CN106833019B - A kind of high fastness indigo plant is to black disperse dye composition and dye preparations - Google Patents
A kind of high fastness indigo plant is to black disperse dye composition and dye preparations Download PDFInfo
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- CN106833019B CN106833019B CN201611268749.XA CN201611268749A CN106833019B CN 106833019 B CN106833019 B CN 106833019B CN 201611268749 A CN201611268749 A CN 201611268749A CN 106833019 B CN106833019 B CN 106833019B
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- component
- blue
- disperse dye
- black disperse
- black
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0079—Azoic dyestuff preparations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of high fastness indigo plants to black disperse dye composition and dye preparations.It is described blue to black disperse dye composition, including component A, component B, component C and component D, the component A is compound shown in formula (I -1) and/or (I -2), the component B is in compound shown in formula (II -1) and/or (II -2), the component C is compound shown in formula (III), and the component D is compound shown in formula (IV -1) and/or (IV -2) and/or (IV -3).It is described blue to black disperse dye product, contain the indigo plant to black disperse dye composition and auxiliary agent.Provided by the invention blue to black disperse dye composition and dye preparations, when being applied to hydrophobic fiber material dyeing, lifting force is high, depth is good, and good dispersion, level-dyeing property are good, and every color fastness is excellent.
Description
(1) technical field
The present invention relates to a kind of blue to black disperse dye composition and dye preparations, especially a kind of suitable printing hydrophobic
The high fastness indigo plant of property fibrous material is to black disperse dye composition and dye preparations.
(2) background technique
Blue-black series dyes usage amount is maximum in disperse dyes, but at present the series dyes be difficult to be provided simultaneously with it is excellent
Dyeability and fastness ability, such as publication CN105111785A, CN102061106A, CN104371370A provide one
The excellent blue-black series dyes composition of the every fastness of kind, but lifting force, dispersibility aspect still have the space further improved.
(3) summary of the invention
To solve the above problems, the present invention provides a kind of high fastness indigo plants to black disperse dye composition and dyestuff system
Product, when being applied to hydrophobic fiber material dyeing, lifting force is high, depth is good, and good dispersion, level-dyeing property are good, and every color jail
It spends excellent.
The technical solution adopted by the present invention is that:
It is a kind of blue to be to black disperse dye composition, including component A, component B, component C and component D, the component A
Compound shown in formula (I -1) and/or (I -2), the component B are shown in formula (II -1) and/or (II -2) in compound, described
Component C be formula (III) shown in compound, the component D be formula (IV -1) and/or (IV -2) and/or (IV -3) shown in chemical combination
Object, based on the component A, component B, component C and component D, the parts by weight of component A are 20~90, and the parts by weight of component B are 5
The parts by weight of~60, component C are 1~50, and the parts by weight of component D are 1~50:
Preferably, of the present invention blue to black disperse dye composition, it include component A, component B, component C and component
D, the mass percentage based on component A, component B, component C and component D, the component A are 20~90%, the quality of component B
Percentage composition is 5~60%, and the mass percentage of the component C is 1~50%, the mass percentage of component D is 1~
50%.
More preferably, indigo plant of the present invention is to black disperse dye composition, by component A, component B, component C and group
Divide D composition, the mass percentage based on component A, component B, component C and component D, the component A is 20~90%, component B
Mass percentage be 5~60%, the mass percentage of the component C is 1~50%, the mass percentage of component D
It is 1~50%.
It is of the present invention blue to black disperse dye composition, as commodity selling or it is applied to textile material coloring
When, it usually also needs that auxiliary agent is added and is post-processed.Therefore, the present invention also provides a kind of blue to black disperse dye product,
It contains the disperse blue to black dye composition and auxiliary agent, auxiliary agent and the blue weight to black disperse dye composition it
Than for 0.2~5:1.Preferably, it is described it is blue to black dyes disperse product by it is described it is blue to black disperse dye composition and
Auxiliary agent composition.The auxiliary agent is common dispersing agent, diffusant and other surfactants etc. when disperse dyes compound, preferably
From one of following or in which two or more mixture: lignosulfonates (such as sodium lignin sulfonate (lignin 85A, lignin
83A)), alkyl naphthalene sulfonic acid formaldehyde condensation products (such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acid-formaldehyde condensation product
(dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF) etc..
It is of the present invention it is blue to black disperse dye product the preparation method is as follows:
It will form after the blue dye monomer compound (former dyestuff) to black disperse dye composition mixes according to the ratio,
Corpusculed is carried out with pulverizers such as sand mill or grinders in the presence of auxiliary agent, water；It in addition can also be by dye monomer chemical combination
Object is mixed in proportion after carrying out corpusculed processing with pulverizers such as sand mill or grinders in the presence of auxiliary agent, water respectively
It closes.Dispersed deep blue dye product of the present invention can be powder after spray drying with being liquid after sand mill or grinder grinding
Shape, graininess, this is well known to those skilled in the art preparation method.
In the present invention, formula (I -1), (I -2), (II -1), (II -1), (III), shown in (IV -1), (IV -2) and (IV -3)
Dye composition is convenient to synthesize by mode well known to those skilled in the art, be also referred to patent CN103613511A,
The method introduced in GB2123845A, GB813906A, JPS61223040A or the preparation of similar method, can also use commercially available
Commodity.
It, can be by ways customary in industry to hydrophobic fiber material using dyestuff made of dye composite of the invention
(such as polyester and its blended fabric) is dyed, and is such as dyed using common dip method or high-temperature and high pressure dyeing process, can also
For direct printing.Wherein, common dip method is to pre-process hydrophobic fiber material, is put into dye vat and is disseminated,
Dye finishes, and cold water wash to neutrality squeezes out, and restores again cleaning, dries；Direct printing is that fabric is carried out to dye pre-treatment, is dried
Dry, setting prints disperse dyes mill base on printing machine, then is evaporated, and the dye fixing on fabric is made in the way of decatize, most
After wash, stentering forming.
The beneficial effects of the present invention are: indigo plant provided by the invention is answered to black disperse dye composition and dye preparations
When for hydrophobic fiber material dyeing, have lifting force height, depth good, good dispersion, level-dyeing property are good, and every color fastness
It is excellent.
(4) specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in
This:
Embodiment 1:
12 grams of formulas (I -1) compound, 12 grams of formula (I -2) compounds, 40 grams of formula (II -2) compounds, 18 grams of formulas (III) are changed
Close object, 18 grams of formula (IV -1) compounds and 200 grams of Dispersant MF, after adding 650 grams of blendings of water, grinding distribution and it is dry to get
Finished product, the dyestuff can be supplied to the excellent black of fabric items fastness ability.
Embodiment 2:
30 grams of formulas (I -1) compound, 30 grams of formula (I -2) compounds, 20 grams of formula (II -1) compounds, 10 grams of formulas (III) are changed
Object, 10 grams of formula (IV -1) compounds and the Dispersant MF with 200 grams are closed, after adding 650 grams of blendings of water, grinding distribution and drying, i.e.,
Finished product is obtained, which can be supplied to the excellent blue of fabric items fastness ability.
Embodiment 3~30:
According to method described in embodiment 1 or 2, the difference is that using the structure and weight of component A~D in table 1, addition is helped
250 grams of agent (Dispersant MF is 200 grams, and sodium lignin sulfonate is 50 grams), adds and slurries is made after 800 grams of blendings of water, grinding distribution,
Dry, finished product, the dyestuff can be supplied to the excellent indigo plant of fabric items fastness ability to black.
Table 1
Dyeing Example:
Disperse dyes made from above-described embodiment 1~30 are chosen respectively, using conventional high temperature high-pressure dyeing and thermal finalization
Dacron is handled, in treatment process, controls dye level (o.w.f) 6.0%, bath raio 1: 25 adjusts Value in Dyeing Process 4~5, room temperature
Enter dye, be warming up to 130 DEG C with 1 DEG C/min, keep the temperature 45min, by well-established law reduction washing, washing, drying, 180 DEG C thermal finalization 60 seconds,
Obtain the dyeing and weaving object of blue to black.According to ISO 105-P01, ISO 105-X12, AATCC 61-2A test respectively it is resistance to distillation,
Rub resistance and washing color fastness:
Dyestuff made from Examples 1 to 30:
Color fastness to sublimation: it fades >=4 grades, cotton is stained with >=4~5 grades, washs and is stained with >=4~5 grades；
Colour fastness to rubbing: unlubricated friction >=4~5 grade, it is wet to rub >=4 grades；
Washing color fastness: cotton staining >=4~5 grade, terylene staining >=4~5 grade, vinegar fibre staining >=3~4 grade, polyamide fibre are stained with
Color >=4 grade.
Comparative example 1~4:
By the embodiment 12 in patent CN105111785A as a comparison case 1.
By the embodiment 11 in patent CN102061106A as a comparison case 2.
Using in patent CN104371370A embodiment 22, comparative example 4 is as comparative example 3~4.
Lifting force embodiment:
By the dyestuff of Examples 1 to 30, comparative example 1~4, according to the method in GB/T 2397-2012, respectively with dyeing
Concentration 1.5% (C), 3% (2C), 6% (4C) carry out high-temperature pressure dyeing, assess its lifting force performance, as a result see the table below 2.
Dispersed embodiment:
By the dyestuff of Examples 1 to 30, comparative example 1~4, according to the method in AATCC 146-2006, its dispersion is tested
Property, it as a result see the table below 2:
Table 2
| Embodiment | Lifting force | Dispersibility |
| 1~30 | A | 5 |
| Comparative example 1 | B | 4~5 |
| Comparative example 2 | A | 4 |
| Comparative example 3 | B | 4 |
| Comparative example 4 | B | 4~5 |
It can be seen that when disperse blue provided by the present invention to black dye composition, is applied to dacron dyeing, phase
Compared with the disperse dyes of comparative example, have clear improvement in terms of lifting force and dispersibility.
Claims (6)
1. it is a kind of blue to black disperse dye composition, including component A, component B, component C and component D, the component A are formula
Compound shown in (I -1) and/or (I -2), the component B are compound shown in formula (II -1) and/or (II -2), the group
Point C is compound shown in formula (III), and the component D is formula (IV -1) and/or (IV -2), based on the component A, component B,
The parts by weight of component C and component D, component A are 20~90, and the parts by weight of component B are 5~60, and the parts by weight of component C are 1~50,
The parts by weight of component D are 1~50:
2. as described in claim 1 blue to black disperse dye composition, it is characterised in that: described is blue to black dispersion dye
Feed composition includes component A, component B, component C and component D, based on component A, component B, component C and component D, the component A
Mass percentage be 20~90%, the mass percentage of component B is 5~60%, the mass percentage of the component C
It is 1~50%, the mass percentage of component D is 1~50%.
3. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that: described is blue to black point
Dye composite is dissipated, is made of component A, component B, component C and component D.
4. it is a kind of blue to black disperse dye product, contain as described in claim 1 blue to black disperse dye composition
And auxiliary agent, auxiliary agent and the blue weight ratio to black disperse dye composition are 0.2~5:1.
5. as claimed in claim 4 blue to black disperse dye product, it is characterised in that: described blue to black disperse dye system
Product are made of indigo plant to the black disperse dye composition and auxiliary agent.
6. blue to black disperse dye product as described in claim 4 or 5, it is characterised in that: the auxiliary agent is selected from following
One of or in which two or more mixtures: lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalenesulfonateformaldehyde formaldehyde condensation
Object, benzyl naphthalene sulfonic acid-formaldehyde condensation product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268749.XA CN106833019B (en) | 2016-12-31 | 2016-12-31 | A kind of high fastness indigo plant is to black disperse dye composition and dye preparations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268749.XA CN106833019B (en) | 2016-12-31 | 2016-12-31 | A kind of high fastness indigo plant is to black disperse dye composition and dye preparations |
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| Publication Number | Publication Date |
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| CN106833019A CN106833019A (en) | 2017-06-13 |
| CN106833019B true CN106833019B (en) | 2019-06-18 |
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| CN112608622B (en) * | 2020-12-07 | 2023-05-23 | 浙江龙盛集团股份有限公司 | Blue-to-black disperse dye composition and dye product |
| CN113136114A (en) * | 2021-03-23 | 2021-07-20 | 王羽蘅 | High-fastness disperse dye composition and dye product |
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| CN104087012B (en) * | 2013-11-14 | 2016-05-25 | 上海安诺其集团股份有限公司 | The application of azo disperse dye goods |
| CN104087014A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Azo disperse dye composition |
| CN104087013B (en) * | 2013-11-14 | 2016-05-25 | 上海安诺其集团股份有限公司 | The preparation method of azo disperse dye goods |
| CN104087011B (en) * | 2013-11-14 | 2016-05-25 | 上海安诺其集团股份有限公司 | Azo disperse dye goods |
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