CN101759858B - 一种高沸点盐型全氟磺酸树脂溶液的制备方法 - Google Patents
一种高沸点盐型全氟磺酸树脂溶液的制备方法 Download PDFInfo
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- CN101759858B CN101759858B CN2008101599791A CN200810159979A CN101759858B CN 101759858 B CN101759858 B CN 101759858B CN 2008101599791 A CN2008101599791 A CN 2008101599791A CN 200810159979 A CN200810159979 A CN 200810159979A CN 101759858 B CN101759858 B CN 101759858B
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- perfluor sulfoacid
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- 239000011347 resin Substances 0.000 title claims abstract description 111
- 229920005989 resin Polymers 0.000 title claims abstract description 111
- 238000009835 boiling Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 150000003839 salts Chemical class 0.000 title claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000011261 inert gas Substances 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000002791 soaking Methods 0.000 claims description 19
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 12
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 12
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 claims description 12
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 8
- -1 sulphonyl functional group Chemical group 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 229910000856 hastalloy Inorganic materials 0.000 claims description 3
- 229910052724 xenon Inorganic materials 0.000 claims description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 abstract description 7
- 239000012528 membrane Substances 0.000 abstract description 6
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 62
- 239000011734 sodium Substances 0.000 description 21
- 238000003756 stirring Methods 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 5
- 229920000557 Nafion® Polymers 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2008101599791A CN101759858B (zh) | 2008-11-14 | 2008-11-14 | 一种高沸点盐型全氟磺酸树脂溶液的制备方法 |
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CN2008101599791A CN101759858B (zh) | 2008-11-14 | 2008-11-14 | 一种高沸点盐型全氟磺酸树脂溶液的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101759858A CN101759858A (zh) | 2010-06-30 |
CN101759858B true CN101759858B (zh) | 2012-07-18 |
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CN2008101599791A Active CN101759858B (zh) | 2008-11-14 | 2008-11-14 | 一种高沸点盐型全氟磺酸树脂溶液的制备方法 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104157864B (zh) * | 2014-07-14 | 2016-07-06 | 浙江大学 | 锂离子型全氟磺酸树脂包覆铝锂合金材料的制备方法 |
CN106925347B (zh) * | 2015-12-29 | 2019-10-29 | 山东东岳未来氢能材料有限公司 | 多孔全氟磺酸树脂催化剂的制备方法 |
CN113856601A (zh) * | 2021-11-04 | 2021-12-31 | 山西国润储能科技有限公司 | 一种高浓度全氟磺酸溶液的制备方法 |
CN114204087B (zh) * | 2021-12-03 | 2023-05-12 | 武汉氢能与燃料电池产业技术研究院有限公司 | 一种低温燃料电池用高致密复合质子交换膜及其制备方法 |
CN114960207B (zh) * | 2022-06-21 | 2023-08-15 | 浙江巨化新材料研究院有限公司 | 一种全氟磺酸碳纤维复合材料及其制备方法和应用 |
CN115036447B (zh) * | 2022-07-15 | 2023-08-29 | 中国科学技术大学 | 一种锂/钠金属电池电极片保护涂层及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005001978A2 (en) * | 2003-05-30 | 2005-01-06 | E. I. Du Pont De Nemours And Company | Fuel cells and their components using catalysts having a high metal to support ratio |
CN1699450A (zh) * | 2005-05-13 | 2005-11-23 | 华东理工大学 | 由废弃全氟离子膜制备全氟磺酸树脂溶液的方法 |
CN1724126A (zh) * | 2005-06-14 | 2006-01-25 | 武汉理工大学 | 用碱金属离子型全氟磺酸树脂制备复合质子交换膜的方法 |
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- 2008-11-14 CN CN2008101599791A patent/CN101759858B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005001978A2 (en) * | 2003-05-30 | 2005-01-06 | E. I. Du Pont De Nemours And Company | Fuel cells and their components using catalysts having a high metal to support ratio |
CN1699450A (zh) * | 2005-05-13 | 2005-11-23 | 华东理工大学 | 由废弃全氟离子膜制备全氟磺酸树脂溶液的方法 |
CN1724126A (zh) * | 2005-06-14 | 2006-01-25 | 武汉理工大学 | 用碱金属离子型全氟磺酸树脂制备复合质子交换膜的方法 |
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CN101759858A (zh) | 2010-06-30 |
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Owner name: DONGGUE SHENZHOU NEW MATERIAL CO., LTD., SHANDONG Free format text: FORMER OWNER: YANG YUSHENG Effective date: 20101229 |
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C41 | Transfer of patent application or patent right or utility model | ||
C53 | Correction of patent for invention or patent application | ||
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Inventor after: Wang Xuejun Inventor after: Zhang Yongming Inventor before: Yang Yusheng |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: YANG YUSHENG TO: WANG XUEJUN ZHANG YONGMING Free format text: CORRECT: ADDRESS; FROM: 256401 301, UNIT 3, BUILDING 1, DONGYUE RESIDENTIAL QUATER, TANGSHAN TOWN, HUANTAI COUNTY, SHANDONG PROVINCE TO: 256401 TANGSHAN TOWN, HUANTAI COUNTY, SHANDONG PROVINCE |
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Effective date of registration: 20101229 Address after: 256401 Tangshan Town, Huantai County, Shandong Province Applicant after: Donggue Shenzhou New Material Co., Ltd., Shandong Address before: 3 No. 301, building 1, Dongyue District, Tangshan Town, Huantai County, Shandong province 256401 Applicant before: Yang Yusheng |
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Address after: 256401 Tangshan Town, Huantai County, Shandong Province Applicant after: Shandong Dongyue Shenzhou New Material Co., Ltd. Address before: 256401 Tangshan Town, Huantai County, Shandong Province Applicant before: Donggue Shenzhou New Material Co., Ltd., Shandong |
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Free format text: CORRECT: APPLICANT; FROM: DONGGUE SHENZHOU NEW MATERIAL CO., LTD., SHANDONG TO: SHANDONG HUAXIA SHENZHOU NEW MATERIAL CO., LTD. |
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Effective date of registration: 20201201 Address after: 256401 Zibo Huantai County, Shandong Province, Tangshan town Dongyue Fluorosilicic Industrial Park Patentee after: Shandong Dongyue future hydrogen energy materials Co., Ltd Address before: 256401 Tangshan Town, Huantai County, Shandong Province Patentee before: SHANDONG HUAXIA SHENZHOU NEW MATERIAL Co.,Ltd. |