CN106883641B - A kind of dispersed ruby dye composition and dye preparations - Google Patents
A kind of dispersed ruby dye composition and dye preparations Download PDFInfo
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- CN106883641B CN106883641B CN201611268712.7A CN201611268712A CN106883641B CN 106883641 B CN106883641 B CN 106883641B CN 201611268712 A CN201611268712 A CN 201611268712A CN 106883641 B CN106883641 B CN 106883641B
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- dispersed ruby
- ruby dye
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- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000010979 ruby Substances 0.000 title claims abstract description 41
- 229910001750 ruby Inorganic materials 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000000975 dye Substances 0.000 claims description 68
- 239000000047 product Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- -1 ethoxy, phenyl Chemical group 0.000 claims description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 229910052794 bromium Inorganic materials 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
- 239000007859 condensation product Substances 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 239000000986 disperse dye Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- VRAKDAYLTPMBAW-UHFFFAOYSA-N [O-][N+](=O)ClC#N Chemical compound [O-][N+](=O)ClC#N VRAKDAYLTPMBAW-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 11
- 230000002209 hydrophobic effect Effects 0.000 abstract description 5
- 239000002657 fibrous material Substances 0.000 abstract description 4
- 238000010186 staining Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 12
- 239000004744 fabric Substances 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 206010007247 Carbuncle Diseases 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- AJKOAOUQPNLZTF-UHFFFAOYSA-N 3-[n-benzyl-4-[(4-nitrophenyl)diazenyl]anilino]propanenitrile Chemical compound C1=CC([N+](=O)[O-])=CC=C1N=NC1=CC=C(N(CCC#N)CC=2C=CC=CC=2)C=C1 AJKOAOUQPNLZTF-UHFFFAOYSA-N 0.000 description 1
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000004044 disperse dyeing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- LEGWLJGBFZBZSC-UHFFFAOYSA-N n-[2-[(2,6-dicyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(C#N)C=C([N+]([O-])=O)C=C1C#N LEGWLJGBFZBZSC-UHFFFAOYSA-N 0.000 description 1
- WFFKSTRPZWRBEW-UHFFFAOYSA-N n-[2-[(2-bromo-4,6-dinitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound CC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=C(Br)C=C([N+]([O-])=O)C=C1[N+]([O-])=O WFFKSTRPZWRBEW-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- HVZWVEKIQMJYIK-UHFFFAOYSA-N nitryl chloride Chemical compound [O-][N+](Cl)=O HVZWVEKIQMJYIK-UHFFFAOYSA-N 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of dispersed ruby dye composition and dye preparations.The dispersed ruby dye composition, including component A, component B and component C, the component A is selected from least one of compound shown in formula (I) and/or (II), the component B is selected from least one of compound shown in formula (III), and the component C is selected from least one of compound shown in formula (IV) and/or (V)；Based on the component A, component B and component C, the mass percentage of component A is 20~90%, and the mass percentage of component B is 5~35%, and the mass percentage of component C is 5~50%.The dispersed ruby dye product contains the dispersed ruby dye composition and auxiliary agent.Dispersed ruby dye composition and dye preparations provided by the invention, when being applied to hydrophobic fiber material dyeing, every color fastness is excellent, and especially water-fastness staining fastness is prominent.
Description
(1) technical field
The present invention relates to a kind of dispersed ruby dye composition and dye preparations, especially a kind of suitable printing hydrophobic is fine
Tie up the dispersed ruby dye composition and dye preparations of material.
(2) background technique
After polyester/polyurethane fabric uses disperse dyeing, at high-temperature process (such as thermal finalization), due to the auxiliary agent of fibrous outer
Dissolution is generated to dyestuff at high temperature, dyestuff is widened by fiber capillary high temperature from fibrous inside and moves to fiber table
Layer accumulates dyestuff in fiber sheath, causes a series of influence, such as color fastness decreased.
The applicant has been provided a kind of with excellent lifting force, reproducibility and brilliance in CN101215245A
The Monoazo compound of wet colour fastness, high-incidence intensity of colour.Even to this day, applicants have discovered that the Monoazo compound is used for
Colorant match can solve the above problem, and obtain one group of dispersed ruby dye composition haveing excellent performance.
(3) summary of the invention
To solve the above problems, being applied to dredge the present invention provides a kind of dispersed ruby dye composition and dye preparations
When aqueous fiber dyeing material, every color fastness is excellent, and especially water-fastness staining fastness is prominent.
The technical solution adopted by the present invention is that:
A kind of dispersed ruby dye composition, including component A, component B and component C, the component A be selected from formula (I) and/
Or at least one of compound shown in (II), the component B is selected from least one of compound shown in formula (III), described
Component C be selected from least one of compound shown in formula (IV) and/or (V)；Based on the component A, component B and component
The mass percentage of C, component A are 20~90%, and the mass percentage of component B is 5~35%, the quality percentage of component C
Content is 5~50%:
In formula (I), in formula (II):
M, n is 1 or 2；
R1For hydrogen, hydroxyl, acetylamino, C1~C4Alkyl or C1~C4Alkoxy；
R2、R3It is independently of one another C1~C4Alkyl；
X1、X2Respectively stand alone as hydrogen, nitro or halogen, X3For nitro or halogen；
In formula (III):
P, q is 1 or 2；
R4、R5For C1~C4Alkyl；
R6For the alkyl of C1~C4；
X4For nitro, cyano or halogen；
In formula (IV):
P, q is 1 or 2；
R8、R9For C1~C4Alkyl；
R7For C1~C4Alkyl, C1~C4Alkoxy, phenyl or amino；
X5For nitro, cyano or halogen；
In formula (V):
R10For hydrogen or C1~C4Alkyl；
R11For hydrogen, C1~C4Alkyl ,-CH2COOC2H4OCH3、-CH2CH2OH or-
Dispersed ruby dye composition of the present invention can also be optionally added into a certain amount of shading components, such as
C.I. disperse violet 93, C.I. disperse blue 366, C.I. disperse blue 165, C.I. disperse orange 288, C.I. disperse yellow 118 etc..
Preferably, the dispersed ruby dye composition is made of, wherein the matter of component A component A, component B and component C
Measuring percentage composition is 20~90%, and the mass percentage of component B is 5~35%, the mass percentage of component C is 5~
50%.
Preferably, in the dispersed ruby dye composition, based on the component A, component B and component C, the component
The mass percentage of A is 30~85%, and the mass percentage of component B is 5~30%, and the mass percentage of component C is 5
~40%.
In the present invention, the C1~C4Alkyl can be methyl, ethyl, n-propyl, isopropyl, normal-butyl, isobutyl group,
Tert-butyl etc., the C1~C4Alkoxy can be methoxyl group, ethyoxyl, positive propoxy, isopropoxy, n-butoxy, isobutyl
Oxygroup, tert-butoxy etc., the halogen can be F, Cl, Br or I, preferably Cl or Br.
Further, R1For hydrogen, hydroxyl, acetylamino, methyl or methoxy.
Further, R2、R3It is independently of one another methyl or ethyl.
Further, X1、X2Respectively stand alone as nitro, hydrogen, chlorine or bromine.
Further, X3For nitro, chlorine or bromine.
Further, X4For chlorine or bromine.
Further, R4、R5For methyl or ethyl.
Further, R6For methyl or ethyl.
Further, R8、R9For methyl or ethyl.
Further, R7For methyl or ethyl, methoxy or ethoxy, phenyl or amino.
Further, X5For nitro, cyano, chlorine or bromine.
Further, R10For hydrogen or methyl.
Further, R11For hydrogen, propyl or butyl or
Further, the dye component A is preferably following formula (I -1)~(I -13), contaminates shown in (II-1)~(II-7)
Expect the mixture of one or more of compound (containing two kinds):
Again further, component A is selected from least one of formula (I -1)~(I -3), (II-1)~(II-3).
Further, the dye component B is preferably one of dye composition shown in formula (III -1)~(III -6)
Or the mixture of two or more (containing two kinds)；
Again further, component B is selected from least one of formula (III -1)~(III -2).
Further, the dye component C is preferably formula (IV -1)~(IV -14), contaminates shown in (V -1)~(V -5)
Expect the mixture of one or more of compound:
Again further, component C is selected from least one of formula (IV -1), (IV -8), (V -1), (V -2), (V -5).
Dispersed ruby dye composition of the present invention preferably comprises component A, component B and component C, in which:
Component A is selected from least one of formula (I -1)~(I -3), (II-1)~(II-3)；
Component B is selected from least one of formula (III -1)~(III -2)；
Component C is selected from least one of formula (IV -1), (IV -8), (V -1), (V -2), (V -5)；
Mass percentage based on the above component A, component B and component C, the component A is 20~90%, component B's
Mass percentage is 5~35%, and the mass percentage of component C is 5~50%.
Dispersed ruby dye composition of the present invention is preferably made of component A, component B and component C, in which:
Component A is selected from least one of formula (I -1)~(I -3), (II-1)~(II-3)；
Component B is selected from least one of formula (III -1)~(III -2)；
Component C is selected from least one of formula (IV -1), (IV -8), (V -1), (V -2), (V -5)；
Mass percentage based on the above component A, component B and component C, the component A is 20~90%, component B's
Mass percentage is 5~35%, and the mass percentage of component C is 5~50%.
Dispersed ruby dye composition of the present invention leads to when as commodity selling or being applied to textile material coloring
It often also needs that auxiliary agent is added and be post-processed.Therefore, the present invention also provides a kind of dispersed ruby dye product, contain described
Dispersed ruby dye composition and auxiliary agent, the weight ratio of auxiliary agent and disperse dye composition is 0.2~5:1.Preferably, institute
The dispersed ruby dye product stated is made of the dispersed ruby dye composition and auxiliary agent.The auxiliary agent is disperse dyes
Common dispersing agent, diffusant and other surfactants etc. when compounding preferably are selected from one of following or in which two or more mix
Close object: lignosulfonates (such as sodium lignin sulfonate (lignin 85A, lignin 83A)), alkyl naphthalene sulfonic acid formaldehyde condensation products
(such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent NNO), benzyl naphthalenesulfonateformaldehyde formaldehyde
Condensation product (dispersing agent CNF) etc..
Dispersed ruby dye product of the present invention the preparation method is as follows:
After the dye monomer compound (former dyestuff) for forming dispersed ruby dye composition is mixed according to the ratio, auxiliary agent,
Corpusculed is carried out with pulverizers such as sand mill or grinders in the presence of water；In addition dye monomer compound can also be existed respectively
It is mixed in proportion after carrying out corpusculed processing with pulverizers such as sand mill or grinders in the presence of auxiliary agent, water.This hair
The bright dispersed ruby dye product can be powdery, particle after spray drying with being liquid after sand mill or grinder grinding
Shape, this is well known to those skilled in the art preparation method, due to can not be by the de- of moisture 100% in spray-drying process
It removes, so even being still to allow that there are a certain amount of moisture, preferably more than dyestuff system in powdery or granular dye preparations
The 10% of product gross weight.
In addition, it is necessary to which explanation makes the promotion of dyeing effect when dye preparations are applied to the printing and dyeing of textile fabric
Contribution is technically characterized in that dye component contained in the product and ratio.
In the present invention, formula (I), (II), (III), (IV), dye composition is convenient to by this field skill shown in (V)
Mode known to art personnel synthesizes, and is also referred to introduce in patent CN101522816A, CN101215245A, US5550217A
Method or similar method preparation, commercial goods can also be used.Formula (II) compound is during formula (I) Dyestuff synthesis
By-product does not have to separate the two under normal conditions, and conventional DMF solvent can also be used when necessary and repeatedly refine to the two progress
Separation.It, can be (such as poly- to hydrophobic fiber material by ways customary in industry using dyestuff made of dye composite of the invention
Ester or its blended fabric) it is dyed, it is such as dyed using common dip method or high-temperature and high pressure dyeing process, it can also be used to straight
Connect stamp.Wherein, common dip method such as pre-processes hydrophobic fiber material, is put into dye vat and is disseminated, and dye finishes, cold
Water is cleaned to neutrality, is squeezed out, and cleaning is restored again, drying；Fabric is such as carried out dye pre-treatment by direct printing, is dried, setting,
Disperse dyes mill base is printed on printing machine, then is evaporated, and the dye fixing on fabric is made in the way of decatize, is finally washed,
Stentering forming.
Dispersed ruby dye composition and dye preparations provided by the invention, when being applied to hydrophobic fiber material dyeing,
Every color fastness is excellent, and especially water-fastness staining fastness is prominent.
(4) specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in
This:
Embodiment 1:
By 45 grams of formulas (I -2) compound, 15 grams of formula (II-1) compounds, 15 grams of formulas (III -1), 25 grams of formula (IV -8) chemical combination
Object and 200 grams of Dispersant MF, after adding 650 grams of blendings of water, grinding distribution is simultaneously dry to get finished product, which can be supplied to and knit
The excellent carbuncle tone of object items fastness ability.
Embodiment 2:
By 30 grams of formulas (I -2) compound, 20 grams of formula (II-1) compounds, 25 grams of formulas (III -1), 5 grams of formula (IV -1) chemical combination
Object, 20 grams of formula (IV -8) compounds and 200 grams of Dispersant MF, after adding 650 grams of blendings of water, grinding distribution and it is dry to get at
Product, the dyestuff can be supplied to the excellent carbuncle tone of fabric items fastness ability.
Embodiment 3:
By 50 grams of formulas (I -3) compound, 30 grams of formulas (III -1), 20 grams of formula (V -1) compounds and 200 grams of Dispersant MF,
After adding 650 grams of blendings of water, grinding distribution is simultaneously dry to get finished product, and it is excellent which can be supplied to fabric items fastness ability
Carbuncle tone.
Embodiment 4~42:
According to method described in embodiment 1,2 or 3, the difference is that being added using the structure and weight of component A~C in table 1
200 grams of auxiliary agent (Dispersant MF is 150 grams, and lignin 85A is 50 grams), adds and slurries is made after 650 grams of blendings of water, grinding distribution,
Dry, finished product, the dyestuff can be supplied to the excellent carbuncle tone of fabric items fastness ability.
Table 1
Dyeing Example:
Disperse dyes made from above-described embodiment 1~42 are chosen respectively, using conventional high temperature high-pressure dyeing and thermal finalization
Polyester fibre/spandex intertexture is handled, in treatment process, controls dye level (o.w.f) 4.0%, bath raio 1: 25 adjusts Value in Dyeing Process 4
~5, room temperature enters dye, is warming up to 130 DEG C with 1 DEG C/min, keeps the temperature 45min, restores washing, washing, drying, 180 DEG C of heat by well-established law
Sizing 60 seconds, obtains dyeing and weaving object rubied/rubious.Rub resistance and water-fastness color jail are tested respectively according to AATCC 8, AATCC 61-2A
It spends, as a result the following table 2:
Table 2
By upper table 2 it is found that the dispersed ruby composition in the present invention, dyed fabric after final finishing high temperature thermal finalization,
Rub resistance and water-fastness staining fastness can satisfy the printing and dyeing that high fastness requires fabric.
Claims (9)
1. a kind of dispersed ruby dye composition, including component A, component B and component C, it is shown that the component B is selected from formula (III)
At least one of compound, the component C are selected from least one of compound shown in formula (IV) and/or (V)；It is based on
The mass percentage of component A, component B and the component C, component A are 20~90%, and the mass percentage of component B is 5
The mass percentage of~35%, component C are 5~50%:
In formula (III):
P, q is 1 or 2；
R4、R5For C1~C4Alkyl；
R6For the alkyl of C1~C4；
X4For halogen；
In formula (IV):
P, q is 1 or 2；
R8、R9For C1~C4Alkyl；
R7For C1~C4Alkyl, C1~C4Alkoxy, phenyl or amino；
X5For nitro, cyano or halogen；
In formula (V):
R10For hydrogen or C1~C4Alkyl；
R11For hydrogen, C1~C4Alkyl ,-CH2COOC2H4OCH3、-CH2CH2OH or-
The component A is following formula (I -1)~(I -6), (I -9)~(I -12), dye composition shown in (II -1)~(II -7)
One or more of mixture:
2. dispersed ruby dye composition as described in claim 1, it is characterised in that: the dispersed ruby dye composition by
Component A, component B and component C composition.
3. dispersed ruby dye composition as claimed in claim 1 or 2, it is characterised in that:
X4For chlorine or bromine；
R4、R5For methyl or ethyl；
R6For methyl or ethyl；
R8、R9For methyl or ethyl；
R7For methyl or ethyl, methoxy or ethoxy, phenyl or amino；
X5For nitro, cyano, chlorine or bromine；
R10For hydrogen or methyl；
R11For hydrogen, propyl or butyl or
4. dispersed ruby dye composition as claimed in claim 1 or 2, it is characterised in that: component B is formula (III -1)~(III -
6) mixture of one or more of dye composition shown in；
5. dispersed ruby dye composition as claimed in claim 1 or 2, it is characterised in that: component C is formula (IV -1)~(IV -
14), the mixture of one or more of dye composition shown in (V -1)~(V -5):
6. dispersed ruby dye composition as claimed in claim 1 or 2, it is characterised in that: the dispersed ruby dye group
It closes in object:
Component A is selected from least one of formula (I -1)~(I -3), (II -1)~(II -3)；
Component B is selected from least one of formula (III -1)~(III -2)；
Component C is selected from least one of formula (IV -1), (IV -8), (V -1), (V -2), (V -5)；
Mass percentage based on the above component A, component B and component C, the component A is 20~90%, the quality of component B
Percentage composition is 5~35%, and the mass percentage of component C is 5~50%；
7. a kind of dispersed ruby dye product is helped containing dispersed ruby dye composition as described in claim 1 and auxiliary agent
The weight ratio of agent and disperse dye composition is 0.2~5:1.
8. dispersed ruby dye product as claimed in claim 7, it is characterised in that: the dispersed ruby dye product is by institute
Dispersed ruby dye composition and the auxiliary agent composition stated.
9. dispersed ruby dye product as claimed in claim 7 or 8, it is characterised in that: the auxiliary agent is selected from one of following
Or in which two or more mixture: lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acid-formaldehyde condensation product, benzyl
Base naphthalene sulfonic acid-formaldehyde condensation product.
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| CN111117291B (en) * | 2019-03-21 | 2021-09-21 | 浙江龙盛集团股份有限公司 | Disperse red dye composition and dye product |
| CN111518414B (en) * | 2020-04-29 | 2021-07-16 | 约克夏(浙江)染化有限公司 | Red disperse dye composition, red disperse dye and preparation method and application thereof |
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| JPH11158403A (en) * | 1997-11-28 | 1999-06-15 | Sumitomo Chem Co Ltd | Disperse dye composition and method for coloring hydrophobic material therbwith |
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