CN101880476A - Yellow-to-orange disperse dye composition - Google Patents
Yellow-to-orange disperse dye composition Download PDFInfo
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- CN101880476A CN101880476A CN 201010212592 CN201010212592A CN101880476A CN 101880476 A CN101880476 A CN 101880476A CN 201010212592 CN201010212592 CN 201010212592 CN 201010212592 A CN201010212592 A CN 201010212592A CN 101880476 A CN101880476 A CN 101880476A
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- yellow
- quality percentage
- percentage composition
- disperse dye
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- 239000000203 mixture Substances 0.000 title claims abstract description 62
- 239000000986 disperse dye Substances 0.000 title claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 12
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 8
- 239000007859 condensation product Substances 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 6
- -1 nitro, methyl Chemical group 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019357 lignosulphonate Nutrition 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 18
- 239000004744 fabric Substances 0.000 abstract description 15
- 238000005406 washing Methods 0.000 abstract description 13
- 239000001048 orange dye Substances 0.000 abstract description 10
- 238000007639 printing Methods 0.000 abstract description 6
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 4
- 229920000742 Cotton Polymers 0.000 abstract description 3
- 229920004934 Dacron® Polymers 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 abstract description 2
- 229920002334 Spandex Polymers 0.000 abstract 1
- 239000004759 spandex Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 29
- 238000000034 method Methods 0.000 description 8
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 7
- 238000009998 heat setting Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920004935 Trevira® Polymers 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010017 direct printing Methods 0.000 description 2
- 238000004044 disperse dyeing Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000009980 pad dyeing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000001089 thermophoresis Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
Abstract
The invention provides a yellow-to-orange disperse dye composition which mainly comprises one or a plurality of components A the structures of which are shown as a formula (I), one or a plurality of components B the structures of which are shown as a formula (II) and one or a plurality of components C the structures of which are shown as a formula (III). Based on the components A, the components B and the components C, the mass percent of the components A is 0.1 to 99 percent, the mass percent of the components B is 0.1 to 99 percent, and the mass percent of the components C is 0 to 60 percent; when the dispersive yellow-to-orange dye is used for dyeing a hydrophobic fibre material, residual dyeing liquid is clear, and scums are little; especially, after high-temperature shaping, very high washing fastness still can be ensured; and the invention effectively solves the problem that the washing fastness of conventional dispersive yellow-to-orange dye is greatly lowered under high-temperature after finishing, and is very suitable for printing and dyeing middle-grade/high-grade fabrics, such as superfine-denier fabrics and blended fabrics of dacron/cotton, dacron/spandex and the like.
Description
(1) technical field
The present invention relates to a kind of Yellow-to-orange disperse dye composition of high washing fastness of suitable printing and dyeing hydrophobic fiber material.
(2) background technology
In recent years, dacron fabric such as Sportswear, Casual Wear, the interior fabrics of automobile etc. are with carrying out the heat setting type processing for guaranteeing that final dimension one makes peace to stablize after the disperse dyeing, because heat setting temperature is generally higher, above 140 ℃, the thermophoresis reverse with when dyeing will take place in the dispersed dye of fibrous inside, the part dyestuff can migrate to fiber surface again, cause dyeing after the fabric washing fastness of heat setting type significantly descends (generally having only about 3 grades), and be infected with adjacent subsides lining and go up or contaminate environment, and existing dispersed dye washing fastness etc. all be polyester piece good with disperse dyeing after reduction clearing but do not carry out the data that heat setting type is handled can't reflect the heat-resisting migration performance of dispersed dye.
In addition, development along with the super fine denier trevira, and wash/development of ammonia, wash/high-grade BLENDED FABRIC such as cotton, existing DISPERSE YELLOW to orange dye can not satisfy its dyeing demand when printing and dyeing, it is serious as above to dye other fibers of contamination, causes the whole color fastness decreased of fabric, spot is problem such as easy-clear not, and further reform the requirement of trevira at the REACH of European Union rules, consider, be necessary to develop a class novel environment friendly dyestuff from environment and ecological aspect with dispersed dye.
(3) summary of the invention
For addressing the above problem, the invention provides a kind of dispersed dye of Yellow-to-orange, when being applied to hydrophobic fiber material dyeing, have splendid washing fastness and heat-resisting migration performance, dyeing residual liquid is clear, and loose colour is few, economic environmental protection can be used for the dyeing of top-grade fashion lining.
The technical solution used in the present invention is:
A kind of Yellow-to-orange disperse dye composition, mainly form suc as formula the component C shown in (III) suc as formula the B component shown in (II) and one or more structures suc as formula the component A shown in (I), one or more structures by one or more structures, based on described component A, B component and component C (promptly based on component A, B component and component C quality sum), the quality percentage composition of component A is 0.1～99%, the quality percentage composition of B component is 0.1～99%, and the quality percentage composition of component C is 0～60%; When component C was 0, based on described component A and B component, the quality percentage composition of component A and B component was respectively 1～99% and 1～99% (being preferably 60～90% and 10～40%);
In the formula (I):
R
1Be C
1～C
4Alkyl or substituted alkyl, the substituting group of described substituted alkyl is C
1～C
4Alkoxyl group; X
1, X
2Independent separately be nitro, methyl or methoxy, and satisfy one of them for nitro, another is methyl or methoxy;
In the formula (II):
R
2Be C
1～C
4Alkyl, be preferably methyl and ethyl;
X
3, X
4Independent separately be H, halogen, nitro ,-COOC
2H
4OC
2H
4OCH
3,-COOC
2H
5Or-OSO
2-ph, ph are phenyl;
In the formula (III):
R
3Be C
1～C
4Alkyl;
R
4, R
5The C that independently is separately
1～C
4Alkyl or substituted alkyl, the substituting group of described substituted alkyl is-OCOR
7,-COOR
8, wherein, R
7, R
8Independent separately is C
1～C
4Alkyl;
X
5Be cyano group or nitro.
Preferably, based on described component A, B component and component C, the quality percentage composition of component A is 20～99%, and the quality percentage composition of B component is 0.1～85%, and the quality percentage composition of component C is 0～50%.
More preferred, based on described component A, B component and component C, the quality percentage composition of component A is 30～99%, and the quality percentage composition of B component is 0.1～60%, and the quality percentage composition of component C is 0～40%.
Preferably, based on described component A, B component and component C, the quality percentage composition of component A is 20～60%, and the quality percentage composition of B component is 20～40%, and the quality percentage composition of component C is 20～40%.
Because the singularity of dye industry is difficult to also there is no need to make pure product, can have the impurity in some preparation process usually, also allows to contain a spot of physics impurity when dye composite of the present invention is made finished product.
The dye monomer compound of formula used in the present invention (I)～formula (III) can be synthetic by mode well known to those skilled in the art easily, or, also can adopt the commercial goods with reference to method described in patent JP61019664A, US3957749A, the US5550217A or similarly method preparation.
DISPERSE YELLOW of the present invention is to orange dye, need when being applied to dye to handle through commercialization, as need to add auxiliary agent and disperse.After for example with structural formula (I), (II) and (III) represented dye monomer compound mixes by above-mentioned proportioning, in the presence of auxiliary agent, water or other wetting agent, carry out corpusculed with pulverizers such as sand mill or shredders; In addition also can with structural formula (I), (II) and (III) represented dye monomer compound in the presence of auxiliary agent, water or other wetting agent, carry out corpusculed respectively and handle the back and mix with above-mentioned ratio with pulverizers such as sand mill or shredders.
Described Yellow-to-orange disperse dye composition also can be made up of component A, B component, component C and auxiliary agent, and described auxiliary agent quality is 0.5～8: 1 with the ratio of component A, B component and component C quality sum.
Commonly used dispersion agent, diffusant and tensio-active agents etc. when described auxiliary agent is the dispersed dye commercialization are preferably one of following or wherein two or more mixtures: naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Particularly, naphthalene sulfonic acidformaldehyde condensation product such as dispersing agent NNO, alkyl naphthalene sulfonic acid formaldehyde condensation products such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic formaldehyde condensation compound such as dispersing agent CNF etc., sulfonated lignin such as sodium lignosulfonate (as commercial dispersants Reax83A, Reax85A) etc.
DISPERSE YELLOW of the present invention is to orange dye, adds auxiliary agent after commercialization is handled, and powdery, graininess behind liquid state, emulsifiable paste attitude or the optionally drying after can corpusculed be supplied with dyeing.Described auxiliary agent can also comprise dust-proofing agent, sanitas, thickening material, oxygenant and stablizer etc. that dye preparations is commonly used except that comprising above-mentioned common dispersants, diffusant and tensio-active agent.
Preferably, described component A is one of following or wherein two or more mixture:
Preferably, described B component is one of following or wherein two or more mixture:
Preferably, described component C is one of following or wherein two or more mixture:
Preferably, described composition is made up of component A, B component, component C and auxiliary agent, described component A is compound (I-1) and/or compound (I-2), B component is compound (II-1) and/or compound (II-2), component C is compound (III-1), and auxiliary agent is Dispersant MF and/or sodium lignosulfonate; Based on described component A, B component and component C, the quality percentage composition of component A is 30～99%, and the quality percentage composition of B component is 0.1～60%, and the quality percentage composition of component C is 0～40%;
To orange dye, can adopt conventional dip method, pad dyeing method to dye according to the DISPERSE YELLOW of making of the present invention, also can be used for direct printing.Wherein, conventional dip method is put into dye vat and is contaminated as polyester textile is carried out pre-treatment, dyes completely, and cold water cleans to neutral, and strand is done, and carries out reduction clearing again, oven dry; Direct printing is as dying pre-treatment with fabric, oven dry, and setting, seal dispersed dye mill base evaporates again on printing machine, utilizes the decatize mode to make dye fixing on the fabric, washing at last, stentering forming.
When dying hydrophobic fiber material with DISPERSE YELLOW of the present invention to orange dye, dyeing residual liquid is clear, loose colour is few; By adjusting proportion among different, can obtain to have the Yellow-to-orange dyeing and weaving thing that gorgeous, the heat-resisting migration performance of coloured light is good, washing fastness is outstanding, particularly behind high-temperature shaping, still can guarantee very high washing fastness, efficiently solve conventional DISPERSE YELLOW to orange dye difficult problem of declining to a great extent of washing fastness under arrangement behind the high temperature, be highly suitable for medium-to-high grade lining such as super fine denier fabric, wash/cotton, wash/printing and dyeing of BLENDED FABRIC such as ammonia.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
With the component A of 50 gram formulas (I-1) and 42 gram formulas (I-2), the B component of 8 gram formulas (II-1), the Dispersant MF of 120 grams, the sodium lignosulfonates of 30 grams, add water 650 gram piece together mix after, grind and disperse and dry, get product, this dyestuff can offer the good golden yellow of the every fastness ability of fabric.
Embodiment 2:
With the component A of 23 gram formulas (I-1) and 23 gram formulas (I-2), the B component of 27 gram formulas (II-1), the component C of 27 gram formulas (III-1), the sodium lignosulfonate of 150 grams, add water 600 gram piece together mix after, grind and disperse and drying, get product, this dyestuff can offer good orange of the every fastness ability of fabric.
Embodiment 3～19
According to embodiment 2 described methods, different is structure and the weight of component A, B component, component C in the employing table 1, (Dispersant MF is 150 grams to add auxiliary agent 165 grams, sodium lignosulfonate is 15 grams), add and make slurries after water 600 gram assemblies mix, grind and disperse, drying, make finished product, this dyestuff can offer the good Yellow-to-orange tone of the every fastness ability of fabric.
Table 1
| Embodiment | Component A | B component | Component C | Weight (g) A: B: C | Tone |
| ??3 | ??(I-1)+(I-2) | ??(II-1) | ??- | ??(45+45)∶10 | Yellow |
| ??4 | ??(I-1) | ??(II-1) | ??- | ??85∶15 | Yellow |
| ??5 | ??(I-2) | ??(II-1) | ??- | ??95∶5 | Yellow |
| ??6 | ??(I-6) | ??(II-2)+(II-5) | ??- | ??70∶(15+15) | Yellow |
| ??7 | ??(I-7)+(I-1) | ??(II-4) | ??- | ??(30+30)∶40 | Yellow |
| ??8 | ??(I-10) | ??(II-3)+(II-1) | ??- | ??90∶(5+5) | Yellow |
| ??9 | ??(I-1) | ??(II-8) | ??- | ??75∶25 | Yellow |
| ??10 | ??(I-3) | ??(II-2) | ??- | ??98∶2 | Yellow |
| Embodiment | Component A | B component | Component C | Weight (g) A: B: C | Tone |
| ??11 | ??(I-1)+(I-2) | ??(II-1) | ??(III-1) | ??(25+25)∶25∶25 | Orange |
| ??12 | ??(I-1) | ??(II-1) | ??(III-1) | ??55∶20∶25 | Orange |
| ??13 | ??(I-2) | ??(II-1) | ??(III-3) | ??45∶35∶20 | Orange |
| ??14 | ??(I-4)+(I-10) | ??(II-3) | ??(III-2) | ??(30+30)∶20∶20 | Orange |
| ??15 | ??(I-5) | ??(II-6) | ??(III-4) | ??40∶30∶30 | Orange |
| ??16 | ??(I-1)+(I-2) | ??(II-2) | ??(III-5) | ??(20+20)∶35∶25 | Orange |
| ??17 | ??(I-8) | ??(II-1)+(II-8) | ??(III-4) | ??30∶(20+20)∶30 | Orange |
| ??18 | ??(I-9) | ??(II-7) | ??(III-1) | ??45∶30∶25 | Orange |
| ??19 | ??(I-2) | ??(II-1) | ??(III-2) | ??20∶40∶40 | Orange |
Embodiment 20:
Choose the dispersed dye that the foregoing description 1～19 makes, adopt conventional high-temperature and high pressure dyeing process and heat setting type to handle polyester textile, in the treating processes, control dye level (o.w.f) 2.0%; bath raio 1: 10 is transferred dye bath pH value 3.5～4.5,250 ℃/3min of heat set conditions.After dyeing finishes, test its washing fastness according to GB/T3921, each dispersed dye all still reaches more than 4 grades.
This shows, dispersion yellow among the present invention is to the orange dye composition, after heat setting type is handled, still can guarantee very high washing fastness, obviously be better than conventional DISPERSE YELLOW to orange dye (conventional dispersed dye are handled the after washing fastness through heat setting type and dropped to about 3 grades), satisfy the printing and dyeing that high fastness requires lining.
Claims (10)
1. Yellow-to-orange disperse dye composition, mainly form suc as formula the component C shown in (III) suc as formula the B component shown in (II) and one or more structures suc as formula the component A shown in (I), one or more structures by one or more structures, based on described component A, B component and component C, the quality percentage composition of component A is 0.1～99%, the quality percentage composition of B component is 0.1～99%, and the quality percentage composition of component C is 0～60%;
In the formula (I):
R
1Be C
1～C
4Alkyl or substituted alkyl, the substituting group of described substituted alkyl is C
1～C
4Alkoxyl group; X
1, X
2Independent separately be nitro, methyl or methoxy, and satisfy one of them for nitro, another is methyl or methoxy;
In the formula (II):
R
2Be C
1～C
4Alkyl;
X
3, X
4Independent separately be H, halogen, nitro ,-COOC
2H
4OC
2H
4OCH
3,-COOC
2H
5Or-OSO
2-ph, ph are phenyl;
In the formula (III):
R
3Be C
1～C
4Alkyl;
R
4, R
5The C that independently is separately
1～C
4Alkyl or substituted alkyl, the substituting group of described substituted alkyl is-OCOR
7,-COOR
8, wherein, R
7, R
8Independent separately is C
1～C
4Alkyl;
X
5Be cyano group or nitro.
2. Yellow-to-orange disperse dye composition as claimed in claim 1, it is characterized in that: based on described component A, B component and component C, the quality percentage composition of component A is 20～99%, and the quality percentage composition of B component is 0.1～85%, and the quality percentage composition of component C is 0～50%.
3. Yellow-to-orange disperse dye composition as claimed in claim 2, it is characterized in that: based on described component A, B component and component C, the quality percentage composition of component A is 30～99%, and the quality percentage composition of B component is 0.1～60%, and the quality percentage composition of component C is 0～40%.
4. Yellow-to-orange disperse dye composition as claimed in claim 3, it is characterized in that: based on described component A, B component and component C, the quality percentage composition of component A is 20～60%, and the quality percentage composition of B component is 20～40%, and the quality percentage composition of component C is 20～40%.
5. Yellow-to-orange disperse dye composition as claimed in claim 1, it is characterized in that described Yellow-to-orange disperse dye composition is made up of component A, B component, component C and auxiliary agent, described auxiliary agent quality is 0.5～8: 1 with the ratio of component A, B component and component C quality sum.
6. Yellow-to-orange disperse dye composition as claimed in claim 5 is characterized in that described auxiliary agent is one of following or wherein two or more mixture: naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.
7. as the described Yellow-to-orange disperse dye composition of one of claim 1～6, it is characterized in that described component A is one of following or wherein two or more mixture:
8. as the described Yellow-to-orange disperse dye composition of one of claim 1～6, it is characterized in that described B component is one of following or wherein two or more mixture:
9. as the described Yellow-to-orange disperse dye composition of one of claim 1～6, it is characterized in that described component C is one of following or wherein two or more mixture:
10. Yellow-to-orange disperse dye composition as claimed in claim 5, it is characterized in that described component A is compound (I-1) and/or compound (I-2), B component is compound (II-1) and/or compound (II-2), component C is compound (III-1), and auxiliary agent is Dispersant MF and/or sodium lignosulfonate; Based on described component A, B component and component C, the quality percentage composition of component A is 30～99%, and the quality percentage composition of B component is 0.1～60%, and the quality percentage composition of component C is 0～40%;
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010212592 CN101880476B (en) | 2010-06-29 | 2010-06-29 | Yellow-to-orange disperse dye composition |
Applications Claiming Priority (1)
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|---|---|---|---|
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