected from least one of compound shown in formula (III), and the component D is selected from compound shown in formula (IV) at least
One kind, based on the component A, component B, component C and component D, the weight percentage of component A is 5~90%, component B's
Weight percentage is 5~85%, and the weight percentage of component C is 1~45%, the weight percentage of component D is 1~
30%:
In formula (I),
X1For halogen；
R1、R2Respectively stand alone as C1~C4Alkyl；
R3、R4Respectively stand alone as-CH2COOK1Or-C2H4COOK2, wherein K1、K2Respectively stand alone as C1~C4Alkyl；
In formula (II):
R5For hydrogen or C1~C4Alkoxy；
R6、R7、R8Respectively stand alone as C1~C4Alkyl；
In formula (III):
X2、X3Respectively stand alone as hydrogen, halogen, nitro, C1~C4Alkoxy ,-COOC2H4OC2H4OCH3、-SO2- Ph or-
CH2O-Ph, wherein Ph is phenyl；
R9For C1~C4Alkyl；
In formula (IV):
X4、X5Respectively stand alone as hydrogen, halogen or cyano；
R10For hydrogen, C1~C4Alkyl or acetylamino；
R11For C1~C4Alkyl or benzyl.
In the present invention, the C1~C4Alkyl can be methyl, ethyl, n-propyl, isopropyl, normal-butyl, isobutyl group,
Tert-butyl etc., the C1~C4Alkoxy can be methoxyl group, ethyoxyl, positive propoxy, isopropoxy, n-butoxy, isobutyl
Oxygroup, tert-butoxy etc..
Further, halogen preferred Cl or Br.
Further, R1、R2Respectively independent is preferably methyl or ethyl.
Further, R3、R4Respectively stand alone as-CH2COOK1Or-C2H4COOK2, wherein K1、K2Respectively independent preferably methyl or
Ethyl.
Further, R6、R7、R8Respectively independent is preferably methyl or ethyl.
Further, R9Preferably methyl or ethyl.
Further, the dye component A is preferably one of dye composition shown in following formula (I -1)~(I -4)
Or two or more mixture:
Further, the dye component B is preferably one in dye composition shown in following formula (II -1)~(II -5)
Kind or two or more mixtures:
Further, the dye component C is preferably one of dye composition shown in formula (III -1)~(III -11)
Or two or more mixture:
Further, the dye component D is preferably one of dye composition shown in formula (IV -1)~(IV -8)
Or two or more mixture:
Again further, of the present invention blue to black disperse dye composition, dye component A is formula (I -1), (I -
2) at least one of dye composition shown in, dye component B are formula (II -1), in dye composition shown in (II -2)
At least one, dye component C are at least one of dye compositions shown in formula (III -1)~(III -6), and dye component D is
Dye composition shown in formula (IV -1).
Further, the indigo plant is total based on described dye component A, B, C, the D into black disperse dye composition
Weight, wherein the weight percentage of dye component A is 5~90% (preferably 10~70%), and the weight percentage of component B is
5~85% (preferably 5~50%), the weight percentage of component C are 1~45% (preferably 5~40%), the weight of component D
Amount percentage composition is 1~30% (1~20%).
Further, the indigo plant is made of to black disperse dye composition component A, component B, component C, component D.
It is particularly preferred that indigo plant of the present invention is to black disperse dye composition by component A, component B, component C, component
D composition, in which:
Component A is at least one of formula (I -1)~(I -4)；
Component B is at least one of formula (II -1)~(II -5)；
Component C is at least one of formula (III -1)~(III -11)；
Component D is at least one of formula (IV -1)~(IV -8)；
Based on the gross weight of described dye component A, B, C, D, wherein the weight percentage of dye component A is 5~90%
(preferably 10~70%), the weight percentage of component B are 5~85% (preferably 5~50%), the weight percent of component C
Content is 1~45% (preferably 5~40%), and the weight percentage of component D is 1~30% (1~20%).
It is of the present invention blue to black disperse dye composition, as commodity selling or it is applied to textile material coloring
When, it usually also needs that auxiliary agent is added and is post-processed.Therefore, the present invention also provides a kind of blue to black disperse dye product,
It contains described blue to black disperse dye composition and auxiliary agent, and the weight ratio of auxiliary agent and disperse dye composition is 0.2
~5:1.Preferably, the indigo plant is to black disperse dye product by the indigo plant to black disperse dye composition and auxiliary agent group
At.The auxiliary agent is common dispersing agent, diffusant and other surfactants etc. when disperse dyes compound, and preferably is selected from following
One of or in which two or more mixtures: lignosulfonates (lignin 85A, lignin 83A etc.), alkyl naphthalene sulfonic acid formaldehyde
Condensation product (such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulphur
Sour formaldehyde condensation products (dispersing agent CNF) etc..
It is of the present invention blue to black disperse dye product the preparation method is as follows: will form blue to black disperse dye
After the dye monomer compound (former dyestuff) of composition mixes according to the ratio, sand mill or grinder in the presence of auxiliary agent, water
Equal pulverizers carry out corpusculed；In addition can also by dye monomer compound respectively in the presence of auxiliary agent, water sand mill or
The pulverizers such as grinder are mixed in proportion after carrying out corpusculed processing.Disperse blue of the present invention is to black dyes system
Product can be powdery, graininess after spray drying, this is those skilled in the art with being liquid after sand mill or grinder grinding
Well known preparation method, due to can not be by the removing of moisture 100%, so even being powdery or particle in spray-drying process
In the dye preparations of shape, still allow that there are a certain amount of moisture, preferably more than the 10% of dye preparations gross weight.
In addition, it is necessary to which explanation makes the promotion of dyeing effect when dye preparations are applied to the printing and dyeing of textile fabric
Contribution is technically characterized in that dye component contained in the product and ratio.
It is of the present invention blue to black disperse dye composition, also allow to be made with the further compound synergic of other dyestuffs
New composition, or other red, blues or the shading components such as orange are added.
In the present invention, formula (I), (II), (III), dye composition is convenient to by those skilled in the art shown in (IV)
Well known mode synthesizes, and is also referred to introduce in patent CN1208057, US5550217, GB2034734, CN101522816
Method or similar method preparation, commercial goods can also be used.
The present invention provides the indigo plants to black disperse dye composition and dye preparations to dye in hydrophobic fiber material
Or the application in stamp.
It, can be by ways customary in industry to hydrophobic fiber material using dyestuff made of dye composite of the invention
(such as polyester and its blended fabric) is dyed, and is such as dyed using common dip method or high-temperature and high pressure dyeing process, can also
For direct printing.Wherein, common dip method such as pre-processes hydrophobic fiber material, is put into dye vat and is disseminated,
Dye finishes, and cold water wash to neutrality squeezes out, and restores again cleaning, dries；Fabric is such as carried out dye pre-treatment by direct printing, is dried
Dry, setting prints disperse dyes mill base on printing machine, then is evaporated, and the dye fixing on fabric is made in the way of decatize, most
After wash, stentering forming.
Disperse blue provided by the invention is applied to hydrophobic fiber material and dyes to black dye composition and dye preparations
Or when stamp, have the characteristics that good lifting force and rub resistance, water-fastness and fastness to sublimation are excellent.
(4) Detailed description of the invention
Fig. 1 is lifting force comparison diagram.
(5) specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in
This:
Embodiment 1:
By 65 grams of formula (I-1) compounds, 15 grams of formula (II-1) compounds, 15 grams of formula (III -1) compounds, 5 grams of formulas (IV -1)
Compound, 250 grams of Dispersant MF, after adding 200 grams of water blendings, grinding distribution is spray-dried to get finished product, which can mention
For fabric blue color.
Embodiment 2:
By 40 grams of formula (I-2) compounds, 22 grams of formula (II-1) compounds, 26 grams of formula (III -1) compounds, 12 grams of formulas (IV -
1) compound, 250 grams of Dispersant MF, after adding 200 grams of water blendings, grinding distribution is spray-dried to get finished product, the finished product energy
Fabric black tone is provided.
Embodiment 3:
By 50 grams of formula (I-1) compounds, 20 grams of formula (II-2) compounds, 11 grams of formula (III -1) compounds, 10 grams of formulas (III -
3) compound, 9 grams of formula (IV -1) compounds, 250 grams of Dispersant MF, after adding 200 grams of water blendings, grinding distribution, spray drying,
It gets product, which can provide fabric black tone.
Embodiment 4~25:
According to method described in embodiment 1, the difference is that using the weight of component A, component B, component C, component D in table 1
Than and auxiliary agent, slurries are made after adding water blending, the solid content for controlling slurries is 35~45% to be advisable, and grinding distribution is dry, system
Finished product, fabric can be supplied to uniformly and the good blue of fastness ability to black tone.85A, 83A in table 1 are respectively wood
Quality 85A, lignin 83A.
Table 1
Comparative example 1:
The compounding dyestuff that embodiment 1 in patent CN105602283A is obtained as a comparison case 1；
Dyeing Example 1:
By disperse dyes obtained in above-described embodiment 1~25, comparative example 1, handled using conventional high temperature high-pressure dyeing
Polyester fibre/spandex intertexture in treatment process, controls dye level (o.w.f) 4.0%, and bath raio 1: 40 adjusts Value in Dyeing Process 4~5,
Room temperature enters dye, is warming up to 130 DEG C with 1 DEG C/min, keeps the temperature 45min, restores washing, washing, drying by well-established law, is cooled to 70 DEG C and takes
Out.Observe sample cloth coloured light, adopt international standards ISO105-X12, ISO105-C10, ISO105-X11 test respectively its rub resistance,
Water-fastness, color fastness to sublimation can provide uniform and the good indigo plant of fastness ability is specifically shown in Table 2 to black dyeing and weaving object:
Table 2
Composite disperse dye obtained in embodiment 3 immediate in the present invention and comparative example 1 is real according to dyeing
The method for applying example 1 carries out different dye level dyeing respectively, and dye level is respectively 0.5%, 1%, 2%, 4%, 6%, 8%.
According to its lifting force of GB/T2397-2012 standard testing, gained lifting force result is as shown in Figure 1.
As shown in Figure 1, of the present invention blue to black disperse dye not only washing fastness, sublimation reliability, crock fastness
It is excellent and better than the enhancing of the dispersed black dye of comparative example 1 Deng every fastness ability.
Claims (10)
1. a kind of blue to black disperse dye composition, including component A, component B, component C and component D, wherein component A is selected from formula
(I) one of compound shown in is a variety of, and component B is selected from one of compound shown in formula (II) or a variety of, described groups
C is divided to be selected from least one of compound shown in formula (III), the component D is selected from least one in compound shown in formula (IV)
Kind, based on the component A, component B, component C and component D, the weight percentage of component A is 5~90%, the weight of component B
Measuring percentage composition is 5~85%, and the weight percentage of component C is 1~45%, the weight percentage of component D is 1~
30%:
In formula (I),
X1For halogen；
R1、R2Respectively stand alone as C1~C4Alkyl；
R3、R4Respectively stand alone as-CH2COOK1Or-C2H4COOK2, wherein K1、K2Respectively stand alone as C1~C4Alkyl；
In formula (II):
R5For hydrogen or C1~C4Alkoxy；
R6、R7、R8Respectively stand alone as C1~C4Alkyl；
In formula (III):
X2、X3Respectively stand alone as hydrogen, halogen, nitro, C1~C4Alkoxy ,-COOC2H4OC2H4OCH3、-SO2- Ph or-CH2O-Ph,
Wherein Ph is phenyl；
R9For C1~C4Alkyl；
In formula (IV):
X4、X5Respectively stand alone as hydrogen, halogen or cyano；
R10For hydrogen, C1~C4Alkyl or acetylamino；
R11For C1~C4Alkyl or benzyl.
2. as described in claim 1 blue to black disperse dye composition, it is characterised in that: the disperse blue to black contaminates
Feed composition is made of component A, component B, component C, component D.
3. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: the component A is following formula
The mixture of one or more of dye composition shown in (I -1)~(I -4):
4. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: the component B is following formula
The mixture of one or more of dye composition shown in (II -1)~(II -5):
5. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: the component C is formula (III-
1) mixture of one or more of dye composition shown in~(III -11):
6. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: the component D is formula (IV-
1) mixture of one or more of dye composition shown in~(IV -8):
7. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: described is blue to black point
It dissipates in dye composite:
Component A is at least one of formula (I -1)~(I -4)；
Component B is at least one of formula (II -1)~(II -5)；
Component C is at least one of formula (III -1)~(III -11)；
Component D is at least one of formula (IV -1)~(IV -8)；
8. as claimed in claim 7 blue to black disperse dye composition, it is characterised in that: the disperse blue to black contaminates
Feed composition, component A is formula (I -1), at least one of dye composition shown in (I -2), component B be formula (II -1),
At least one of dye composition shown in (II -2), component C are in dye composition shown in formula (III -1)~(III -6)
At least one, component D be formula (IV -1) shown in dye composition.
9. a kind of blue to black disperse dye product, containing it is described in claim 1 it is blue to black disperse dye composition and
The weight ratio of auxiliary agent, auxiliary agent and disperse dye composition is 0.2~5:1.
10. as described in claim 1 blue to black disperse dye composition or as claimed in claim 9 blue to black dispersion
Application of the dye preparations in the dyeing of hydrophobic fiber material or stamp.
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| CN108102422B (en) * | 2017-12-12 | 2019-08-13 | 浙江龙盛化工研究有限公司 | A kind of yellow disperse dye composition and dye preparations |
| CN109504127A (en) * | 2018-12-10 | 2019-03-22 | 杭州申航新材料有限公司 | A kind of high fastness disperse black dye composition and preparation method |
| CN109971213B (en) * | 2018-12-21 | 2021-02-02 | 浙江龙盛集团股份有限公司 | Disperse blue-to-black dye composition, dye product and application thereof |
| CN109971214B (en) * | 2018-12-21 | 2020-11-20 | 浙江龙盛集团股份有限公司 | Disperse dark blue dye composition, dye product and application thereof |
| CN109679373B (en) * | 2018-12-21 | 2021-03-30 | 浙江闰土股份有限公司 | Disperse dye composition, disperse dye, and preparation method and application thereof |
| CN110373043B (en) * | 2019-06-10 | 2021-04-09 | 浙江龙盛染料化工有限公司 | Blue-to-black disperse dye composition and dye product |
| CN115124858B (en) * | 2022-06-30 | 2023-08-29 | 浙江龙盛集团股份有限公司 | Disperse orange dye composition and product thereof |
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