CN101035902A - 脂肪醇作为可塑剂在用于改善phb及其共聚物的物理-机械性质和加工性中的用途 - Google Patents
脂肪醇作为可塑剂在用于改善phb及其共聚物的物理-机械性质和加工性中的用途 Download PDFInfo
- Publication number
- CN101035902A CN101035902A CNA200480043761XA CN200480043761A CN101035902A CN 101035902 A CN101035902 A CN 101035902A CN A200480043761X A CNA200480043761X A CN A200480043761XA CN 200480043761 A CN200480043761 A CN 200480043761A CN 101035902 A CN101035902 A CN 101035902A
- Authority
- CN
- China
- Prior art keywords
- phb
- condition
- composition
- saturated
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Biological Depolymerization Polymers (AREA)
- Wrappers (AREA)
Abstract
Description
样品 | 温度(℃) | 速度(rpm) | ||||||
区域(zone) | C1 | C2 | C3 | C4 | C5 | 基质 | 熔融 | |
PHB纯度 | 128 | 132 | 154 | 140 | 150 | 152 | 152 | 140 |
PHB/可塑剂(80/20) | 130 | 137 | 138 | 140 | 148 | 148 | 154 | 150 |
PHB/可塑剂(70/30) | 130 | 135 | 135 | 140 | 145 | 145 | 152 | 150 |
PHB/可塑剂(60/40) | 120 | 135 | 135 | 140 | 145 | 145 | 150 | 150 |
温度曲线(℃) | 压力/时间曲线 |
区域1:152 | 压力(巴):400 |
区域2:156 | 增压(巴):380 |
区域3:172 | 流速(cm3/s):20 |
区域4:172 | 固定压力(巴):300 |
区域5:170 | 固定时间(s):12 |
模塑(℃):35 | 后压力(巴):40 |
冷却时间(s):32 | 剂量速度(mm/min):12 |
样品 | 密度(g/cm3) | 熔融流速(g/10min) | 抗张强度(MPa) | %延长 | 拉伸模量(MPa) | 艾佐德冲击强度(缺口的) | %cristalinity(DSC) | TM(DSC) |
PHB(MW-380,000) | 1,228 | 33,5 | 36,68 | 2,23 | 3,24 | 21,09 | 61,4 | 173,9 |
F2080 | 1,137 | 57,2 | 19,64 | 2,68 | 1,72 | 18,65 | 56,1 | 170,5 |
F3080 | 1,088 | 95,6 | 15,25 | 3,77 | 1,13 | 21,09 | 55,3 | 166,7 |
F4080 | 1,074 | 133,7 | 12,93 | 3,58 | 0,98 | 23,85 | 58,5 | 165,6 |
F2100 | 1,126 | 49,6 | 19,40 | 3,22 | 1,59 | 19,23 | 57,0 | 168 |
F3100 | 1,08 | 115 | 15,49 | 3,00 | 1,26 | 18,65 | 56,5 | 161,1 |
F4100 | 1,042 | >150,0 | 10,27 | 2,89 | 0,82 | 25,13 | 58,8 | 164,8 |
可塑剂组合物 | 油醇 | 大豆油甘油酯 | PHB |
F2080 | 8% | 2% | 90% |
F3080 | 16% | 4% | 80% |
F4080 | 24% | 6% | 70% |
F2100 | 10% | - | 90% |
F3100 | 20% | - | 80% |
F4100 | 30% | - | 70% |
Claims (8)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2004/008874 WO2006012917A1 (en) | 2004-08-06 | 2004-08-06 | Use of fatty alcohols as plasticizer to improve the physical-mechanical properties and processability of phb and its co-polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101035902A true CN101035902A (zh) | 2007-09-12 |
CN101035902B CN101035902B (zh) | 2012-07-04 |
Family
ID=34958289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200480043761XA Expired - Fee Related CN101035902B (zh) | 2004-08-06 | 2004-08-06 | 脂肪醇作为可塑剂在用于改善phb及其共聚物的物理-机械性质和加工性中的用途 |
Country Status (13)
Country | Link |
---|---|
US (1) | US20080139702A1 (zh) |
EP (1) | EP1781798B1 (zh) |
JP (1) | JP4787830B2 (zh) |
CN (1) | CN101035902B (zh) |
AT (1) | ATE469977T1 (zh) |
AU (1) | AU2004322084B2 (zh) |
BR (1) | BRPI0418990B1 (zh) |
CA (1) | CA2575273C (zh) |
DE (1) | DE602004027554D1 (zh) |
ES (1) | ES2344951T3 (zh) |
MX (1) | MX2007001297A (zh) |
PT (1) | PT1781798E (zh) |
WO (1) | WO2006012917A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110283745A (zh) * | 2019-06-27 | 2019-09-27 | 浙江工业大学 | 医院不动杆菌fk2及其在降解有机污染物中的应用 |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0600681A (pt) * | 2006-02-24 | 2007-11-20 | Phb Ind Sa | blenda polimérica ambientalmente degradável e seu processo de obtenção |
BRPI0600783A (pt) * | 2006-02-24 | 2007-11-20 | Phb Ind Sa | composição polimérica biodegradável e método para produção de uma composição polimérica biodegradável |
WO2007142784A1 (en) | 2006-05-31 | 2007-12-13 | Archer-Daniels-Midland Company | Enzymatic method of making aldehydes from fatty acids |
JPWO2008099586A1 (ja) * | 2007-02-15 | 2010-05-27 | 国立大学法人東京工業大学 | 生分解性樹脂組成物 |
WO2008110541A2 (de) * | 2007-03-14 | 2008-09-18 | Basf Se | Stabilisierung von polyhydroxybutyraten gegen thermischen abbau |
TW201042103A (en) | 2008-12-23 | 2010-12-01 | Metabolix Inc | Production of non-woven materials from polyhydroxyalkanoate |
PL2338966T3 (pl) | 2009-12-22 | 2014-04-30 | Procter & Gamble | Ciekła kompozycja czyszcząca i/lub oczyszczająca |
EP2516609B1 (en) | 2009-12-22 | 2013-11-27 | The Procter and Gamble Company | Liquid cleaning and/or cleansing composition |
CA2796947C (en) | 2010-04-21 | 2015-11-24 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
EP2431452B1 (en) | 2010-09-21 | 2015-07-08 | The Procter & Gamble Company | Liquid cleaning composition |
EP2431451A1 (en) | 2010-09-21 | 2012-03-21 | The Procter & Gamble Company | Liquid detergent composition with abrasive particles |
BRPI1102456B1 (pt) | 2011-05-26 | 2021-03-30 | Oxiteno S/a Industria E Comércio | Composição de agentes de coalescência, e, uso da composição de agentes de coalescência |
WO2012177615A1 (en) | 2011-06-20 | 2012-12-27 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
US8852643B2 (en) | 2011-06-20 | 2014-10-07 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
CN103717726A (zh) * | 2011-06-20 | 2014-04-09 | 宝洁公司 | 液体清洁和/或净化组合物 |
EP3016938A4 (en) * | 2013-07-01 | 2017-05-24 | Polymer Additives, Inc. | Biobased epoxidized fatty acid ester plasticizers |
DE102015206645A1 (de) | 2014-04-16 | 2015-10-22 | Basf Se | Verwendung modifizierter Fettsäureester als Weichmacher |
KR20230018413A (ko) | 2020-06-02 | 2023-02-07 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 고분자 성형물의 제조방법 |
WO2021246434A1 (ja) | 2020-06-02 | 2021-12-09 | 三菱瓦斯化学株式会社 | 加熱による前処理を伴う高分子成形物の製造方法 |
CN115613155B (zh) * | 2022-11-18 | 2023-05-16 | 北京微构工场生物技术有限公司 | 一种长丝或短纤及其制备方法 |
Family Cites Families (21)
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US3044942A (en) * | 1960-09-27 | 1962-07-17 | Grace W R & Co | Process for preparing poly-beta-hydroxybutyric acid |
US3107172A (en) * | 1960-12-30 | 1963-10-15 | Grace W R & Co | Molded product containing poly-beta-hydroxybutyric acid and method of making |
US3275610A (en) * | 1964-03-24 | 1966-09-27 | Mobil Oil Corp | Microbial synthesis of polymers |
FR2446859A1 (fr) * | 1979-01-22 | 1980-08-14 | Solvay | Procede de separation de poly-b-hydroxybutyrates d'une biomasse |
GB8311677D0 (en) * | 1983-04-28 | 1983-06-02 | Ici Plc | Extraction process |
FR2567149B1 (fr) * | 1984-07-06 | 1986-12-05 | Solvay | Procede pour l'extraction de poly-beta-hydroxybutyrates au moyen d'un solvant a partir d'une suspension aqueuse de micro-organismes |
GB9311399D0 (en) * | 1993-06-02 | 1993-07-21 | Zeneca Ltd | Polyester composition |
GB9311402D0 (en) * | 1993-06-02 | 1993-07-21 | Zeneca Ltd | Processing of polyesters |
JPH08217967A (ja) * | 1995-02-10 | 1996-08-27 | Sekisui Chem Co Ltd | 不飽和ポリエステル樹脂組成物及び不飽和ポリエステル樹脂成形体の製造方法 |
WO1999023146A1 (en) * | 1997-10-31 | 1999-05-14 | Monsanto Company | Plasticized polyhydroxyalkanoate compositions and methods for their use in the production of shaped polymeric articles |
KR100757968B1 (ko) * | 2000-04-18 | 2007-09-11 | 도소 가부시키가이샤 | 열가소성수지 조합물의 제조방법 |
WO2001092393A2 (en) * | 2000-05-31 | 2001-12-06 | Ciba Specialty Chemicals Holding Inc. | Stabilizer mixtures |
JP2005501927A (ja) * | 2001-04-20 | 2005-01-20 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 核剤および可塑剤を用いたポリヒドロキシアルカノエートの加工 |
DE60224293T2 (de) * | 2001-09-21 | 2008-12-11 | Egalet A/S | Feste dispersionen mit kontrollierter freisetzung von carvedilol |
JP3597809B2 (ja) * | 2001-10-04 | 2004-12-08 | 三菱樹脂株式会社 | 帯電防止性ポリ乳酸系組成物 |
KR20030061675A (ko) * | 2002-01-11 | 2003-07-22 | 뉴 아이스 리미티드 | 생분해성 또는 부패성 컨테이너 |
US20050215677A1 (en) * | 2002-06-13 | 2005-09-29 | Gaggar Satish K | Thermoplastic compositions and process for making thereof |
DE10254600B4 (de) * | 2002-11-22 | 2007-12-27 | Bayer Materialscience Ag | Verfahren zur Herstellung von thermoplastischen, nicht klebenden Polyurethanen |
US7098292B2 (en) * | 2003-05-08 | 2006-08-29 | The Procter & Gamble Company | Molded or extruded articles comprising polyhydroxyalkanoate copolymer and an environmentally degradable thermoplastic polymer |
US20050282456A1 (en) * | 2004-06-17 | 2005-12-22 | The Procter & Gamble Company | Laminate comprising a polyhydroxyalkanoate copolymer |
WO2008018951A1 (en) * | 2006-08-04 | 2008-02-14 | Exxonmobil Chemical Patents Inc. | Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers |
-
2004
- 2004-08-06 CA CA2575273A patent/CA2575273C/en not_active Expired - Fee Related
- 2004-08-06 CN CN200480043761XA patent/CN101035902B/zh not_active Expired - Fee Related
- 2004-08-06 US US11/573,278 patent/US20080139702A1/en not_active Abandoned
- 2004-08-06 JP JP2007524183A patent/JP4787830B2/ja not_active Expired - Fee Related
- 2004-08-06 WO PCT/EP2004/008874 patent/WO2006012917A1/en active Application Filing
- 2004-08-06 AU AU2004322084A patent/AU2004322084B2/en not_active Ceased
- 2004-08-06 EP EP04763902A patent/EP1781798B1/en not_active Not-in-force
- 2004-08-06 AT AT04763902T patent/ATE469977T1/de active
- 2004-08-06 ES ES04763902T patent/ES2344951T3/es active Active
- 2004-08-06 BR BRPI0418990-6A patent/BRPI0418990B1/pt not_active IP Right Cessation
- 2004-08-06 PT PT04763902T patent/PT1781798E/pt unknown
- 2004-08-06 DE DE602004027554T patent/DE602004027554D1/de active Active
- 2004-08-06 MX MX2007001297A patent/MX2007001297A/es active IP Right Grant
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110283745A (zh) * | 2019-06-27 | 2019-09-27 | 浙江工业大学 | 医院不动杆菌fk2及其在降解有机污染物中的应用 |
CN110283745B (zh) * | 2019-06-27 | 2021-05-11 | 浙江工业大学 | 医院不动杆菌fk2及其在降解有机污染物中的应用 |
Also Published As
Publication number | Publication date |
---|---|
JP4787830B2 (ja) | 2011-10-05 |
ES2344951T3 (es) | 2010-09-10 |
EP1781798A1 (en) | 2007-05-09 |
AU2004322084B2 (en) | 2009-11-26 |
CA2575273C (en) | 2012-10-16 |
ATE469977T1 (de) | 2010-06-15 |
EP1781798B1 (en) | 2010-06-02 |
AU2004322084A1 (en) | 2006-02-09 |
DE602004027554D1 (de) | 2010-07-15 |
CA2575273A1 (en) | 2006-02-09 |
PT1781798E (pt) | 2010-06-16 |
CN101035902B (zh) | 2012-07-04 |
WO2006012917A1 (en) | 2006-02-09 |
MX2007001297A (es) | 2008-03-04 |
BRPI0418990A (pt) | 2007-12-11 |
JP2008509234A (ja) | 2008-03-27 |
US20080139702A1 (en) | 2008-06-12 |
BRPI0418990B1 (pt) | 2014-08-26 |
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ASS | Succession or assignment of patent right |
Owner name: PHB INDUSTRIAL STOCK CO., LTD. Free format text: FORMER OWNER: KOEGELNIX INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.; APPLICANT Effective date: 20071123 |
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C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20071123 Address after: Brazil Serrana Applicant after: Cognis IP Man GmbH Address before: Dusseldorf Applicant before: Cognis IP Man GmbH Co-applicant before: Cognis IP Man GmbH |
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C14 | Grant of patent or utility model | ||
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120704 Termination date: 20170806 |
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CF01 | Termination of patent right due to non-payment of annual fee |