CN101336282A - 使用具有新型反应器分离系统的反应器对重油进行改质的方法 - Google Patents

使用具有新型反应器分离系统的反应器对重油进行改质的方法 Download PDF

Info

Publication number
CN101336282A
CN101336282A CNA2006800518885A CN200680051888A CN101336282A CN 101336282 A CN101336282 A CN 101336282A CN A2006800518885 A CNA2006800518885 A CN A2006800518885A CN 200680051888 A CN200680051888 A CN 200680051888A CN 101336282 A CN101336282 A CN 101336282A
Authority
CN
China
Prior art keywords
oil
reactor
slurry
hydrogen
logistics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2006800518885A
Other languages
English (en)
Inventor
D·法希德
J·墨菲
B·雷诺兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Publication of CN101336282A publication Critical patent/CN101336282A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
    • C10G49/12—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G63/00—Treatment of naphtha by at least one reforming process and at least one other conversion process
    • C10G63/02—Treatment of naphtha by at least one reforming process and at least one other conversion process plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1033—Oil well production fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1077—Vacuum residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

申请人已经开发了新型渣油完全加氢转化浆料反应器系统，该系统允许所述催化剂、未转化的油、氢气和转化了的油以连续混合物在整个反应器循环，而对所述混合物没有限制。所述混合物在一个或多个所述反应器的内部被分离，以便仅分离出所述转化了的油和氢气进入蒸气产物，而允许未转化的油和浆料催化剂作为液体产物继续进入下一个后续反应器。然后在下一个反应器中将一部分未转化的油转化成较低沸点的烃，再一次产生未转化的油、氢气、转化了的油和浆料催化剂的混合物。可以在额外的反应器中进行进一步加氢处理，完全转化所述油。所述油可以被交替地部分转化，在未转化的油中留下浓缩的催化剂，可将其直接再循环至所述第一反应器。

Description

使用具有新型反应器分离系统的反应器对重油进行改质的方法
发明领域
本发明涉及使用浆料催化剂组合物对重油进行改质的方法。
发明背景
由于全世界对于石油产品的更大的需求，目前对于重油加工的兴趣提高了。加拿大和委内瑞拉是重油的来源地。导致重油原料完全转化为有用产品的方法是特别令人感兴趣的。
美国专利号6278034陈述了加氢工艺，其采用具有将气体产物与油和催化剂的浆料分开的内部装置的反应器。
下面的专利申请，在此引用作为参考，涉及高活性浆料催化剂组合物的制备和它们在重油改质方法中的用途：
美国专利序列号10/938202涉及适合于重油加氢转化的催化剂组合物的制备。所述催化剂组合物通过一系列步骤制备，包括混合VIB族金属和氨水以形成含水混合物，并硫化所述混合物以形成浆料。然后用VIII族金属促进所述浆料。随后的步骤包括将所述浆料与烃油混合，并使得到的混合物与氢气和第二种烃油混合，其中所述第二种烃油比所述第一种油的粘度低。从而制得活性催化剂组合物。
美国专利序列号10/938003涉及浆料催化剂组合物的制备。所述浆料催化剂组合物在一系列步骤中制备，包括混合VIB族金属氧化物和氨水以形成含水混合物并硫化所述混合物以形成浆料。然后用VIII族金属促进所述浆料。随后的步骤包括使所述浆料与烃油混合，并使得到的混合物与氢气(在维持水为液相的条件下)混合以生成活性浆料催化剂。
美国专利序列号10/938438涉及将浆料催化剂组合物用于重油改质的方法。不允许所述浆料催化剂组合物沉降，沉降可能导致失活。将所述浆料再循环至改质反应器来重复使用，且产物不需要进一步分离程序来除去催化剂。
美国专利序列号10/938200涉及使用浆料组合物进行重油改质的方法。所述浆料组合物在一系列步骤中制备，包括混合VIB族金属氧化物和氨水以形成含水混合物并硫化所述混合物以形成浆料。然后用VIII族金属化合物促进所述浆料。随后的步骤包括使所述浆料与烃油混合，并使得到的混合物与氢气(在维持水为液相的条件下)混合以生成活性浆料催化剂。
美国专利序列号10/938269涉及使用浆料组合物进行重油改质的方法。所述浆料组合物通过一系列步骤中制备，包括混合VIB族金属氧化物和氨水以形成含水混合物，和硫化所述混合物以形成浆料。然后用VIII族金属促进所述浆料。随后的步骤包括使所述浆料与烃油混合，并使得到的混合物与氢气和第二种烃油混合，其中所述第二种烃油比所述第一种油的粘度低。由此生成活性催化剂组合物。
发明概述
重油的加氢转化方法，所述方法采用内部具有分离器的上流式反应器，所述分离器用来进行相分离。可采用至少一个具有内部分离器的反应器，尽管更通常使用多个串联反应器。使用多个串联反应器的加氢转化方法可采用以下步骤：
(a)使加热后的重油原料、活性浆料催化剂组合物和含氢气体混合以形成混合物；
(b)使步骤(a)的混合物进入反应器的底部，所述反应器维持在包括升高的温度和压力在内的加氢处理条件下；
(c)在所述反应器内部将包含反应产物、氢气、未转化的油和浆料催化剂的物流分成两股物流：包含反应产物和氢气的蒸气物流，和包含未转化的物料和浆料催化剂的液体物流；
(d)将所述蒸气物流从顶部送去进一步加工，并将所述液体物流的至少一部分送到下一个串联的反应器中。
本发明打算在所描述的工艺方案中在一个或多个反应器内进行相分离，以使得单一的蒸气相产物是离开所述反应器顶部的唯一产物。液相产物是离开所述反应器的较低部分(经过底部或侧线)的用于进一步加工的唯一物流。如果进行内部分离，不需要热的高压分离器或闪蒸罐来分离所述相，然后它们离开所述反应器。
本发明还采用了反应器差压控制系统，该系统调节离开所述反应器顶部的蒸气产物，因此不再需要通往下一个反应器的原料物流的控制阀。
附图简述
附图显示了应用至多个串联的反应器系统的本发明的工艺方案。
发明详述
本发明涉及催化剂活化的浆料加氢裂化方法。气体反应产物与包含未转化的油和催化剂的液体物流的级间分离对于维持工艺中的热平衡是有效的。在附图中，物流1包含重原料，例如减压渣油。其它原料可以包括常压渣油、减压渣油、来自溶剂脱沥青单元的焦油、常压瓦斯油、减压瓦斯油、脱沥青油、烯烃、衍生自焦油砂或沥青的油、衍生自煤的油、重原油、来自费-托工艺的合成油以及衍生自回收废油和聚合物的油。
所述原料进入炉80中加热，并以物流4离开。物流4与含氢气体(物流2)、再循环浆料(物流17)和包含活性浆料组合物的物流(物流3)混合，得到混合物(物流24)。物流24进入所述第一反应器10的底部。由于所述反应器内部的分离装置(未示出)，主要包含反应产物和氢气的蒸气物流31离开所述反应器的顶部。液体物流26，其含有与未转化的油混合的浆料，离开反应器10的底部或侧线。
物流26与包含氢气的气体物流(物流15)混合产生物流27。物流27进入第二反应器20的底部。
主要包含反应产物和氢气的蒸气物流8，离开所述反应器20的顶部并汇入来自反应器20的蒸气产物。液体物流27，其含有与未转化的油混合的浆料，离开反应器20的底部或侧线。
物流32与包含氢气的气体物流(物流16)混合产生物流28。物流28进入反应器30的底部。蒸气物流12，其主要包含反应产物和氢气，离开所述反应器的顶部并汇入来自前两个反应器的作为物流14的蒸气产物。液体物流17，其含有与未转化的油混合的浆料，离开反应器30的底部或侧线。该物流的一部分可以作为物流18排放，或作为物流17再循环回所述第一反应器10。
来自反应器10、20和30的顶部物流(分别为物流31、8和12)产生物流14，该物流进入下游设备进一步加工。
本发明中优选的反应器类型是液体循环反应器，但也可以使用其它类型的上流式反应器。液体循环反应器在同时待审的申请S.N.-(T-6493)中有进一步讨论，将该申请引入供参考。
液体循环反应器是上流式反应器，其在升高了的压力和温度下进料重烃油和富氢气体用于加氢转化。用于该液体循环反应器的工艺条件包括：压力为1500-3500psia，优选2000-3000psia。温度为700-900F，优选775-850F。
加氢转化包括例如加氢裂化和除去杂原子污染物(例如硫和氮)的工艺。在浆料催化剂的使用中，催化剂颗粒非常小(1-10微米)。可以使用泵来循环浆料，但通常不需要用泵。
在本发明中使用的催化剂浆料组合物的制备方法陈述于美国专利序列号10/938003和美国专利序列号10/938202中，将它们引入供参考。所述催化剂组合物用于但不限于加氢改质工艺，例如加氢裂化、加氢处理、加氢脱硫、加氢脱氮和加氢脱金属。

Claims (11)

1.重油的加氢转化方法，所述方法采用带有分离器的多个上流式反应器，所述分离器位于至少一个反应器的内部，所述方法包括以下步骤：
(a)使加热后的重油原料、活性浆料催化剂组合物和含氢气体混合以形成混合物；
(b)使步骤(a)的混合物进入所述第一反应器的底部，所述第一反应器维持在包括升高的温度和压力在内的加氢处理条件下；
(c)在所述第一反应器内部将包含反应产物、氢气、未转化的物料和浆料催化剂的物流分成两股物流：包含反应器产物和氢气的蒸气物流，和包含未转化的物料和浆料催化剂的液体物流；
(d)将所述蒸气物流从顶部送去进一步加工，并使包含未转化的物料和浆料催化剂的所述液体物流作为底部物流从所述第一反应器流出；
(e)将步骤(d)的所述液体物流的至少一部分送至所述第二反应器的底部，所述第二反应器维持在包括升高的温度和压力在内的加氢处理条件下；
(f)在所述第二反应器内部将包含反应产物、氢气、未转化的物料和浆料催化剂的物流分成两股物流：包含反应器产物和氢气的蒸气物流，和包含未转化的物料和浆料催化剂的液体物流；
(g)将所述蒸气物流从顶部送去进一步加工，并使包含未转化的物料和浆料催化剂的所述液体物流作为底部物流从所述第二反应器送去进一步加工。
2.权利要求1的方法，其中将步骤(g)的液体物流再循环至步骤(a)，步骤(a)的混合物还包含再循环的未转化的物料和浆料催化剂。
3.权利要求1的方法，其中第三反应器的底部维持在包括升高的温度和压力在内的浆料加氢处理条件下。
4.权利要求1的方法，其中所述循环反应器使用泵。
5.权利要求1的方法，其中在每个反应器中所采用的加氢处理条件包括1500-3500psia的总压和700-900F的反应温度。
6.权利要求5的方法，其中优选的总压为200-3000psia，和优选的温度为775-850F。
7.权利要求1的加氢转化方法，其中所述重油选自常压渣油、减压渣油、来自溶剂脱沥青单元的焦油、常压瓦斯油、减压瓦斯油、脱沥青油、烯烃、衍生自焦油砂或沥青的油、衍生自煤的油、重原油、来自费-托工艺的合成油以及衍生自回收废油和聚合物的油。
8.权利要求1的加氢转化方法，其中所述方法选自加氢裂化、加氢处理、加氢脱硫、加氢脱氮和加氢脱金属。
9.权利要求1的方法，其中权利要求1的活性浆料催化剂组合物通过以下步骤来制备：
(a)混合VIB族金属氧化物和氨水以形成VIB族金属化合物的含水混合物；
(b)在初始反应区域中，用包含硫化氢的气体将步骤(a)的含水混合物硫化至大于8SCF硫化氢每磅VIB族金属的剂量，以形成浆料；
(c)用VIII族金属化合物促进所述浆料；
(d)将步骤(c)的浆料与在212°F下粘度至少为2cSt的烃油混合以形成中间混合物；
(e)在第二反应区中在维持所述中间混合物中的水为液相的条件下将所述中间混合物与氢气混合，从而形成与液体烃混合的活性催化剂组合物；和
(f)回收所述活性催化剂组合物。
10.权利要求1的方法，其中至少90wt％的原料转化为更低沸点的产物。
11.权利要求1的加氢转化方法，其中所述重油选自常压渣油、减压渣油、来自溶剂脱沥青单元的焦油、常压瓦斯油、减压瓦斯油、脱沥青油、烯烃、衍生自焦油砂或沥青的油、衍生自煤的油、重原油、来自费-托工艺的合成油以及衍生自回收废油和聚合物的油。
CNA2006800518885A 2005-12-16 2006-12-08 使用具有新型反应器分离系统的反应器对重油进行改质的方法 Pending CN101336282A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/303,427 US7431822B2 (en) 2005-12-16 2005-12-16 Process for upgrading heavy oil using a reactor with a novel reactor separation system
US11/303,427 2005-12-16

Publications (1)

Publication Number Publication Date
CN101336282A true CN101336282A (zh) 2008-12-31

Family

ID=38172201

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2006800518885A Pending CN101336282A (zh) 2005-12-16 2006-12-08 使用具有新型反应器分离系统的反应器对重油进行改质的方法

Country Status (10)

Country Link
US (2) US7431822B2 (zh)
EP (1) EP1960498A4 (zh)
JP (1) JP2009520062A (zh)
KR (1) KR101343167B1 (zh)
CN (1) CN101336282A (zh)
BR (1) BRPI0619988A2 (zh)
CA (1) CA2633902C (zh)
EA (1) EA013065B1 (zh)
NO (1) NO20083158L (zh)
WO (1) WO2007078621A2 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109027691A (zh) * 2018-08-16 2018-12-18 北京航天石化技术装备工程有限公司 一种减压系统的高压热力平衡方法

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010033480A2 (en) * 2008-09-18 2010-03-25 Chevron U.S.A. Inc. Systems and methods for producing a crude product
US20100122934A1 (en) * 2008-11-15 2010-05-20 Haizmann Robert S Integrated Solvent Deasphalting and Slurry Hydrocracking Process
US8110090B2 (en) * 2009-03-25 2012-02-07 Uop Llc Deasphalting of gas oil from slurry hydrocracking
US8658030B2 (en) * 2009-09-30 2014-02-25 General Electric Company Method for deasphalting and extracting hydrocarbon oils
US8491783B2 (en) * 2010-01-21 2013-07-23 Shell Oil Company Process for treating a hydrocarbon-containing feed
CA2785761C (en) 2010-01-21 2018-10-23 Shell Internationale Research Maatschappij B.V. Hydrocarbon composition
CA2785583C (en) * 2010-01-21 2018-10-23 Shell Internationale Research Maatschappij B.V. Hydrocarbon composition
US8940268B2 (en) * 2010-01-21 2015-01-27 Shell Oil Company Process for producing a thiometallate or a selenometallate material
EP2525906A2 (en) * 2010-01-21 2012-11-28 Shell Oil Company Nano-tetrathiometallate or nano-tetraselenometallate material
US8597498B2 (en) * 2010-01-21 2013-12-03 Shell Oil Company Process for treating a hydrocarbon-containing feed
EP2526169A2 (en) * 2010-01-21 2012-11-28 Shell Oil Company Process for cracking a hydrocarbon- containing feed
EP2526061B1 (en) * 2010-01-21 2015-09-16 Shell Oil Company Process for producing a thiometallate or a selenometallate material
CA2785580A1 (en) * 2010-01-21 2011-07-28 Shell Internationale Research Maatschappij B.V. Process for treating a hydrocarbon-containing feed
CA2784140C (en) * 2010-01-21 2018-01-09 Shell Internationale Research Maatschappij B.V. Process for producing a copper thiometallate or a selenometallate material
WO2011091221A2 (en) 2010-01-21 2011-07-28 Shell Oil Company Manganese tetrathiotungstate material
US8491784B2 (en) * 2010-01-21 2013-07-23 Shell Oil Company Process for treating a hydrocarbon-containing feed
WO2011091210A2 (en) * 2010-01-21 2011-07-28 Shell Oil Company Process for treating a hydrocarbon-containing feed
SG182268A1 (en) * 2010-01-21 2012-08-30 Shell Int Research Hydrocarbon composition
US8815184B2 (en) 2010-08-16 2014-08-26 Chevron U.S.A. Inc. Process for separating and recovering metals
EP2648843A1 (en) 2010-12-10 2013-10-16 Shell Oil Company Hydrocracking of a heavy hydrocarbon feedstock using a copper molybdenum sulfided catalyst
US8858784B2 (en) 2010-12-10 2014-10-14 Shell Oil Company Process for treating a hydrocarbon-containing feed
CA2820266A1 (en) 2010-12-10 2012-06-14 Shell Internationale Research Maatschappij B.V. Process for treating a hydrocarbon-containing feed
CN104471035B (zh) * 2012-05-04 2017-03-08 沙特阿拉伯石油公司 用于全原油提质的集成式沸腾床工艺
US8936714B2 (en) * 2012-11-28 2015-01-20 Uop Llc Process for producing diesel
ITMI20130131A1 (it) 2013-01-30 2014-07-31 Luigi Patron Processo a migliorata produttività per la conversione di olii pesanti
CA2843041C (en) 2013-02-22 2017-06-13 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US9364773B2 (en) 2013-02-22 2016-06-14 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US11440815B2 (en) 2013-02-22 2022-09-13 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US9708196B2 (en) 2013-02-22 2017-07-18 Anschutz Exploration Corporation Method and system for removing hydrogen sulfide from sour oil and sour water
US20140238897A1 (en) * 2013-02-26 2014-08-28 Chevron U.S.A. Inc. Reconfiguration of recirculation stream in upgrading heavy oil
US8815185B1 (en) 2013-03-04 2014-08-26 Chevron U.S.A. Inc. Recovery of vanadium from petroleum coke slurry containing solubilized base metals
US20150075450A1 (en) * 2013-09-13 2015-03-19 Uop Llc Heat recovery from a high pressure stream
KR102339837B1 (ko) * 2013-11-25 2021-12-15 사우디 아라비안 오일 컴퍼니 업그레이딩 공정에 수소처리 단계를 부가하여 중유의 향상된 업그레이딩 방법
CN105316037B (zh) * 2014-07-30 2018-01-09 中国石化工程建设有限公司 渣油加氢的方法
EP3328968A1 (en) 2015-07-27 2018-06-06 Saudi Arabian Oil Company Integrated ebullated-bed hydroprocessing, fixed bed hydroprocessing and coking process for whole crude oil conversion into hydrotreated distillates and petroleum green coke
WO2017024061A1 (en) * 2015-08-04 2017-02-09 P.D. Technology Development, Llc Hydroprocessing method with high liquid mass flux
CN106876710B (zh) * 2016-12-22 2020-03-24 湖南中科星城石墨有限公司 一种用于锂离子电池的软碳负极材料及其制备方法
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US10597590B2 (en) * 2017-11-14 2020-03-24 Uop Llc Process and apparatus for stripping slurry hydrocracked product
KR102088997B1 (ko) * 2018-07-17 2020-03-13 한국화학연구원 수첨분해반응용 촉매 전구체 및 이를 이용한 중질유의 수첨분해방법
RU2699226C1 (ru) * 2018-12-27 2019-09-04 Акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" (АО "ВНИИ НП") Способ гидрогенизационного облагораживания остаточного нефтяного сырья
TW202117027A (zh) 2019-07-08 2021-05-01 美商雪維隆美國有限公司 自廢催化劑回收金屬
CN112745955B (zh) * 2019-10-31 2023-04-07 中国石油化工股份有限公司 一种利用催化裂化油浆的方法和系统

Family Cites Families (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2909476A (en) * 1954-12-13 1959-10-20 Exxon Research Engineering Co Upgrading of crude petroleum oil
US3215617A (en) * 1962-06-13 1965-11-02 Cities Service Res & Dev Co Hydrogenation cracking process in two stages
BE759284A (fr) * 1969-11-24 1971-05-24 Shell Int Research Procede et appareil pour la mise en contact d'un liquide avec des particules solides
US4151070A (en) * 1977-12-20 1979-04-24 Exxon Research & Engineering Co. Staged slurry hydroconversion process
US4221653A (en) * 1978-06-30 1980-09-09 Hydrocarbon Research, Inc. Catalytic hydrogenation process and apparatus with improved vapor liquid separation
US4457831A (en) * 1982-08-18 1984-07-03 Hri, Inc. Two-stage catalytic hydroconversion of hydrocarbon feedstocks using resid recycle
US4485004A (en) 1982-09-07 1984-11-27 Gulf Canada Limited Catalytic hydrocracking in the presence of hydrogen donor
US4592827A (en) 1983-01-28 1986-06-03 Intevep, S.A. Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water
US4710486A (en) 1983-08-29 1987-12-01 Chevron Research Company Process for preparing heavy oil hydroprocessing slurry catalyst
US5164075A (en) 1983-08-29 1992-11-17 Chevron Research & Technology Company High activity slurry catalyst
US4824821A (en) * 1983-08-29 1989-04-25 Chevron Research Company Dispersed group VIB metal sulfide catalyst promoted with Group VIII metal
US4970190A (en) 1983-08-29 1990-11-13 Chevron Research Company Heavy oil hydroprocessing with group VI metal slurry catalyst
US5178749A (en) 1983-08-29 1993-01-12 Chevron Research And Technology Company Catalytic process for treating heavy oils
US5162282A (en) 1983-08-29 1992-11-10 Chevron Research And Technology Company Heavy oil hydroprocessing with group VI metal slurry catalyst
US5484755A (en) * 1983-08-29 1996-01-16 Lopez; Jaime Process for preparing a dispersed Group VIB metal sulfide catalyst
US4684456A (en) 1985-12-20 1987-08-04 Lummus Crest Inc. Control of bed expansion in expanded bed reactor
US4765882A (en) * 1986-04-30 1988-08-23 Exxon Research And Engineering Company Hydroconversion process
US5041404A (en) 1988-09-13 1991-08-20 Cri Ventures, Inc. Method of presulfiding a hydrotreating, hydrocracking or tail gas treating catalyst
US4943547A (en) 1988-09-13 1990-07-24 Seamans James D Method of presulfiding a hydrotreating catalyst
US5039392A (en) 1990-06-04 1991-08-13 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate
US5298152A (en) 1992-06-02 1994-03-29 Chevron Research And Technology Company Process to prevent catalyst deactivation in activated slurry hydroprocessing
CA2104044C (en) * 1992-08-25 2004-11-02 Johan W. Gosselink Process for the preparation of lower olefins
US5527473A (en) * 1993-07-15 1996-06-18 Ackerman; Carl D. Process for performing reactions in a liquid-solid catalyst slurry
US6270654B1 (en) 1993-08-18 2001-08-07 Ifp North America, Inc. Catalytic hydrogenation process utilizing multi-stage ebullated bed reactors
US5374348A (en) 1993-09-13 1994-12-20 Energy Mines & Resources - Canada Hydrocracking of heavy hydrocarbon oils with heavy hydrocarbon recycle
US5871638A (en) * 1996-02-23 1999-02-16 Hydrocarbon Technologies, Inc. Dispersed anion-modified phosphorus-promoted iron oxide catalysts
US6139723A (en) * 1996-02-23 2000-10-31 Hydrocarbon Technologies, Inc. Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
US6190542B1 (en) * 1996-02-23 2001-02-20 Hydrocarbon Technologies, Inc. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds
US5914010A (en) 1996-09-19 1999-06-22 Ormat Industries Ltd. Apparatus for solvent-deasphalting residual oil containing asphaltenes
DE69708829T2 (de) 1996-12-27 2002-04-04 Inst Francais Du Petrole Wasserstoffbehandlung und Hydrocrackkatalysator enthaltend ein Mischsulfid mit Schwefel, zumindest ein Element der Gruppe 5B und zumindest ein Element der Gruppe 6B
ZA98586B (en) * 1997-02-20 1999-07-23 Sasol Tech Pty Ltd "Hydrogenation of hydrocarbons".
US5954945A (en) 1997-03-27 1999-09-21 Bp Amoco Corporation Fluid hydrocracking catalyst precursor and method
US5925238A (en) 1997-05-09 1999-07-20 Ifp North America Catalytic multi-stage hydrodesulfurization of metals-containing petroleum residua with cascading of rejuvenated catalyst
US6712955B1 (en) 1997-07-15 2004-03-30 Exxonmobil Research And Engineering Company Slurry hydroprocessing using bulk multimetallic catalysts
US7229548B2 (en) * 1997-07-15 2007-06-12 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US6620313B1 (en) 1997-07-15 2003-09-16 Exxonmobil Research And Engineering Company Hydroconversion process using bulk group VIII/Group VIB catalysts
US6758963B1 (en) 1997-07-15 2004-07-06 Exxonmobil Research And Engineering Company Hydroprocessing using bulk group VIII/group vib catalysts
US6156695A (en) 1997-07-15 2000-12-05 Exxon Research And Engineering Company Nickel molybdotungstate hydrotreating catalysts
US6635599B1 (en) 1997-07-15 2003-10-21 Exxonmobil Research & Engineering Company Mixed metal catalyst, its preparation by co-precipitation, and its use
US6755963B2 (en) 1997-07-15 2004-06-29 Exxonmobil Chemical Patents Inc. Hydrogenation process for hydrocarbon resins
US7232515B1 (en) 1997-07-15 2007-06-19 Exxonmobil Research And Engineering Company Hydrofining process using bulk group VIII/Group VIB catalysts
US6162350A (en) 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US5935418A (en) 1997-08-29 1999-08-10 Exxon Research And Engineering Co. Slurry hydroprocessing
DE69920489T2 (de) 1998-07-29 2005-12-01 Texaco Development Corp. Integriertes lösungsmittelentasphaltierungs- und vergasungsverfahren
US6156693A (en) 1998-10-09 2000-12-05 Penn State Research Foundation Method for preparing a highly active, unsupported high-surface-area ub. MoS.s2 catalyst
US6291391B1 (en) 1998-11-12 2001-09-18 Ifp North America, Inc. Method for presulfiding and preconditioning of residuum hydroconversion catalyst
US5977192A (en) 1998-11-13 1999-11-02 Exxon Research And Engineering Co. Small catalyst particle addition to slurry reactor
US6630066B2 (en) 1999-01-08 2003-10-07 Chevron U.S.A. Inc. Hydrocracking and hydrotreating separate refinery streams
US6534437B2 (en) 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
US6554994B1 (en) 1999-04-13 2003-04-29 Chevron U.S.A. Inc. Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks
US6299760B1 (en) 1999-08-12 2001-10-09 Exxon Research And Engineering Company Nickel molybodtungstate hydrotreating catalysts (law444)
US6277895B1 (en) * 1999-09-21 2001-08-21 Hydrocarbon Technologies, Inc. Skeletal iron catalyst having improved attrition resistance and product selectivity in slurry-phase synthesis processes
US6451729B1 (en) 1999-10-06 2002-09-17 The Penn State Research Foundation Method for preparing a highly active, unsupported high surface-area MoS2 catalyst
US20030129109A1 (en) 1999-11-01 2003-07-10 Yoram Bronicki Method of and apparatus for processing heavy hydrocarbon feeds description
FR2803596B1 (fr) * 2000-01-11 2003-01-17 Inst Francais Du Petrole Procede de conversion de fractions petrolieres comprenant une etape d'hydroconversion lit bouillonnant, une etape de separation, une etape d'hydrodesulfuration et une etape de craquage
US6726832B1 (en) 2000-08-15 2004-04-27 Abb Lummus Global Inc. Multiple stage catalyst bed hydrocracking with interstage feeds
CN1098337C (zh) * 2000-11-02 2003-01-08 中国石油天然气股份有限公司 一种采用多金属液体催化剂的常压重油悬浮床加氢新工艺
US7166209B2 (en) 2001-03-01 2007-01-23 Intevep, S.A. Hydroprocessing process
US6755962B2 (en) 2001-05-09 2004-06-29 Conocophillips Company Combined thermal and catalytic treatment of heavy petroleum in a slurry phase counterflow reactor
ITMI20011438A1 (it) 2001-07-06 2003-01-06 Snam Progetti Procedimento per la conversione di cariche pesanti quali i graggi pesanti e i residui di distillazione
FR2843050B1 (fr) 2002-08-01 2005-04-15 Inst Francais Du Petrole Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde
US7922894B2 (en) 2002-12-06 2011-04-12 Albemarle Netherlands, B.V. HPC process using a mixture of catalysts
PL205245B1 (pl) 2002-12-20 2010-03-31 Eni Spa Sposób konwersji ciężkich surowców węglowodorowych lub węglowych
RU2352615C2 (ru) 2002-12-20 2009-04-20 Эни С.П.А. Способ переработки тяжелого сырья, такого как тяжелая сырая нефть и кубовые остатки
US7214308B2 (en) 2003-02-21 2007-05-08 Institut Francais Du Petrole Effective integration of solvent deasphalting and ebullated-bed processing
FR2851569B1 (fr) 2003-02-21 2007-04-20 Inst Francais Du Petrole Procede d'hydrocraquage en deux etapes utilisant un catalyseur amorphe a base de platine et de palladium
US20050075527A1 (en) * 2003-02-26 2005-04-07 Institut Francais Du Petrole Method and processing equipment for hydrocarbons and for separation of the phases produced by said processing
WO2005023416A1 (en) 2003-04-07 2005-03-17 Board Of Regents, The University Of Texas System Molybdenum sulfide/carbide catalysts
US7150823B2 (en) 2003-07-02 2006-12-19 Chevron U.S.A. Inc. Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream
US7435330B2 (en) 2003-10-07 2008-10-14 Hitachi, Ltd. Heavy oil reforming method, an apparatus therefor, and gas turbine power generation system
US20070000810A1 (en) 2003-12-19 2007-01-04 Bhan Opinder K Method for producing a crude product with reduced tan
US20070000808A1 (en) 2003-12-19 2007-01-04 Bhan Opinder K Method and catalyst for producing a crude product having selected properties
US7763160B2 (en) 2003-12-19 2010-07-27 Shell Oil Company Systems and methods of producing a crude product
US20050167328A1 (en) 2003-12-19 2005-08-04 Bhan Opinder K. Systems, methods, and catalysts for producing a crude product
US20060289340A1 (en) 2003-12-19 2006-12-28 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
US20070012595A1 (en) 2003-12-19 2007-01-18 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
US7413669B2 (en) 2004-04-06 2008-08-19 Intevep, S.A. Separator for liquids and/or multiphase fluids
EP1753846B1 (en) * 2004-04-28 2016-06-08 Headwaters Heavy Oil, LLC Ebullated bed hydroprocessing methods and systems
WO2005104786A2 (en) 2004-04-28 2005-11-10 Headwaters Heavy Oil, Llc Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
CN1950484A (zh) 2004-04-28 2007-04-18 上游重油有限公司 使用胶体催化剂或分子催化剂提高重油品质的加氢处理法和系统
US7358413B2 (en) 2004-07-14 2008-04-15 Exxonmobil Chemical Patents Inc. Process for reducing fouling from flash/separation apparatus during cracking of hydrocarbon feedstocks
KR20070104517A (ko) 2004-09-08 2007-10-26 쉘 인터내셔날 리써취 마트샤피지 비.브이. 수소화분해 촉매 조성물
US7238273B2 (en) 2004-09-10 2007-07-03 Chevron U.S.A. Inc Process for upgrading heavy oil using a highly active slurry catalyst composition
FR2875509B1 (fr) 2004-09-20 2006-11-24 Inst Francais Du Petrole Procede d'hydroconversion d'une charge lourde avec un catalyseur disperse
US7648941B2 (en) 2004-09-22 2010-01-19 Exxonmobil Research And Engineering Company Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts
US7544632B2 (en) 2004-09-22 2009-06-09 Exxonmobil Research And Engineering Company Bulk Ni-Mo-W catalysts made from precursors containing an organic agent
US7591942B2 (en) 2004-09-22 2009-09-22 Exxonmobil Research And Engineering Company Bulk bi-metallic catalysts made from precursors containing an organic agent
ITMI20042445A1 (it) 2004-12-22 2005-03-22 Eni Spa Procedimento per la conversione di cariche pesanti quali greggi pesanti e residui di distillazione
ITMI20042446A1 (it) 2004-12-22 2005-03-22 Eni Spa Procedimento per la conversione di cariche pesantyi quali i greggi pesanti e i residui di distillazione
EP1874897A1 (en) 2005-04-11 2008-01-09 Shell Internationale Research Maatschappij B.V. Method and catalyst for producing a crude product having a reduced mcr content
ES2621425T3 (es) 2005-08-16 2017-07-04 Research Institute Of Petroleum Proceso para la hidroconversión de un material de alimentación hidrocarbonado pesado.
WO2007050636A2 (en) 2005-10-26 2007-05-03 Exxonmobil Research And Engineering Company Hydroprocessing using bulk bimetallic catalysts
WO2007050635A2 (en) 2005-10-26 2007-05-03 Exxonmobil Research And Engineering Company Hydroprocessing using hydrothermally-prepared bulk multimetallic catalysts
CA2630365C (en) 2005-11-23 2010-03-16 Pedro Pereira-Almao Ultradispersed catalyst compositions and methods of preparation
US7842635B2 (en) 2006-01-06 2010-11-30 Headwaters Technology Innovation, Llc Hydrocarbon-soluble, bimetallic catalyst precursors and methods for making same
US7670984B2 (en) 2006-01-06 2010-03-02 Headwaters Technology Innovation, Llc Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same
US20070284285A1 (en) 2006-06-09 2007-12-13 Terence Mitchell Stepanik Method of Upgrading a Heavy Oil Feedstock
US20070295646A1 (en) 2006-06-22 2007-12-27 Bhan Opinder K Method for producing a crude product with a long-life catalyst
JP2009541535A (ja) 2006-06-22 2009-11-26 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 水素の最小限の吸収による全生成物の製造方法
CA2655581A1 (en) 2006-06-22 2007-12-27 Shell Internationale Research Maatschappij B.V. Methods for producing a crude product from selected feed
RU2009101923A (ru) 2006-06-22 2010-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способы получения суммарного продукта с селективным получением углеводородов
FR2906814B1 (fr) 2006-10-06 2012-09-21 Inst Francais Du Petrole Procede de conversion d'une huile desasphaltee
US20080085225A1 (en) 2006-10-06 2008-04-10 Bhan Opinder K Systems for treating a hydrocarbon feed
US7744743B2 (en) 2006-10-30 2010-06-29 Exxonmobil Chemical Patents Inc. Process for upgrading tar

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109027691A (zh) * 2018-08-16 2018-12-18 北京航天石化技术装备工程有限公司 一种减压系统的高压热力平衡方法

Also Published As

Publication number Publication date
EP1960498A2 (en) 2008-08-27
JP2009520062A (ja) 2009-05-21
CA2633902A1 (en) 2007-07-12
CA2633902C (en) 2015-03-31
KR20080077395A (ko) 2008-08-22
US20070138056A1 (en) 2007-06-21
WO2007078621A2 (en) 2007-07-12
BRPI0619988A2 (pt) 2011-10-25
EP1960498A4 (en) 2012-01-04
KR101343167B1 (ko) 2013-12-19
EA200870067A1 (ru) 2008-12-30
US7901569B2 (en) 2011-03-08
WO2007078621A3 (en) 2007-12-13
EA013065B1 (ru) 2010-02-26
NO20083158L (no) 2008-07-15
US20090057194A1 (en) 2009-03-05
US7431822B2 (en) 2008-10-07

Similar Documents

Publication Publication Date Title
CN101336282A (zh) 使用具有新型反应器分离系统的反应器对重油进行改质的方法
CN101360808B (zh) 使用高活性浆料催化剂组合物进行重油改质的方法
CN101356252B (zh) 集成的重油改质方法和在线加氢精制方法
US7431823B2 (en) Process for upgrading heavy oil using a highly active slurry catalyst composition
US7431831B2 (en) Integrated in-line pretreatment and heavy oil upgrading process
CN101553555B (zh) 重质原料全部转化为蒸馏物的方法
CN102071053B (zh) 用于重质油和超重油以及渣油的加氢转化方法
JP2008524386A (ja) 高転化率水素化処理
CN105793395A (zh) 进行选择性级联脱沥青的精炼含重质烃原料的方法
CN103102986B (zh) 一种渣油加氢处理–延迟焦化组合工艺方法
CN103059938A (zh) 一种重烃类加氢处理方法
CN103059960B (zh) 一种灵活加氢裂化方法
CN104004541B (zh) 一种煤基高芳烃潜含量原料油的制备方法
CN110003945A (zh) 包括夹带床深度加氢转化阶段和脱沥青阶段的改进的残余物转化方法
CN105754648A (zh) 煤焦油加工方法及其系统
CN102417826B (zh) 一种重油加氢转化方法
CN102329639B (zh) 一种联合加氢处理方法
MX2008007551A (en) Process for upgrading heavy oil using a highly active slurry catalyst composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20081231