CN106833019A - A kind of fastness high is blue to black disperse dye composition and dye preparations - Google Patents
A kind of fastness high is blue to black disperse dye composition and dye preparations Download PDFInfo
- Publication number
- CN106833019A CN106833019A CN201611268749.XA CN201611268749A CN106833019A CN 106833019 A CN106833019 A CN 106833019A CN 201611268749 A CN201611268749 A CN 201611268749A CN 106833019 A CN106833019 A CN 106833019A
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- component
- blue
- disperse dye
- black disperse
- black
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- 0 CC(N(C(C)=C)C(C(OC)=C1)=CC(*)[C@]1N=Nc(c([N+]([O-])=O)cc([N+]([O-])=O)c1)c1Br)=C Chemical compound CC(N(C(C)=C)C(C(OC)=C1)=CC(*)[C@]1N=Nc(c([N+]([O-])=O)cc([N+]([O-])=O)c1)c1Br)=C 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0079—Azoic dyestuff preparations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
It is blue to black disperse dye composition and dye preparations the invention discloses a kind of fastness high.It is described blue to black disperse dye composition, including component A, component B, component C and component D, described component A is formula (I 1) and/or compound shown in (I 2), described component B is in formula (II 1) and/or compound shown in (II 2), described component C is compound shown in formula (III), and described component D is formula (IV 1) and/or (IV 2) and/or compound shown in (IV 3).Described blue to black disperse dye product, it contains described indigo plant to black disperse dye composition and auxiliary agent., to black disperse dye composition and dye preparations, when being applied to hydrophobic fiber material dyeing, lifting force is high, depth is good, and good dispersion, level-dyeing property are good for the indigo plant that the present invention is provided, and every color fastness is excellent.
Description
(1) technical field
The present invention relates to a kind of blue to black disperse dye composition and dye preparations, especially a kind of suitable printing hydrophobic
Property fibrous material fastness high it is blue to black disperse dye composition and dye preparations.
(2) background technology
Blue-black series dyes usage amount is maximum in disperse dyes, but at present the series dyes be difficult to be provided simultaneously with it is excellent
Dyeability and fastness ability, such as publication CN105111785A, CN102061106A, CN104371370A provide one
The excellent blue-black series dyes composition of every fastness is planted, but lifting force, dispersiveness aspect still have the further space for improving.
(3) content of the invention
It is blue to black disperse dye composition and dyestuff system the invention provides a kind of fastness high to solve the above problems
Product, when being applied to hydrophobic fiber material dyeing, lifting force is high, depth is good, and good dispersion, level-dyeing property are good, and every color jail
Degree is excellent.
The technical solution adopted by the present invention is：
It is a kind of blue to be to black disperse dye composition, including component A, component B, component C and component D, described component A
Formula (I -1) and/or compound shown in (I -2), it is described during described component B is for formula (II -1) and/or compound shown in (II -2)
Component C be compound shown in formula (III), described component D is formula (IV -1) and/or (IV -2) and/or chemical combination shown in (IV -3)
Thing, based on described component A, component B, component C and component D, the weight portion of component A is 20~90, and the weight portion of component B is 5
The weight portion of~60, component C is 1~50, and the weight portion of component D is 1~50：
Preferably, it is of the present invention blue to black disperse dye composition, comprising component A, component B, component C and component
D, the weight/mass percentage composition based on component A, component B, component C and component D, the component A is 20~90%, the quality of component B
Percentage composition is 5~60%, and the weight/mass percentage composition of the component C is 1~50%, the weight/mass percentage composition of component D for 1~
50%.
It is more highly preferred to, it is of the present invention blue to black disperse dye composition, by component A, component B, component C and group
Divide D compositions, the weight/mass percentage composition based on component A, component B, component C and component D, the component A is 20~90%, component B
Weight/mass percentage composition be 5~60%, the weight/mass percentage composition of the component C is 1~50%, the weight/mass percentage composition of component D
It is 1~50%.
It is of the present invention blue to black disperse dye composition, as commodity selling or it is applied to textile material and colours
When, generally also need to add auxiliary agent to be post-processed.Therefore, present invention also offers a kind of indigo plant to black disperse dye product,
It contains described disperse blue to black dye composition and auxiliary agent, auxiliary agent and the blue weight to black disperse dye composition it
Than being 0.2~5:1.Preferably, it is described it is blue to black dyes disperse product by it is described it is blue to black disperse dye composition and
Auxiliary agent is constituted.Described auxiliary agent is dispersant, diffusant and other surfactants for being commonly used when disperse dyes are compounded etc., preferably
Mixture from more than one of following or two of which：Lignosulfonates (such as sodium lignin sulfonate (lignin 85A, lignin
83A)), alkyl naphthalene sulfonic acid formaldehyde condensation products (such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulfonic acid-formaldehyde condensation product
(dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF) etc..
Indigo plant of the present invention is as follows to the preparation method of black disperse dye product：
After the blue dye monomer compound (former dyestuff) to black disperse dye composition will be constituted by proportioning mixing,
In the presence of auxiliary agent, water corpusculed is carried out with pulverizers such as sand mill or grinders；In addition also can be by dye monomer chemical combination
Thing is mixed in proportion after carrying out corpusculed treatment with pulverizers such as sand mill or grinders in the presence of auxiliary agent, water respectively
Close.Dispersed deep blue dye product of the present invention, is liquid after being ground with sand mill or grinder, can be powder after spray drying
Shape, graininess, this is well known to a person skilled in the art preparation method.
In the present invention, formula (I -1), (I -2), (II -1), (II -1), (III), shown in (IV -1), (IV -2) and (IV -3)
Dye composition easily can be synthesized by mode well known to those skilled in the art, it is also possible to reference patent CN103613511A,
Prepared by the method introduced in GB2123845A, GB813906A, JPS61223040A or similar method, it would however also be possible to employ commercially available
Commodity.
The dyestuff being made using dye composite of the invention, can be by ways customary in industry to hydrophobic fiber material
(such as polyester and its blended fabric) is dyeed, and is such as dyeed using common dip method or high-temperature and high pressure dyeing process, also may be used
For direct printing.Wherein, common dip method is to be pre-processed hydrophobic fiber material, is put into dye vat and is contaminated,
Dye finishes, and cold water wash is squeezed out to neutrality, then carries out reduction cleaning, drying；Direct printing is that fabric is carried out into dye pre-treatment, is dried
Dry, setting prints disperse dyes mill base on printing machine, then is evaporated, and the dye fixing on fabric is made using decatize mode, most
After wash, stentering forming.
The beneficial effects of the present invention are：The indigo plant that the present invention is provided, should to black disperse dye composition and dye preparations
When being dyeed for hydrophobic fiber material, with lifting force is high, depth is good, good dispersion, level-dyeing property are good, and every color fastness
It is excellent.
(4) specific embodiment
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in
This：
Embodiment 1：
12 grams of formulas (I -1) compound, 12 grams of formula (I -2) compounds, 40 grams of formula (II -2) compounds, 18 grams of formulas (III) are changed
Compound, 18 grams of formula (IV -1) compounds and 200 grams of Dispersant MF, after the 650 grams of blendings that add water, grinding distribution is simultaneously dried, and is obtained final product
Finished product, the dyestuff can be supplied to the excellent black of fabric items fastness ability.
Embodiment 2：
30 grams of formulas (I -1) compound, 30 grams of formula (I -2) compounds, 20 grams of formula (II -1) compounds, 10 grams of formulas (III) are changed
Compound, 10 grams of formula (IV -1) compounds and the Dispersant MF with 200 grams, after the 650 grams of blendings that add water, grinding distribution is simultaneously dried, i.e.,
Finished product is obtained, the dyestuff can be supplied to the excellent blueness of fabric items fastness ability.
Embodiment 3~30：
According to the method described in embodiment 1 or 2, the difference is that using the structure and weight of component A~D in table 1, addition is helped
250 grams of agent (Dispersant MF is 200 grams, and sodium lignin sulfonate is 50 grams), is made slurries after the 800 grams of blendings that add water, grinding distribution,
Dry, finished product, the dyestuff can be supplied to the excellent indigo plant of fabric items fastness ability to black.
Table 1
Dyeing Example：
Disperse dyes obtained in above-described embodiment 1~30 are chosen respectively, using conventional high temperature high-pressure dyeing and thermal finalization
Treatment dacron, in processing procedure, control dye level (o.w.f) 6.0%, bath raio 1: 25 adjusts Value in Dyeing Process 4~5, room temperature
Enter dye, 130 DEG C are warming up to 1 DEG C/min, be incubated 45min, by well-established law reduction washing, washing, drying, 180 DEG C of thermal finalization 60 seconds,
Obtain the blue dyeing and weaving thing to black.According to ISO 105-P01, ISO 105-X12, AATCC 61-2A test respectively resistance to distillation,
Rub resistance and washing color fastness：
Dyestuff obtained in embodiment 1~30：
Color fastness to sublimation：Fade >=4 grades, cotton is stained with >=4~5 grades, washs and is stained with >=4~5 grades；
Colour fastness to rubbing：Unlubricated friction >=4~5 grade, it is wet to rub >=4 grades；
Washing color fastness：Cotton staining >=4~5 grade, terylene staining >=4~5 grade, vinegar fibre staining >=3~4 grade, polyamide fibre is stained with
Color >=4 grade.
Comparative example 1~4：
By the embodiment 12 in patent CN105111785A as a comparison case 1.
By the embodiment 11 in patent CN102061106A as a comparison case 2.
Using the embodiment 22 in patent CN104371370A, comparative example 4 as comparative example 3~4.
Lifting force embodiment：
By embodiment 1~30, the dyestuff of comparative example 1~4, according to the method in GB/T 2397-2012, respectively with dyeing
Concentration 1.5% (C), 3% (2C), 6% (4C) carry out high-temperature pressure dyeing, assess its lifting force performance, as a result see the table below 2.
Dispersed embodiment：
By embodiment 1~30, the dyestuff of comparative example 1~4, according to the method in AATCC 146-2006, its dispersion is tested
Property, as a result see the table below 2：
Table 2
| Embodiment | Lifting force | Dispersiveness |
| 1~30 | A | 5 |
| Comparative example 1 | B | 4~5 |
| Comparative example 2 | A | 4 |
| Comparative example 3 | B | 4 |
| Comparative example 4 | B | 4~5 |
As can be seen here, disperse blue provided by the present invention is to black dye composition, when being applied to dacron and dyeing, phase
Compared with the disperse dyes of comparative example, had clear improvement in terms of lifting force and dispersiveness.
Claims (6)
1. a kind of blue to black disperse dye composition, including component A, component B, component C and component D, described component A are formula
(I -1) and/or compound shown in (I -2), it is described during described component B is for formula (II -1) and/or compound shown in (II -2)
Component C is compound shown in formula (III), and described component D is formula (IV -1) and/or (IV -2) and/or chemical combination shown in (IV -3)
Thing, based on described component A, component B, component C and component D, the weight portion of component A is 20~90, and the weight portion of component B is 5
The weight portion of~60, component C is 1~50, and the weight portion of component D is 1~50：
2. as claimed in claim 1 blue to black disperse dye composition, it is characterised in that：Described is blue to black dispersion dye
Feed composition, comprising component A, component B, component C and component D, based on component A, component B, component C and component D, the component A
Weight/mass percentage composition be 20~90%, the weight/mass percentage composition of component B is 5~60%, the weight/mass percentage composition of the component C
It is 1~50%, the weight/mass percentage composition of component D is 1~50%.
3. as claimed in claim 1 or 2 blue to black disperse dye composition, it is characterised in that：Described is blue to black point
Dye composite is dissipated, is made up of component A, component B, component C and component D.
4. to black disperse dye product, it contains as claimed in claim 1 blue to black disperse dye composition a kind of indigo plant
And auxiliary agent, auxiliary agent and the blue weight ratio to black disperse dye composition are 0.2~5:1.
5. as claimed in claim 4 blue to black disperse dye product, it is characterised in that：It is described blue to black disperse dye system
Product are made up of described indigo plant to black disperse dye composition and auxiliary agent.
6. blue to black disperse dye product as described in claim 4 or 5, it is characterised in that：Described auxiliary agent is selected from following
One of or two of which more than mixture：Lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalenesulfonateformaldehyde formaldehyde condensation
Thing, benzyl naphthalene sulfonic acid-formaldehyde condensation product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268749.XA CN106833019B (en) | 2016-12-31 | 2016-12-31 | A kind of high fastness indigo plant is to black disperse dye composition and dye preparations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611268749.XA CN106833019B (en) | 2016-12-31 | 2016-12-31 | A kind of high fastness indigo plant is to black disperse dye composition and dye preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106833019A true CN106833019A (en) | 2017-06-13 |
| CN106833019B CN106833019B (en) | 2019-06-18 |
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ID=59117603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611268749.XA Active CN106833019B (en) | 2016-12-31 | 2016-12-31 | A kind of high fastness indigo plant is to black disperse dye composition and dye preparations |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112608622A (en) * | 2020-12-07 | 2021-04-06 | 浙江龙盛集团股份有限公司 | Blue-to-black disperse dye composition and dye product |
| CN113136114A (en) * | 2021-03-23 | 2021-07-20 | 王羽蘅 | High-fastness disperse dye composition and dye product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087012A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Use of azo disperse dye product |
| CN104087013A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Preparation method of azo disperse dye product |
| CN104087011A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Azo disperse dye product |
| CN104087014A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Azo disperse dye composition |
-
2016
- 2016-12-31 CN CN201611268749.XA patent/CN106833019B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087012A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Use of azo disperse dye product |
| CN104087013A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Preparation method of azo disperse dye product |
| CN104087011A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Azo disperse dye product |
| CN104087014A (en) * | 2013-11-14 | 2014-10-08 | 上海安诺其纺织化工股份有限公司 | Azo disperse dye composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112608622A (en) * | 2020-12-07 | 2021-04-06 | 浙江龙盛集团股份有限公司 | Blue-to-black disperse dye composition and dye product |
| CN112608622B (en) * | 2020-12-07 | 2023-05-23 | 浙江龙盛集团股份有限公司 | Blue-to-black disperse dye composition and dye product |
| CN113136114A (en) * | 2021-03-23 | 2021-07-20 | 王羽蘅 | High-fastness disperse dye composition and dye product |
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| Publication number | Publication date |
|---|---|
| CN106833019B (en) | 2019-06-18 |
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