CN106947288B - A kind of disperse dye composition, disperse dyes and its preparation method and purposes - Google Patents
A kind of disperse dye composition, disperse dyes and its preparation method and purposes Download PDFInfo
- Publication number
- CN106947288B CN106947288B CN201710188860.6A CN201710188860A CN106947288B CN 106947288 B CN106947288 B CN 106947288B CN 201710188860 A CN201710188860 A CN 201710188860A CN 106947288 B CN106947288 B CN 106947288B
- Authority
- CN
- China
- Prior art keywords
- component
- weight percent
- formula
- disperse
- dye composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Abstract
A kind of disperse dye composition, disperse dyes and its preparation method and purposes.The disperse dyes are suitable for dyeing and the stamp of fabric, especially terylene and its blended fabric.
Description
The application be the applying date be on December 30th, 2013, application No. is 201310752449.9, it is entitled " a kind of
Disperse dye composition, disperse dyes and its preparation method and purposes " application divisional application.
Technical field
The present invention relates to a kind of disperse dye composition, disperse dyes and its preparation method and purposes.The dispersion dye
Material is suitable for dyeing and the stamp of fabric, especially terylene and its blended fabric.
Background technique
With people's increasing emphasis on environmental protection, especially some European countries have put into effect some regulations, policy etc. in succession.
Likewise, in recent years, higher requirements are also raised to environmental protection for China, control, dyestuff enterprise are carried out to some polluted enterprises
How survival and development are acquired, is that pendulum is maximum in face of dye manufacturers, and is the problem for most needing urgently to solve.
Summary of the invention
The present invention provides the economy that a kind of pH value range is wide, light fastness is good, compatibility is excellent, intensity is high, washing fastness is good
Environmental-friendly disperse dye.
The present invention provides a kind of disperse dye composition, characterized by comprising:
The component A as shown in formula (1):
One or more component B as shown in formula (2):
In formula (2), X1For bromine or chlorine；R1、R2Respectively stand alone as C1~C4Alkyl；
The component C as shown in formula (3-1) and (3-2):
(disperse blue 291:2)
(C.I. disperse blue 291:1)
Optional one or more component D as shown in formula (4):
In formula (4), X2、X3Respectively stand alone as hydrogen, chlorine or bromine, R3、R4Respectively stand alone as C2~C4Alkyl or C1~C4Alkane
The group that a hydrogen in base is replaced by cyano, phenyl, acetoxyl group or benzoyloxy；Wherein component D is not C.I. dispersion
Orange 76；
Optional one or more component E as shown in formula (5):
In formula (5), X4、X5Respectively stand alone as hydrogen, chlorine or nitro, R5For C1~C4Alkyl；
Optional one or more component F as shown in formula (6):
In formula (6), X6、X7Respectively stand alone as cyano, bromine, chlorine or nitro, R6For hydrogen or C1~C4Alkoxy, R9For C1~
C4Alkyl amido or C1~C4Alkyl, R7、R8Respectively stand alone as C1~C4Alkyl；
The optional component G as shown in formula (7):
(disperse blue 2BLM).
Disperse dye composition according to the present invention, it is preferable that the component B be one of following compound or
Two kinds:
(C.I. disperse violet 93)
(disperse violet 93:1).
Disperse dye composition according to the present invention, it is preferable that the component D be one of following compound or
It is two or more:
(disperse orange 288)
(C.I. disperse orange 73)
(C.I. disperse orange 61)
(C.I. disperse orange 30)
(disperse orange 278)
(disperse orange 30:2)
(C.I. disperse orange 25)
(C.I. disperse orange 33).
Disperse dye composition according to the present invention, it is preferable that the component E be one of following compound or
It is two or more:
(C.I. disperse yellow 119)
(C.I. DISPERSE Yellow 211).
Disperse dye composition according to the present invention, it is preferable that the component F be one of following compound or
It is two or more:
(C.I. disperse blue 165:1)
(C.I. disperse blue 366)
(C.I. disperse blue 165)
(C.I. disperse blue 291)
Based on the total weight of the disperse dye composition, the weight percent of component A is 2-73%, preferably 2-
72%, or preferably 2-60%, or preferably 2-51%, or preferably 3-50%, or preferably 3-6%.The weight hundred of component B
Divide than being 7-40%, preferably 7-37%, or preferably 12-39%, or preferably 12-37%.The weight percent of component C is
20-58%, preferably 38-58%, or preferably 20-48%, or preferably 30-55%, or preferably 35-55%.Component D's
Weight percent is 0-70%, preferably 2-50%, or preferably 3-6%.The weight percent of component E is 0-10%, preferably
For 2-6%.The weight percent of component F is 0-47%, preferably 1-10%.The weight percent of component G is 0-47%, preferably
For 1-10%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition, comprising:
The component A that weight percent is 2~73%,
The component B that weight percent is 7~40%,
The component C that weight percent is 20~58%,
The component D that optional weight percent is 0~70%,
The component E that optional weight percent is 0~10%,
The component F that optional weight percent is 0~47%, and
The component G that optional weight percent is 0~47%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 3~50%,
The weight percent of component B is 12~39%,
The weight percent of component C is 38~58%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 2~60%,
The weight percent of component B is 7~37%,
The weight percent of component C is 30~55%,
The weight percent of component D is 3~6%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 3~6%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component D is 2~50%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 2~51%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component E is 2~6%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 2~72%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component F is 1~10%.
Disperse dye composition according to the present invention, it is preferable that the total weight based on the composition,
The weight percent of component A is 2~72%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component G is 1~10%.
Disperse dye composition according to the present invention, it is preferable that in the component C, change shown in the formula (3-1)
The weight percent for closing object is 1~99%, preferably 70~90%, the weight percent of formula (3-2) compound represented
It is 1~99%, preferably 10~30%, the poidometer based on the component C.
In the actual production process, each dye component of the invention usually may be with some by-products and other miscellaneous
Matter, as long as not influencing implementation of the invention.
The present invention also provides a kind of disperse dyes, which is characterized in that combines comprising disperse dyes according to the present invention
Object and auxiliary material.
Disperse dyes according to the present invention, it is preferable that the auxiliary material includes auxiliary agent and water.
Disperse dyes according to the present invention, it is preferable that the auxiliary agent includes the group of one or more below
It closes: naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulphate, surfactant, fungicide or other dye dispersants.
Disperse dyes according to the present invention, it is preferable that the weight ratio of the auxiliary agent and disperse dye composition is
0.3~4:1.
The present invention also provides a kind of methods for preparing disperse dyes according to the present invention, which is characterized in that including with
Lower step:
After each dye component is mixed, particlized processing is carried out with sand mill or grinder in the presence of auxiliary material；
Or each dye component is subjected to particlized processing with sand mill or grinder in the presence of auxiliary material respectively, then mixed
It closes.
Disperse dyes of the present invention, with can be after sand mill or grinder grinding liquid (usual solid content for 20~
It 50%), can be powdery or graininess after spray drying (usual solid content is 87~96%).
The present invention also provides a kind of disperse dyes according to the present invention for the dyeing of fabric and/or the use of stamp
On the way.
The present invention also provides a kind of fabrics, which is characterized in that is carried out by using disperse dyes according to the present invention
Dyeing and/or stamp are prepared.
The pH value range of disperse dyes of the invention is wide, light fastness is good, compatibility is excellent, intensity is high, washing fastness is good.
Specific embodiment
Embodiment
Below with reference to embodiment, the invention will be further described, but the scope of protection of the present invention is not limited thereto.
In embodiment, component A, B, C of the invention and optional component D, E, F, G, by certain proportion and auxiliary agent and
After water blending, grinding distribution is carried out with sand mill, slurry or further progress spray drying is made, so that dyestuff be made.
Described component A, B, C, D, E, F, G are known dye composition and can buy on the market, Huo Zheke
It is prepared by existing method.
Embodiment 1:
By 41 grams of formula (1) dye components, 16 grams of formula (2-2) dye components, 30 grams of formula (3-1) dye components and 13 grams of formulas
The mixture of (3-2) dye component, 80 grams of Dispersant MFs and 80 grams of lignin 85A add 390 grams of water to stir, grinding
Disperse and dry to get dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 1:
Embodiment 1 is repeated, other than the formula of embodiment 1 (1) dye component is substituted for following formula (8) dye component,
It is constant.
The dyestuff finished product of embodiment 1 and comparative example 1 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 1 and comparative example 1 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the intensity that them are measured using GB/T6688-2008, measurement result are shown in Table 1.
Table 1
| Title | Intensity |
| Embodiment 1 | 102% |
| Comparative example 1 | 100% |
Intensity it is high it is meant that same depth textile, whens printing and dyeing can reduce dye dosage, reduce printing and dyeing cost.
Embodiment 2:
By 41 grams of formula (1) dye components, 16 grams of formula (2-1) dye components, 30 grams of formula (3-1) dye components and 13 grams of formulas
The mixture of (3-2) dye component, 80 grams of Dispersant MFs and 80 grams of lignin 83A add 390 grams of water to stir, grinding
Disperse and dry to get dyestuff finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 2:
Embodiment 2 is repeated, other than the formula of embodiment 2 (1) dye component is substituted for following formula (9) dye component,
It is constant.
The dyestuff finished product of embodiment 2 and comparative example 2 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 2 and comparative example 2 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the light fastness that them are measured using AATCC16-2004, the results are shown in Table 2.
Table 2
| Title | Light fastness (40h) |
| Embodiment 2 | 3 |
| Comparative example 2 | 2 |
Embodiment 3:
By 41 grams of formula (1) dye components, 16 grams of formula (2-1) dye components, 30 grams of formula (3-1) dye components and 13 grams of formulas
The mixture of (3-2) dye component and 30 grams of Dispersant MFs add 200 grams of water to stir, and pulp is made in grinding distribution
Expect finished product, dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 3:
Embodiment 3 is repeated, other than the formula of embodiment 3 (1) dye component is replaced an accepted way of doing sth (4-1) dye component,
It is constant.
The dyestuff finished product of embodiment 3 and comparative example 3 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 3 and comparative example 3 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, AATCC16-2004, and surveyed referring to GB/T2400-2006
Intensity, light fastness and the compatibility for determining them, the results are shown in Table 3.
Table 3
| Title | Intensity | Light fastness | Compatibility |
| Embodiment 3 | 105% | 2~3 | Ⅱ |
| Comparative example 3 | 100% | 2 | III |
The method for measuring compatibility are as follows: dyed referring to GB/T2394-2003, enter dye from 60 DEG C, when temperature is raised to 80
DEG C when at once take a sample, a sample is taken every 10 DEG C later, until 130 DEG C, also, 130 DEG C keep the temperature 10 minutes, 20 points
It is separately sampled when clock, 30 minutes, 50 minutes, 10 pieces of cloth specimens are taken altogether.50 minutes are kept the temperature as standard specimen with 130 DEG C, and each shelves temperature is taken
Cloth specimen is sample, observes whether the variation of its form and aspect synchronizes.(the instrument: Computer color testing instrument of the Pyatyi system of being divided into I, II, III, IV, V
Datacolor 600, colour difference formula CMC 2:1).For black hues, DC (gorgeous degree is poor) is calculated, DH (hue difference) is respectively less than
0.6 cloth specimen block number.
I grade: five piece and five pieces or more
II grade: four piece
III grade: three piece
IV grade: two piece
V grade: one piece.
Embodiment 4:
By 41 grams of formula (1) dye components, 16 grams of formula (2-2) dye components, 30 grams of formula (3-1) dye components and 13 grams of formulas
The mixture of (3-2) dye component, 30 grams of Dispersant MFs and 30 grams of dispersing agent NNOs add 250 grams of water to stir, grinding
Slurry dyestuff finished product is made in dispersion, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 4:
Embodiment 4 is repeated, other than the formula of embodiment 4 (1) dye component is substituted for following formula (10) dye component,
It is constant.
The dyestuff finished product of embodiment 4 and comparative example 4 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 4 and comparative example 4 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, and measure their intensity, pH referring to GB/T2403-2006
It is worth range, the results are shown in Table 4.
Table 4
| Title | Intensity | PH stable range |
| Embodiment 4 | 107% | 3~9 |
| Comparative example 4 | 100% | 3~7 |
Note: pH stable range: using the pH value range of intensity >=95% as pH stable range.
Embodiment 5:
By 44 grams of formula (1) dye components, 22 grams of formula (2-2) dye components, 30.6 grams of formula (3-1) dye components and 3.4 grams
The mixture, 31 grams of Dispersant MFs and 31 grams of dispersing agent NNOs of formula (3-2) dye component, add 200 grams of water to stir, grind
Mill disperses and drying is to get dyestuff finished product, and dyeing obtains the excellent black polyester of every fastness ability.
Comparative example 5:
Embodiment 5 is repeated, in addition to 44 grams of formula (1) dye components in embodiment 5 are substituted for 41.4 grams of formula (10) dyestuffs
It is other constant except component and 2.6 grams of formula (11) dye components.
The dyestuff finished product of embodiment 5 and comparative example 5 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 5 and comparative example 5 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, and measure their intensity, pH with reference to GB/T2403-2006
It is worth range, the results are shown in Table 5.
Table 5
| Title | Intensity | PH stable range |
| Embodiment 5 | 107% | 3~9 |
| Comparative example 5 | 100% | 3~7 |
Note: pH stable range: using the pH value range of intensity >=95% as pH stable range.
Embodiment 6:
By 7.8 grams of formula (1) dye components, 7.8 grams of formula (4-1) dye components, 6.0 grams of formula (2-1) dye components, 13.1 grams
The mixture of formula (3-1) dye component and 3.3 grams of formula (3-2) dye components, 31 grams of dispersing agent MFs and 31 grams of lignin 85A, add
200 grams of water stir, and grinding distribution is simultaneously dry to get dyestuff finished product, and dyeing obtains excellent black of every fastness ability
Color polyester.
Comparative example 6:
Embodiment 6 is repeated, other than formula (1) dye component in embodiment 6 is replaced an accepted way of doing sth (8) dye component,
It is constant.
The dyestuff finished product of embodiment 6 and comparative example 6 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 6 and comparative example 6 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Observation cloth specimen coloured light and the intensity that them are measured using GB/T6688-2008, the results are shown in Table 6.
Table 6
| Title | Intensity |
| Embodiment 6 | 102% |
| Comparative example 6 | 100% |
Embodiment 7:
By 9.5 grams of formula (1) dye components, 36.5 grams of formula (2-2) dye components, 27 grams of formula (3-1) dye components and 27 grams
The mixture, 80 grams of Dispersant MFs and 80 grams of lignin 83A of formula (3-2) dye component, add 390 grams of water to stir, grind
Mill disperses and drying is to get dyestuff finished product, and dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 7:
Embodiment 7 is repeated, in addition to by 27 grams of formula (3-1) dye components and 27 grams of formula (3-2) dye components in embodiment 7
Mixture be substituted for except 54 grams of formula (3-1) dye components, it is other constant.
The dyestuff finished product of embodiment 7 and comparative example 7 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 7 and comparative example 7 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T3921-2008, measure their washing fastness, the results are shown in Table 7.
Table 7
| Title | Washing fastness |
| Embodiment 7 | 4~5 |
| Comparative example 7 | 4 |
Embodiment 8:
By 12 grams of formula (1) dye components, 34 grams of formula (2-2) dye components, 10.8 grams of formula (3-1) dye components and 43.2 grams
The mixture, 80 grams of Dispersant MFs and 80 grams of lignin 83A of formula (3-2) dye component, add 390 grams of water to stir, grind
Mill disperses and drying is to get dyestuff finished product, and dyeing obtains the excellent blue polyester of every fastness ability.
Comparative example 8:
Embodiment 8 is repeated, in addition to by 10.8 grams of formula (3-1) dye components and 43.2 grams of formula (3-2) dyestuffs in embodiment 8
The mixture of component is substituted for except 54 grams of formula (3-2) dye components, other constant.
The dyestuff finished product of embodiment 8 and comparative example 8 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 8 and comparative example 8 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T6688-2008, AATCC16-2004, measure their intensity, light fastness,
It the results are shown in Table 8.
Table 8
| Title | Intensity | Light fastness (40h) |
| Embodiment 8 | 103.5% | 2~3 |
| Comparative example 8 | 100% | 2 |
Embodiment 9
According to the formula in table 9, dyestuff finished product is made according to the method for embodiment 8.
9 unit of table: gram
The dyestuff finished product of embodiment 9 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 9 is weighed into the water of 250ml,
Disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath pH to 5 with acetic acid,
Then 60 DEG C are warming up to, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, 130 DEG C are warming up in 35 minutes,
Heat preservation 45 minutes, is cooled to 80 DEG C of samplings.
Cloth specimen coloured light and the method using AATCC16-2004 are observed, their light fastness is measured, the results are shown in Table 10.
Table 10
| Embodiment | Light fastness |
| 9 | 3 |
Embodiment 10-17
According to the formula in table 11, dyestuff finished product is made according to the method for embodiment 8.
11 unit of table: gram
The dyestuff finished product of embodiment 10-17 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 10-17 is weighed respectively to 250ml
Water in, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath with acetic acid
Then pH to 5 is warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, is warming up in 35 minutes
130 DEG C, 45 minutes are kept the temperature, 80 DEG C of samplings are cooled to.
Observe cloth specimen coloured light simultaneously use AATCC16-2004, and using embodiment 3 method measure they light fastness,
Compatibility the results are shown in Table 12.
Table 12
| Embodiment | Light fastness | Compatibility |
| 10 | 3 | Ⅱ |
| 11 | 2~3 | Ⅱ |
| 12 | 3 | Ⅱ |
| 13 | 2~3 | Ⅱ |
| 14 | 3 | Ⅱ |
| 15 | 2~3 | Ⅱ |
| 16 | 2~3 | Ⅱ |
| 17 | 3 | Ⅱ |
Embodiment 18 and 19
According to the formula in table 13, appropriate amount of addition agent is added, dyestuff finished product is made.
13 unit of table: gram
The dyestuff finished product of embodiment 18 and 19 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 18 and 19 is weighed respectively extremely
In the water of 250ml, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, with acetic acid tune
Dye bath pH to 5 is saved, is then warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, in 35 minutes
130 DEG C are warming up to, 45 minutes is kept the temperature, is cooled to 80 DEG C of samplings.
Cloth specimen coloured light and the method using AATCC16-2004 are observed, their light fastness is measured, the results are shown in Table 14.
Table 14
| Embodiment | Light fastness |
| 18 | 3 |
| 19 | 3 |
Embodiment 20-35
According to the formula in table 15, appropriate amount of addition agent is added, dyestuff finished product is made.
15 unit of table: gram
The dyestuff finished product of embodiment 20-35 is tested for the property.
The specific test method is as follows:
According to the similar method of GB/T2394-2003, the dyestuff finished product of 0.5 gram of embodiment 20-35 is weighed respectively to 250ml
Water in, disperse dyes suspension is made.It draws 10ml disperse dyes suspension to mix with the water of 90ml, adjusts dye bath with acetic acid
Then pH to 5 is warming up to 60 DEG C, while being respectively put into 2g polyester fiber and carrying out high-temperature pressure dyeing, is warming up in 35 minutes
130 DEG C, 45 minutes are kept the temperature, 80 DEG C of samplings are cooled to.
Observe cloth specimen coloured light simultaneously use AATCC16-2004, and using embodiment 3 method measure they light fastness,
Compatibility the results are shown in Table 16.
Table 16
| Embodiment | Light fastness | Compatibility |
| 20 | 2~3 | Ⅱ |
| 21 | 2~3 | Ⅱ |
| 22 | 2~3 | Ⅰ |
| 23 | 3 | Ⅱ |
| 24 | 3 | Ⅱ |
| 25 | 3 | Ⅰ |
| 26 | 2~3 | Ⅰ |
| 27 | 3 | Ⅰ |
| 28 | 2~3 | Ⅱ |
| 29 | 2~3 | Ⅱ |
| 30 | 2~3 | Ⅱ |
| 31 | 2~3 | Ⅱ |
| 32 | 3 | Ⅱ |
| 33 | 2~3 | Ⅱ |
| 34 | 3 | Ⅱ |
| 35 | 3 | Ⅱ |
Claims (21)
1. a kind of disperse dye composition, characterized by comprising:
The component A as shown in formula (1):
One or more component B as shown in formula (2):
In formula (2), X1For bromine or chlorine；R1、R2Respectively stand alone as C1~C4Alkyl；
The component C as shown in formula (3-1) and (3-2):
Optional one or more component D as shown in formula (4) or formula (4-5):
In formula (4), X2、X3Respectively stand alone as hydrogen, chlorine or bromine, R3、R4Respectively stand alone as C2~C4Alkyl or C1~C4In alkyl
The group that is replaced by cyano, phenyl, acetoxyl group or benzoyloxy of a hydrogen；Wherein component D is not C.I. disperse orange 76；
Optional one or more component E as shown in formula (5):
In formula (5), X4、X5Respectively stand alone as hydrogen, chlorine or nitro, R5For C1~C4Alkyl；
Optional one or more component F as shown in formula (6):
In formula (6), X6、X7Respectively stand alone as cyano, bromine, chlorine or nitro, R6For hydrogen or C1~C4Alkoxy, R9For C1~C4's
Alkyl amido or C1~C4Alkyl, R7、R8Respectively stand alone as C1~C4Alkyl；
The optional component G as shown in formula (7):
Wherein, the total weight based on the composition, the weight percent of the component A are 2~38%, the weight of the component B
Measuring percentage is 7~40%, and the weight percent of the component C is 20~58%, and the weight percent of optional component D is 0
The weight percent of~70%, optional component E are 0~10%, and the weight percent of optional component F is 0~47%, and is appointed
The weight percent of the component G of choosing is 0~47%.
2. disperse dye composition according to claim 1, which is characterized in that the component B is in following compound
It is one or two kinds of:
3. disperse dye composition according to claim 1 or 2, which is characterized in that the component D is in following compound
One or more:
4. disperse dye composition according to claim 1 or 2, which is characterized in that the component E is in following compound
One or more:
5. disperse dye composition according to claim 1 or 2, which is characterized in that the component F is in following compound
One or more:
6. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
The weight percent of component A is 3~38%,
The weight percent of component B is 12~39%,
The weight percent of component C is 38~58%.
7. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
The weight percent of component A is 2~38%,
The weight percent of component B is 7~37%,
The weight percent of component C is 30~55%,
The weight percent of component D is 3~6%.
8. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
The weight percent of component A is 3~6%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component D is 2~50%.
9. disperse dye composition according to claim 1 or 2, which is characterized in that the total weight based on the composition,
The weight percent of component A is 2~38%,
The weight percent of component B is 12~37%,
The weight percent of component C is 35~55%,
The weight percent of component E is 2~6%.
10. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount,
The weight percent of component A is 2~38%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component F is 1~10%.
11. disperse dye composition according to claim 1 or 2, which is characterized in that the gross weight based on the composition
Amount,
The weight percent of component A is 2~38%,
The weight percent of component B is 7~40%,
The weight percent of component C is 20~48%,
The weight percent of component G is 1~10%.
12. disperse dye composition according to claim 1 or 2, which is characterized in that in the component C, the formula (3-
1) weight percent of compound represented is 1~99%, the weight percent of formula (3-2) compound represented is 1~
99%, the poidometer based on the component C.
13. disperse dye composition according to claim 12, which is characterized in that in the component C, the formula (3-1)
The weight percent of compound represented is 70~90%, the weight percent of formula (3-2) compound represented is 10~
30%, the poidometer based on the component C.
14. a kind of disperse dyes, which is characterized in that include disperse dyes group described according to claim 1~any one of 13
Close object and auxiliary material.
15. disperse dyes according to claim 14, which is characterized in that the auxiliary material includes auxiliary agent and water.
16. disperse dyes according to claim 15, which is characterized in that the auxiliary agent include it is below it is one or two kinds of with
On combination: naphthalene sulfonic formaldehyde condensation compound, lignosulfonates, sodium sulphate, surfactant, fungicide or other dyestuffs
Dispersing agent.
17. disperse dyes according to claim 15 or 16, which is characterized in that the auxiliary agent and disperse dye composition
Weight ratio is 0.3~4:1.
18. disperse dyes according to any one of claims 14-16, which is characterized in that the disperse dyes are sanded
Machine or grinder grinding after be liquid, solid content be 20~50% or the disperse dyes be spray-dried after be powdery or
Granular, solid content is 87~96%.
19. a kind of method for preparing disperse dyes described in any one of 4~18 according to claim 1, which is characterized in that including
Following steps:
After each dye component is mixed, particlized processing is carried out with sand mill or grinder in the presence of auxiliary material；Or
Each dye component is subjected to particlized processing with sand mill or grinder in the presence of auxiliary material respectively, then is mixed.
20. a kind of disperse dyes described in any one of 4~18 according to claim 1 are for the dyeing of fabric and the use of stamp
On the way.
21. a kind of fabric, which is characterized in that by using disperse dyes described according to claim 1 any one of 4~18 into
Row dyeing and stamp are prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188860.6A CN106947288B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710188860.6A CN106947288B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
| CN201310752449.9A CN104371362B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310752449.9A Division CN104371362B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106947288A CN106947288A (en) | 2017-07-14 |
| CN106947288B true CN106947288B (en) | 2019-11-22 |
Family
ID=52550571
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310752449.9A Active CN104371362B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
| CN201710188860.6A Active CN106947288B (en) | 2013-12-30 | 2013-12-30 | A kind of disperse dye composition, disperse dyes and its preparation method and purposes |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310752449.9A Active CN104371362B (en) | 2013-12-30 | 2013-12-30 | Disperse dye composition and disperse dye, and preparation method and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN104371362B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112608622B (en) * | 2020-12-07 | 2023-05-23 | 浙江龙盛集团股份有限公司 | Blue-to-black disperse dye composition and dye product |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
-
2013
- 2013-12-30 CN CN201310752449.9A patent/CN104371362B/en active Active
- 2013-12-30 CN CN201710188860.6A patent/CN106947288B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3793305A (en) * | 1970-09-14 | 1974-02-19 | Du Pont | One-step process of preparing azo dyes by simultaneous diazotization |
| CN1696204A (en) * | 2005-06-07 | 2005-11-16 | 浙江闰土股份有限公司 | Composite environmental protection type grey disperse dyes |
| CN101280122A (en) * | 2008-05-16 | 2008-10-08 | 浙江闰土股份有限公司 | Black-blue series environment-friendly disperse dyes |
| CN101760045A (en) * | 2009-12-30 | 2010-06-30 | 浙江闰土股份有限公司 | Medium-low temperature environmental-friendly disperse dye composition |
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104371362A (en) | 2015-02-25 |
| CN104371362B (en) | 2017-04-12 |
| CN106947288A (en) | 2017-07-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104371358B (en) | Disperse dye composition and disperse dye and preparation method and use thereof | |
| CN104448928B (en) | Disperse blue dye composition, disperse dye, preparation method and application | |
| CN102002259A (en) | High-fastness black and blue disperse dye composite | |
| CN106479221B (en) | It is a kind of dark blue to black disperse dye mixture | |
| CN105602284B (en) | A kind of blue disperse dye composition, blue disperse dye and its production and use | |
| CN104371361B (en) | Yellow disperse dye composition and disperse dye and preparation method and use thereof | |
| CN104650621B (en) | Disperse dye composition, disperse dyes and its production and use | |
| WO2015101290A1 (en) | Disperse dye composition, disperse dye and preparation method and use thereof | |
| CN106928749B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN105670341B (en) | A kind of blue disperse dye composition, blue disperse dye and its preparation method and application | |
| CN105623308B (en) | A kind of disperse dye composition, disperse dyes and its production and use | |
| CN106928750B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN106084886A (en) | A kind of blue disperse dye mixture and disperse dyes | |
| CN106947286B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN105086513A (en) | Environment-friendly type disperse red dye mixture and applciation | |
| CN105001672B (en) | A kind of orange disperse dye composition, disperse dyes and its production and use | |
| CN106947288B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN104371363B (en) | A kind of Yellow disperse dye, its preparation method and purposes | |
| CN106046855B (en) | A kind of disperse dye composition | |
| CN106947287B (en) | A kind of disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN104371364B (en) | Disperse dye composition and disperse dye, and preparation method and use thereof | |
| CN104371359B (en) | Disperse dye composition and disperse dye and preparation method and use thereof | |
| CN109735136B (en) | Yellow disperse dye composition, disperse dye, and preparation method and application thereof | |
| CN104497628B (en) | Disperse dye composition, disperse dyes and its preparation method and purposes | |
| CN104327548B (en) | A kind of disperse yellow is to orange compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |