CN101054477B - Dispersion dyes composition - Google Patents
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- CN101054477B CN101054477B CN 200710068737 CN200710068737A CN101054477B CN 101054477 B CN101054477 B CN 101054477B CN 200710068737 CN200710068737 CN 200710068737 CN 200710068737 A CN200710068737 A CN 200710068737A CN 101054477 B CN101054477 B CN 101054477B
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- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000000975 dye Substances 0.000 title description 35
- 239000006185 dispersion Substances 0.000 title description 7
- 239000000986 disperse dye Substances 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- -1 acetyl oxygen ethyl Chemical group 0.000 claims description 6
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 abstract description 8
- 239000004753 textile Substances 0.000 abstract description 3
- 229920000728 polyester Polymers 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 235000009508 confectionery Nutrition 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 description 23
- 239000000178 monomer Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000007859 condensation product Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 3
- 239000012954 diazonium Substances 0.000 description 3
- 150000001989 diazonium salts Chemical class 0.000 description 3
- 238000006193 diazotization reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 235000019357 lignosulphonate Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- RXQNKKRGJJRMKD-UHFFFAOYSA-N 5-bromo-2-methylaniline Chemical compound CC1=CC=C(Br)C=C1N RXQNKKRGJJRMKD-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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Abstract
The invention provides a dispersive dye composition, mainly comprising one or a plurality of component A with the formula (I), one or a plurality of component B with the formula (II) and one or a plurality of component C with the formula (III), wherein the component A has the mass percentage of 30-95%, the component B has the mass percentage of 1-60% and the component C has the mass percentage of1-20%. When using the dispersive dye composition in the invention for dyeing the polyester fiber materials, textiles with dark blue to black color with the good performances of bright color, good dispersibility, sun-burning resistance, washing resistance and sweet resistance etc. can be obtained.
Description
(1) technical field
The present invention relates to a kind of disperse dye composition, relate in particular to the disperse dye composition of a kind of terylene and BLENDED FABRIC thereof printing and dyeing usefulness.
(2) background technology
Azo disperse dye is the important dyestuff of a class, has characteristics such as bright-colored, that fastness is good, its color and luster, various in style, and performance is different, is widely used at dyeing.Wherein the purposes of black, navy azo dispersion dyes is very extensive, but single deep color dispersion dyes often exists depth, lifting force deficiency, the shortcoming of fastness ability difference is during especially for textile printing, because of the sublimation fastness difference causes white background staining serious.
(3) summary of the invention
The object of the invention is to provide a kind of disperse dye composition, when being applied to textile dyeing, can provide dark blue to black hues.
For reaching goal of the invention the technical solution used in the present invention be:
A kind of disperse dye composition, mainly comprise one or more suc as formula the component A shown in (I), one or more are suc as formula the B component shown in (II), and one or more are suc as formula the component C shown in (III); Based on described component A, B component and component C, the weight fraction of component A is 30～95%, and the weight fraction of B component is 1～60%, and the weight fraction of component C is 1～20%;
In the formula (I), R
1, R
2Independent separately is C
1～C
4Alkyl, C
1～C
4Alkyloyloxyethyl alkyl, C
1～C
4Earboalkoxy alkyl, cyanoethyl, alkoxyalkyl or allyl group;
In the formula (II), X
1Be halogen; R
3And R
4Independently be-R separately
9COOR
10, wherein, R
9, R
10Independent separately is methyl or ethyl; R
5For hydrogen or-NHCOR
11, wherein, R
11Be methyl or ethyl;
In the formula (III), R
6Be hydrogen, methyl or ethyl; R
7, R
8Independently separately be-H, halogen, nitro ,-OSO
2-Ph ,-COOC
2H
4OC
2H
4OCH
3Or-SO
2N (CH
3)
2
Preferably, based on described component A, B component and component C, the weight fraction of component A is 30～70%, and the weight fraction of B component is 20～60%, and the weight fraction of component C is 1～15%.
Preferred, based on described component A, B component and component C, the weight fraction of component A is 40～65%, and the weight fraction of B component is 30～50%, and the weight fraction of component C is 1～12%.
Especially, described disperse dye composition is made up of component A, B component and component C, and the weight fraction of component A is 40～65%, and the weight fraction of B component is 30～50%, and the weight fraction of component C is 1～12%.
Preferably, described R
1, R
2Independent separately is ethyl, cyanoethyl, allyl group, acetyl oxygen ethyl, methoxycarbonyl ethyl, methoxy phosphinylidyne methyl, ethoxy phosphinylidyne ethyl or ethoxy phosphinylidyne methyl.
Preferably, described X
1Be chlorine or bromine.
When preparing disperse dye composition of the present invention, employed dye monomer A preparation method is as follows:
(1) with the amino of the 3-shown in the formula V-5-nitro-2, the 1-benzisothiazole carries out diazotization reaction and obtains 3-amino-5-nitro-2, the diazonium salt of 1-benzisothiazole in diazo reagent;
(2) with 3-amino-5-nitro-2, the diazonium salt of 1-benzisothiazole and following formula (VI) compound carries out coupled reaction, promptly gets described compound (I);
Usually also contain by product in the product that obtains: the isomers (IV) of compound (I), it is as follows that the former makes method only: the mixture filter cake adds in the DMF solution, be heated to 80～100 ℃, make it to dissolve fully, after be cooled to 10 ℃, filter, use the DMF washing leaching cake, wash with water at last do not have DMF to filter cake till, the filter cake of compound (I).In the actual production, need not remove by product, compound (IV) can be directly and compound (I) participate in the colorant match reaction.
Described diazotization reaction and coupled reaction are common reactant in this area, its popular response condition also is applicable to the preparation of The compounds of this invention, adopt following reaction conditions among the present invention: diazo reagent is the mixing solutions of nitrosyl sulfuric acid solution, hydrochloric acid or sulfuric acid and Sodium Nitrite in the described step (1), and diazotization reaction is carried out under-10 ℃～10 ℃; Coupled reaction is carried out in the sulphuric acid soln of mass concentration 5～20%, under-10 ℃～10 ℃ in the described step (2).
Preferably, the 3-amino-5-nitro-2 shown in the formula V in the described step (1), the 1-benzisothiazole with the amount of substance ratio that feeds intake of diazo reagent is: 1: 1.0～1.2; 3-amino in the step (2)-5-nitro-2, the ratio of the compound amount of substance of the diazonium salt of 1-benzisothiazole and formula (VI) is 1.0～1.2: 1.
Monomers B and monomer C are known dyestuff, and it is synthetic also can to know the ground mode by those skilled in the art easily, or with reference to the method preparation of introducing among patent JP11158402, JP10077583, the FR2305470 etc., also can adopt the commercial goods.
Preferably, described component A is one of following or two or more mixture wherein:
What wherein, component A obtained in synthesizing with the corresponding isomers of aforesaid compound (I-1)～(I-12) is:
Described disperse dye composition, B component be one or more in following compound preferably:
Described disperse dye composition, component C be one or more in following compound preferably:
Because the singularity of dye industry is difficult to also there is no need to make pure product, can have the impurity in some preparation process usually, dye ligand compound of the present invention also allows to contain the physics impurity of a spot of moisture content and trace when making finished product.
Disperse dye composition of the present invention generally needs to add auxiliary agent and disperses during application.After for example structural formula (I), (II), (III), (IV) represented former dye component being mixed by above-mentioned proportioning, in the presence of auxiliary agent, water or other wetting agent, carry out corpusculed with pulverizers such as sand mill or shredders; Also structural formula (I), (II), (III), (IV) represented former dye component can be carried out mixing with above-mentioned ratio after corpusculed is handled with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other wetting agent in addition.Usually, auxiliary agent is 0.8～5: 1 with the ratio of former dyestuff weight.
Described auxiliary agent is dispersed dye dispersion agent commonly used, diffusants etc. when composite, one of preferred following or its several mixture arbitrarily: anionic dispersing agents such as naphthalene sulfonic acidformaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, benzyl naphthalene sulfonic formaldehyde condensation compound, sulfonated lignin.Particularly, naphthalene sulfonic acidformaldehyde condensation product such as dispersing agent NNO, alkyl naphthalene sulfonic acid formaldehyde condensation products such as Dispersant MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), benzyl naphthalene sulfonic formaldehyde condensation compound such as dispersing agent CNF etc., sulfonated lignin such as sodium lignosulfonate (as commercial dispersants Reax 83A, Reax 85A) etc.
Disperse dye composition of the present invention, the liquid state after can corpusculed, emulsifiable paste attitude or with spray-drying process etc. carry out dried powdery, graininess is supplied with dyeing.When dying Polyester Fibers, can obtain to have that coloured light is gorgeous with disperse dye composition of the present invention, premium properties such as good dispersity, sun-proof, washable, perspiration resistance dark blue to black dyeing and weaving thing.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
Dye monomer A, dye monomer B, the dye monomer C of 3 gram formulas (III-1) of 43 gram formulas (II-1), 195 sodium lignosulfonates that restrain with 54 gram formulas (I-1), add water 500 gram piece together mix after, grind dispersion with shredder, spraying drying, get product, this dyestuff can offer the bright-coloured navy of fabric.
Embodiment 2:
Dye monomer A, dye monomer B, the dye monomer C of 8 gram formulas (III-2) of 41 gram formulas (II-1), 200 sodium lignosulfonates that restrain with 51 gram formulas (I-3), add water 550 gram piece together mix after, grind dispersion with shredder, spraying drying, get product, this dyestuff can offer the bright-coloured black of fabric.
Embodiment 3～24:
According to data shown in the table 1, with dye monomer A, dye monomer B, dye monomer C, auxiliary agent (commercial), add water 600 gram piece together mix after, grind dispersion with shredder, spraying drying makes finished product then.
Table 1
| Embodiment | Dye monomer A | Weight (g) | Dye monomer B | Weight (g) | Dye monomer C | Weight (g) | Auxiliary agent | Weight (g) |
| 3 | (I-2) | 30 | (II-2) | 55 | (III-2) | 15 | Reax85A | 195 |
| 4 | (I-4) | 70 | (II-3) | 22 | (III-3) | 8 | Dispersant MF | 195 |
| 5 | (I-5) | 50 | (II-4) | 49 | (III-4) | 1 | Dispersant MF | 195 |
| Embodiment | Dye monomer A | Weight (g) | Dye monomer B | Weight (g) | Dye monomer C | Weight (g) | Auxiliary agent | Weight (g) |
| 6 | (I-6) | 45 | (II-1) | 35 | (III-1) (III-5) | 10 10 | Dispersant MF | 195 |
| 7 | (I-7) | 55 | (II-4) | 40 | (III-7) | 5 | Dispersing agent CNF | 195 |
| 8 | (I-8) | 50 | (II-2) | 39 | (III-6) | 11 | Dispersing agent CNF | 195 |
| 9 | (I-9) | 37 | (II-2) | 60 | (III-4) | 3 | Dispersing agent NNO | 195 |
| 10 | (I-10) | 60 | (II-1) | 30 | (III-1) | 10 | The Dispersant MF dispersing agent NNO | 150 50 |
| 11 | (I-11) | 55 | (II-1) (II-2) | 20 20 | (III-1) | 5 | Reax83A | 180 |
| 12 | (I-12) | 50 | (II-1) | 41 | (III-3) | 9 | Dispersing agent CNF | 180 |
| 13 | (I-1) | 35 | (II-1) | 41 | (III-1) | 4 | Dispersing agent CNF | 240 |
| (IV-1) | 20 | |||||||
| 14 | (I-2) (IV-2) | 40 16 | (II-1) | 38 | (III-2) | 6 | Dispersing agent NNO | 240 |
| 15 | (I-3) (IV-3) | 34 14 | (II-2) | 45 | (III-1) | 7 | The Dispersant MF dispersing agent NNO | 160 80 |
| 16 | (I-4) (IV-4) | 34 14 | (II-3) | 45 | (III-4) | 7 | Reax83A | 190 |
| Embodiment | Dye monomer A | Weight (g) | Dye monomer B | Weight (g) | Dye monomer C | Weight (g) | Auxiliary agent | Weight (g) |
| 17 | (I-5) (IV-5) | 32 13 | (II-4) | 45 | (III-1) | 10 | Dispersing agent CNF | 190 |
| 18 | (I-6) (IV-6) | 39 17 | (II-1) | 40 | (III-5) | 4 | Dispersing agent CNF | 205 |
| 19 | (I-7) (IV-7) | 43 19 | (II-2) | 30 | (III-6) | 8 | Dispersing agent NNO | 205 |
| 20 | (I-8) (IV-8) | 41 17 | (II-1) | 35 | (III-7) | 7 | The Dispersant MF dispersing agent NNO | 180 60 |
| 21 | (I-9) (IV-9) | 38 16 | (II-2) | 42 | (III-1) | 4 | Reax83A | 195 |
| 22 | (I-10) (IV-10) | 36 15 | (II-1) | 44 | (III-2) | 5 | Reax83A | 195 |
| 23 | (I-11) (IV-11) | 35 20 | (II-1) | 41 | (III-2) | 4 | Reax83A | 195 |
| 24 | (I-12) (IV-12) | 40 16 | (II-1) | 38 | (III-2) | 6 | Reax83A | 195 |
Dyeing embodiment:
Respectively getting 0.5 dispersed dye that make of gram embodiment 1～24 is dispersed in 500 ml waters, mix with 60 milliliters water after drawing 20 milliliters, transferring dye bath PH with acetic acid is 5, be warming up to 70 ℃ put into simultaneously 2 the gram trevira dye, in 30 minutes, be warmed up to 130 ℃ by 70 ℃, be incubated 30 minutes, begin sampling when being cooled to 90 ℃.Obtain dark blue dyeing and weaving thing to black, adopt that GB GB/T3921-1997, GB/T3920-1997, GB/T3922-1997, GB/T8427-1998 test respectively that it is washable, rub resistance, perspiration resistance, sun-resistant fastness, test result shows: the every fastness excellent property of disperse dye composition provided by the invention, composite effect is remarkable.
Claims (8)
1. disperse dye composition, by one or more suc as formula the component A shown in (I), one or more form suc as formula the component C shown in (III) suc as formula the B component shown in (II) and one or more; Based on described component A, B component and component C, the weight fraction of component A is 30～95%, and the weight fraction of B component is 1～60%, and the weight fraction of component C is 1～20%;
(II)
In the formula (I), R
1, R
2Independent separately is C
1～C
4Alkyl, C
1～C
4Alkyloyloxyethyl alkyl, C
1～C
4Earboalkoxy alkyl, cyanoethyl or allyl group;
In the formula (II), X
1Be halogen; R
3And R
4Independently be-R separately
9COOR
10, wherein, R
9, R
10Independent separately is methyl or ethyl; R
5For hydrogen or-NHCOR
11, wherein, R
11Be methyl or ethyl;
In the formula (III), R
6Be hydrogen, methyl or ethyl; R
7, R
8Independently separately be-H, halogen, nitro ,-OSO
2-Ph ,-COOC
2H
4OC
2H
4OCH
3Or-SO
2N (CH
3)
2
2. disperse dye composition as claimed in claim 1 is characterized in that: based on described component A, B component and component C, the weight fraction of component A is 30～70%, and the weight fraction of B component is 20～60%, and the weight fraction of component C is 1～15%.
3. disperse dye composition as claimed in claim 2 is characterized in that: based on described component A, B component and component C, the weight fraction of component A is 40～65%, and the weight fraction of B component is 30～50%, and the weight fraction of component C is 1～12%.
4. as the described disperse dye composition of one of claim 1～3, it is characterized in that described R
1, R
2Independent separately is ethyl, cyanoethyl, allyl group, acetyl oxygen ethyl, methoxycarbonyl ethyl, methoxy phosphinylidyne methyl, ethoxy phosphinylidyne ethyl or ethoxy phosphinylidyne methyl.
5. as the described disperse dye composition of one of claim 1～3, it is characterized in that described X
1Be chlorine or bromine.
6. as the described disperse dye composition of one of claim 1～3, it is characterized in that described component A is one of following or wherein two or more mixture:
7. as the described disperse dye composition of one of claim 1～3, it is characterized in that described B component is one of following or wherein two or more mixture:
(II-4)。
8. as the described disperse dye composition of one of claim 1～3, it is characterized in that described component C is one of following or wherein two or more mixture:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710068737 CN101054477B (en) | 2007-05-18 | 2007-05-18 | Dispersion dyes composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710068737 CN101054477B (en) | 2007-05-18 | 2007-05-18 | Dispersion dyes composition |
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| Publication Number | Publication Date |
|---|---|
| CN101054477A CN101054477A (en) | 2007-10-17 |
| CN101054477B true CN101054477B (en) | 2010-05-26 |
Family
ID=38794540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710068737 Expired - Fee Related CN101054477B (en) | 2007-05-18 | 2007-05-18 | Dispersion dyes composition |
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|---|---|
| CN (1) | CN101054477B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831202B (en) * | 2010-05-01 | 2013-03-20 | 绍兴县精细化工有限公司 | Black disperse dye and preparation method thereof |
| CN104371370B (en) * | 2013-12-30 | 2017-02-15 | 陈百龙 | Disperse dye composition and disperse dye, and preparation method and use thereof |
| CN104087016B (en) * | 2014-06-05 | 2016-05-04 | 浙江龙盛集团股份有限公司 | A kind of disperse dye composition, disperse dyes goods and application thereof |
| CN105062139A (en) * | 2015-07-31 | 2015-11-18 | 杭州福莱蒽特精细化工有限公司 | Disperse black dye mixture |
| CN106317953A (en) * | 2016-08-29 | 2017-01-11 | 浙江昱泰染化科技有限公司 | Black disperse dye composition |
| CN106893357A (en) * | 2017-01-10 | 2017-06-27 | 泉州市希姆色彩研究院有限公司 | A kind of disperse navy blue dyestuff of fastness high and preparation method thereof |
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|---|---|---|---|---|
| CN1297001A (en) * | 2000-12-04 | 2001-05-30 | 武汉大学 | Disperse blud dye and its synthetic process and application |
| CN1726261A (en) * | 2002-12-20 | 2006-01-25 | 克莱里安特财务(Bvi)有限公司 | Dye compositions for dyeing or printing of fibre products comprising celluloseacetate |
| CN1916083A (en) * | 2006-08-09 | 2007-02-21 | 浙江龙盛集团股份有限公司 | Disperse dye mixture |
-
2007
- 2007-05-18 CN CN 200710068737 patent/CN101054477B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1297001A (en) * | 2000-12-04 | 2001-05-30 | 武汉大学 | Disperse blud dye and its synthetic process and application |
| CN1726261A (en) * | 2002-12-20 | 2006-01-25 | 克莱里安特财务(Bvi)有限公司 | Dye compositions for dyeing or printing of fibre products comprising celluloseacetate |
| CN1916083A (en) * | 2006-08-09 | 2007-02-21 | 浙江龙盛集团股份有限公司 | Disperse dye mixture |
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| CN101054477A (en) | 2007-10-17 |
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