CN101175844A - 快速溶解膨润土颗粒 - Google Patents
快速溶解膨润土颗粒 Download PDFInfo
- Publication number
- CN101175844A CN101175844A CNA2006800160818A CN200680016081A CN101175844A CN 101175844 A CN101175844 A CN 101175844A CN A2006800160818 A CNA2006800160818 A CN A2006800160818A CN 200680016081 A CN200680016081 A CN 200680016081A CN 101175844 A CN101175844 A CN 101175844A
- Authority
- CN
- China
- Prior art keywords
- wilkinite
- water
- weight
- bentonite
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 title claims abstract description 184
- 239000000440 bentonite Substances 0.000 title claims abstract description 62
- 229910000278 bentonite Inorganic materials 0.000 title claims abstract description 62
- 239000008187 granular material Substances 0.000 title claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 67
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 60
- 239000011734 sodium Substances 0.000 claims abstract description 45
- 238000000034 method Methods 0.000 claims abstract description 42
- 229910001413 alkali metal ion Inorganic materials 0.000 claims abstract description 32
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 21
- 238000005341 cation exchange Methods 0.000 claims abstract description 11
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000011591 potassium Substances 0.000 claims abstract description 3
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 77
- 239000004927 clay Substances 0.000 claims description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 55
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 22
- 238000005469 granulation Methods 0.000 claims description 22
- 230000003179 granulation Effects 0.000 claims description 22
- 230000008961 swelling Effects 0.000 claims description 19
- 230000004913 activation Effects 0.000 claims description 16
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 14
- 229910052791 calcium Inorganic materials 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- 206010037211 Psychomotor hyperactivity Diseases 0.000 claims description 8
- 235000017550 sodium carbonate Nutrition 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 6
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 5
- 229910001415 sodium ion Inorganic materials 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910001414 potassium ion Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 2
- 229940038773 trisodium citrate Drugs 0.000 claims description 2
- 235000019263 trisodium citrate Nutrition 0.000 claims description 2
- -1 wherein Substances 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 235000017557 sodium bicarbonate Nutrition 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 34
- 239000004744 fabric Substances 0.000 description 24
- 239000000203 mixture Substances 0.000 description 23
- 239000000463 material Substances 0.000 description 18
- 238000005406 washing Methods 0.000 description 18
- 238000004140 cleaning Methods 0.000 description 12
- 150000001339 alkali metal compounds Chemical class 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 10
- 229960000907 methylthioninium chloride Drugs 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 238000005303 weighing Methods 0.000 description 9
- 229910021647 smectite Inorganic materials 0.000 description 8
- 239000004115 Sodium Silicate Substances 0.000 description 7
- 238000005054 agglomeration Methods 0.000 description 7
- 230000002776 aggregation Effects 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 229910052911 sodium silicate Inorganic materials 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000006210 lotion Substances 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001177 diphosphate Substances 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 3
- 235000015320 potassium carbonate Nutrition 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 230000002522 swelling effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000005337 ground glass Substances 0.000 description 2
- 230000002650 habitual effect Effects 0.000 description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 2
- 229910000271 hectorite Inorganic materials 0.000 description 2
- 230000001404 mediated effect Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 231100000652 hormesis Toxicity 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000007686 potassium Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 229940093916 potassium phosphate Drugs 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001507 sample dispersion Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- RZLVQBNCHSJZPX-UHFFFAOYSA-L zinc sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[O-]S([O-])(=O)=O RZLVQBNCHSJZPX-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Detergent Compositions (AREA)
- Disintegrating Or Milling (AREA)
- Glanulating (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
性能 | 值 |
经由亚甲基蓝吸附的蒙脱石含量 | 75% |
经由X-射线测量的次级矿物含量 | |
石英方英石长石 | <1%重量<5%重量<12%重量 |
通过NH4法的阳离子交换容量 | 75meq/100g |
膨润土 | 活化 | 所加苏打量(%重量) | 洗出液中Na+的浓度(meq/100g) | 总CEC中的Na+含量(%) |
1 | 无 | 0 | 15 | 20 |
2 | 化学计量的 | 3 | 76 | 100 |
3 | 超化学计量的 | 4.3 | 96 | 126 |
水玻璃 | SiO2∶Na2O比 |
A | 2.65 |
B | 3.2 |
膨润土 | 附聚物 | 溶胀体积 | 溶解度 | pH | 水玻璃含量 | |
ml/2mg | 90s | 30s | (%) | |||
1 | 水 | 12 | 70 | 52 | 9.5 | - |
1 | 296g A(10%) | 12 | 75 | 61 | 1.2 | |
1 | 313g A(20%) | 18 | 91 | 83 | 2.6 | |
1 | 426g A(40%) | 18 | 99 | 98 | 10.6 | 7.2 |
2 | 314g水 | 20 | 66 | 30 | 10.7 | - |
2 | 352g A(10%) | 14 | 63 | 44 | 10.7 | 1.5 |
2 | 364g A(20%) | 14 | 98 | 91 | 10.6 | 3.1 |
2 | 430g A(40%) | 14 | >99.5 | >99.5 | 10.6 | 7.3 |
3 | 450g水 | 15 | 90 | 74 | 10.5 | - |
3 | 284g A(10%) | 20 | 100 | 100 | 10.5 | 1.2 |
3 | 330g A(20%) | 19 | 100 | 99.5 | 10.6 | 2.8 |
3 | 352g A(40%) | 17 | >99.5 | >99.5 | 10.5 | 6.0 |
膨润土 | 附聚物 | 溶胀体积 | 溶解度 | pH | 水玻璃含量 | |
ml/2mg | 90s | 30s | (%) | |||
1 | 水 | 12 | 70 | 52 | 9.5 | - |
1 | 252g B(10%) | 11 | 77 | 62 | 0.9 | |
1 | 275g B(20%) | 13 | 96 | 84 | 1.9 | |
1 | 341g B(40%) | 16 | 97 | 93 | 4.8 | |
2 | 314g水 | 20 | 66 | 30 | 10.7 | - |
2 | 519g B(10%) | 13 | 99 | 94 | 10.4 | 1.5 |
2 | 410g B(20%) | 13 | 98 | 94 | 10.4 | 3.0 |
2 | 457g B(40%) | 18 | >99.5 | >99.5 | 10.1 | 6.6 |
3 | 258g水 | 15 | 90 | 74 | 10.5 | -- |
3 | 305g B(10%) | 16.5 | >99.0 | 97.0 | 10.7 | 0.85 |
3 | 330g B(20%) | 17.0 | >99.5 | >99.5 | 10.6 | 1.8 |
3 | 352g B(40%) | 19.0 | >99.5 | >99.5 | 10.5 | 3.9 |
Claims (15)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE102005022075.4 | 2005-05-12 | ||
DE102005022075A DE102005022075A1 (de) | 2005-05-12 | 2005-05-12 | Schnell zerfallende Betonitgranulate |
PCT/EP2006/004489 WO2006120011A1 (de) | 2005-05-12 | 2006-05-12 | Schnell zerfallende bentonitgranulate |
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CN101175844A true CN101175844A (zh) | 2008-05-07 |
CN101175844B CN101175844B (zh) | 2010-06-09 |
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CN2006800160818A Expired - Fee Related CN101175844B (zh) | 2005-05-12 | 2006-05-12 | 快速溶解膨润土颗粒 |
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EP (1) | EP1891191B1 (zh) |
JP (1) | JP4971310B2 (zh) |
CN (1) | CN101175844B (zh) |
AT (1) | ATE492622T1 (zh) |
BR (1) | BRPI0608600A2 (zh) |
DE (2) | DE102005022075A1 (zh) |
ES (1) | ES2358212T3 (zh) |
MX (1) | MX2007013874A (zh) |
PL (1) | PL1891191T3 (zh) |
WO (1) | WO2006120011A1 (zh) |
ZA (1) | ZA200709019B (zh) |
Cited By (1)
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CN108004054A (zh) * | 2017-12-20 | 2018-05-08 | 苏州国建慧投矿物新材料有限公司 | 一种用于洗衣粉的柔顺功能粒子及其制备方法 |
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JP2008290923A (ja) * | 2007-05-28 | 2008-12-04 | Kurosaki Hakudo Kogyo Kk | 水分散性強化型改質ベントナイト及びその製造方法 |
US20150291477A1 (en) * | 2012-09-28 | 2015-10-15 | Korea Institute Of Energy Research | Method for preparing granulated bentonite formed body and granulated bentonite formed body prepared thereby |
KR101348134B1 (ko) | 2012-09-28 | 2014-01-07 | 한국에너지기술연구원 | 그래뉼화 된 벤토나이트 성형체의 제조방법 및 이에 따라 제조된 그래뉼화 된 벤토나이트 성형체의 제조방법 |
CN111024884B (zh) * | 2019-12-02 | 2022-04-22 | 武汉科技大学 | 一种用于冶金球团粘结剂的膨润土质量检测评价方法 |
NL2032305B1 (nl) * | 2022-06-28 | 2024-01-16 | Trisoplast Int B V | Geconsolideerd droog mengsel dat granulair materiaal en bentoniet |
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JPS58117294A (ja) * | 1981-12-30 | 1983-07-12 | ライオン株式会社 | 芳香性洗剤組成物 |
DE3362488D1 (en) * | 1982-02-19 | 1986-04-17 | Laporte Industries Ltd | A process for the manufacture of absorbent materials |
DE3311568C2 (de) * | 1982-04-08 | 1994-10-20 | Colgate Palmolive Co | Teilchenförmiges und weichmachendes Grobwaschmittel, Verfahren zu dessen Herstellung und als Zusatz für Grobwaschmittel geeignetes Bentonit-Agglomerat |
US4746445A (en) * | 1982-04-08 | 1988-05-24 | Colgate-Palmolive Company | Process for manufacturing bentonite agglomerates |
DE3311368A1 (de) * | 1982-04-08 | 1983-10-27 | Colgate-Palmolive Co., 10022 New York, N.Y. | Teilchenfoermiges, bleichendes und weichmachendes textilwaschmittel |
US4767546A (en) * | 1982-04-08 | 1988-08-30 | Colgate-Palmolive Co. | Fabric softening bentonite agglomerates for use in laundry detergents |
US4536316A (en) * | 1983-06-01 | 1985-08-20 | Colgate-Palmolive Co. | Fabric softening composition containing surface modified clay |
US4609473A (en) * | 1984-11-26 | 1986-09-02 | Colgate Palmolive Company | Bentonite-sulfate fabric softening particulate agglomerate, processes for manufacture and use thereof, and detergent compositions containing it |
JPS63150390A (ja) * | 1986-12-15 | 1988-06-23 | 株式会社豊田中央研究所 | 洗剤組成物 |
US4997695A (en) * | 1988-11-21 | 1991-03-05 | James Clem Corporation | Clay mixture having contamination resistance |
DE3908628A1 (de) * | 1989-03-16 | 1990-09-20 | Manfred Dr Ing Braun | Brikettierung von tonmehlgemengen mit zusaetzen auf walzenpressen mit formmulden und verarbeitung dieser briketts zur errichtung von wasserdichten sperrschichten |
DE4243389A1 (de) * | 1992-12-21 | 1994-06-23 | Sued Chemie Ag | Verfahren zur Herstellung von Sorptionsmitteln zur Aufnahme von Flüssigkeiten |
CN1061946C (zh) * | 1997-03-31 | 2001-02-14 | 孙忠 | 一种用钙基膨润土生产钠基膨润土的方法 |
DE19943551A1 (de) * | 1999-09-11 | 2001-03-15 | Clariant Gmbh | Schwerlösliches Alkalisilikat |
DE10121051A1 (de) * | 2001-04-28 | 2002-10-31 | Clariant Gmbh | Builder-Zusammensetzung |
CN1155515C (zh) * | 2002-04-16 | 2004-06-30 | 张兴华 | 颗粒膨润土的生产方法 |
JP2004073053A (ja) * | 2002-08-14 | 2004-03-11 | Kurosaki Hakudo Kogyo Kk | ペット用トイレ砂 |
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CN108004054A (zh) * | 2017-12-20 | 2018-05-08 | 苏州国建慧投矿物新材料有限公司 | 一种用于洗衣粉的柔顺功能粒子及其制备方法 |
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ATE492622T1 (de) | 2011-01-15 |
CN101175844B (zh) | 2010-06-09 |
ZA200709019B (en) | 2009-02-25 |
EP1891191B1 (de) | 2010-12-22 |
DE502006008561D1 (de) | 2011-02-03 |
JP4971310B2 (ja) | 2012-07-11 |
JP2008540749A (ja) | 2008-11-20 |
BRPI0608600A2 (pt) | 2010-01-19 |
MX2007013874A (es) | 2008-01-28 |
ES2358212T3 (es) | 2011-05-06 |
DE102005022075A1 (de) | 2006-11-16 |
PL1891191T3 (pl) | 2011-07-29 |
EP1891191A1 (de) | 2008-02-27 |
WO2006120011A1 (de) | 2006-11-16 |
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