CN101417863B - 壳体及表面处理方法 - Google Patents
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Abstract
本发明涉及一种壳体,其包括基材及形成于该基材表面的涂层,该涂层包括靠近该基材的镀膜层与处于外表面的外覆层,其中该涂层在该镀膜层与该外覆层之间还包括一粘合层,该粘合层的材质包括含氯聚烯烃。另外,本发明还提供一种表面处理方法。上述壳体具有可避免涂层损坏而影响外观的优点。
Description
技术领域
本发明是涉及一种壳体及表面处理方法,尤其是一种带有涂层的壳体及表面处理方法。
背景技术
随着电子产品之快速发展,便携式电子装置(如手机、MP3播放器、个人数字助理)之使用已非常普遍。并且为使便携式电子装置的具有较好的外观以及手感,通常会在便携式电子装置的壳体上形成各种各样的涂层。
为使便携式电子装置具有金属外观,通常会在该便携式电子装置壳体表面形成涂层。在生产过程中,一般是在便携式电子装置壳体基材的表面涂布底漆先形成一层底层,然后再在该底层上采用真空镀膜的方法镀上一层金属膜层。
然而,采用真空镀膜的方法形成的镀膜层一般具有一定的化学活性,因此镀膜层处于外表面而暴露在空气中时,容易被刮伤、磨损及氧化,从而影响手机的外观。
为避免镀膜层被刮伤、磨损及氧化,现有技术中是采用在镀膜层上涂布面漆形成外覆层来保护镀膜层。外覆层可对镀膜层起到一定的保护作用,但在使用一段时间后,外覆层本身却容易发生脱落、腐蚀,致使镀膜层得不到保护,而仍影响产品的外观。
发明内容
鉴于以上内容,有必要提供一种可避免涂层损坏而影响外观的壳体及表面处理方法。
一种壳体,其包括基材及形成于该基材表面的涂层,该涂层包括靠近该基材的镀膜层与处于外表面的外覆层,其中该涂层在该镀膜层与该外覆层之间还包括一粘合层,该粘合层的材质包括含氯聚烯烃。
一种表面处理方法,其包括以下步骤:在一基材表面沉积一层镀膜层;在该镀膜层上涂布粘合剂,形成粘合层,该粘合层的材质包括含氯聚烯烃;及在该粘合层上涂布面漆,形成外覆层。
另一种表面处理方法,其包括以下步骤:在一基材表面涂布底漆,形成一层底层;在该底层沉积一层镀膜层;在该镀膜层上涂布粘合剂,形成一层粘合层;及在该粘合层上涂布面漆,形成外覆层。
上述壳体在镀膜层与外覆层之间形成有粘合层,粘合层可增强镀膜层与外覆层之间的结合力,因此可防止或减少外覆层在使用时脱落,从而避免该涂层损坏,确保产品具有较好的外观。
附图说明
图1是本发明较佳实施方式一的壳体。
图2是本发明较佳实施方式二的壳体。
具体实施方式
下面将结合附图及实施例对壳体及表面处理方法做进一步详细说明。
请参见图1,所示为本发明较佳实施方式一的壳体10,其可用于便携式电子装置。壳体10包括基材12及形成于基材12表面的涂层14。涂层14包括与基材12表面相连接的镀膜层142,形成于镀膜层142上的粘合层144,及形成于粘合层144上且处于外表面的外覆层146。其中,镀膜层142的厚度可为10纳米至10微米,粘合层144的厚度可为1微米至20微米,外覆层146的厚度可为10微米至80微米。
基材12的材质可为玻璃、陶瓷、聚碳酸酯、聚丙烯腈-丁二烯-苯乙烯、聚甲基丙烯酸甲酯及玻璃纤维-尼龙复合材料之一或其组合物。此外,为确保壳体10具有较好的外观,基材12与镀膜层142相接的表面最好较为光滑。
镀膜层142可为导电层或电绝缘层,其材质可为锡、铝、硅铝合金、钛、碳化钛、氮化钛、镉、铟、二氧化硅及不锈钢之一或其组合物。
粘合层144的材质可由含氯聚烯烃(如聚氯乙烯,聚氯丙稀)构成,或由1%至99%的含氯聚烯烃及其他材质构成,该其他材质可为羟基聚合物、胺基聚合物、羧基聚合物及环氧基聚合物之一或其组合。
一种可制备壳体10的表面处理方法包括以下步骤:
步骤一,在基材12的表面真空沉积一层镀膜层142。其中沉积的方式可为物理气相沉积(Physical Vapor Deposition)、绝缘真空镀膜(Non ConductiveVacuum Metallization)或化学气相沉积(Chemical Vapor Deposition)。其中当采用物理气相沉积或绝缘真空镀膜形成镀膜层142时,可用锡、铝、硅铝合金、钛、碳化钛、氮化钛、镉、铟、二氧化硅及不锈钢之一或其组合物为靶材,用磁控溅射、等离子溅镀或蒸镀的方式把靶材沉积到基材12上形成镀膜层142。需要重点说明的是,用绝缘真空镀膜方法沉积的镀膜层142可为电绝缘层。
步骤二,在镀膜层142上涂布粘合剂,形成一层粘合层144。该步骤可在常温下进行。该粘合剂可全部由含氯聚烯烃构成(如聚氯乙烯,聚氯丙稀),或由1%至99%的含氯聚烯烃及其他物质构成,该其他物质可为羟基聚合物、胺基聚合物、羧基聚合物、环氧基聚合物之一或其组合。
步骤三,在粘合层144上涂布面漆,形成一层外覆层146。其中涂布方式可为喷涂或手涂。该面漆可以是透明漆或色漆,一般选用主要成分为丙烯酸树脂的面漆。将面漆涂布在粘合层144上后,可再依次经过流平、固化等步骤来形成外覆层146。固化方式可为热固化或光固化,例如当该面漆为紫外线固化漆时,面漆的固化就采用紫外线固化。
上述壳体10,由于在镀膜层142与外覆层146之间形成有粘合层144,粘合层144可增强镀膜层142与外覆层146之间的结合力,因此可防止或减少外覆层146在使用时脱落,避免镀膜层142被损坏,从而确保产品具有较好的外观。
具体在本实施方式中,粘合层144包括含氯聚烯烃,含氯聚烯烃的氯可与镀膜层142中的金属原子相作用形成具有较强作用力的化学键,且含氯聚烯烃中的有机分子链可与外覆层146的有机分子链相互吸引形成较强的结合力,因此粘合层144可使外覆层146与镀膜层142的结合力增强,从而防止外覆层146从基材12上脱落,避免或减少镀膜层142被氧化或腐蚀。并且由于粘合层144是由聚合物材料组成,其还具有一定的弹性,因此会增加处于外表面的外覆层146的柔软度,从而提升壳体10的手感。
另外,在壳体10的表面处理过程中,通过使用不同的靶材来沉积镀膜层142或改变面漆的颜色,还易于对壳体10的颜色进行变更,从而满足不同的外观需求。以及采用绝缘真空镀膜法形成绝缘镀膜层142时,绝缘镀膜层142可让电磁信号穿过,因此其不会影响便携式电子装置的射频(RF)性能与电磁相容(ESD)性能。
请参见图2,所示为本发明较佳实施方式二的壳体20。壳体20与壳体10相似,包括基材22与涂层24,涂层24包括镀膜层242、粘合层244及外覆层246,其不同点在于:涂层24还包括一底层241。底层241形成在基材22的表面,处于基材22与镀膜层242之间。底层241的厚度可为1微米至30微米。表面处理过程是先在基材22上涂布底漆,并依次经过流平、固化等步骤形成底层241,然后再依次在底层241沉积镀膜层242,涂布粘合剂形成粘合层244及涂布面漆形成外覆层246。其中底漆的主要成份可为丙烯酸树脂,固化方式可为热固化或光固化。可以理解,在壳体20中,由于存在底层241,因此基材22与底层241的相接表面即使为粗糙面也可确保壳体20具有较好的外观。
可以理解,上述表面处理方法并不限于制备壳体,例如其还可用于处理部分表面处于设备外部的零件的表面。
另外,本领域技术人员还可在本发明精神内做其他变化,当然,这些依据本发明精神所做的变化,都应包含在本发明所要求保护的范围内。
Claims (8)
1.一种壳体,其包括基材及形成于该基材表面的涂层,该涂层包括靠近该基材的镀膜层与处于外表面的外覆层,其特征在于:该涂层在该镀膜层与该外覆层之间还包括一粘合层,该粘合层的材质包括含氯聚烯烃。
2.如权利要求1所述的壳体,其特征在于:该基材的材质为玻璃、陶瓷、聚碳酸酯、聚丙烯腈-丁二烯-苯乙烯、聚甲基丙烯酸甲酯、及玻璃纤维-尼龙复合材料之一或其组合物。
3.如权利要求1所述的壳体,其特征在于:该粘合层的材质还包括羟基聚合物、胺基聚合物、羧基聚合物及环氧基聚合物之一或其组合。
4.如权利要求1所述的壳体,其特征在于:该镀膜层的材质为锡、铝、硅铝合金、钛、碳化钛、氮化钛、镉、铟、二氧化硅及不锈钢之一或其组合物。
5.如权利要求1所述的壳体,其特征在于:该涂层可包括一层底层,其位于该基材与该镀膜层之间。
6.一种表面处理方法,其包括以下步骤:
在一基材表面沉积一层镀膜层;
在该镀膜层上涂布粘合剂,形成粘合层,该粘合剂包括含氯聚烯烃;及
在该粘合层上涂布面漆,形成外覆层。
7.如权利要求6所述的表面处理方法,其特征在于:该沉积为物理气相沉积或绝缘真空镀膜。
8.一种表面处理方法,其包括以下步骤:
在一基材表面涂布底漆,形成一层底层;
在该底层沉积一层镀膜层;
在该镀膜层上涂布粘合剂,形成一层粘合层;及
在该粘合层上涂布面漆,形成外覆层。
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US11/966,969 US7923086B2 (en) | 2007-10-25 | 2007-12-28 | Housing and surface treating method for making the same |
US13/041,542 US20110151120A1 (en) | 2007-10-25 | 2011-03-07 | Surface treating method for making the same |
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CN101730409A (zh) * | 2008-10-17 | 2010-06-09 | 深圳富泰宏精密工业有限公司 | 壳体及其制造方法 |
TW201023716A (en) * | 2008-12-12 | 2010-06-16 | Fih Hong Kong Ltd | Housing for electronic device and method for making the same |
CN101959378A (zh) * | 2009-07-14 | 2011-01-26 | 深圳富泰宏精密工业有限公司 | 壳体的制作方法及由该方法制得的壳体 |
CN102076185B (zh) * | 2009-11-20 | 2014-12-10 | 深圳富泰宏精密工业有限公司 | 壳体的制作方法及由该方法制得的壳体 |
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US9671838B2 (en) * | 2013-01-10 | 2017-06-06 | Dell Products L.P. | Composite chassis for lowering surface temperature |
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CN104540341A (zh) * | 2014-10-23 | 2015-04-22 | 深圳富泰宏精密工业有限公司 | 壳体、应用该壳体的电子装置及其制作方法 |
CN104602476B (zh) * | 2014-12-23 | 2017-06-13 | 深圳富泰宏精密工业有限公司 | 壳体、应用该壳体的电子装置及其制作方法 |
CN114096092A (zh) * | 2021-11-18 | 2022-02-25 | Oppo广东移动通信有限公司 | 电子设备壳体及其制备方法、电子设备 |
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US20110151120A1 (en) | 2011-06-23 |
US7923086B2 (en) | 2011-04-12 |
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