CN101768377A - Environment-friendly yellow disperse dye composition - Google Patents
Environment-friendly yellow disperse dye composition Download PDFInfo
- Publication number
- CN101768377A CN101768377A CN200910156641A CN200910156641A CN101768377A CN 101768377 A CN101768377 A CN 101768377A CN 200910156641 A CN200910156641 A CN 200910156641A CN 200910156641 A CN200910156641 A CN 200910156641A CN 101768377 A CN101768377 A CN 101768377A
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- CN
- China
- Prior art keywords
- dye
- yellow
- environment
- dye composition
- fastness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 239000000986 disperse dye Substances 0.000 title claims abstract description 12
- 239000000975 dye Substances 0.000 claims abstract description 31
- 239000000178 monomer Substances 0.000 claims abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 150000002367 halogens Chemical class 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 238000004043 dyeing Methods 0.000 abstract description 8
- 238000000859 sublimation Methods 0.000 abstract description 7
- 230000008022 sublimation Effects 0.000 abstract description 7
- 238000005406 washing Methods 0.000 abstract description 7
- RTZYVAQWQXPIAC-UHFFFAOYSA-N 4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound C1=CC(O)=CC=C1N=NC1=CC=C(N=NC=2C=CC=CC=2)C=C1 RTZYVAQWQXPIAC-UHFFFAOYSA-N 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
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Abstract
The invention discloses an environment-friendly yellow disperse dye composition, which mainly comprises the following components in percentage by weight: 80 to 96 percent of dye monomer A shown in formula (1), 4 to 20 percent of one or more dye monomers B shown in formula (2), wherein X1Is H or halogen, R1Is C1~C4Alkyl of or C in which one hydrogen is substituted by a phenyl ring1~C4Alkyl group of (1). The dye has excellent lifting power, color fixing rate and exhaustion degree, excellent compatibility, level dyeing property, covering property and various fastnesses, and particularly has the advantages of sublimation fastness and washing fastness overDisperse yellow 23# makes up the defects of poor sublimation fastness and poor washing fastness of the disperse yellow 23 #.
Description
Technical field
The present invention relates to a kind of Yellow environment-friendly disperse dye composition, be particularly suitable for the dyeing and the stamp of terylene and BLENDED FABRIC thereof, vinegar fibre, polyamide fibre.
Background technology
Along with industrial continuous development, energy consumption is serious day by day, and energy-conserving and environment-protective are increasingly important.Therefore the picture dyeing is had higher requirement to the environmental protection and energy saving performance and the dyeing behavior of dyestuff.As DISPERSE YELLOW 23# discover recently in its dye structure to nitrogen benzide have carinogenicity but, low price gorgeous, lifting force because of its coloured light good, exhaust rate power height be widely used in low temperature dyeing and stamp.Though the substitute products of existing many environment-friendly types occur on the market now, its energy-efficient performance particularly aspects such as lifting force, dye uptake, degree of fixation has obvious defects.
Summary of the invention
The invention provides a kind of Yellow environment-friendly disperse dye composition, this dyestuff is not only having tangible improvement than original Yellow disperse dye aspect lifting force, degree of fixation, the degree of exhaustion, and the subject range of the pH of this dyestuff is extremely wide, good level-dyeing property, opacifying property good, and particularly sublimation fastness and washing fastness spy are good.
Yellow disperse dye composition of the present invention by weight percentage, mainly comprises following component:
80%~96% as the formula (1) dye monomer A:
4%~20% one or more dye monomer B as the formula (2):
X wherein
1Be H or halogen, R
1Be C
1~C
4Alkyl or the C that hydrogen is replaced by phenyl ring
1~C
4Alkyl.
Described dye monomer B is made up of following one or more dye monomers:
Yellow environment-friendly disperse dye composition of the present invention generally needs to add auxiliary agent during application.Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.Usually, the ratio of auxiliary agent and former dyestuff weight is 1.5~7: 1.
Yellow environment-friendly disperse dye composition of the present invention can be with the preparation of following method: after the former dyestuff of dye monomer is mixed in proportion, in the presence of auxiliary agent, water or other tensio-active agent, carry out corpusculed, then spraying drying with pulverizers such as sand mill or shredders.Above-mentioned dye monomer all can adopt the commercially available prod.
Disperse dye composition of the present invention can be aqueous behind the corpusculed, can be powdery, particulate state after the spraying drying.This dyestuff lifting force, degree of fixation, degree of exhaustion are fabulous, compatibleness is splendid, level-dyeing property, opacifying property, every fastness are all good, especially the superiority of sublimation fastness, washing fastness aspect has surmounted C.I.DISP YELLOW 23# (DISPERSE YELLOW 23#), has remedied that DISPERSE YELLOW 23# sublimation fastness is poor, the deficiency of washing fastness difference.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1~17
According to data shown in the table 1, with dye monomer A, dye monomer B, after adding water and piece together to mix by certain proportioning and condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), sodium lignosulfonate (xylogen 85A, 83A), grind dispersion with sand milling, carry out spraying drying then.
The C.I.DISPYELLOW 2# that produces of the optional Zhejiang Province Runtu intercalated Co., Ltd of dye monomer A wherein, C.I.DISP ORANGE 25#, C.I.DISP ORANGE 288#, C.I.DISPORANGE 298# that dye monomer (2-1), (2-2), (2-3) optional Zhejiang Province Runtu intercalated Co., Ltd produce.
Table 1:
The dye composition that dispersed dye, auxiliary agent, the water that the foregoing description is made makes after mixing carries out performance test, and with DISPERSE YELLOW 23# performance comparison, testing method is as follows:
Respectively get the dispersed dye that 1.0 gram embodiment 1~17 make, water is mixed with the dispersed dye suspension that concentration is 1g/500ml respectively, get 10ml, 20ml, 40ml mixes with the water of 90ml, 80ml, 60ml, dye abundant PH to 5 with the acetic acid adjusting, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt GB/T5718-1997, GB/T3921-1997, GB/T2397-2003, GB/T2396-2003 to measure its dyefastness.Measurement result sees Table 2.
Table 2
The embodiment title | Sublimation fastness (180 ℃) | Washing fastness | Lifting force | Degree of fixation |
Embodiment 1 | ??4-5 | ??4 | ??A-B | ??90% |
The embodiment title | Sublimation fastness (180 ℃) | Washing fastness | Lifting force | Degree of fixation |
Embodiment 2 | ??4-5 | ??4-5 | ??A-B | ??80% |
Embodiment 3 | ??4-5 | ??4-5 | ??B | ??90% |
Embodiment 4 | ??4-5 | ??4 | ??A-B | ??85% |
Embodiment 5 | ??4-5 | ??4 | ??A-B | ??88% |
Embodiment 6 | ??4-5 | ??4-5 | ??A-B | ??87% |
Embodiment 7 | ??4-5 | ??4 | ??A-B | ??90% |
Embodiment 8 | ??4-5 | ??4-5 | ??A-B | ??88% |
Embodiment 9 | ??4-5 | ??4-5 | ??A-B | ??89% |
Embodiment 10 | ??4-5 | ??4-5 | ??B | ??90% |
Embodiment 11 | ??4-5 | ??4 | ??A-B | ??88% |
Embodiment 12 | ??4-5 | ??4-5 | ??A-B | ??87% |
Embodiment 13 | ??4-5 | ??4 | ??A-B | ??88% |
Embodiment 14 | ??4-5 | ??4-5 | ??A-B | ??85% |
Embodiment 15 | ??4-5 | ??4-5 | ??A-B | ??85% |
Embodiment 16 | ??4-5 | ??4-5 | ??A-B | ??89% |
Embodiment 17 | ??4-5 | ??4-5 | ??B | ??90% |
DISPERSE YELLOW 23# | ??3 | ??3 | ??B-C | ??70% |
Claims (2)
1. Yellow environment-friendly disperse dye composition by weight percentage, mainly comprises following component: 80%~96% as the formula (1) dye monomer A:
4%~20% one or more dye monomer B as the formula (2):
X wherein
1Be H or halogen, R
1Be C
1~C
4Alkyl or the C that hydrogen is replaced by phenyl ring
1~C
4Alkyl.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910156641 CN101768377B (en) | 2009-12-30 | 2009-12-30 | Yellow environment-friendly disperse dye composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910156641 CN101768377B (en) | 2009-12-30 | 2009-12-30 | Yellow environment-friendly disperse dye composition |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101768377A true CN101768377A (en) | 2010-07-07 |
CN101768377B CN101768377B (en) | 2013-04-03 |
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Family Applications (1)
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CN 200910156641 Active CN101768377B (en) | 2009-12-30 | 2009-12-30 | Yellow environment-friendly disperse dye composition |
Country Status (1)
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CN (1) | CN101768377B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104530757A (en) * | 2014-12-31 | 2015-04-22 | 浙江闰土股份有限公司 | Yellow disperse dye combination, disperse dye and preparation method and application of disperse dye |
CN111500088A (en) * | 2020-04-24 | 2020-08-07 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH352310A (en) * | 1960-06-20 | 1961-02-28 | Sandoz Ag | Resistant dye preparations |
GB1016367A (en) * | 1963-01-25 | 1966-01-12 | Sandoz Ltd | Dyeing process for cellulose acetate and polyester materials |
-
2009
- 2009-12-30 CN CN 200910156641 patent/CN101768377B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH352310A (en) * | 1960-06-20 | 1961-02-28 | Sandoz Ag | Resistant dye preparations |
GB1016367A (en) * | 1963-01-25 | 1966-01-12 | Sandoz Ltd | Dyeing process for cellulose acetate and polyester materials |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104530757A (en) * | 2014-12-31 | 2015-04-22 | 浙江闰土股份有限公司 | Yellow disperse dye combination, disperse dye and preparation method and application of disperse dye |
CN111500088A (en) * | 2020-04-24 | 2020-08-07 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
CN111500088B (en) * | 2020-04-24 | 2021-08-17 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
Also Published As
Publication number | Publication date |
---|---|
CN101768377B (en) | 2013-04-03 |
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