CN101590002A - A kind of repairing anti-wrinkle composite cosmetic and preparation method thereof - Google Patents
A kind of repairing anti-wrinkle composite cosmetic and preparation method thereof Download PDFInfo
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- CN101590002A CN101590002A CNA2009100406673A CN200910040667A CN101590002A CN 101590002 A CN101590002 A CN 101590002A CN A2009100406673 A CNA2009100406673 A CN A2009100406673A CN 200910040667 A CN200910040667 A CN 200910040667A CN 101590002 A CN101590002 A CN 101590002A
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Abstract
The invention discloses a kind of repairing anti-wrinkle composite cosmetic, percentage composition comprises following component by weight: the crease-resistant component of A. maintenance; B. oil phase components; C. water component; D. triethanolamine; E. auxiliary agent component; A kind of method for preparing above-mentioned repairing anti-wrinkle composite cosmetic is warmed up to 65～95 ℃ comprising following steps: a. mutually with B, is incubated 75～85 ℃, and stirring and dissolving is complete; B. C is warmed up to 65～95 ℃ mutually, is incubated 75～85 ℃, stirring and dissolving is complete; C. earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 5～15min, insulated and stirred 5～15min, evacuation cooling; ℃ d.50～70 add the D phase time, the A phase, homogenizing 2-3min stirs; ℃ e.30～50 add the E phase time, stir, promptly get product of the present invention.The objective of the invention is in order to overcome weak point of the prior art, provide a kind of fast, the repairing anti-wrinkle composite cosmetic of efficient, green safety.
Description
Technical field
The present invention relates to a kind of repairing anti-wrinkle composite cosmetic, the invention still further relates to a kind of method for preparing this repairing anti-wrinkle composite cosmetic.
Background technology
The pale exquisiteness of teen-age skin, ruddy gloss, high resilience, with advancing age, skin begins naturally-aged, effects such as spirit, nutrition, endocrine, medicine and ultraviolet radiation in addition, can quicken the aging of skin, it is coarse to show as the complexion Rhizoma Curcumae Longae, elasticity attenuation, atrophoderma, wrinkle manifest and pigmentation etc.The reason of skin aging is a lot, but its main cause is infringement with radical pair skin substantial connection is arranged.Aforementioned skin aging factor can produce a large amount of free radicals in vivo, pass through peroxidation, cause cell tissue function and cellular morphology structural damage at last, show as degeneration of skin, atrophy, coarse unglazed, elasticity attenuation, the feature that the wrinkle skin aging occurs and mechanism: 1, the essence of skin aging is skin cell proliferation, metabolic capacity decline; 2, the extracellular matrix of skin histology mainly is connective tissues such as collagen, elastin laminin, mucopolysaccharide and structural elasticity albumen, also comprises lipoids and some nature moisturizing factor, and they are keeping the barrier function and the hydration of skin.Along with the aging of skin, these extracellular matrixs also change on content and qualitatively; 3, UV-induced photoaging is proved to be the main factor of skin aging.Ultraviolet can cause that the content of epidermal area vitamin A descends, and during ultraviolet radiation, histiocytic infringement of radical pair and the Proteolytic enzyme problems such as degraded to connective tissue is arranged in addition; The reactive oxygen free radical that ion and low-energy radiation produce has detrimental effect to skin lipid protein, living an ancient unit of weight film; 4, environmental pollution causes the skin allergy inflammatory reaction, can quicken the process of skin aging.
Existing have reparation, nursing, crease-resistant cosmetics, and its general effect is all not obvious, and much all can bring symptom such as allergy to user, brings many inconvenience to user.
Summary of the invention
The objective of the invention is in order to overcome weak point of the prior art, provide a kind of fast, the repairing anti-wrinkle composite cosmetic of efficient, green safety;
Another object of the present invention is for a kind of preparation method of this repairing anti-wrinkle composite cosmetic is provided.
In order to achieve the above object, the present invention adopts following scheme:
A kind of repairing anti-wrinkle composite cosmetic, percentage composition comprises following component by weight:
A, the crease-resistant component 0.41～9.2% of maintenance
B, oil phase components 12.5～29.5%
C, water component 59.8～86.69%
D, triethanolamine 0.1～0.5%
E, auxiliary agent component 0.3～1.0%;
Aforesaid a kind of repairing anti-wrinkle composite cosmetic, the crease-resistant component of wherein said maintenance is made up of following components in weight percentage content:
Flavonoids of Glycyrrhiza 0.1～3.0%
Hyaluronate sodium 0.01～0.2%
Beta glucan 0.1～3.0%
Ceramide 1 0.1～1.0%
Tocopherol acetas 0.1～2.0%
Aforesaid a kind of repairing anti-wrinkle composite cosmetic, wherein said oil phase components is made up of following components in weight percentage content:
PEG-100 stearate 1.0～3.0%
Cetearyl alcohol 1.5～3.5%
Polydimethylsiloxane 3.0～5.0%
Caprylic/capric triglyceride 4.0～8.0%
Hydrogenated polydecene 3.0～10.0%;
Aforesaid a kind of repairing anti-wrinkle composite cosmetic, wherein said water component is made up of following components in weight percentage content:
EDTA disodium 0.01～0.2%
Allantoin 0.1～0.5%
Glycerol 1.0～10.0%
1,3 butylene glycol 1.0～10.0%
Carbomer 0.1～0.5%
Water 38.6～84.48%.
Aforesaid a kind of repairing anti-wrinkle composite cosmetic, wherein said auxiliary agent component are one or both the mixture in essence, the antiseptic.
A kind of method for preparing above-mentioned repairing anti-wrinkle composite cosmetic, comprising following steps:
A, B is warmed up to 65～95 ℃ mutually, is incubated 75～85 ℃, stirring and dissolving is complete;
B, C is warmed up to 65～95 ℃ mutually, is incubated 75～85 ℃, stirring and dissolving is complete;
C, earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 5～15min, insulated and stirred 5～15min, evacuation cooling;
D, add the D phase 50～70 ℃ the time, the A phase, homogenizing 2-3min stirs;
E, add the E phase 30～50 ℃ the time, stir, promptly get product of the present invention.
In sum, beneficial effect of the present invention:
Product of the present invention can not produce anaphylaxis to user, and is safe in utilization; Product of the present invention has remarkable result reducing wrinkle formation, delaying decrepitude of skin and then reach on the effect of looks improving and the skin nourishing.
The specific embodiment
Below in conjunction with the specific embodiment the present invention is described further:
Embodiment 1
Repairing anti-wrinkle composite cosmetic of the present invention, percentage composition comprises following component by weight:
A, the crease-resistant component 0.41% of maintenance
B, oil phase components 29.5%
C, water component 68.59%
D, triethanolamine 0.5%
E, auxiliary agent component 1.0%;
The crease-resistant component of wherein said maintenance is made up of following components in weight percentage content:
Flavonoids of Glycyrrhiza 0.1%
Hyaluronate sodium 0.01%
Beta glucan 0.1%
Ceramide 1 0.1%
Tocopherol acetas 0.1%;
Wherein said oil phase components is made up of following components in weight percentage content:
PEG-100 stearate 3.0%
Cetearyl alcohol 3.5%
Polydimethylsiloxane 5.0%
Caprylic/capric triglyceride 8.0%
Hydrogenated polydecene 10.0%;
Wherein said water component is made up of following components in weight percentage content:
EDTA disodium 0.2%
Allantoin 0.5%
Glycerol 10.0%
1,3 butylene glycol 10.0%
Carbomer 0.5%
Water 47.39%;
Wherein said auxiliary agent component is 1.0% essence, the mixture in the antiseptic.
The described repairing anti-wrinkle composite cosmetic of present embodiment is to prepare by following steps:
A, B is warmed up to 65 ℃ mutually, is incubated 75 ℃, stirring and dissolving is complete;
B, C is warmed up to 65 ℃ mutually, is incubated 75 ℃, stirring and dissolving is complete;
C, earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 5min, insulated and stirred 5min, evacuation cooling;
D, add the D phase 50 ℃ the time, the A phase, homogenizing 2-3min stirs;
E, add the E phase 30 ℃ the time, stir, promptly get product of the present invention.
Embodiment 2
Repairing anti-wrinkle composite cosmetic of the present invention, percentage composition comprises following component by weight:
A, the crease-resistant component 9.2% of maintenance
B, oil phase components 12.5%
C, water component 77.9%
D, triethanolamine 0.1%
E, auxiliary agent component 0.3%;
The crease-resistant component of wherein said maintenance is made up of following components in weight percentage content:
Flavonoids of Glycyrrhiza 3.0%
Hyaluronate sodium 0.2%
Beta glucan 3%
Ceramide 1 1.0%
Tocopherol acetas 2.0%;
Wherein said oil phase components is made up of following components in weight percentage content:
PEG-100 stearate 1.0%
Cetearyl alcohol 1.5%
Polydimethylsiloxane 3.0%
Caprylic/capric triglyceride 4.0%
Hydrogenated polydecene 3.0%;
Wherein said water component is made up of following components in weight percentage content:
EDTA disodium 0.01%
Allantoin 0.1%
Glycerol 1.0%
1,3 butylene glycol 1.0%
Carbomer 0.1%
Water 75.69%;
Wherein said auxiliary agent component is 0.3% antiseptic.
The described repairing anti-wrinkle composite cosmetic of present embodiment is to prepare by following steps:
A, B is warmed up to 95 ℃ mutually, is incubated 85 ℃, stirring and dissolving is complete;
B, C is warmed up to 95 ℃ mutually, is incubated 85 ℃, stirring and dissolving is complete;
C, earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 15min, insulated and stirred 15min, evacuation cooling;
D, add the D phase 70 ℃ the time, the A phase, homogenizing 2-3min stirs;
E, add the E phase 50 ℃ the time, stir, promptly get product of the present invention.
Embodiment 3
Repairing anti-wrinkle composite cosmetic of the present invention, percentage composition comprises following component by weight:
A, the crease-resistant component 6% of maintenance
B, oil phase components 25%
C, water component 68%
D, triethanolamine 0.3%
E, auxiliary agent component 0.7%;
The crease-resistant component of wherein said maintenance is made up of following components in weight percentage content:
Flavonoids of Glycyrrhiza 1.5%
Hyaluronate sodium 0.1%
Beta glucan 2%
Ceramide 1 0.9%
Tocopherol acetas 1.5%;
Wherein said oil phase components is made up of following components in weight percentage content:
PEG-100 stearate 1.5%
Cetearyl alcohol 2.5%
Polydimethylsiloxane 6.0%
Caprylic/capric triglyceride 6.0%
Hydrogenated polydecene 9.0%;
Wherein said water component is made up of following components in weight percentage content:
EDTA disodium 0.1%
Allantoin 0.3%
Glycerol 5.0%
1,3 butylene glycol 5.0%
Carbomer 0.2%
Water 57.4%;
Wherein said auxiliary agent component is 0.7% essence.
The described repairing anti-wrinkle composite cosmetic of present embodiment is to prepare by following steps:
A, B is warmed up to 85 ℃ mutually, is incubated 80 ℃, stirring and dissolving is complete;
B, C is warmed up to 85 ℃ mutually, is incubated 80 ℃, stirring and dissolving is complete;
C, earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 10min, insulated and stirred 10min, evacuation cooling;
D, add the D phase 60 ℃ the time, the A phase, homogenizing 2-3min stirs;
E, add the E phase 40 ℃ the time, stir, promptly get product of the present invention.
Repairing anti-wrinkle composite cosmetic to embodiment 1 to 3 is done some testing performance indexes, and its test is as follows
1. outward appearance: fine and smooth cream frost
2.pH value: 5.0-7.0
3. viscosity: 100000-150000mpa.s
4. heat-resistant stability investigation (48 ℃ * 24h): qualified
5. cold-resistant study on the stability (15 ℃ * 24h): qualified.
In order to prove the performance of product of the present invention, carried out following test:
One, skin irritation test:
Select 40 of 2.5～3kg healthy rabbits, every rabbit back left-right symmetric selects 20 to shave a mao 2.5cm
2, carry out with the own control test method(s), be coated with 0.5g product of the present invention or blank substrate, every day twice, the administration at random of left side or right side, the reacting phenomenon of skin behind observation and record 24h, the 72h at every turn.
The result shows: be coated with reaction such as the local excitations of not seeing skin rubefaction, dermexanthesis, water lump behind product 24h of the present invention, the 72h, illustrate that repairing anti-wrinkle composite cosmetic of the present invention is to be perfectly safe, do not have any untoward reaction.
Two, animal pharmacodynamics test
Wrinkle of skin is one of common sign of human senility.The main component of skin histology is a collagen protein, and in the collagen protein in what and the skin of distinctive hydroxyproline content some other amino acid whose content what are closely related with skin aging.
1 experiment material
1.1 reagent
The embodiment of the invention 1 to 3 described product; Olay nutrition essence cream is the commercial goods; Acetone: Changzhou Wanda chemical reagent work produces; The about 9cm of quantitative filter paper: Hangzhou Xinhua Paper Making Mill.
1.2 instrument
40 type stepless speed regulation electric blender: Jiangyin, Jiangsu scientific research apparatus factory produces; 202-2 type electrically heated drying cabinet: Shanghai City Shanghai County experimental apparatus factory produces; 835 type automatic amino acid analyzers: Japan produces.
1.3 animal:
Kunming mouse is provided by The Fourth Military Medical University's Experimental Animal Center.
2 methods and result
Get 50 of Kunming mouses, male and female half and half, body weight are 18-22g, are divided into 5 groups at random by sex and body weight, are respectively: blank group, 1 group of the embodiment of the invention, 2 groups of the embodiment of the invention, 3 groups of the embodiment of the invention, Olay nutrition essence cream group.Each test sample 2g with the water mixing batter, is evenly spread upon respectively and respectively organizes mouse back, application area 4cmx3cm, once a day, continuous 35 days.Smeared back 24 hours in last, the hair that each group mouse back is tried to distinguish shaves off (in order to avoid the interference of the protein in the hair) and the skin that will distinguish is cut, behind the tissues such as removing skin fat, distilled water flushing filter paper is wiped away dried, put in 37 ℃ of baking ovens and did behaviour 24 hours, taking-up shreds and with acetone defat 48 hours, breaks into homogenate with high speed homogenizer then, put again in 37 ℃ of baking ovens dry 24 hours, for the sample of measuring usefulness.Sample thief 40mg at 110 ℃ of following hydrochloric acid hydrolysiss, evaporates deacidification in 80 ℃ of water-baths, add the 0.02mol/L dissolving with hydrochloric acid again after, produce 835-50 type automatic amino acid analyzer with Japan and carry out several amino acids Determination on content such as hydroxyproline.
The results are shown in Table 1,2
The various cream of table 1 are to the influence of mouse skin hydroxyproline content
Annotate: the clothes group is compared * * P＜0.01, * * * P＜0.001 with blank.
The various cream of table 2 are sweet to mouse skin, the influence of paddy, proline content (g/100g)
Annotate: the clothes group is compared * P＜0.05, * * P＜0.01, * * * P＜0.001 with blank.
Table 1,2 experimental data show:
The described repairing anti-wrinkle composite cosmetic of embodiment of the invention 1-3 can make the content of hydroxyproline in the mouse skin, glycine, glutamic acid and proline significantly raise, use the mice of Olay nutrition essence cream, above-mentioned amino acid whose content only has trickle rising in its skin, compares no significant difference with the blank group.Above-mentioned experimental result shows: product of the present invention significantly is better than Olay nutrition essence cream reducing wrinkle formation, delaying decrepitude of skin and then reach on the effect of looks improving and the skin nourishing.
Three, product curative effect checking of the present invention:
The curative effect statistics of product of the present invention: trial volunteer 500 examples, male 170 examples, women 330 examples, age reckling 17 years old, the maximum 67 years old, 34.76 years old mean age.Dry skin 410 examples, neutral skin 60 example and oily skin 30 examples.Every routine experimenter uses repairing anti-wrinkle composite cosmetic of the present invention, and every day, sooner or later each rubbed wiping gently with being applied to face about 0.5g after clean, used one month (course of treatment) continuously.
Effect criterion:
Excellent: conscious comfortable, objective sign (wrinkle) disappearance;
Very: conscious general and objective sign (wrinkle) disappearance 〉=2/3;
Difference: do not see obvious change before and after using.
The result: in 500 examples, effect is judged the superior's 480 examples, accounts for 96%; Effect is judged good person's 20 examples, accounts for 4%, and effective percentage is 100% altogether.Whole experimenters do not have 1 example and untoward reaction occurs.
Claims (6)
1, a kind of repairing anti-wrinkle composite cosmetic is characterized in that percentage composition comprises following component by weight:
A, the crease-resistant component 0.41～9.2% of maintenance
B, oil phase components 12.5～29.5%
C, water component 59.8～86.69%
D, triethanolamine 0.1～0.5%
E, auxiliary agent component 0.3～1.0%.
2, a kind of repairing anti-wrinkle composite cosmetic according to claim 1 is characterized in that the crease-resistant component of described maintenance is made up of following components in weight percentage content:
Flavonoids of Glycyrrhiza 0.1～3.0%
Hyaluronate sodium 0.01～0.2%
Beta glucan 0.1～3.0%
Ceramide 10.1～1.0%
Tocopherol acetas 0.1～2.0%.
3, a kind of repairing anti-wrinkle composite cosmetic according to claim 1 is characterized in that described oil phase components is made up of following components in weight percentage content:
PEG-100 stearate 1.0～3.0%
Cetearyl alcohol 1.5～3.5%
Polydimethylsiloxane 3.0～5.0%
Caprylic/capric triglyceride 4.0～8.0%
Hydrogenated polydecene 3.0～10.0%.
4, a kind of repairing anti-wrinkle composite cosmetic according to claim 1 is characterized in that described water component is made up of following components in weight percentage content:
EDTA disodium 0.01～0.2%
Allantoin 0.1～0.5%
Glycerol 1.0～10.0%
1,3 butylene glycol 1.0～10.0%
Carbomer 0.1～0.5%
Water 38.6～84.48%.
5, a kind of repairing anti-wrinkle composite cosmetic according to claim 1 is characterized in that described auxiliary agent component is one or both the mixture in essence, the antiseptic.
6, a kind of method for preparing the described repairing anti-wrinkle composite cosmetic of claim 1 is characterized in that may further comprise the steps:
A, B is warmed up to 65～95 ℃ mutually, is incubated 75～85 ℃, stirring and dissolving is complete;
B, C is warmed up to 65～95 ℃ mutually, is incubated 75～85 ℃, stirring and dissolving is complete;
C, earlier with B mixed phase suction emulsifying pot, suction C phase slowly again, homogenizing 5～15min, insulated and stirred 5～15min, evacuation cooling;
D, add the D phase 50～70 ℃ the time, the A phase, homogenizing 2-3min stirs;
E, add the E phase 30～50 ℃ the time, stir, promptly get product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100406673A CN101590002B (en) | 2009-06-23 | 2009-06-23 | Repairing anti-wrinkle composite cosmetic and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100406673A CN101590002B (en) | 2009-06-23 | 2009-06-23 | Repairing anti-wrinkle composite cosmetic and preparation method thereof |
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| CN101590002A true CN101590002A (en) | 2009-12-02 |
| CN101590002B CN101590002B (en) | 2011-06-29 |
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| CN2009100406673A Active CN101590002B (en) | 2009-06-23 | 2009-06-23 | Repairing anti-wrinkle composite cosmetic and preparation method thereof |
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| CN102198064A (en) * | 2011-05-30 | 2011-09-28 | 天津天狮生物发展有限公司 | Hair treatment composition and preparation method thereof |
| CN102579285A (en) * | 2012-03-26 | 2012-07-18 | 陕西语泽化妆品有限公司 | Fibrinolytic protein peptide canthus wrinkle removing cream and preparation method thereof |
| CN102793656A (en) * | 2012-08-10 | 2012-11-28 | 彭再辉 | Firming anti-wrinkle essence cosmetic and preparation method |
| CN102793655A (en) * | 2012-08-10 | 2012-11-28 | 彭再辉 | Regenerating and repairing mask liquid by applying snail mucus extract and preparation method thereof |
| CN103550128A (en) * | 2013-10-10 | 2014-02-05 | 皖南医学院 | Skin beautifying and moistening gel and preparation method thereof |
| CN104138346A (en) * | 2014-08-07 | 2014-11-12 | 广州雅纯化妆品制造有限公司 | Anti-wrinkle cosmetic composition and preparation method thereof |
| CN104434747A (en) * | 2014-10-13 | 2015-03-25 | 金日制药（中国）有限公司 | Face cream with anti-aging function and preparation method of face cream |
| CN105476886A (en) * | 2015-11-30 | 2016-04-13 | 广州保税区雅兰国际化妆品有限公司 | Post-basking repairing composition and preparation method thereof |
| CN105581963A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Eye cream capable of resisting wrinkles and compacting skin |
| CN105581933A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Anti-aging face cream |
| CN105581921A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Skin moisturizer for repairing skin |
| CN106491447A (en) * | 2016-12-09 | 2017-03-15 | 广州聚澜健康产业研究院有限公司 | A kind of frost of the wrinkle resistance, whitening containing brassica campestris var purpurea polyphenol |
| CN109674679A (en) * | 2019-01-28 | 2019-04-26 | 贝德氏（上海）健康科技股份有限公司 | A kind of skin barrier maintenance biomembrane and preparation method thereof |
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| CN1813664A (en) * | 2005-11-24 | 2006-08-09 | 曾能 | Hydrogel beauty skin care paster and essence skin care liquid manufacturing process and product |
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| CN102198064A (en) * | 2011-05-30 | 2011-09-28 | 天津天狮生物发展有限公司 | Hair treatment composition and preparation method thereof |
| CN102198064B (en) * | 2011-05-30 | 2013-01-23 | 天津天狮生物发展有限公司 | Hair treatment composition and preparation method thereof |
| CN102579285A (en) * | 2012-03-26 | 2012-07-18 | 陕西语泽化妆品有限公司 | Fibrinolytic protein peptide canthus wrinkle removing cream and preparation method thereof |
| CN102793656A (en) * | 2012-08-10 | 2012-11-28 | 彭再辉 | Firming anti-wrinkle essence cosmetic and preparation method |
| CN102793655A (en) * | 2012-08-10 | 2012-11-28 | 彭再辉 | Regenerating and repairing mask liquid by applying snail mucus extract and preparation method thereof |
| CN102793656B (en) * | 2012-08-10 | 2013-12-25 | 彭再辉 | Firming anti-wrinkle essence cosmetic and preparation method |
| CN102793655B (en) * | 2012-08-10 | 2013-12-25 | 彭再辉 | Regenerating and repairing mask liquid by applying snail mucus extract and preparation method thereof |
| CN103550128A (en) * | 2013-10-10 | 2014-02-05 | 皖南医学院 | Skin beautifying and moistening gel and preparation method thereof |
| CN104138346A (en) * | 2014-08-07 | 2014-11-12 | 广州雅纯化妆品制造有限公司 | Anti-wrinkle cosmetic composition and preparation method thereof |
| CN104434747A (en) * | 2014-10-13 | 2015-03-25 | 金日制药（中国）有限公司 | Face cream with anti-aging function and preparation method of face cream |
| CN105581963A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Eye cream capable of resisting wrinkles and compacting skin |
| CN105581933A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Anti-aging face cream |
| CN105581921A (en) * | 2014-10-24 | 2016-05-18 | 胡伟杰 | Skin moisturizer for repairing skin |
| CN105476886A (en) * | 2015-11-30 | 2016-04-13 | 广州保税区雅兰国际化妆品有限公司 | Post-basking repairing composition and preparation method thereof |
| CN105476886B (en) * | 2015-11-30 | 2018-11-09 | 广州保税区雅兰国际化妆品有限公司 | A kind of after-sun composition and preparation method thereof |
| CN106491447A (en) * | 2016-12-09 | 2017-03-15 | 广州聚澜健康产业研究院有限公司 | A kind of frost of the wrinkle resistance, whitening containing brassica campestris var purpurea polyphenol |
| CN109674679A (en) * | 2019-01-28 | 2019-04-26 | 贝德氏（上海）健康科技股份有限公司 | A kind of skin barrier maintenance biomembrane and preparation method thereof |
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