CN106833021A - A kind of fastness to perspiration disperse dyes high - Google Patents
A kind of fastness to perspiration disperse dyes high Download PDFInfo
- Publication number
- CN106833021A CN106833021A CN201710085786.5A CN201710085786A CN106833021A CN 106833021 A CN106833021 A CN 106833021A CN 201710085786 A CN201710085786 A CN 201710085786A CN 106833021 A CN106833021 A CN 106833021A
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- component
- mass fraction
- structural formula
- auxiliary agent
- dye composition
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- 0 CCN(*)c(cc1)cc(C)c1N=Nc(c(*)cc(S(C)(=O)=O)c1)c1Cl Chemical compound CCN(*)c(cc1)cc(C)c1N=Nc(c(*)cc(S(C)(=O)=O)c1)c1Cl 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0079—Azoic dyestuff preparations
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of fastness to perspiration disperse dye composition high, the component C shown in component A of the disperse dye composition shown in structural formula (I), the component B shown in structural formula (II), structural formula (III), the component D shown in structural formula (IV), the component E shown in structural formula (V), the component F described in structural formula (VI), the component G shown in structural formula (VII), the component H shown in structural formula (VIII) and auxiliary agent are constituted；As mass fraction, the mass fraction of the component A is 2~10%, the mass fraction of the component B is 3~10%, the mass fraction of the component C is 5~10%, and the mass fraction of the component D is 8~25%, and the mass fraction of the component E is 4~15%, the mass fraction of the component F is 2~10%, the mass fraction of the component G is 3~18%, and the mass fraction of the component H is 3~9%, and remaining is auxiliary agent.The sample cloth bright in color light of present invention dyeing, with excellent fastness to washing, fastness to rubbing, fastness to perspiration, light fastness and dye uptake.
Description
Technical field
The present invention relates to a kind of technical field of dye, and in particular to a kind of fastness to perspiration disperse dyes high.
Background technology
Into after 21 century, the competition in world textile market is more and more fierce, and the economy in Southeast Asia has turned into low cost, height
The synonym of growth, and the textile industry business in Europe, U.S. etc. also accelerates to be shifted to Asia.Swash to adapt to piece market
The situation of strong competition, the production cost for making textile is constantly reduced, product quality is improved constantly, carrying capacity of environment constantly mitigates,
As the common target of textile enterprise.
With the development of synthetic fibers, polyamide fibre, terylene occur in succession, especially terylene, due to high, the fiber with permutation degree
Space is few, the characteristic such as hydrophobicity is strong, to make swelling of fiber in the case where having carrier or high temperature, thermosol, dyestuff could enter fiber and on
Dye.Disperse dyes are the water-soluble relatively low nonionic dyes of a class, and solubility is very low in water, and particle is very thin, in dye liquor
In dispersion, the dyeing of acetate fiber, referred to as cellulose acetate dye, its dyeing for being mainly used in terylene to be used for earliest.
With the fast-developing and raising of the people to textile demand of polyester Fresh fats in recent years, correspondingly, to dyestuff sheet
Dyeability that body has, environmental-protecting performance it is also proposed requirement higher, it is desirable to which dyestuff has lifting force high and every dyeing jail
Degree.But most study is the good disperse dyes of alkali resistance at this stage, but these dyestuffs are difficult to be provided simultaneously with excellent dye
Color performance and fastness ability.
The content of the invention
The invention provides a kind of fastness to perspiration disperse dye composition high, the disperse dye composition has preferable
Dyefastness.
The technical scheme is that：A kind of disperse dye composition, component A, structural formula as shown in structural formula (I)
(II) the component C shown in component B, structural formula (III) shown in, the component D shown in structural formula (IV), shown in structural formula (V)
The component G shown in component F, structural formula (VII), the component H shown in structural formula (VIII) described in component E, structural formula (VI) and help
Agent is constituted：
As mass fraction, the mass fraction of the component A is 2~10%, the mass fraction of the component B for 3~
The mass fraction of 10%, the component C is 5~10%, and the mass fraction of the component D is 8~25%, the matter of the component E
Amount fraction is 4~15%, and the mass fraction of the component F is 2~10%, and the mass fraction of the component G is 3~18%, institute
It is 3~9% to state the mass fraction of component H, and remaining is auxiliary agent.
Each component in the present invention can use existing commercial goods, also can be according to side well-known to those skilled in the art
Method synthesizes.
The present invention is by rational allocation so that every dyefastness and dye uptake of disperse dye composition are higher, table
There is certain synergy between bright each component.
Preferably, as mass fraction, the mass fraction of the component A is 4~10%, the quality point of the component B
Number is 4~10%, and the mass fraction of the component C is 5~10%, and the mass fraction of the component D is 12~25%, described group
The mass fraction of point E is 6~15%, and the mass fraction of the component F is 4~10%, the mass fraction of the component G for 3~
The mass fraction of 15%, the component H is 4~9%, and remaining is auxiliary agent.
Preferably, as mass fraction, the mass fraction of the component A is 6~10%, the quality point of the component B
Number is 6~10%, and the mass fraction of the component C is 5~8%, and the mass fraction of the component D is 12~20%, described group
The mass fraction of point E is 8~15%, and the mass fraction of the component F is 6~10%, the mass fraction of the component G for 5~
The mass fraction of 15%, the component H is 5~9%, and remaining is auxiliary agent.
Preferably, as mass fraction, the mass fraction of the component A is 6~10%, the quality point of the component B
Number is 8~10%, and the mass fraction of the component C is 6~8%, and the mass fraction of the component D is 14~20%, described group
The mass fraction of point E is 8~13%, and the mass fraction of the component F is 8~10%, the mass fraction of the component G for 6~
The mass fraction of 15%, the component H is 5~9%, and remaining is auxiliary agent.
Preferably, as mass fraction, the mass fraction of the component A is 6~10%, the quality point of the component B
Number is 8~10%, and the mass fraction of the component C is 6~8%, and the mass fraction of the component D is 16~20%, described group
The mass fraction of point E is 10~13%, and the mass fraction of the component F is 8~10%, the mass fraction of the component G for 6~
The mass fraction of 12%, the component H is 6~9%, and remaining is auxiliary agent.
Preferably, as mass fraction, the mass fraction of the component A is 7%, and the mass fraction of the component B is
The mass fraction of 8%, the component C is 8%, and the mass fraction of the component D is 18%, and the mass fraction of the component E is
The mass fraction of 12%, the component F is 9%, and the mass fraction of the component G is 10%, and the mass fraction of the component H is
8%, remaining is auxiliary agent.
Preferably, the component H as shown in formula (VIII -1) and formula (VIII -2) compound with mass ratio be 1:3 mixing and
Into：
Auxiliary agent in the present invention can select auxiliary agent conventional in the art (including dispersant, wetting agent, etc.), used as excellent
Choosing, the auxiliary agent be naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates and benzyl sulfonate and formaldehyde condensation product in one kind or
It is two or more.
Preferably, the auxiliary agent is the mixture of lignosulfonates and benzyl sulfonate and formaldehyde condensation product, the wood
Mahogany sulfonate is 1~3 with the mass ratio of benzyl sulfonate and formaldehyde condensation product:2~5.
Preferably, the lignosulfonates are 1 with the mass ratio of benzyl sulfonate and formaldehyde condensation product:1.
Preferably, the mass fraction of the auxiliary agent is no more than 55%.
Disperse dye composition of the invention can be obtained by preparation method conventional in the industry, such as by component A
After~H is by default proportioning mixing, with reducing mechanisms such as sand mill or grinders in the presence of auxiliary agent, water or other wetting agents
Corpusculed is carried out, that is, obtains the disperse dye composition；Can also be first by component A~H respectively in auxiliary agent, water or other profits
Corpusculed is carried out with reducing mechanisms such as sand mill or grinders in the presence of humectant, is then mixed according to default proportioning
Close, that is, obtain the disperse dye composition.
Compared with prior art, beneficial effects of the present invention are：
Instant component C, E, F and H are a kind of disperse dyes, although component C and H have certain hyperchromic effect, E and
F has certain hypsochromic effect, but the present invention by rational allocation so that every dyefastness of disperse dye composition and upper
Color rate is higher, shows there is certain synergy between each component.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment
Disperse dye composition of the invention, the component B shown in component A, structural formula (II) as shown in structural formula (I),
The component D shown in component C, structural formula (IV) shown in structural formula (III), the component E shown in structural formula (V), structural formula (VI)
Component G, the component H shown in structural formula (VIII) and auxiliary agent composition shown in described component F, structural formula (VII)：
The preparation method of above-mentioned disperse dye composition is：After component A~H is pressed into the default proportioning mixing of table 1, in auxiliary agent
In the presence of carry out corpusculed with reducing mechanisms such as sand mill or grinders, that is, obtain the disperse dye composition.
Wherein, component H contained (VIII -1) and compound shown in formula (VIII -2)：
Table 1 is the quality proportioning of each component in the embodiment of the present invention 1~5 and comparative example 1~2
The composition of component C and component F in the 1~embodiment of embodiment 5 of table 2
Performance indications are detected
Disperse dye composition obtained in respectively taking 1.0g embodiments 1~5, is scattered in 500mL water, obtains dispersion liquid, then
Draw 20mL dispersion liquids to mix with 60mL water, obtain dye liquor, it is 5 to adjust dye bath pH with acetic acid, 4g is put into when being warming up to 70 DEG C and is gathered
Ester fiber is dyeed, and with 30min in dye bath temperature is warming up to 130 DEG C from 70 DEG C, be incubated at 130 DEG C cold after 30min
But to 90 DEG C, sampling.Observation sample cloth coloured light, and GB GB/T3921-1997, GB/T3920-1997, GB/ is respectively adopted
The washing fastness of T3922-1997, GB/T8427-1998 test specimens cloth, fastness to rubbing, fastness to perspiration and sun-resistant
Fastness, dyestuff dye uptake is determined using GB/T9337-2009 methods, and test result is shown in Table 3.
Table 3
From the point of view of the comparison data of table 1, the fastness to perspiration of embodiment 1~5, sunlight fastness and dye uptake relative to
Comparative example 1~2 is even more and increases.This result shows in disperse dye composition prepared by embodiment 1~5 that each component is simultaneously
It is non-individually to play a role, but there is synergy.From table 3, especially when component H is by formula (VIII -1) and formula (VIII -2)
Shown compound is with mass ratio 1：During 3 composition, the dye composite for preparing, with good dyeability.
Claims (8)
1. a kind of fastness to perspiration disperse dye composition high, it is characterised in that component A, structure as shown in structural formula (I)
Shown in the component C shown in component B, structural formula (III) shown in formula (II), the component D shown in structural formula (IV), structural formula (V)
Component E, the component F described in structural formula (VI), the component G shown in structural formula (VII), the component H shown in structural formula (VIII) and
Auxiliary agent is constituted：
As mass fraction, the mass fraction of the component A is 2~10%, and the mass fraction of the component B is 3~10%, institute
It is 5~10% to state the mass fraction of component C, and the mass fraction of the component D is 8~25%, and the mass fraction of the component E is
The mass fraction of 4~15%, the component F is 2~10%, and the mass fraction of the component G is 3~18%, the component H's
Mass fraction is 3~9%, and remaining is auxiliary agent.
2. disperse dye composition as claimed in claim 1, it is characterised in that as mass fraction, the quality of the component A
Fraction is 4~10%, and the mass fraction of the component B is 4~10%, and the mass fraction of the component C is 5~10%, described
The mass fraction of component D is 12~25%, and the mass fraction of the component E is 6~15%, and the mass fraction of the component F is 4
The mass fraction of~10%, the component G is 3~15%, and the mass fraction of the component H is 4~9%, and remaining is auxiliary agent.
3. disperse dye composition as claimed in claim 1, it is characterised in that as mass fraction, the quality of the component A
Fraction is 6~10%, and the mass fraction of the component B is 6~10%, and the mass fraction of the component C is 5~8%, described group
The mass fraction of point D is 12~20%, and the mass fraction of the component E is 8~15%, the mass fraction of the component F for 6~
The mass fraction of 10%, the component G is 5~15%, and the mass fraction of the component H is 5~9%, and remaining is auxiliary agent.
4. disperse dye composition as claimed in claim 1, it is characterised in that the component H by formula (VIII -1) and formula (VIII -
2) compound shown in mass ratio be 1:3 mix：
5. disperse dye composition as claimed in claim 1, it is characterised in that as mass fraction, the quality of the component A
Fraction is 7%, and the mass fraction of the component B is 8%, and the mass fraction of the component C is 8%, the quality point of the component D
Number is 18%, and the mass fraction of the component E is 12%, and the mass fraction of the component F is 9%, the quality point of the component G
Number is 10%, and the mass fraction of the component H is 8%, and remaining is auxiliary agent.
6. disperse dye composition as claimed in claim 1, it is characterised in that the auxiliary agent be naphthalene sulfonic acid-formaldehyde condensation product,
One or more in lignosulfonates and benzyl sulfonate and formaldehyde condensation product.
7. disperse dye composition as claimed in claim 6, it is characterised in that the auxiliary agent is lignosulfonates and benzyl
The mixture of sulfonate and formaldehyde condensation product, the mass ratio of the lignosulfonates and benzyl sulfonate and formaldehyde condensation product for 1~
3:2~5.
8. disperse dye composition as claimed in claim 7, it is characterised in that the lignosulfonates and benzyl sulfonate
The mass ratio of formaldehyde condensation products is 1:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710085786.5A CN106833021A (en) | 2017-02-17 | 2017-02-17 | A kind of fastness to perspiration disperse dyes high |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710085786.5A CN106833021A (en) | 2017-02-17 | 2017-02-17 | A kind of fastness to perspiration disperse dyes high |
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| CN106833021A true CN106833021A (en) | 2017-06-13 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057403A (en) * | 2017-05-10 | 2017-08-18 | 浙江山峪科技股份有限公司 | A kind of golden yellow disperse dye composition, disperse dyes product and its application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN105970671A (en) * | 2016-07-22 | 2016-09-28 | 沈阳化工研究院有限公司 | Dyeing and coating integrated dye dyeing and printing paste-shaped compound and application thereof |
| CN106221380A (en) * | 2016-08-19 | 2016-12-14 | 常州江昇化工有限公司 | A kind of environmental-protection water-based pigment mill base and preparation method thereof |
-
2017
- 2017-02-17 CN CN201710085786.5A patent/CN106833021A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768376A (en) * | 2009-12-30 | 2010-07-07 | 浙江闰土股份有限公司 | Environment-friendly disperse dye composition |
| CN105970671A (en) * | 2016-07-22 | 2016-09-28 | 沈阳化工研究院有限公司 | Dyeing and coating integrated dye dyeing and printing paste-shaped compound and application thereof |
| CN106221380A (en) * | 2016-08-19 | 2016-12-14 | 常州江昇化工有限公司 | A kind of environmental-protection water-based pigment mill base and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 环境保护部科技标准司编: "《环境标志产品技术要求（上册）》", 31 August 2014, 中国环境出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057403A (en) * | 2017-05-10 | 2017-08-18 | 浙江山峪科技股份有限公司 | A kind of golden yellow disperse dye composition, disperse dyes product and its application |
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Application publication date: 20170613 |