CN101426384A - 防腐剂 - Google Patents
防腐剂 Download PDFInfo
- Publication number
- CN101426384A CN101426384A CNA2007800143408A CN200780014340A CN101426384A CN 101426384 A CN101426384 A CN 101426384A CN A2007800143408 A CNA2007800143408 A CN A2007800143408A CN 200780014340 A CN200780014340 A CN 200780014340A CN 101426384 A CN101426384 A CN 101426384A
- Authority
- CN
- China
- Prior art keywords
- beverage
- dicarboxylic acids
- acid
- esters
- organic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003755 preservative agent Substances 0.000 title description 2
- 230000002335 preservative effect Effects 0.000 title 1
- 235000013361 beverage Nutrition 0.000 claims abstract description 26
- 150000003628 tricarboxylic acids Chemical class 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 150000007524 organic acids Chemical class 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 238000004321 preservation Methods 0.000 claims abstract description 6
- 230000001954 sterilising effect Effects 0.000 claims abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 15
- 150000005686 dimethyl carbonates Chemical class 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 13
- 235000020965 cold beverage Nutrition 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 235000015203 fruit juice Nutrition 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- BPHVHMBNGQRCNN-ZVGUSBNCSA-N [K].C([C@H](O)[C@@H](O)C(=O)O)(=O)O Chemical compound [K].C([C@H](O)[C@@H](O)C(=O)O)(=O)O BPHVHMBNGQRCNN-ZVGUSBNCSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- -1 alkaline-earth metal salts Chemical class 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 claims description 2
- 239000001354 calcium citrate Substances 0.000 claims description 2
- 239000001362 calcium malate Substances 0.000 claims description 2
- OLOZVPHKXALCRI-UHFFFAOYSA-L calcium malate Chemical compound [Ca+2].[O-]C(=O)C(O)CC([O-])=O OLOZVPHKXALCRI-UHFFFAOYSA-L 0.000 claims description 2
- 229940016114 calcium malate Drugs 0.000 claims description 2
- 235000011038 calcium malates Nutrition 0.000 claims description 2
- GUPPESBEIQALOS-UHFFFAOYSA-L calcium tartrate Chemical compound [Ca+2].[O-]C(=O)C(O)C(O)C([O-])=O GUPPESBEIQALOS-UHFFFAOYSA-L 0.000 claims description 2
- 239000001427 calcium tartrate Substances 0.000 claims description 2
- 235000011035 calcium tartrate Nutrition 0.000 claims description 2
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims description 2
- JNWGMESTOMYLND-UHFFFAOYSA-N hexanedioic acid;sodium Chemical compound [Na].OC(=O)CCCCC(O)=O JNWGMESTOMYLND-UHFFFAOYSA-N 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- GCHCGDFZHOEXMP-UHFFFAOYSA-L potassium adipate Chemical compound [K+].[K+].[O-]C(=O)CCCCC([O-])=O GCHCGDFZHOEXMP-UHFFFAOYSA-L 0.000 claims description 2
- 239000001608 potassium adipate Substances 0.000 claims description 2
- 235000011051 potassium adipate Nutrition 0.000 claims description 2
- 239000001508 potassium citrate Substances 0.000 claims description 2
- 229960002635 potassium citrate Drugs 0.000 claims description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 2
- 235000011082 potassium citrates Nutrition 0.000 claims description 2
- 239000001415 potassium malate Substances 0.000 claims description 2
- 235000011033 potassium malate Nutrition 0.000 claims description 2
- SVICABYXKQIXBM-UHFFFAOYSA-L potassium malate Chemical compound [K+].[K+].[O-]C(=O)C(O)CC([O-])=O SVICABYXKQIXBM-UHFFFAOYSA-L 0.000 claims description 2
- 239000001472 potassium tartrate Substances 0.000 claims description 2
- 229940111695 potassium tartrate Drugs 0.000 claims description 2
- 235000011005 potassium tartrates Nutrition 0.000 claims description 2
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 claims description 2
- 229940074404 sodium succinate Drugs 0.000 claims description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 2
- 239000001433 sodium tartrate Substances 0.000 claims description 2
- 229960002167 sodium tartrate Drugs 0.000 claims description 2
- 235000011004 sodium tartrates Nutrition 0.000 claims description 2
- 229960005137 succinic acid Drugs 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 229960001367 tartaric acid Drugs 0.000 claims description 2
- 235000013337 tricalcium citrate Nutrition 0.000 claims description 2
- 241001122767 Theaceae Species 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229960003975 potassium Drugs 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 claims 1
- GZDFHIJNHHMENY-UHFFFAOYSA-N Dimethyl dicarbonate Chemical compound COC(=O)OC(=O)OC GZDFHIJNHHMENY-UHFFFAOYSA-N 0.000 abstract description 14
- 235000010300 dimethyl dicarbonate Nutrition 0.000 abstract description 14
- 239000004316 dimethyl dicarbonate Substances 0.000 abstract description 2
- 244000269722 Thea sinensis Species 0.000 description 6
- 241000219095 Vitis Species 0.000 description 6
- 235000009754 Vitis X bourquina Nutrition 0.000 description 6
- 235000012333 Vitis X labruscana Nutrition 0.000 description 6
- 235000014787 Vitis vinifera Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 235000013616 tea Nutrition 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 4
- 244000005700 microbiome Species 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000079253 Byssochlamys spectabilis Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 241000235342 Saccharomycetes Species 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RYDFXSRVZBYYJV-TYYBGVCCSA-N (e)-but-2-enedioic acid;sodium Chemical compound [Na].OC(=O)\C=C\C(O)=O RYDFXSRVZBYYJV-TYYBGVCCSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000001747 Potassium fumarate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 238000009455 aseptic packaging Methods 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 235000020344 instant tea Nutrition 0.000 description 1
- 235000015122 lemonade Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- SHPKCSFVQGSAJU-SEPHDYHBSA-L potassium fumarate Chemical compound [K+].[K+].[O-]C(=O)\C=C\C([O-])=O SHPKCSFVQGSAJU-SEPHDYHBSA-L 0.000 description 1
- 235000019295 potassium fumarate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- CJWHWKXAABCWLT-UHFFFAOYSA-L potassium;sodium;butanedioate Chemical compound [Na+].[K+].[O-]C(=O)CCC([O-])=O CJWHWKXAABCWLT-UHFFFAOYSA-L 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F3/00—Tea; Tea substitutes; Preparations thereof
- A23F3/16—Tea extraction; Tea extracts; Treating tea extract; Making instant tea
- A23F3/163—Liquid or semi-liquid tea extract preparations, e.g. gels, liquid extracts in solid capsules
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/42—Preservation of non-alcoholic beverages
- A23L2/44—Preservation of non-alcoholic beverages by adding preservatives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
- A23L3/3517—Carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/12—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages without precipitation
- C12H1/14—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages without precipitation with non-precipitating compounds, e.g. sulfiting; Sequestration, e.g. with chelate-producing compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Nutrition Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- General Chemical & Material Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Genetics & Genomics (AREA)
- Microbiology (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Non-Alcoholic Beverages (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Storage Of Fruits Or Vegetables (AREA)
Abstract
二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类的一个混合物有利地适合于饮料的灭菌和保存。
Description
技术领域
本申请涉及二碳酸二甲酯(dimethyl dicarbonate，DMDC)以及二羧酸和三羧酸系列的多种有机酸的混合物用于饮料的灭菌和保存的用途。
背景技术
基于果汁的清凉饮料、速溶茶饮料、许多其他特征类型的清凉饮料、葡萄酒冷饮品、还有多种脱醇葡萄酒以及其他葡萄酒，总体上必须得到保护来对抗由细菌、酵母菌以及霉菌造成的侵染/腐败。已知有很多方法，例如无菌包装、热包装、巴斯德灭菌隧道、使用持续性防腐剂，这仅提及最重要的方法。二碳酸二甲酯(DMDC)作为冷型灭菌剂的已知用途对于许多难保存的产品也一直在获得日益增加的重要性。然而，本领域的普通技术人员经常会遇到难题的情况。具体地说，在不加二氧化碳的、无泡清凉饮料，基于果汁和/或茶的饮料，以及还有具有一定风味的饮料的情况下，当使用已知的保存方法时会产生一些问题，例如，像山梨酸和苯甲酸的盐类的使用的耐受现象，在高剂量率时的味道损害以及还有由国家立法的允许剂量的限制。
具体到可重复使用的塑料包装的使用，特别是引入PET瓶(如人们所知，它不能在标准实施方式中用于通过巴斯德灭菌法来由于保存)也显著地增强了对没有热处理的有效的保存方法的要求。
从专业文献中人们已知，饮料防腐剂DMDC对在酒类饮料中的酵母菌以及细菌的效果通过二氧化硫而协同地得到增强(见J.Enol.Vitic.39：4：279-282(1988))。
人们进一步已知，DMDC的作用与抗坏血酸以及山梨酸钾防腐剂相结合而可以协同地得到增强(见EP-A 0 804 093)。
然而，基于DMDC的已知的多种防腐剂需要改善，因为它们对抗某些微生物的孢子是不够活跃的。
完全出人意料地，现在已经发现二碳酸二甲酯与常规的作为二羧酸和三羧酸系列的酸化剂的多种有机酸以及还有它们的盐类的混合物是高度地适合于饮料的灭菌和保存。在许多情况下，通过添加这些有机酸，此时DMDC的效果可以协同地得到增强，这就是说该混合物的效果是大于这些单独组分的效果，其中这些有关的酸类本身不具有一种抗微生物的作用。
发明内容
因此，本发明涉及将包含二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类的用于饮料的灭菌和保存的混合物的用途。
优选地，这些二羧酸和三羧酸的盐类是碱金属以及碱土金属的盐。
根据本发明，有待使用的这些二羧酸和三羧酸及其盐类优选是柠檬酸、柠檬酸钠、柠檬酸钾、柠檬酸钙；苹果酸、苹果酸钠、苹果酸钾、苹果酸钙；酒石酸、酒石酸钠、酒石酸钾、酒石酸钙；己二酸、己二酸钠、己二酸钾；琥珀酸、琥珀酸钠、琥珀酸钠钾；富马酸、富马酸钠、富马酸钾。
根据本发明所要使用的这些混合物优选地包含二碳酸二甲酯以及一个协同地活性的量的二羧酸和三羧酸系列的至少一种有机酸及其盐类。
具体地说，这些混合物包含20ppm到1000ppm的二碳酸二甲酯以及100到30 000ppm的二羧酸和三羧酸系列的至少一种有机酸及其盐类，特别优选50ppm到250ppm的二碳酸二甲酯以及500ppm到10 000ppm的二羧酸和三羧酸系列的至少一种有机酸及其盐类。
对于本发明的目的，饮料优选是指清凉饮料例如无醇风味清凉饮料，例如柠檬汽水、包含果汁的清凉饮料、茶(被称为即饮茶饮料)、茶/含果汁的清凉饮料的混合饮料、还有相应的浓缩剂、以及还有葡萄酒冷饮品和多种脱醇葡萄酒。
为了不同的国家立法的目的，通过根据本发明所要使用的混合物，在极大减少的SO2含量下葡萄酒类也可以可靠地保存，如果这是立法所允许的。主要的是，根据本发明所要使用混合物是用于上述类型的无泡饮料中，但还有轻度地含二氧化碳的饮料以及还有含二氧化碳的饮料可以有利地由这些混合物进行灭菌。
优选地，根据本发明所要使用的混合物是用于被称为无泡的饮料，这就是说不含二氧化碳的茶以及茶/混合的饮料。
具体实施方式
这些饮料根据常规的方法生产。例如，在根据本发明的用途的情况下，总体上，将二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类的一种混合物结合到要保存的饮料中。还有可能将该混合物的这些单独的组分分别加入该饮料中。优选地，为此，首先将该饮料或其组分与二羧酸和三羧酸系列的至少一种有机酸及其盐类进行混合，并且随后通过一个适当的计量装置将它们与二碳酸二甲酯混合，特别是例如LEWA DA9、或相应的Burdomat类型的计量系统。
实例
将一种含有水果组分的饮料与柠檬酸的不同的浓缩物进行混合，并且随后接种多变拟青霉菌的真菌分生孢子。随后，用不同的DMDC浓缩物对这些接种的饮料样本进行处理，并且在27℃下培养两周。在随后的评估中，清楚的是对于阻止多变拟青霉菌的生长来说，单独的250ppm的DMDC以及单独的30000ppm的柠檬酸都是不足够的，而结合在一起，少至200ppm的DMDC以及3000ppm的柠檬酸就足以防止真菌生长(参见表1)。
表1
| MHC[ppm] | |
| DMDC(纯活性化合物) | >250 |
| 柠檬酸(纯酸化剂) | >30000 |
| DMDC/柠檬酸的组合 | 200/3000 |
该协同作用是根据Kull等人(F.C.Kull，P.C.Eismann，H.D.Sylvestrowicz，R.L.Mayer，Applied Microbiology 9，538 to 541，1961)的方法来确定的。在这种方法中，适用以下关系：
QA/Qa+QB/Qb＝SI
Qa＝物质A的浓度，它是MIC
Qb＝物质B的浓度，它是MIC
QA＝在抑制微生物生长的A/B的浓度中的物质A的浓度
QB＝在抑制微生物生长的A/B的浓度中的物质B的浓度
SI＝协同指数
SI＝1意味着相加作用
SI>1意味着拮抗作用
SI<1意味着协同作用
对于组合DMDC/柠檬酸，计算出以下的协同指数：
SI＝3000/30000+200/250＝0.9
Claims (10)
1.一种包含二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类的混合物用于饮料的灭菌和保存的用途。
2.根据权利要求1所述的用途，其特征在于这些二羧酸类和三羧酸类的盐类是它们的碱金属盐类以及碱土金属盐类。
3.根据权利要求1和2中至少一项所述的用途，其特征在于这些二羧酸类和三羧酸类及其盐类是柠檬酸、柠檬酸钠、柠檬酸钾、柠檬酸钙；苹果酸、苹果酸钠、苹果酸钾、苹果酸钙；酒石酸、酒石酸钠、酒石酸钾、酒石酸钙；己二酸、己二酸钠、己二酸钾；琥珀酸、琥珀酸钠、琥珀酸钾。
4.根据权利要求1到3中至少一项所述的用途，其特征在于该混合物包含协同作用的量的二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类。
5.根据权利要求1到4中至少一项所述的用途，其特征在于该混合物包含20ppm到1000ppm的二碳酸二甲酯以及100ppm到30000ppm的二羧酸和三羧酸系列的至少一种有机酸及其盐类。
6.根据权利要求1到5中至少一项所述的用途，其特征在于这些被灭菌和保存的饮料是果汁或包含果汁的饮料、含二氧化碳的清凉饮料、不起泡的、不含二氧化碳的清凉饮料、含酒精的混合饮料、茶或茶/果汁混合物。
7.用于饮料的灭菌和保存的方法，其特征在于将二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类结合到有待保存的饮料之中。
8.根据权利要求7所述的方法所生产的饮料。
9.包含20ppm到1000ppm的二碳酸二甲酯以及100ppm到30000ppm的二羧酸和三羧酸系列的至少一种有机酸及其盐类的饮料。
10.用于饮料灭菌的防腐剂，包含二碳酸二甲酯以及二羧酸和三羧酸系列的至少一种有机酸及其盐类。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396930A (zh) * | 2013-07-10 | 2013-11-20 | 上海应用技术学院 | 一种抑制红葡萄酒酒香酵母菌B. bruxellensis生长的方法 |
| CN105340981A (zh) * | 2015-10-29 | 2016-02-24 | 无锡苏芽食品有限公司 | 一种豆粒天然灭菌浸泡液 |
| CN109337773A (zh) * | 2019-01-07 | 2019-02-15 | 中粮长城葡萄酒（蓬莱）有限公司 | 一种中止葡萄酒酒精发酵的方法 |
| CN111886327A (zh) * | 2018-03-22 | 2020-11-03 | 朗盛德国有限责任公司 | 用于保存含葡萄酒的液体的方法和装置 |
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| DE102008048714A1 (de) * | 2008-09-24 | 2010-03-25 | Lanxess Deutschland Gmbh | Verfahren zur Konservierung von Getränken |
| ES2625013T3 (es) * | 2014-09-29 | 2017-07-18 | Lanxess Deutschland Gmbh | Procedimiento para esterilizar bebidas contaminadas con acetobacterias |
| RU2631903C2 (ru) * | 2015-08-06 | 2017-09-28 | Федеральное государственное бюджетное учреждение науки "Научный центр биомедицинских технологий Федерального медико-биологического агентства" (ФГБУН НЦБТМ ФМБА России) | Способ консервации пищевых продуктов |
| RU2601599C1 (ru) * | 2015-08-06 | 2016-11-10 | Федеральное государственное бюджетное учреждение науки "Научный центр биомедицинских технологий Федерального медико-биологического агентства" (ФГБУН НЦБТМ ФМБА России) | Способ консервации пищевых продуктов |
| JP7057160B2 (ja) * | 2018-03-02 | 2022-04-19 | 株式会社 伊藤園 | 香料を含まない野菜搾汁液含有飲料における劣化の抑制方法。 |
| RU2701641C1 (ru) * | 2019-02-26 | 2019-09-30 | Ольга Дмитриевна Бакулина | Способ стерилизации и консервации негазированных напитков |
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| US6063428A (en) * | 1996-02-26 | 2000-05-16 | The Procter & Gamble Company | Green tea extract subjected to cation exchange treatment and nanofiltration to improve clarity and color |
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| EP1629732A1 (en) * | 2004-08-27 | 2006-03-01 | Purac Biochem BV | Composition for inactivating yeasts or molds in soft drinks |
| DE102006018845A1 (de) * | 2006-04-22 | 2007-10-25 | Lanxess Deutschland Gmbh | Stabilisierung von Dikohlensäurediestern mit Protonen-Säuren |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396930A (zh) * | 2013-07-10 | 2013-11-20 | 上海应用技术学院 | 一种抑制红葡萄酒酒香酵母菌B. bruxellensis生长的方法 |
| CN105340981A (zh) * | 2015-10-29 | 2016-02-24 | 无锡苏芽食品有限公司 | 一种豆粒天然灭菌浸泡液 |
| CN111886327A (zh) * | 2018-03-22 | 2020-11-03 | 朗盛德国有限责任公司 | 用于保存含葡萄酒的液体的方法和装置 |
| CN109337773A (zh) * | 2019-01-07 | 2019-02-15 | 中粮长城葡萄酒（蓬莱）有限公司 | 一种中止葡萄酒酒精发酵的方法 |
| CN109337773B (zh) * | 2019-01-07 | 2019-05-07 | 中粮长城葡萄酒（蓬莱）有限公司 | 一种中止葡萄酒酒精发酵的方法 |
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| Publication number | Publication date |
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| NO20084474L (no) | 2008-11-04 |
| UA93712C2 (en) | 2011-03-10 |
| CA2649544A1 (en) | 2007-11-01 |
| EP2012600A1 (de) | 2009-01-14 |
| ZA200808932B (en) | 2010-01-27 |
| IL194504A0 (en) | 2009-08-03 |
| MX2008013495A (es) | 2009-02-10 |
| DE102006018844A1 (de) | 2007-10-25 |
| RU2008145988A (ru) | 2010-05-27 |
| RU2441400C2 (ru) | 2012-02-10 |
| CN101426384B (zh) | 2013-08-07 |
| US20100021599A1 (en) | 2010-01-28 |
| JP2009534328A (ja) | 2009-09-24 |
| AU2007241456A1 (en) | 2007-11-01 |
| KR20090006105A (ko) | 2009-01-14 |
| BRPI0710515A2 (pt) | 2011-08-16 |
| WO2007121858A1 (de) | 2007-11-01 |
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