CN101578396A - 多层涂层切削刀具 - Google Patents

多层涂层切削刀具 Download PDF

Info

Publication number
CN101578396A
CN101578396A CNA2007800484455A CN200780048445A CN101578396A CN 101578396 A CN101578396 A CN 101578396A CN A2007800484455 A CNA2007800484455 A CN A2007800484455A CN 200780048445 A CN200780048445 A CN 200780048445A CN 101578396 A CN101578396 A CN 101578396A
Authority
CN
China
Prior art keywords
multilayered structure
coating
cemented carbide
single layer
matrix
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007800484455A
Other languages
English (en)
Other versions
CN101578396B (zh
Inventor
玛丽亚·阿斯特兰德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandvik Intellectual Property AB
Original Assignee
Sandvik Intellectual Property AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandvik Intellectual Property AB filed Critical Sandvik Intellectual Property AB
Publication of CN101578396A publication Critical patent/CN101578396A/zh
Application granted granted Critical
Publication of CN101578396B publication Critical patent/CN101578396B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/148—Composition of the cutting inserts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
    • C04B41/5062—Borides, Nitrides or Silicides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/87—Ceramics
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0635—Carbides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0664—Carbonitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/044—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/40—Coatings including alternating layers following a pattern, a periodic or defined repetition
    • C23C28/42—Coatings including alternating layers following a pattern, a periodic or defined repetition characterized by the composition of the alternating layers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12389—All metal or with adjacent metals having variation in thickness
    • Y10T428/12403—Longitudinally smooth and symmetrical
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12632—Four or more distinct components with alternate recurrence of each type component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y10T428/24975—No layer or component greater than 5 mils thick
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)
  • Drilling Tools (AREA)

Abstract

本发明涉及一种涂层切削刀具，包括基体和涂层，涂层包括单个金属氮化物层X和Y交替的非周期性多层结构，其具有(Ti(1－a－b－c)AlaCrbSic)N的平均组分，其中0＜a＜0.5、优选为0.05＜a＜0.4、最优选为0.25＜a＜0.3，其中0＜b＜0.15、优选为0.02＜b＜0.10、最优选为0.04＜b＜0.08，其中0.01＜c＜0.17、优选为0.02＜c＜0.10、最优选为0.04＜c＜0.08，以及a+b+c＜1，并且其中单个层的平均厚度是0.1nm到100nm。所述涂层切削刀具较硬并且具有较高的抗月牙洼磨损性以及较高的抗后刀面磨损性。

Description

多层涂层切削刀具
技术领域
本发明涉及一种涂层切削刀具，其中涂层具有由(Ti，Al，Cr，Si)N组成的非周期性多层结构。
背景技术
最近刀具的发展已经朝向更尖的切削刃。这要求更薄的涂层，以便保持尖的切削刃，因为厚的涂层会导致对切削性能不利的增加的刃钝化(edge rounding)。由于较高的界面剪切力，因此较厚的涂层也更易于使刃线剥落，刃越尖，则这种情况越严重。如果较薄的涂层被沉积，则要求增加的硬度，即抗磨料磨损性来维持刀具的耐磨性。
实现薄的硬涂层的一种方法是使用多层纳米复合材料涂层。用于这种多层纳米复合材料涂层的常见涂层组分是(Ti，Al)N。
提高PVD涂层的如硬度和抗氧化性的特性的另一方法是通过添加诸如Cr、Si、B的元素。
对于含Al的氮化物PVD涂层，众所周知，高的铝含量(＞40at％)有利于获得高的抗后刀面磨损性和抗氧化性。但是，太高的铝含量也导致增加的月牙洼磨损，这是由于AlN从亚稳态硬立方相到更稳定的较软的六角相的相转变的缘故。
尖刃在许多切削操作，例如钻孔操作中是重要的。当钻孔时，不是仅在切削刃中发现有磨损。通常，在钻头的边缘也发现明显磨损。当打算修复钻头，即重新研磨和重新涂层时，严重的边缘磨损出现问题，因为整个磨损区都必须被去除。一般地，当重新涂层钻头时，对于每次重新涂层，总涂层厚度增加。边缘上增加的涂层厚度将增加边缘上的磨损，其中该边缘远离角落一定距离。同样，增加的涂层厚度将增加刃钝化。因此，更薄的、更耐磨的涂层是非常有利的。
切削刀具上的(Ti，Al，Cr，Si)N涂层在本领域是已知的。
EP 1 219 723 A公开了用于切削刀具的硬膜，该硬膜由Ti1-a-b-c-dAlaCrbSicBd(C1-eNe)组成，其中0.5＜a＜0.8、b＞0.06、0≤c＜0.1、0≤d＜0.1、0＜c+d＜0.1、和0.5＜e＜1。该硬膜可以是多层结构的形式。
US2006/0222893公开了包括重复的层堆的多层涂层，其包括至少一个50-150nm的(Al，Cr)N层和/或至少一个75-200nm的(Ti，Si)N层以及(Al，Cr，Ti，Si)N+(Ti，Si)N+(Al，Cr，Ti，Si)N+(Al，Cr)N构成的至少一个层堆。混合的(Al，Cr，Ti，Si)N层具有多层结构，且这通过同时操作所有靶材(target)来获得。这导致涂层具有非常薄的层，在几纳米范围内。(Al，Cr，Ti，Si)N层具有20±10nm的厚度。
发明内容
本发明的目的是提供具有较高的抗月牙洼磨损性和较高的抗后刀面磨损性的涂层切削刀具。
本发明的另一目的是提供具有增加的硬度的涂层。
本发明的另一目的是提供适合于尖刃的涂层。
本发明的另一目的是提供经历较少的边缘磨损的涂层钻头。
已经令人惊讶地发现，通过用具有根据本发明的组分的非周期性多层涂敷的涂层切削刀具，可满足这些目的。
附图说明
图1示出在钻200个孔之后根据现有技术的涂有(Ti，Al，Cr，Si)N涂层的钻头上的边缘磨损。
图2示出在钻200个孔之后根据本发明的涂有(Ti，Al，Cr，Si)N涂层的钻头上的边缘磨损。
具体实施方式
根据本发明，提供了一种涂层切削刀具，包括硬质合金、金属陶瓷、陶瓷、立方氮化硼或高速钢制成的硬合金基体和涂层，该涂层包括具有交替的X和Y单个金属氮化物层、组分为(Ti，Al，Cr，Si)N的非周期性多层结构。
非周期性应理解为，多层结构中特定单个层的厚度与紧接在它下面的单个层的厚度没有关系，也与上面的特定单个层没有关系。这种多层结构在至少10个连续单个层的序列中不具有任何重复的周期。
多层结构在此意味着包括至少5个单个层的结构。但是，其可包括高达几千个单个层。
单个层的平均厚度大于0.1nm，但小于100nm，优选为大于0.5nm，但小于50nm，最优选为大于1nm，但小于30nm。多层结构中任何十个连续层的总和小于300nm。
整个涂层的总厚度是0.5μm到20μm，优选为1μm到10μm，最优选为1μm到5μm。
粘着地结合到基体或预涂覆基体的所述多层结构包括交替的层X和Y的叠层状、非周期性多层结构，其中单个层X和Y是金属氮化物，优选为多晶金属氮化物，优选为具有立方结构，其中金属元素选自钛(Ti)、铝(Al)、硅(Si)、铬(Cr)或其混合物。单个层X和Y的化学组分彼此不同。
由于小的厚度的缘故，在没有相邻层的帮助下，多层结构中每个单个层的组分不易被测量。可测量的是在整个多层结构上的平均组分。但是，每个单个层的组分可从所用的靶材组分估算出来，但不能给出确切的组分。当已经沉积了较厚的层时，厚到足以被分析，已经显示，与靶材材料的组分相比，沉积层的组分可有百分之几的不同。由于该事实，以下根据本发明的多层结构的单个层的任何组分是从沉积过程中使用的靶材组分估计出来的。
多层结构中的平均化学组分在涂层横截面范围内使用EDS(能量色散谱仪)来测量。根据本发明的整个多层结构的平均组分是(Ti(1-a-b-c)AlaCrbSic)N，其中0＜a＜0.5、优选为0.05＜a＜0.4、最优选为0.25＜a＜0.3，其中0＜b＜0.15、优选为0.02＜b＜0.10、最优选为0.04＜b＜0.08，其中0.01＜c＜0.17、优选为0.02＜c＜0.10、最优选为0.04＜c＜0.08，且a+b+c＜1。
在本发明的一个实施例中，基体预涂覆有TiN、TiC、TiCN或(Ti，Al)N的薄的单层或多层涂层，且厚度在0.1-1μm之间，优选为0.05-0.5μm。
在本发明的一个实施例中，单个层X和Y的组分可以是(Al，Cr)N、(Ti，Si)N、(Al，Ti，Si)N、TiN、(Al，Si)N和(Al，Ti，Cr，Si)N中的任一个。
在本发明的一个实施例中，涂层包括交替的(Al，Cr)N和(Ti，Si)N的单个层的多层结构。
在本发明的一个实施例中，基体是硬质合金、金属陶瓷、陶瓷或立方氮化硼制成的切削刀具刀片。
在本发明的一个实施例中，基体是硬质合金或高速钢制成的钻头或端铣刀。
本发明还涉及一种制造涂层切削刀具的方法。该方法包括以下步骤：提供硬质合金、金属陶瓷、陶瓷或立方氮化硼或高速钢制成的硬合金基体，将涂层通过PVD技术沉积到所述基体上，该涂层包括非周期性多层结构。
可通过使用选自钛(Ti)、铝(Al)、硅(Si)、铬(Cr)或其合金的元素制成的靶材在N2或混合的N2+Ar气氛中沉积涂层。
靶材中的金属元素的组分可不同于整个多层结构中金属元素的平均组分，且仍形成本发明范围内的涂层。
在本发明的一个实施例中，靶材是(Al，Cr)、(Ti，Si)、(Al，Ti，Si)、Ti、(Al，Si)、(Al，Ti，Cr，Si)中的任一种。
在本发明的一个实施例中，靶材是(Al，Cr)和(Ti，Si)。
包括多层结构的涂层可通过不同的PVD技术并通过交替地形成单个层来沉积。单个层的厚度的非周期序列可通过从单个层靶材随机打开和闭合闸板(shutter)，或者通过随机打开和闭合所述靶材来制成。另一可想到的方法是通过在所述靶材前面随机旋转或移动待涂覆基体。这优选地通过将基体放置在为获得非周期性结构而布置的3维旋转基体台上来完成。3维旋转可相对于旋转速度和旋转方向顺时针或逆时针调节。
多层结构以这样一种方式沉积，即：使得单个层的平均厚度大于0.1nm，但小于100nm，优选为大于0.5nm，但小于50nm，最优选为大于1nm，但小于30nm。多层结构中任意10个连续层的和小于300nm。
整个涂层的厚度是0.5μm到20μm，优选为1μm到10μm，最优选为1μm到5μm。
根据本发明方法制成的整个多层结构的平均组分是(Ti(1-a-b-c)AlaCrbSic)N，其中0＜a＜0.5、优选为0.05＜a＜0.4、最优选为0.25＜a＜0.3，其中0＜b＜0.15、优选为0.02＜b＜0.10、最优选为0.04＜b＜0.08，其中0.01＜c＜0.17、优选为0.02＜c＜0.10、最优选为0.04＜c＜0.08，且a+b+c＜1。
大多数PVD技术可用于根据本发明的方法，优选使用电子束蒸发、磁控溅射或阴极电弧沉积或其组合。
在本发明的一个实施例中，本方法中使用的基体是硬质合金、金属陶瓷、陶瓷或立方氮化硼制成的切削刀具刀片。
在本发明的一个实施例中，本方法中使用的基体是硬质合金或高速钢制成的钻头或端铣刀。
示例1(本发明)
直径8mm的钻头、直径10mm的球头整体端铣刀和可转位刀片由具有10wt％的Co和余量WC的组分的硬质合金基体制成。这三种不同类型的刀具都使用阴极电弧蒸发涂覆有非周期性多层(Ti，Al，Cr，Si)N涂层。涂层厚度调节为适合于具体的刀具及其应用。多层结构从由两种不同化学组分构成的两对电弧靶材沉积，其中刀具安装在为获得非周期性结构而布置的3维旋转基体台上。在Ar+N2气氛中进行电弧蒸发。沉积之后，钻头上的涂层经受湿喷砂处理。
在表1中示出电弧靶材的组分、在涂层横截面上使用EDS测量的涂层的平均组分、以及在钻头和端铣刀的周边上和在所述刀片的后刀面上使用光学显微镜测量的每个刀具的涂层厚度。
多层结构具有非周期性，即非重复性的厚度的单个层的序列。横截面透射电子显微镜调查揭示，单个氮化物层厚度从1nm到30nm，且每个层系统中层的总数目超过100。
表1
  刀具   靶材1   靶材2   平均化学组分  厚度[μm]
  钻头   Al0.70Cr0.30   Ti0.90Si0.10   Ti0.53Al0.29Si0.06Cr0.06  3.3
  端铣刀   Al0.70Cr0.30   Ti0.90Si0.10   Ti0.53Al0.29Si0.06Cr0.06  3.3
  刀片   Al0.70Cr0.30   Ti0.90Si0.10   Ti0.53Al0.29Si0.06Cr0.06  3.0
示例2(参照)
为了对比，与示例1中的形状和组分相同的基体被涂覆有不同的商用涂层。
表2
*根据US 2006/0222893生产
示例3
将根据示例1制成的钻头与根据示例2制成的钻头进行对比。在以下切削条件中，在底部钻孔操作中测试每种钻头类型的两个钻头：
工件材料：            SS2541-03(34CrNiMo6)
操作：                钻孔
Vc[m/分钟]：          100
进给速度[mm/转]：     0.15
a，孔深度[mm]：       20
内部冷却：            是
可在下面看到结果。结果是两次试验的平均数。刀具寿命标准是后刀面磨损Vb＝0.3mm，前刀面磨损/剥落kb＝0.5mm，断裂或长屑(longchip)。
表3
  钻头类型No.   孔数
  本发明   1550
  商用1   525
  商用2   600
  商用3   1010
示例4
将根据示例1制成的钻头和根据示例2制成的钻头对比。在以下切削条件中，在钻通孔操作中测试每种钻头类型的3个钻头：
工件材料：            SS2244-05(42CrMo4)
操作：                钻孔
Vc[m/分钟]：          70
进给速度[mm/转]：     0.15
a，孔深度[mm]：       18
内部冷却：            是
可在下面看到结果。结果是三次试验的平均数。刀具寿命标准是后刀面磨损Vb＝0.3mm，前刀面磨损或剥落kb＝0.5mm，断裂或长屑。
表4
  钻头类型No.   孔数
  本发明   1300
  商用1   200
  商用2   700
  商用3   573
示例5
球头整体端铣刀，直径10mm，用于机加工根据示例1制成的硬化钢，并且与根据示例2制成的球头整体端铣刀进行对比。在以下切削条件中，在铣削操作下测试每种类型的两个端铣刀：
工件材料：        1.237952HRC，硬化钢
操作：            仿形铣削
ae[mm]：          0.2
ap[mm]：          0.2
Vc[m/分钟]：      196
fz，[mm/齿]：     0.127
冷却剂：          压缩空气
可在下面看到结果。刀具寿命标准是平均后刀面磨损Vb为0.15mm，或最大后刀面磨损Vb，max为0.20mm。
表5
  端铣刀   铣削距离(m)
  本发明   720
  商用1   450
示例6
将根据示例1制成的可转位刀片和根据示例2制成的可转位刀片进行对比。在以下切削条件中，在铣削操作下测试每种类型的两个可转位刀片：
工件材料：    Dievar 47HRC，硬化钢
操作：        铣削
Vc[m/分钟]：  120
ae，[mm]：    2.0
ap，[mm]：    4.0
fz，[mm/齿]： 0.12
可在下面看到结果。结果是两次测试的平均数。刀具寿命标准是Vb为0.2mm，或者破裂或缺口磨损为0.30mm。
表6
  刀片No.   铣削距离(m)
  本发明   40.25
  商用4   13.1

Claims (8)

1.一种涂层切削刀具，包括基体和涂层，所述涂层包括单个金属氮化物层X和Y交替的非周期性多层结构，其特征在于，所述涂层的平均组分是(Ti(1-a-b-c)AlaCrbSic)N，其中0＜a＜0.5、0＜b＜0.15、0.01＜c＜0.17、并且a+b+c＜1。
2.根据权利要求1所述的涂层切削刀具，其特征在于，单个层的平均厚度为0.1nm到100nm。
3.根据前述权利要求中任一项所述的涂层切削刀具，其特征在于，0.05＜a＜0.4、0.02＜b＜0.10并且0.02＜c＜0.10。
4.根据前述权利要求中任一项所述的涂层切削刀具，其特征在于，所述多层结构包括交替的(Ti，Si)N和(Al，Cr)N的单个层。
5.一种制作涂层切削刀具的方法，包括提供基体，通过PVD技术在所述基体上沉积涂层，所述涂层包括单个金属氮化物层X和Y交替的非周期性多层结构，其特征在于，所述多层结构的平均组分是(Ti(1-a-b-c)AlaCrbSic)N，其中0＜a＜0.5、0＜b＜0.15、0.01＜c＜0.17并且a+b+c＜1。
6.根据权利要求5所述的方法，其特征在于，单个层的平均厚度为0.1nm到100nm。
7.根据权利要求5和6中任一项所述的方法，其特征在于，0.05＜a＜0.4、0.02＜b＜0.10并且0.02＜c＜0.10。
8.根据权利要求5、6和7中任一项所述的方法，其特征在于，所述多层结构通过使用(Ti，Si)和(Al，Cr)靶材来沉积。
CN2007800484455A 2006-12-27 2007-12-14 多层涂层切削刀具 Active CN101578396B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
SE0602814A SE0602814L (sv) 2006-12-27 2006-12-27 Skärverktyg med multiskiktbeläggning
SE0602814-6 2006-12-27
SE06028146 2006-12-27
PCT/SE2007/051010 WO2008079088A2 (en) 2006-12-27 2007-12-14 Multilayered coated cutting tool

Publications (2)

Publication Number Publication Date
CN101578396A true CN101578396A (zh) 2009-11-11
CN101578396B CN101578396B (zh) 2012-05-09

Family

ID=39126498

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2007800484455A Active CN101578396B (zh) 2006-12-27 2007-12-14 多层涂层切削刀具
CN2007101605961A Active CN101209611B (zh) 2006-12-27 2007-12-27 多层涂覆切削刀具

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2007101605961A Active CN101209611B (zh) 2006-12-27 2007-12-27 多层涂覆切削刀具

Country Status (7)

Country Link
US (2) US8227098B2 (zh)
EP (2) EP1939327B1 (zh)
JP (2) JP5406041B2 (zh)
KR (2) KR101465278B1 (zh)
CN (2) CN101578396B (zh)
SE (1) SE0602814L (zh)
WO (1) WO2008079088A2 (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102091923A (zh) * 2009-12-04 2011-06-15 山特维克知识产权股份有限公司 多层涂覆切削工具
CN104662195A (zh) * 2012-09-28 2015-05-27 瓦尔特公开股份有限公司 具有TiAlCrSiN PVD涂层的工具
CN107636190A (zh) * 2015-05-21 2018-01-26 瓦尔特公开股份有限公司 具有多层电弧pvd涂层的刀具
CN108778585A (zh) * 2016-03-11 2018-11-09 三菱综合材料株式会社 耐崩刀性和耐磨性优异的表面包覆切削工具

Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8109350B2 (en) * 2006-01-26 2012-02-07 University Of Utah Research Foundation Polycrystalline abrasive composite cutter
JP4440980B2 (ja) * 2008-01-31 2010-03-24 ユニオンツール株式会社 切削工具用硬質皮膜
JP5235607B2 (ja) * 2008-10-23 2013-07-10 京セラ株式会社 表面被覆工具
SE533883C2 (sv) * 2009-06-01 2011-02-22 Seco Tools Ab Nanolaminerat belagt skärverktyg
SE533884C2 (sv) 2009-06-01 2011-02-22 Seco Tools Ab Nanolaminerat belagt skärverktyg
JP5193153B2 (ja) 2009-10-02 2013-05-08 株式会社神戸製鋼所 硬質皮膜、塑性加工用金型、塑性加工方法、及び硬質皮膜用ターゲット
KR101751562B1 (ko) * 2010-01-11 2017-06-27 이스카 엘티디. 코팅된 절삭 공구
JP5194306B2 (ja) * 2010-02-17 2013-05-08 住友電工ハードメタル株式会社 表面被覆切削工具
JP5093530B2 (ja) * 2010-03-31 2012-12-12 住友電工ハードメタル株式会社 表面被覆切削工具
US8409695B2 (en) 2010-05-28 2013-04-02 Kennametal Inc. Multilayer nitride hard coatings
KR101685450B1 (ko) * 2010-09-29 2016-12-12 쿄세라 코포레이션 절삭 공구
RU2013128471A (ru) * 2010-11-23 2014-12-27 Секо Тулз Аб Режущая пластина с покрытием
EP2434032A1 (en) * 2010-12-08 2012-03-28 SECO TOOLS AB (publ) Coated fine grained cermet for finish turning applications
US8691374B2 (en) 2011-09-14 2014-04-08 Kennametal Inc. Multilayer coated wear-resistant member and method for making the same
JP6093363B2 (ja) * 2011-09-30 2017-03-08 セメコン アーゲー Ｈｉｐｉｍｓを用いた基材のコーティング
US9698229B2 (en) * 2012-01-17 2017-07-04 United Microelectronics Corp. Semiconductor structure and process thereof
KR101351843B1 (ko) 2012-05-02 2014-01-16 한국야금 주식회사 절삭공구용 경질피막
JP6014959B2 (ja) * 2012-06-29 2016-10-26 住友電工ハードメタル株式会社 表面被覆切削工具
RU2495957C1 (ru) * 2012-07-03 2013-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
RU2495960C1 (ru) * 2012-07-03 2013-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
RU2494169C1 (ru) * 2012-07-03 2013-09-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
RU2503743C1 (ru) * 2012-07-03 2014-01-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
JP2014069258A (ja) * 2012-09-28 2014-04-21 Nachi Fujikoshi Corp 硬質皮膜被覆切削工具
WO2014104111A1 (ja) * 2012-12-27 2014-07-03 京セラ株式会社 切削工具
US9428967B2 (en) 2013-03-01 2016-08-30 Baker Hughes Incorporated Polycrystalline compact tables for cutting elements and methods of fabrication
US9103036B2 (en) 2013-03-15 2015-08-11 Kennametal Inc. Hard coatings comprising cubic phase forming compositions
JP6016271B2 (ja) * 2013-03-29 2016-10-26 住友電工ハードメタル株式会社 表面被覆窒化硼素焼結体工具
CN103215542B (zh) * 2013-04-15 2015-01-28 中国兵器科学研究院宁波分院 一种纳米多层涂层及其制备方法
CN103273687B (zh) * 2013-05-13 2015-02-18 山东大学 TiSiN+ZrSiN复合纳米涂层刀具及其制备方法
MX361325B (es) * 2013-07-03 2018-11-20 Oerlikon Surface Solutions Ag Pfaeffikon Capas de tixsi1 - xn y su produccion.
RU2548856C2 (ru) * 2013-07-19 2015-04-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
US9168664B2 (en) 2013-08-16 2015-10-27 Kennametal Inc. Low stress hard coatings and applications thereof
US9896767B2 (en) 2013-08-16 2018-02-20 Kennametal Inc Low stress hard coatings and applications thereof
KR101551963B1 (ko) 2013-09-12 2015-09-10 현대자동차주식회사 알루미늄 다이캐스팅용 코팅재 및 이의 코팅방법
JP6155204B2 (ja) * 2014-02-21 2017-06-28 株式会社神戸製鋼所 硬質皮膜およびその形成方法
EP3124146B1 (en) * 2014-03-27 2020-06-24 Tungaloy Corporation Coated tool
CN105473261B (zh) * 2014-06-06 2017-08-18 住友电工硬质合金株式会社 表面被覆工具及其制造方法
AT516062B1 (de) * 2015-01-15 2016-02-15 Boehlerit Gmbh & Co Kg Verfahren zum Beschichten eines Gegenstandes und damit hergestellte Beschichtung
RU2622541C1 (ru) * 2015-12-15 2017-06-16 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный технический университет" Способ получения многослойного покрытия для режущего инструмента
CN105543780B (zh) * 2015-12-28 2018-02-09 富耐克超硬材料股份有限公司 超硬刀具表面复合硬质涂层及其制备方法
EP3228726A1 (en) * 2016-04-08 2017-10-11 Seco Tools Ab Coated cutting tool
JP7061603B2 (ja) * 2016-08-01 2022-04-28 三菱マテリアル株式会社 多層硬質皮膜被覆切削工具
WO2018100849A1 (ja) 2016-11-29 2018-06-07 住友電工ハードメタル株式会社 表面被覆切削工具
CN106995913A (zh) * 2016-12-29 2017-08-01 西安交通大学青岛研究院 一种CrTiAlSiN基多元复合硬质涂层
CN106835014A (zh) * 2016-12-29 2017-06-13 西安交通大学青岛研究院 一种多元复合硬质涂层制备方法
ES2767356T3 (es) * 2017-05-19 2020-06-17 Walter Ag Herramienta de corte de metal con revestimiento multicapa
US10570501B2 (en) 2017-05-31 2020-02-25 Kennametal Inc. Multilayer nitride hard coatings
JP6858347B2 (ja) * 2017-07-28 2021-04-14 株式会社タンガロイ 被覆切削工具
JPWO2019044715A1 (ja) * 2017-08-29 2020-09-17 京セラ株式会社 被覆工具及びこれを備えた切削工具
JPWO2019044714A1 (ja) * 2017-08-29 2020-09-17 京セラ株式会社 被覆工具及びこれを備えた切削工具
JP6918951B2 (ja) 2017-09-27 2021-08-11 京セラ株式会社 被覆工具及びこれを備えた切削工具
WO2019065707A1 (ja) 2017-09-27 2019-04-04 京セラ株式会社 被覆工具及びこれを備えた切削工具
CN107915476A (zh) * 2017-12-06 2018-04-17 王增倍 一种穿孔顶头及制备方法
WO2019188967A1 (ja) * 2018-03-27 2019-10-03 三菱マテリアル株式会社 表面被覆切削工具
KR102112084B1 (ko) * 2018-11-30 2020-05-18 한국야금 주식회사 절삭공구용 경질피막
JP7165594B2 (ja) * 2019-02-07 2022-11-04 京セラ株式会社 被覆工具及びこれを備えた切削工具
KR102074469B1 (ko) * 2019-05-13 2020-02-07 주식회사 다올플라즈마 포밍 치형공구용 다층나노 경질 코팅막
CN110144541B (zh) * 2019-06-18 2021-08-06 上海交通大学 一种高温钛合金热障涂层材料及其制备方法
JP7312382B2 (ja) * 2021-03-18 2023-07-21 株式会社タンガロイ 被覆切削工具
US11731202B2 (en) 2021-04-19 2023-08-22 Kennametal Inc. Coating, method for coating, and coated cutting tool
EP4170064A1 (en) * 2021-10-20 2023-04-26 AB Sandvik Coromant Coated cutting tool
CN114672786B (zh) * 2022-03-17 2023-04-28 赣州澳克泰工具技术有限公司 一种耐高温氧化、自润滑的多层涂层刀具及其制备方法
DE102022115550A1 (de) * 2022-06-22 2023-12-28 Rainer Cremer Beschichtetes Werkzeug, Verfahren zu dessen Herstellung sowie Verwendung des Werkzeugs

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE518145C2 (sv) * 1997-04-18 2002-09-03 Sandvik Ab Multiskiktbelagt skärverktyg
JP4185172B2 (ja) 1997-06-19 2008-11-26 住友電工ハードメタル株式会社 被覆硬質工具
JP3343727B2 (ja) * 1999-05-19 2002-11-11 日立ツール株式会社 硬質皮膜被覆工具
JP3417907B2 (ja) * 2000-07-13 2003-06-16 日立ツール株式会社 多層皮膜被覆工具
DE60139818D1 (de) * 2000-12-28 2009-10-15 Kobe Steel Ltd Target zur Bildung einer Hartschicht
JP3454428B2 (ja) * 2001-05-11 2003-10-06 日立ツール株式会社 耐摩耗皮膜被覆工具
JP3948013B2 (ja) * 2001-12-11 2007-07-25 三菱マテリアル株式会社 硬質被覆層がすぐれた耐熱性を発揮する表面被覆超硬合金製切削工具
SE526338C2 (sv) * 2002-09-04 2005-08-23 Seco Tools Ab Skär med utskiljningshärdad slitstark refraktär beläggning
SE526339C2 (sv) * 2002-09-04 2005-08-23 Seco Tools Ab Skär med slitstark refraktär beläggning med kompositstruktur
JP2005271190A (ja) * 2003-12-05 2005-10-06 Sumitomo Electric Hardmetal Corp 表面被覆切削工具
SE0402180D0 (sv) * 2004-09-10 2004-09-10 Sandvik Ab Deposition of Ti1-xAlxN using Bipolar Pulsed Dual Magnetron Sputtering
JP3934136B2 (ja) 2004-11-11 2007-06-20 日立ツール株式会社 硬質皮膜被覆部材及びその被覆方法
JP4373897B2 (ja) * 2004-11-25 2009-11-25 日立ツール株式会社 硬質皮膜被覆部材及びその被覆方法
JP4072155B2 (ja) * 2004-12-28 2008-04-09 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
WO2006070509A1 (ja) * 2004-12-28 2006-07-06 Sumitomo Electric Hardmetal Corp. 表面被覆切削工具および表面被覆切削工具の製造方法
SE528671C2 (sv) * 2005-01-31 2007-01-16 Sandvik Intellectual Property Hårdmetallskär för seghetskrävande korthålsborrning samt förfarande för att framställa detsamma
JP4702520B2 (ja) * 2005-02-14 2011-06-15 三菱マテリアル株式会社 高硬度鋼の高速切削加工で硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆超硬合金製切削工具
SE528891C2 (sv) * 2005-03-23 2007-03-06 Sandvik Intellectual Property Skär belagt med ett multiskikt av metaloxid
US7348074B2 (en) * 2005-04-01 2008-03-25 Oc Oerlikon Balzers Ag Multilayer hard coating for tools
SE0500994L (sv) * 2005-04-29 2006-10-30 Seco Tools Ab Tunt slitstarkt skikt
US7537822B2 (en) * 2005-05-26 2009-05-26 Hitachi Tool Engineering, Ltd. Hard-coated member
SE529161C2 (sv) * 2005-06-22 2007-05-22 Seco Tools Ab Skärverktyg med kompositbeläggning för finbearbetning av härdade stål
JP2007152456A (ja) * 2005-12-02 2007-06-21 Mitsubishi Materials Corp 高硬度鋼の高速切削加工で硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102091923A (zh) * 2009-12-04 2011-06-15 山特维克知识产权股份有限公司 多层涂覆切削工具
US8758890B2 (en) 2009-12-04 2014-06-24 Sandvik Intellectual Property Ab Multilayered coated cutting tool
CN102091923B (zh) * 2009-12-04 2015-04-01 山特维克知识产权股份有限公司 多层涂覆切削工具
CN104662195A (zh) * 2012-09-28 2015-05-27 瓦尔特公开股份有限公司 具有TiAlCrSiN PVD涂层的工具
US10487388B2 (en) 2012-09-28 2019-11-26 Walter Ag Tool with TiAlCrSiN PVD coating
CN107636190A (zh) * 2015-05-21 2018-01-26 瓦尔特公开股份有限公司 具有多层电弧pvd涂层的刀具
CN108778585A (zh) * 2016-03-11 2018-11-09 三菱综合材料株式会社 耐崩刀性和耐磨性优异的表面包覆切削工具
US10751806B2 (en) 2016-03-11 2020-08-25 Mitsubishi Materials Corporation Surface-coated cutting tool having excellent chipping resistance and wear resistance

Also Published As

Publication number Publication date
KR101465278B1 (ko) 2014-11-26
US20080166588A1 (en) 2008-07-10
WO2008079088A3 (en) 2008-08-14
CN101209611B (zh) 2012-12-05
US8119262B2 (en) 2012-02-21
EP1939328B1 (en) 2018-02-21
EP1939328A1 (en) 2008-07-02
US20080166583A1 (en) 2008-07-10
CN101578396B (zh) 2012-05-09
EP1939327A1 (en) 2008-07-02
KR20080061323A (ko) 2008-07-02
JP2008162009A (ja) 2008-07-17
KR20090094108A (ko) 2009-09-03
SE0602814L (sv) 2008-06-28
JP4874947B2 (ja) 2012-02-15
KR101520962B1 (ko) 2015-05-15
CN101209611A (zh) 2008-07-02
WO2008079088A2 (en) 2008-07-03
EP1939327B1 (en) 2018-06-27
JP2010514578A (ja) 2010-05-06
JP5406041B2 (ja) 2014-02-05
US8227098B2 (en) 2012-07-24

Similar Documents

Publication Publication Date Title
CN101578396B (zh) 多层涂层切削刀具
CN104662195B (zh) 具有TiAlCrSiN PVD涂层的工具
CN107636190B (zh) 具有多层电弧pvd涂层的刀具
US9476114B2 (en) TiAlN-coated tool
CN104805436A (zh) 具有硬涂层的工件
KR20090068174A (ko) 코팅된 절삭 공구 및 코팅된 절삭 공구를 제조하는 방법
JP5261018B2 (ja) 表面被覆切削工具
JP7061603B2 (ja) 多層硬質皮膜被覆切削工具
JP2010094744A (ja) 硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具
JP4991244B2 (ja) 表面被覆切削工具
CN102883840A (zh) 表面被覆切削工具
CN103339282A (zh) 硬质层叠被膜
JP6141886B2 (ja) 被覆された切削工具
CN104508185A (zh) 涂层切削刀片
Su et al. Tribological properties of Ti2N–Wx% coatings deposited by magnetron sputtering
JP2000317706A (ja) 被覆工具
CN101517126A (zh) 具有硬涂层的工件
JP2003145318A (ja) 耐摩耗被覆層がすぐれた密着性を有する表面被覆超硬合金製切削工具
WO2023232869A1 (en) A coated cutting tool
JP2023531295A (ja) 被覆切削工具
JP2003080406A (ja) 耐摩耗被覆層がすぐれた密着性および耐チッピング性を有する表面被覆超硬合金製切削工具
JP2009061572A (ja) 切削工具
JP2002254207A (ja) 切粉に対する表面潤滑性にすぐれた表面被覆超硬合金製切削工具
JP2004314188A (ja) 重切削加工条件で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆超硬合金製切削工具
JP2004330360A (ja) 重切削加工条件で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆超硬合金製切削工具

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CI01 Correction of invention patent gazette

Correction item: International Day of publication

Correct: 20080703

False: 20080814

Number: 19

Volume: 28

CI03 Correction of invention patent

Correction item: International Day of publication

Correct: 20080703

False: 20080814

Number: 19

Page: The title page

Volume: 28

ERR Gazette correction

Free format text: CORRECT: INTERNATIONAL PROCLAMATION DATE; FROM: 2008.08.14 TO: 2008.07.03