CN109957259A - It is a kind of yellow to orange disperse dye composition and dye preparations - Google Patents
It is a kind of yellow to orange disperse dye composition and dye preparations Download PDFInfo
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- CN109957259A CN109957259A CN201910158006.4A CN201910158006A CN109957259A CN 109957259 A CN109957259 A CN 109957259A CN 201910158006 A CN201910158006 A CN 201910158006A CN 109957259 A CN109957259 A CN 109957259A
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- Prior art keywords
- component
- yellow
- disperse dye
- orange
- formula
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- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000000986 disperse dye Substances 0.000 title claims abstract description 56
- 239000000975 dye Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 abstract description 6
- 239000002657 fibrous material Substances 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 description 15
- 239000000047 product Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000004043 dyeing Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 229920004933 Terylene® Polymers 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- -1 methoxyl group Chemical group 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- ZLCUIOWQYBYEBG-UHFFFAOYSA-N 1-Amino-2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=C(N)C(C)=CC=C3C(=O)C2=C1 ZLCUIOWQYBYEBG-UHFFFAOYSA-N 0.000 description 1
- GRMDKKJYMUDEJO-UHFFFAOYSA-N 2-[n-(2-acetyloxyethyl)-4-[(2-cyano-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCOC(C)=O)CCOC(=O)C)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1C#N GRMDKKJYMUDEJO-UHFFFAOYSA-N 0.000 description 1
- NMDKWAQVRNUKQH-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid formaldehyde Chemical compound C=O.C(C1=CC=CC=C1)C1=C(C2=CC=CC=C2C=C1)S(=O)(=O)O NMDKWAQVRNUKQH-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- AJKOAOUQPNLZTF-UHFFFAOYSA-N 3-[n-benzyl-4-[(4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound C1=CC([N+](=O)[O-])=CC=C1N=NC1=CC=C(N(CCC#N)CC=2C=CC=CC=2)C=C1 AJKOAOUQPNLZTF-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052789 astatine Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
- D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
- D06P3/8233—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye using dispersed dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of yellow to orange disperse dye composition and dye preparations.Huang to the orange disperse dye composition includes component A and component B, the component A is selected from least one of compound shown in formula (I), the component B is selected from least one of compound shown in formula (II), the mass percent of the yellow component A into orange disperse dye composition is 5~95%, and the mass percent of component B is 5~95%.Huang to the orange disperse dye product contains the Huang to orange disperse dye composition and auxiliary agent, and auxiliary agent and the yellow weight ratio to orange disperse dye composition are 0.2~5:1.Huang of the present invention is to orange disperse dye product application when hydrophobic fiber material dyes, and color is full, compatibility is good, every color fastness is excellent.
Description
(1) technical field
The present invention relates to a kind of yellow to orange composition and dye preparations, especially a kind of suitable printing hydrophobic fibre
Tie up the yellow to orange disperse dye composition and dye preparations of material.
(2) background technique
With the development of super fine denier polyester fiber ,/the development of the high-grade blended fabric such as ammonia, polyester cotton, existing Huang and are washed
Its dyeing demand is had been unable to meet in printing and dyeing to orange disperse dye, as above other fibers of dye contamination are serious, cause fabric whole
Body color fastness decreased, spot not easy-clear the problems such as, and for EU REACH Legislation further reform polyester fiber dispersion contaminate
The requirement of material, from the aspect of environment and ecology, it is necessary to develop a kind of novel environment friendly dyestuff.ZL201711309007.1,
ZL201010212592.5 has developed the dyestuff that can meet above-mentioned requirements, but still has improved space.
(3) summary of the invention
The present invention provides a kind of Huangs to orange disperse dye composition and dye preparations, are applied to hydrophobic fiber material
When dyeing, color is full, compatibility is good, every color fastness is excellent.
The technical solution adopted by the present invention is that:
A kind of yellow to orange disperse dye composition, including component A and component B, it is shown that the component A is selected from formula (I)
At least one of compound, the component B are selected from least one of compound shown in formula (II), and the Huang is to orange point
The mass percent for dissipating component A in dye composite is 5~95%, and the mass percent of component B is 5~95%,
In formula (I):
R1、R2Respectively stand alone as C1~C18Alkyl；
In formula (II):
R3For C1~C4Alkyl；
R4For halogen, C1~C4Alkoxy,Wherein m is
1 or 2, K1For C1~C4Alkyl, C1~C4Alkoxy or halogen.
In above-mentioned formula (I) or (II), the C1~C18Alkyl can be methyl, ethyl, linear chain or branched chain propyl, straight
The butyl of chain or branch, the hexyl of linear chain or branched chain, the octyl of linear chain or branched chain, the dodecyl of linear chain or branched chain, straight chain or
The octadecyl etc. of branch.The C1~C4Alkyl can be methyl, ethyl, the propyl of linear chain or branched chain, linear chain or branched chain
Butyl.The C1~C4Alkoxy can be methoxyl group, ethyoxyl, the propoxyl group of linear chain or branched chain, linear chain or branched chain fourth oxygen
Base.The halogen can be F, Cl, Br, I.
Preferably, the component A is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
Preferably, the component B is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
As a further preference, the Huang includes component A and component B to orange disperse dye composition, in which:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11).
The Huang is into orange disperse dye composition, and the mass percentage of component A is 5~95%, component B's
Mass percentage is 5~95%.
Preferably, the described Huang is made of to orange disperse dye composition component A and component B, the wherein matter of component A
Measuring percentage composition is 5~95%, and the mass percentage of component B is 5~95%.
As a further preference, the Huang is made of to orange disperse dye composition component A and component B, in which:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11).
The Huang is into orange disperse dye composition, and the mass percentage of component A is 5~95%, component B's
Mass percentage is 5~95%.
It is of the present invention yellow to orange disperse dye composition, it also can further include component C, the Huang is to orange point
It dissipates in dye composite, the mass percent 5~90% of the component A, the mass percent of component B is 5~90%, component C
Mass percent be 1~50%, the component C is selected from one of compound shown in formula (III) and/or (IV) or a variety of:
In formula (III):
R5For C1~C4Alkyl；
R6、R7In, when one of them is hydrogen, another is nitro ,-OSO2-Ph、C1~C4Alkoxy or-
COOC2H4OC2H4OCH3, wherein Ph is phenyl；
In formula (IV):
R8For cyano or nitro；
R9For C1~C4Alkyl；
R10、R11Respectively stand alone as C1~C4Alkyl or replace alkyl, it is described replace alkyl substituent group be-OCOK2、-
COOK3, wherein K2、K3Respectively stand alone as C1~C4Alkyl.
In above-mentioned formula (III) or (IV), the C1~C4Alkyl can be methyl, ethyl, linear chain or branched chain propyl,
The butyl of linear chain or branched chain.The C1~C4Alkoxy can be methoxyl group, ethyoxyl, the propoxyl group of linear chain or branched chain, straight chain
Or the butoxy of branch.
Preferably, the component C is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
As a further preference, described yellow to orange disperse dye composition, it include component A, component B and component C,
Wherein:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11)；
Component C is selected from least one of formula (III-2), (III-4), (IV-1)；
The Huang is into orange disperse dye composition, and the mass percentage of the component A is 5~90%, component B
Mass percentage be 5~90%, the mass percentage of component C is 1~50% (more preferably 1~40%).
Preferably, the Huang is made of to orange disperse dye composition component A, component B and component C, wherein described
The mass percentage of component A is 5~90%, and the mass percentage of component B is 5~90%, the mass percentage of component C
For 1~50% (preferably 1~40%).
As a further preference, the Huang is to orange disperse dye composition by component A, component B and component C group
At, in which:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11)；
Component C is selected from least one of formula (III-2), (III-4), (IV-1)；
The Huang is into orange disperse dye composition, and the mass percentage of the component A is 5~90%, component B
Mass percentage be 5~90%, the mass percentage of component C is 1~50% (more preferably 1~40%).
It is emphasized that dye composition (I) of the present invention, (II), (III), in pyridone hydroxyl ortho position idol
The dyestuff of conjunction exists usually in the form of quinone hydrazone body, that is, logical formula (I), (II), (III) dyestuff substantially have following formula (Ia),
(IIa), quinone hydrazone body structure shown in (IIIa), it is contemplated that the writing style of those skilled in the art, in summary of the invention and implementation
Example part still uses the written form of azo body, this has no effect on essence of the invention:
Wherein R1~R7It is identical as the definition in above-mentioned formula (I), (II), (III) compound.
Huang of the present invention can also be optionally added into a certain amount of shading components, example to orange disperse dye composition
Such as C.I. disperse orange 288, C.I. disperse red 82 also allow that new red, indigo plant is made with the further compound synergic of other dyestuffs
Color or orange equal compositions.
It is of the present invention yellow to orange disperse dye composition, as commodity selling or directly apply to textile material
When coloring, it usually needs conven-tional adjuvants are added.Therefore, the present invention also provides a kind of as commodity selling or directly applies to spinning
The yellow to orange disperse dye product of material coloring is knitted, contains the Huang to orange disperse dye composition and auxiliary agent, helps
Agent and the yellow weight ratio to orange disperse dye composition are 0.2~5:1.Preferably, described yellow to orange disperse dye
Product is made of Huang to the orange disperse dye composition and auxiliary agent.The auxiliary agent is that disperse dyes are common when compounding
Dispersing agent, diffusant and other surfactants etc. preferably are selected from the mixture of one of following or in which two or more arbitrary proportions:
[such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (divides for naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products
Powder MF)], naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF), sulfomethylated lignin
Sour sodium (lignin 85A, lignin 83A), anhydrous sodium sulphate (sodium sulphate) etc..
It is of the present invention yellow to orange disperse dye product the preparation method is as follows: will form yellow to orange disperse dye
After the dye monomer compound (former dyestuff) of composition mixes according to the ratio, sand mill or grinder in the presence of auxiliary agent, water
Equal pulverizers carry out corpusculed；In addition can also by each dye monomer compound sand mill in the presence of auxiliary agent, water respectively
Or it is mixed in proportion after the progress corpusculed processing of the pulverizers such as grinder.It is of the present invention yellow to orange disperse dye
Product can be powdery, graininess after spray drying, this is those skilled in the art with being liquid after sand mill or grinder grinding
Preparation method well known to member.
In the present invention, formula (I), (II), (III), dye composition is convenient to by those skilled in the art shown in (IV)
Mode known to member synthesizes, and can also use commercial goods.
It, can be by ways customary in industry to hydrophobic fibre material using dye preparations made of dye composite of the invention
Material (such as polyester and its blended fabric) is dyed, and is such as dyed using common dip method or high-temperature and high pressure dyeing process,
It can be directly used for stamp.Wherein, common dip method is such as: hydrophobic fiber material being pre-processed, is put into dye vat and is soaked
Dye, dye finish, and cold water wash to neutrality squeezes out, and restore again cleaning, dry；Direct printing is such as: fabric being carried out to contaminate preceding place
Reason is dried, and setting prints disperse dyes mill base on printing machine, then evaporated, and makes the dyestuff on fabric solid in the way of decatize
Color is finally washed, stentering forming.
It is provided by the invention yellow to orange disperse dye composition and dye preparations, it, can when upper dye hydrophobic fiber material
Obtaining has that coloured light is gorgeous, heat-resisting migration performance is good, washing fastness Yellow-to-orange dyeing and weaving object outstanding, especially fixed in high temperature
After type, very high washing fastness is still ensured that, efficiently solve conventional Huang and wash under high temperature final finishing to orange disperse dye
The problem that fastness declines to a great extent is highly suitable for medium-to-high grade fabric such as super fine denier fabric, polyester cotton, washs the/print of the blended fabric such as ammonia
Dye.
(4) specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in
This:
Embodiment 1:
By the component A of 50 grams of formulas (I-1) and 40 grams of formulas (I-3), component B, 150 grams of the dispersing agent of 10 grams of formulas (II-1)
MF, 30 grams of sodium lignin sulfonate, after adding 650 grams of blendings of water, grinding distribution is simultaneously dry to get finished product, which can be supplied to
Terylene and its excellent yellow of blended fabric items fastness ability.
Embodiment 2:
By the component A of 45 grams of formulas (I-1), the component B of 28 grams of formulas (II-1), the component C of 27 grams of formulas (III-1), 150 grams
Sodium lignin sulfonate, after adding 600 grams of blendings of water, grinding distribution is simultaneously dry to get finished product, which can be supplied to terylene and its mix
The excellent yellow of textile fabric items fastness ability.
Embodiment 3:
By the component A of 55 grams of formulas (I-3), the component B of 28 grams of formulas (II-10), 12 grams of formulas (III-2), 5 grams of formulas (IV-1)
Component C, 150 grams of sodium lignin sulfonate, after adding 600 grams of blendings of water, grinding distribution is simultaneously dry to get finished product, which can mention
Supply terylene and its excellent orange of blended fabric items fastness ability.
Embodiment 4~33
According to method described in embodiment 3, the difference is that using the structure and weight of component A, component B, component C in table 1,
200 grams of auxiliary agent (Dispersant MF is 150 grams, and sodium lignin sulfonate is 50 grams) is added, slurries are made after adding 850 grams of blendings of water, grind
Mill dispersion, dry, finished product, the dyestuff can be supplied to terylene and its excellent yellow of blended fabric items fastness ability to orange
Color tone.
Table 1
Embodiment 34:
By the component A of 45 grams of formulas (I-1), the component B of 52 grams of formulas (II-2), 3 grams 288,150 grams of C.I. disperse orange wooden
Plain sodium sulfonate, after adding water blending, with grinder grinding distribution and dry to get finished product dyestuff, the dyestuff can be supplied to terylene and
Its blended fabric uniformly and the good yellow of fastness ability.
Embodiment 35:
By the component A of 43 grams of formulas (I-1), the component B of 28 grams of formulas (II-1), 14 grams of formulas (III-4), 10 grams of formulas (IV-1), 5
Grams 82,200 grams of C.I. disperse red of Dispersant MF, after adding water blending, with grinder grinding distribution and dry to get finished product dye
Material, which can be supplied to terylene and its blended fabric uniformly and fastness ability is good orange.
Comparative example 1:
By embodiment 2 in CN108102422A as a comparison case 1；
Comparative example 2:
By embodiment 2 in CN101880476A as a comparison case 2.
Dyeing Example:
The dyestuff for weighing disperse dyes made from 2 grams of Examples 1 to 35, comparative example 1~2 respectively, using conventional high temperature height
It is padded color method and thermal finalization handles and washs/ammonia blended fabric, in treatment process, control dye level (o.w.f) 4.0%, bath raio 1:
25, Value in Dyeing Process 4~5 is adjusted, room temperature enters dye, is warming up to 125 DEG C with 1 DEG C/min, keeps the temperature 45min, restores washing, water by well-established law
Wash, dry, 180 DEG C thermal finalization 60 seconds, obtain yellow to orange dyeing and weaving object.According to ISO 105-P01, ISO 105-X12,
AATCC61-2A tests resistance to distillation, rub resistance and washing color fastness respectively, as a result see the table below 2:
Table 2
It can be seen that it is provided by the present invention yellow to orange disperse dye composition, when being applied to dyeing terylene, compared to
Existing yellow to orange disperse dye, dyeability is more excellent, can further compound with pinkish red, dark blue disperse dyes, enrich dyestuff
Kind.
Claims (10)
1. a kind of Huang to orange disperse dye composition, including component A and component B, the component A is selected from formula (I) shownization
At least one of object is closed, the component B is selected from least one of compound shown in formula (II), described yellow to orange dispersion
The mass percent of component A is 5~95% in dye composite, and the mass percent of component B is 5~95%,
In formula (I):
R1、R2Respectively stand alone as C1~C18Alkyl；
In formula (II):
R3For C1~C4Alkyl；
R4For halogen, C1~C4Alkoxy,Wherein m is 1 or 2,
K1For C1~C4Alkyl, C1~C4Alkoxy or halogen.
2. as described in claim 1 yellow to orange disperse dye composition, it is characterised in that: described is yellow to orange dispersion dye
Feed composition is made of component A and component B, and wherein the mass percentage of component A is 5~95%, and the quality percentage of component B contains
Amount is 5~95%.
3. as described in claim 1 yellow to orange disperse dye composition, it is characterised in that: described is yellow to orange dispersion dye
Feed composition further includes component C, the Huang into orange disperse dye composition, the mass percent 5 of the component A~
The mass percent of 90%, component B are 5~90%, and the mass percent of component C is 1~50%, and the component C is selected from formula
(III) and/or one of compound shown in (IV) or a variety of:
In formula (III):
R5For C1~C4Alkyl；
R6、R7In, when one of them is hydrogen, another is nitro ,-OSO2-Ph、C1~C4Alkoxy or-COOC2H4OC2H4OCH3,
Middle Ph is phenyl；
In formula (IV):
R8For cyano or nitro；
R9For C1~C4Alkyl；
R10、R11Respectively stand alone as C1~C4Alkyl or replace alkyl, it is described replace alkyl substituent group be-OCOK2、-COOK3,
Wherein, K2、K3Respectively stand alone as C1~C4Alkyl.
4. as claimed in claim 3 yellow to orange disperse dye composition, it is characterised in that: described yellow to orange disperse dye
Composition is made of component A, component B and component C, wherein the mass percentage of the component A is 5~90%, component B's
Mass percentage is 5~90%, and the mass percentage of component C is 1~50% (preferably 1~40%).
5. yellow to orange disperse dye composition as described in one of claim 1-4, it is characterised in that: the component A is selected from
The mixture of one of following formula or in which two or more arbitrary proportions:
6. yellow to orange disperse dye composition as described in one of claim 1-4, it is characterised in that: the component B is selected from
The mixture of one of following formula or in which two or more arbitrary proportions:
7. as claimed in claim 1 or 2 yellow to orange disperse dye composition, it is characterised in that: the Huang is to orange point
It dissipates in dye composite:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11)；
8. as described in claim 3 or 4 yellow to orange disperse dye composition, it is characterised in that: the component C is selected from following formula
One of or in which two or more arbitrary proportions mixture:
9. as described in claim 3 or 4 yellow to orange disperse dye composition, it is characterised in that: the Huang is to orange point
It dissipates in dye composite:
Component A is selected from least one of formula (I-1), (I-2), (I-6)；
Component B is selected from least one of formula (II-1), (II-2), (II-10), (II-11)；
Component C is selected from least one of formula (III-2), (III-4), (IV-1)；
10. a kind of yellow to orange disperse dye product, containing it is described in claim 1 it is yellow to orange disperse dye composition and
Auxiliary agent, auxiliary agent and the yellow weight ratio to orange disperse dye composition are 0.2~5:1.
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| CN110204922A (en) * | 2019-07-12 | 2019-09-06 | 约克夏(浙江)染化有限公司 | Black disperse dye composition, disperse dyes and its preparation method and purposes |
| CN110669356A (en) * | 2019-10-23 | 2020-01-10 | 约克夏(浙江)染化有限公司 | Yellow dye composition, yellow dye and preparation method and application thereof |
| CN111423741A (en) * | 2020-05-06 | 2020-07-17 | 杭州福莱蒽特科技有限公司 | Disperse yellow dye and synthetic method thereof |
| CN112574594A (en) * | 2020-12-31 | 2021-03-30 | 绍兴市上虞金冠化工有限公司 | Disperse yellow-orange dye composition and product thereof |
| CN112708287A (en) * | 2020-12-31 | 2021-04-27 | 绍兴市上虞金冠化工有限公司 | Disperse yellow dye composition, and product and application thereof |
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| CN112574594A (en) * | 2020-12-31 | 2021-03-30 | 绍兴市上虞金冠化工有限公司 | Disperse yellow-orange dye composition and product thereof |
| CN112708287A (en) * | 2020-12-31 | 2021-04-27 | 绍兴市上虞金冠化工有限公司 | Disperse yellow dye composition, and product and application thereof |
| CN112708287B (en) * | 2020-12-31 | 2022-11-22 | 绍兴市上虞金冠化工有限公司 | Disperse yellow dye composition, and product and application thereof |
| CN112574594B (en) * | 2020-12-31 | 2023-05-23 | 绍兴市上虞金冠化工有限公司 | Disperse yellow-orange dye composition and product thereof |
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