CN101031577A - 聚亚芳基醚组合物 - Google Patents
聚亚芳基醚组合物 Download PDFInfo
- Publication number
- CN101031577A CN101031577A CNA200580032979XA CN200580032979A CN101031577A CN 101031577 A CN101031577 A CN 101031577A CN A200580032979X A CNA200580032979X A CN A200580032979XA CN 200580032979 A CN200580032979 A CN 200580032979A CN 101031577 A CN101031577 A CN 101031577A
- Authority
- CN
- China
- Prior art keywords
- composition
- poly
- arylene ether
- resin
- alkenyl aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- -1 Poly(arylene ether Chemical compound 0.000 title claims abstract description 100
- 239000000203 mixture Substances 0.000 title claims abstract description 98
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 229920005989 resin Polymers 0.000 claims abstract description 45
- 239000011347 resin Substances 0.000 claims abstract description 45
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 150000001412 amines Chemical class 0.000 claims abstract description 31
- 239000004611 light stabiliser Substances 0.000 claims abstract description 29
- 239000000975 dye Substances 0.000 claims description 28
- 150000002118 epoxides Chemical class 0.000 claims description 22
- 125000005340 bisphosphate group Chemical group 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 20
- 239000000654 additive Substances 0.000 claims description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 239000012965 benzophenone Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 150000005204 hydroxybenzenes Chemical class 0.000 claims description 17
- 230000031700 light absorption Effects 0.000 claims description 17
- 230000000996 additive effect Effects 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 15
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 13
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 229940106691 bisphenol a Drugs 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 10
- 230000032683 aging Effects 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 230000002745 absorbent Effects 0.000 claims description 7
- 239000002250 absorbent Substances 0.000 claims description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 125000004104 aryloxy group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 239000012744 reinforcing agent Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- ULKZXPVMGVENDU-UHFFFAOYSA-N phenol;phosphono dihydrogen phosphate Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.OP(O)(=O)OP(O)(O)=O ULKZXPVMGVENDU-UHFFFAOYSA-N 0.000 abstract 1
- 239000002585 base Substances 0.000 description 25
- 229920005669 high impact polystyrene Polymers 0.000 description 20
- 239000004797 high-impact polystyrene Substances 0.000 description 20
- 239000004721 Polyphenylene oxide Substances 0.000 description 19
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 19
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 17
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- 239000000178 monomer Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 150000002576 ketones Chemical class 0.000 description 11
- 239000002904 solvent Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- BGGGMYCMZTXZBY-UHFFFAOYSA-N (3-hydroxyphenyl) phosphono hydrogen phosphate Chemical compound OC1=CC=CC(OP(O)(=O)OP(O)(O)=O)=C1 BGGGMYCMZTXZBY-UHFFFAOYSA-N 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 150000008301 phosphite esters Chemical class 0.000 description 6
- FISZAKVDTCHVGC-UHFFFAOYSA-N (2-butoxyphenyl)-phenylmethanone Chemical compound CCCCOC1=CC=CC=C1C(=O)C1=CC=CC=C1 FISZAKVDTCHVGC-UHFFFAOYSA-N 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000008065 acid anhydrides Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- WWMFRKPUQJRNBY-UHFFFAOYSA-N (2,3-dimethoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OC WWMFRKPUQJRNBY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003607 modifier Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- OJFZCPMENWLPRI-UHFFFAOYSA-N (2-ethylphenyl)-phenylmethanone Chemical compound CCC1=CC=CC=C1C(=O)C1=CC=CC=C1 OJFZCPMENWLPRI-UHFFFAOYSA-N 0.000 description 3
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 3
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000004103 aminoalkyl group Chemical group 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 150000002905 orthoesters Chemical class 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920006380 polyphenylene oxide Polymers 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- NLELYIIJDKQXTL-UHFFFAOYSA-N (2,3-diethoxyphenyl)-phenylmethanone Chemical compound CCOC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OCC NLELYIIJDKQXTL-UHFFFAOYSA-N 0.000 description 2
- VBQMOUFTQANISV-UHFFFAOYSA-N (2-butylphenyl)-phenylmethanone Chemical compound CCCCC1=CC=CC=C1C(=O)C1=CC=CC=C1 VBQMOUFTQANISV-UHFFFAOYSA-N 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical class ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 description 2
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 2
- OXQXGKNECHBVMO-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptane-4-carboxylic acid Chemical compound C1C(C(=O)O)CCC2OC21 OXQXGKNECHBVMO-UHFFFAOYSA-N 0.000 description 2
- VJUKWPOWHJITTP-UHFFFAOYSA-N 81-39-0 Chemical compound C1=CC(C)=CC=C1NC1=CC=C2C3=C1C(=O)C1=CC=CC=C1C3=CC(=O)N2C VJUKWPOWHJITTP-UHFFFAOYSA-N 0.000 description 2
- IPHMDNXLZVKWES-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)C1=CC=CC=C1.[Br] Chemical compound C(C1=CC=CC=C1)(=O)C1=CC=CC=C1.[Br] IPHMDNXLZVKWES-UHFFFAOYSA-N 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- REHQKRLHYALORV-UHFFFAOYSA-N P(=O)(OC1=CC=CC=C1)(OC1=CC=CC=C1)O.P(=O)(OC1=CC=CC=C1)(OC1=CC=CC=C1)O Chemical compound P(=O)(OC1=CC=CC=C1)(OC1=CC=CC=C1)O.P(=O)(OC1=CC=CC=C1)(OC1=CC=CC=C1)O REHQKRLHYALORV-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000004946 alkenylalkyl group Chemical group 0.000 description 2
- 125000005038 alkynylalkyl group Chemical group 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000001188 haloalkyl group Chemical group 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229940094933 n-dodecane Drugs 0.000 description 2
- 229940038384 octadecane Drugs 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- LHLMMJPVLGZOEK-UHFFFAOYSA-N phenyl-(2,3,4-trimethoxyphenyl)methanone Chemical compound COC1=C(OC)C(OC)=CC=C1C(=O)C1=CC=CC=C1 LHLMMJPVLGZOEK-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 2
- 229940116351 sebacate Drugs 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229960005137 succinic acid Drugs 0.000 description 2
- 229960002317 succinimide Drugs 0.000 description 2
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- BZWGZQNUCNUCES-UHFFFAOYSA-N (2,3-dibromophenyl)-phenylmethanone Chemical compound BrC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1Br BZWGZQNUCNUCES-UHFFFAOYSA-N 0.000 description 1
- GCLUVALWCCPTBS-UHFFFAOYSA-N (2,3-dibutoxyphenyl)-phenylmethanone Chemical compound CCCCOC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OCCCC GCLUVALWCCPTBS-UHFFFAOYSA-N 0.000 description 1
- VDVQFBKVEPIPIQ-UHFFFAOYSA-N (2,3-dibutylphenyl)-phenylmethanone Chemical compound CCCCC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1CCCC VDVQFBKVEPIPIQ-UHFFFAOYSA-N 0.000 description 1
- DALZMRATCHERCN-UHFFFAOYSA-N (2,3-dipropoxyphenyl)-phenylmethanone Chemical compound CCCOC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OCCC DALZMRATCHERCN-UHFFFAOYSA-N 0.000 description 1
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical compound CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 description 1
- VMHYWKBKHMYRNF-UHFFFAOYSA-N (2-chlorophenyl)-phenylmethanone Chemical class ClC1=CC=CC=C1C(=O)C1=CC=CC=C1 VMHYWKBKHMYRNF-UHFFFAOYSA-N 0.000 description 1
- IADJBCIKCXGXDN-UHFFFAOYSA-N (4-butoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCC)=CC=C1C(=O)C1=CC=CC=C1 IADJBCIKCXGXDN-UHFFFAOYSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- NBZYOWJKOWTTRO-UHFFFAOYSA-N 1-(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical class O=C1NC(=O)NC(=O)N1CC1OC1 NBZYOWJKOWTTRO-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- XDDLRVYDQACVBC-UHFFFAOYSA-N 10-oxo-10-(1,2,2,6,6-pentamethylpiperidin-4-yl)oxydecanoic acid Chemical compound CN1C(C)(C)CC(OC(=O)CCCCCCCCC(O)=O)CC1(C)C XDDLRVYDQACVBC-UHFFFAOYSA-N 0.000 description 1
- HEJCZAMFVMNFLC-UHFFFAOYSA-N 10-oxo-10-(2,2,6,6-tetramethylpiperidin-4-yl)oxydecanoic acid Chemical compound CC1(C)CC(OC(=O)CCCCCCCCC(O)=O)CC(C)(C)N1 HEJCZAMFVMNFLC-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
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- 239000001415 potassium malate Substances 0.000 description 1
- 235000011033 potassium malate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical class C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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Abstract
一种组合物,其包含聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物,其中组合物的色移(dE)小于6。
Description
发明背景
本发明涉及聚亚芳基醚组合物。具体地,本发明涉及具有良好的颜色稳定性的聚亚芳基醚/聚(链烯基芳香族)共混物。
聚亚芳基醚/聚(链烯基芳香族)组合物具有大量合乎需要的性质并应用于各种用途中。当该组合物包含阻燃剂时,应用范围可以进一步扩展。然而,在一些情况下,聚亚芳基醚/聚(链烯基芳香族)组合物会随时间推移而褪色。
因此,仍存在着对随时间极少褪色或不褪色的阻燃性聚亚芳基醚/聚(链烯基芳香族)组合物的需要。
发明简述
一种组合物,其包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物,其中组合物的色移(dE)小于6,阻燃性为V1或更好,该色移(dE)是根据ASTM D4459气候老化300小时之后依照ASTM D2244测定的,该阻燃性是在3毫米厚度下依照UL94测定的。
详细描述
长期以来一直寻求聚亚芳基醚组合物的颜色稳定性。随着时间的推移,已采用了各种光稳定剂和颜色稳定剂,但阻燃性聚亚芳基醚组合物的颜色稳定性仍存在问题。令人惊讶地发现,阻燃剂的选择,加上颜色稳定剂和光稳定剂的选择对于阻燃性聚亚芳基醚/聚(链烯基芳香族)组合物的颜色稳定性具有重要影响。出乎意料的是,包含双(羟基苯)二磷酸酯(如下所述)的组合物表现出比含有其他磷酸酯阻燃剂(例如间苯二酚二磷酸酯)的组合物明显优异的颜色稳定性。
在一实施方案中,组合物包含聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺(hindered amine)光稳定剂和紫外光吸收化合物,其中受阻胺光稳定剂和紫外光吸收化合物存在的总量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为2.5~5重量%,组合物的色移小于6,根据UL94在3毫米厚度下测定时的阻燃性为V1或更好。色移是在组合物的样品依照ASTM D4459进行气候老化规程(weathering protocol)之后测定的。如ASTM D2244中所述,色移(dE)是在反射模式下使用分光光度计基于L*、a*和b*测量值测定的。根据以下公式计算色移:
UL 94是标题为“塑性材料可燃性的测试(Tests for Flammability of PlasticMaterials),UL94”的Underwriter′s Laboratory Bulletin 94程序的缩写。所述组合物可进一步包括光致漂白性染料、抗氧化剂、环氧化合物、颜料、染料,或两种或多种上述添加剂的组合。
在另一实施方案中,组合物包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂、紫外光吸收化合物和环氧化合物。该组合物可获得小于或等于5的色移(dE),且根据UL 94,阻燃性为V1或更好。
在另一实施方案中,组合物包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂、光致漂白性染料、紫外光吸收化合物、抗氧化剂和环氧化合物。
在本文中使用时,“聚亚芳基醚”包括多个式(I)的结构单元:
其中对于每个结构单元,各Q1独立地为氢、卤素、低级伯烷基或仲烷基(例如,含有1至约7个碳原子的烷基)、苯基、卤代烷基、氨基烷基、链烯基烷基、炔基烷基、烃氧基、芳基和其中至少两个碳原子隔开卤素和氧原子的卤代烃氧基;各Q2独立地为氢、卤素、低级伯烷基或仲烷基、苯基、卤代烷基、氨基烷基、链烯基烷基、炔基烷基、烃氧基,其中至少两个碳原子隔开卤素和氧原子的卤代烃氧基。在一些实施方案中,各Q1独立地为烷基或苯基,例如,C1-4烷基,各Q2独立地为氢或甲基。聚亚芳基醚可包含具有含氨基烷基的端基的分子,该端基通常位于羟基的邻位。还经常存在的是4-羟基联苯基端基,其通常得自于存在副产物二苯酚合苯醌的反应混合物。
聚亚芳基醚可以为以下形式:均聚物;共聚物;接枝共聚物;离聚物(ionomer);嵌段共聚物,例如,包含亚芳基醚单元和衍生自链烯基芳香族化合物的嵌段;以及包含至少一种上述形式的组合。聚亚芳基醚包括含有2,6-二甲基-1,4-亚苯基醚单元,任选结合有2,3,6-三甲基-1,4-亚苯基醚单元的聚苯醚。
通过氧化偶合单羟基芳香族化合物例如2,6-二甲苯酚和/或2,3,6-三甲基苯酚可以制备聚亚芳基醚。对于该偶合通常采用催化剂体系;该催化剂体系可以含有重金属化合物例如铜、锰或钴的化合物,通常结合各种其他物质,例如仲胺、叔胺、卤化物和上述两种或多种物质的组合。
当通过凝胶渗透色谱法测定时,聚亚芳基醚的数均分子量可以为约3,000至约40,000原子质量单位(amu),且重均分子量为约5,000至约80,000amu。在25℃氯仿中测量时,聚亚芳基醚的特性粘度可以为约0.10至约0.60分升/克(dl/g),或更具体地,为约0.29至约0.48dl/g。可以利用高特性粘度聚亚芳基醚和低特性粘度聚亚芳基醚的组合。当使用两种特性粘度时,精确比率的确定将多少取决于所用聚亚芳基醚的确切特性粘度和所希望的最终的物理性质。
另外,全部或部分聚亚芳基醚可以为聚亚芳基醚和官能化剂的反应产物。官能化剂包括多官能化合物。可用作官能化剂的多官能化合物有三种类型。第一种类型的多官能化合物是分子中既具有(a)碳-碳双键或碳-碳三键又具有(b)至少一个羧酸、酸酐、酰胺、酯、酰亚胺、氨基、环氧、原酸酯或羟基基团的化合物。这些多官能化合物的实例包括马来酸;马来酸酐;富马酸;丙烯酸缩水甘油酯;衣康酸;乌头酸;马来酰亚胺;马来酰肼;由二胺和马来酸酐、马来酸、富马酸等得到的反应产物;二氯马来酸酐;马来酰胺;不饱和二羧酸(例如,丙烯酸、巴豆酸、甲基丙烯酸、乙基丙烯酸、戊烯酸;癸烯酸、十一烯酸、十二烯酸、亚油酸等);上述不饱和羧酸的酯、酰胺或酸酐;不饱和醇(例如,烷基醇、巴豆基醇、甲基乙烯基甲醇、4-戊烯-1-醇、1,4-己二烯-3-醇、3-丁烯-1,4-二醇、2,5-二甲基-3-己烯-2,5-二醇,以及通式为CnH2n-5OH、CnH2n-7OH和CnH2n-9OH的醇,其中n为小于或等于30的正整数);用NH2基团取代上述不饱和醇的-OH基团得到的不饱和胺;官能化二烯聚合物和共聚物;以及包括上述一种或多种物质的组合。在一实施方案中,所述官能化剂包括马来酸酐和/或富马酸。
第二种类型的多官能官能化剂的特征在于,其既具有(a)由式(OR)表示的基团(其中R为氢或烷基、芳基、酰基或羰酰二氧基(carbonyl dioxy))又具有(b)至少两个可以相同或相异的选自以下的基团:羧酸、酰卤、酸酐、酰卤酸酐、酯、原酸酯、酰胺、亚氨基、氨基,以及它们的各种盐。典型的这类官能化剂是由下式表示的脂肪族多元羧酸、酸酯和酰胺:
(RIO)mR(COORII)n(CONRIIIRIV)s
其中R为具有2至约20个碳原子、更具体地2至约10个碳原子的直链或支链饱和脂肪烃;RI为氢或具有1至约10个碳原子,或者更具体地1至约6个碳原子,或者甚至更具体地1至约4个碳原子的烷基、芳基、酰基或羰酰二氧基;各RII独立地为氢或具有1至约20个碳原子,或者更具体地为1至约10个碳原子的烷基或芳基;各RIII和RIV独立地为氢或具有1至约10个碳原子,或者更具体地1至约6个碳原子,或者甚至更具体地为1至约4个碳原子的烷基或芳基;m等于1,(n+s)大于或等于2,或者更具体地等于2或3,n和s各自大于或等于0,其中(ORI)在羰基的α或β位,且至少两个羰基被2至约6个碳原子隔开。显然,当相应的取代基小于6个碳原子时,RI、RII、RIII和R不能为芳基。
合适的多元羧酸包括,例如,柠檬酸、苹果酸、2-十六烷基柠檬酸;包括它们的各种商品形式,例如无水酸和水合酸;以及包含上述一种或多种酸的组合。在一实施方案中,增容剂(compatibilizing agent)包括柠檬酸。本文中可用的示例性酯包括,例如乙酰基柠檬酸酯、柠檬酸单硬脂基酯和/或柠檬酸二硬脂基酯,等等。本文中可用的合适的酰胺包括,例如,N,N′-二乙基柠檬酰胺;N-苯基柠檬酰胺;N-十二烷基柠檬酰胺;N,N′-双十二烷基柠檬酰胺;和N-十二烷基苹果酸。衍生物包括它们的盐,包括和胺生成的盐、碱金属盐和碱土金属盐。示例性的合适的盐包括苹果酸钙、柠檬酸钙、苹果酸钾和柠檬酸钾。
第三种类型的多官能官能化剂的特征在于,在分子中既包含(a)酰卤基团又包括(b)至少一个羧酸、酸酐、酯、环氧、原酸酯或酰胺基团,优选羧酸或酸酐基团。实例包括偏苯三酸酐酰氯、氯甲酰琥珀酸酐、氯甲酰琥珀酸、氯甲酰戊二酸酐、氯甲酰戊二酸、氯乙酰琥珀酸酐、氯乙酰琥珀酸、偏苯三酰氯(trimellitic acid chloride)和氯乙酰戊二酸。在一实施方案中,官能化剂包括偏苯三酸酐酰氯。
组合物包括含量为20~80重量%的聚亚芳基醚。在该范围内,聚亚芳基醚存在的量可以大于或等于22重量%,或者更具体地,该量大于或等于25重量%,或者甚至更具体地,该量大于或等于27重量%。同样在该范围内,聚亚芳基醚存在的量可以小于或等于77重量%,或者更具体地,该量小于或等于75重量%,或者甚至更具体地,该量小于或等于73重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
组合物还包括聚(链烯基芳香族)树脂。本文中使用的术语“聚(链烯基芳香族)树脂”包括通过本领域已知的方法(包括本体聚合、悬浮聚合和乳液聚合)制备的聚合物,该聚合物含有至少25重量%衍生自下式链烯基芳香族单体的结构单元:
其中R1为氢、C1-C8烷基或卤素;Z1为乙烯基、卤素或C1-C8烷基;p为0~5。示例性的链烯基芳香族单体包括苯乙烯、氯苯乙烯和乙烯基甲苯。聚(链烯基芳香族)树脂包括链烯基芳香族单体的均聚物;链烯基芳香族单体和一种或多种不同单体的无规共聚物,链烯基芳香族单体例如苯乙烯,所述一种或多种不同单体如丙烯腈、丁二烯、α-甲基苯乙烯、乙基乙烯基苯、二乙烯基苯和马来酸酐;以及橡胶改性的聚(链烯基芳香族)树脂,包括橡胶改性剂和链烯基芳香族单体(如上所述)均聚物的共混物和/或接枝物,其中该橡胶改性剂可以是至少一种C4-C10非芳香族二烯单体(例如丁二烯或异戊二烯)的聚合产物,且其中该橡胶改性的聚(链烯基芳香族)树脂包括约98至约70重量%链烯基芳香族单体的均聚物和约2至约30重量%橡胶改性剂,或者更具体地,约88至约94重量%的链烯基芳香族单体均聚物和约6至约12重量%橡胶改性剂。橡胶改性聚苯乙烯还称为高抗冲聚苯乙烯或HIPS。
组合物包括含量为20~80重量%的聚(链烯基芳香族)树脂。在该范围内,(链烯基芳香族)树脂存在的量可以大于或等于22重量%,或者更具体地,该量大于或等于25重量%,或者甚至更具体地,该量大于或等于27重量%。同样在该范围内,该(链烯基芳香族)树脂存在的量可小于或等于77重量%,或者更具体地小于或等于75重量%,或者甚至更具体地小于或等于73重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
双(羟基苯)二磷酸酯是具有下式的二磷酸酯化合物:
其中R3为具有1~5个碳的烷基,R5各自独立地为具有1~8个碳的烷基或具有6~12个碳的芳基;R4各自为具有1~12个碳的烷基、芳基、烷氧基或芳氧基;X2和X3独立地为卤素或甲基;h和r为0或1~4的整数,以及q为1~10。
在一实施方案中,R3为异丙基,R4为苯氧基,R5为苯基,且h和r为0。当R3为异丙基时,该双(羟基苯)二磷酸酯可称为双酚A二磷酸酯(BPADP)。在示例性的BPADP中,R4为苯氧基,R5为苯基,且h和r为0。
组合物包括含量为5~30重量%的双(羟基苯)二磷酸酯。在该范围内,双(羟基苯)二磷酸酯存在的量可大于或等于6重量%,或者更具体地,该量大于或等于7重量%,或者甚至更具体地,该量大于或等于8重量%。同样在该范围内,双(羟基苯)二磷酸酯存在的量可小于或等于29重量%,或者更具体地小于或等于28重量%,或者甚至更具体地小于或等于27重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
作为功能等同的化合物,受阻胺光稳定剂(通常称为HALS)在聚合物技术中被看作是可确定的一类。这类化合物的结构特点是在哌啶环的2位和6位上存在多取代基和/或位阻大的基团。因此,受阻胺光稳定剂包括至少一以下结构部分:
其中各R6独立地为具有1~8个碳的烷基,E各自独立地为氧基(oxyl)、羟基、烷氧基、环烷氧基、芳烷氧基、芳氧基、-O-CO-OZ3、-O-Si(Z4)3、-O-PO(OZ5S)2或-O-CH2-OZ6,其中Z3、Z4、Z5和Z6选自氢、具有1~8个碳的脂肪烃和具有1~8个碳的芳香烃。E还可以为-O-T-(OH)b,其中T是1~18个碳的直链或支链烷基,5~18个碳的环烷基,具有7~14个碳的烷芳基,且b是1、2或3,条件是b不能超过T的碳原子数,并且当b为2或3时,每个羟基与T上不同的碳原子连接。受阻胺光稳定剂可以是单体、低聚物或聚合物。
在一实施方案中,受阻胺光稳定剂可以由下式表示:
其中A为链烷二基(alkanediyl),即具有2~10个碳原子的亚甲基链,衍生自链烷双酸,例如琥珀酸、戊二酸、己二酸、癸二酸等。R6定义如上,各个Z可以是相同或相异的具有1~8个碳的低级烷基或氢。在一些实施方案中,两次出现的R一起形成五亚甲基。
示例性的受阻胺光稳定剂包括但不限于双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯,双(2,2,6,6-四甲基-4-哌啶基)琥珀酸酯,双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯,双(1-辛氧基-2,2,6,6-四甲基-4-哌啶基)癸二酸酯,双(1,2,2,6,6-五甲基4-哌啶基)正丁基-3,5-二叔丁基-4-羟基苄基丙二酸酯,1-(2-羟乙基)-2,2,6,6-四甲基-4-羟基哌啶和琥珀酸的缩合物,N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺和4-叔辛基氨基-2,6-二氯-1,3,5-三嗪的线性或环状缩合物,三(2,2,6,6-四甲基-4-哌啶基)次氮基三乙酸酯,四(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁烷-四羧酸酯,1,1′-(1,2-乙烷二基)-双(3,3,5,5-四甲基哌嗪酮),4-苯甲酰基-2,2,6,6-四甲基哌啶,4-十八烷氧基-2,2,6,6-四甲基哌啶,双(1,2,2,6,6-五甲基哌啶基)-2-正丁基-2-(2-羟基-3,5-二叔丁基苯甲基)-丙二酸酯,3-正辛基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸-2,4-二酮,双(1-辛氧基-2,2,6,6-四甲基哌啶基)癸二酸酯,双(1-辛氧基-2,2,6,6-四甲基哌啶基)琥珀酸酯,N,N′-双-(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺和4-吗啉代-2,6-二氯-1,3,5-三嗪的线性或环状缩合物,2-氯-4,6-双(4-正丁基氨基-2,2,6,6-四甲基哌啶基)-1,3,5-三嗪和1,2-双(3-氨基丙氨基)乙烷的缩合物,2-氯-4,6-二-(4-正丁基氨基-1,2,2,6,6-五甲基哌啶基)-1,3,5-三嗪和1,2-双-(3-氨基丙氨基)乙烷的缩合物,8-乙酰基-3-十二烷基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸-2,4-二酮,3-十二烷基-1-(2,2,6,6-四甲基-4-哌啶基)吡咯烷-2,5-二酮,3-十二烷基-1-(1,2,2,6,6-五甲基-4-哌啶基)吡咯烷-2,5-二酮,4-十六烷氧基-和4-十八烷氧基-2,2,6,6-四甲基哌啶的混合物,N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺和4-环己基氨基-2,6-二氯-1,3,5-三嗪的缩合产物,1,2-双(3-氨基丙氨基)乙烷和2,4,6-三氯-1,3,5-三嗪以及4-丁氨基-2,2,6,6-四甲基哌啶的缩合产物(CAS Reg.No.[136504-96-6]);N-(2,2,6,6-四甲基-4-哌啶基)-正十二烷基琥珀酰亚胺,N-(1,2,2,6,6-五甲基-4-哌啶基)-正十二烷基琥珀酰亚胺,2-十一烷基-7,7,9,9-四甲基-1-氧杂-3,8-二氮杂-4-氧代-螺[4,5]癸烷,7,7,9,9-四甲基-2-环十一烷基-1-氧杂-3,8-二氮杂-4-氧代螺[4,5]癸烷和表氯醇的反应产物,1,1-双(1,2,2,6,6-五甲基-4-哌啶氧基羰基)-2-(4-甲氧基苯基)乙烯,N,N′-二-甲酰基-N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺,4-甲氧基-亚甲基-丙二酸和1,2,2,6,6-五甲基4-羟基哌啶的二酯,聚[甲基丙基-3-氧基-4-(2,2,6,6-四甲基4-哌啶基)]硅氧烷,马来酸酐-α-烯烃-共聚物和2,2,6,6-四甲基-4-氨基哌啶或1,2,2,6,6-五甲基-4-氨基哌啶的反应产物,1,1′-(1,2-乙烷二基)双(3,3,5,5-四甲基哌啶酮),二甲基琥珀酸酯聚合物和4-羟基-2,2,6,6-四甲基-1-哌啶乙醇(CibaGeigy TINUVIN622),和得自Ciba Geigy、商品名为CHIMASSORB944的聚合受阻胺。
组合物可包括含量为0.5~3.0重量%的受阻胺光稳定剂。在该范围内,受阻胺光稳定剂的存在量可大于或等于0.6重量%,或者更具体地,该量大于或等于0.7重量%,或者甚至更具体地,该量大于或等于0.8重量%。同样在该范围内,受阻胺光稳定剂的存在量可小于或等于2.9重量%,或者更具体地小于或等于2.8重量%,或者甚至更具体地小于或等于2.7重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
紫外光吸收化合物包括苯并三唑化合物和二苯酮化合物。苯并三唑和二苯酮可以单独使用或结合使用。有用的苯并三唑化合物可包括2-(2′-羟苯基)苯并三唑。示例性的苯并三唑化合物包括但不限于2-(2′-羟基-5′-甲基苯基)-苯并三唑,2-(3′,5′-二叔丁基-2′-羟苯基)苯并三唑,2-(5′-叔丁基-2′-羟苯基)苯并三唑,2-(2′-羟基-5′-(1,1,3,3-四甲基丁基)苯基)苯并三唑,2-(3′,5′-二叔丁基-2′-羟苯基)-5-氯-苯并三唑,2-(3′-叔丁基-2′-羟基-5′-甲基苯基)-5-氯-苯并三唑,2-(3′-仲丁基-5′-叔丁基-2′-羟苯基)苯并三唑,2-(2′-羟基-5′-环己基苯基)-苯并三唑,2-(2′-羟基-3′-甲基-5′-叔丁基苯基)-苯并三唑,2-(2′-羟基-3′,5′-二甲基苯基)-苯并三唑,2-(2′-羟基-4′-辛氧基苯基)苯并三唑,2-(3′,5′-二叔戊基-2′-羟苯基)苯并三唑,2-(3′,5′-双-(α,α-二甲基苯甲基)-2′-羟苯基)苯并三唑,2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)-5-氯-苯并三唑,2-(3′-叔丁基-5′-[2-(2-乙基己氧基)-羰基乙基]-2′-羟苯基)-5-氯-苯并三唑,2-(3′-叔丁基-2′-羟基-5′-(2-甲氧基羰基乙基)苯基)-5-氯-苯并三唑,2-(3′-叔丁基-2′-羟基-5′-(2-甲氧基羰基乙基)苯基)苯并三唑,2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)苯并三唑,2-(3′-叔丁基-5′-[2-(2-乙基己氧基)羰基乙基]-2′-羟苯基)苯并三唑,2-(3′-十二烷基-2′-羟基-5′-甲基苯基)苯并三唑,2-(3′-叔丁基-2′-羟基-5′-(2-异辛氧基羰基乙基)苯基苯并三唑,2,2′-亚甲基-双[4-(1,1,3,3-四甲基丁基)-6-苯并三唑-2-烷基苯酚],2-[3′-叔丁基-5′-(2-甲氧基羰基乙基)-2′-羟苯基]-2H-苯并三唑和聚乙二醇300的酯交换产物;[R-CH2CH2-COO-CH2CH2]2,其中R=3′-叔丁基-4′-羟基-5′-2H-苯并三唑-2-基苯基,2-[2′-羟基-3′-(α,α-二甲基苯甲基)-5′-(1,1,3,3-四甲基丁基)-苯基]-苯并三唑,2-[2′-羟基-3′-(1,1,3,3-四甲基丁基)-5′-(α,α-二甲基苯甲基)-苯基]苯并三唑,2-(2′-羟基-5′-叔丁基苯基)-5-氯-苯并三唑,以及2-(2′-羟基-3′-二叔丁基苯基)-苯并三唑。
二苯酮化合物可包含在一个或多个芳环上取代的一个或多个羟基。在一实施方案中,二苯酮化合物包括在邻(2)位的羟基(也称为β-羟基取代),以及在同一环上其他位置的,特别是“4”位或对位上的羟基、烷氧基或烷基醚基团。通常,这些化合物是具有下式的那些:
其中R9为氢、具有1~25个碳原子的直链或支链烷烃的一价或二价基团,未取代的或被一个羟基或多个羟基取代;R10和R9的定义相同,不同的是它总是一价基团,其中在同一化合物中R9和R10相同或相异;R7和R8独立地为羟基、具有1~约10个碳原子的直链或支链烷基,或者具有1~约10个碳原子的烷氧基;f为0或1,但当R9代表氢原子时总是为0;t为0或1~5的整数;以及w为0或1~3的整数。
示例性的二苯酮化合物包括但不限于,2-羟基二苯酮,例如4-羟基,4-甲氧基,4-辛氧基,4-癸氧基,4-十二烷氧基,4-苯甲氧基,4,2′,4′-三羟基和2′-羟基-4,4′-二甲氧基衍生物。示例性的二苯酮化合物还包括2,2′-二羟基二苯酮;2,2′4,4′-四羟基二苯酮;2,2′-二羟基-4,4′-二甲氧基二苯酮;2,2′-二羟基-4,4′-二乙氧基二苯酮;2,2′-二羟基-4,4′-二丙氧基二苯酮;2,2′-二羟基-4,4′-二丁氧基二苯酮;2,2′-二羟基-4-甲氧基-4′-乙氧基二苯酮;2,2′-二羟基-4-甲氧基-4′-丙氧基二苯酮;2,2′-二羟基-4-甲氧基-4′-丁氧基二苯酮;2,2′-二羟基-4-乙氧基-4′-丙氧基二苯酮;2,2′-二羟基-4-乙氧基-4′-丁氧基二苯酮;2,3′-二羟基-4,4′-二甲氧基二苯酮;2,3′-二羟基-4-甲氧基-4′-丁氧基二苯酮;2-羟基-4,4′,5′-三甲氧基二苯酮;2-羟基-4,4′,6′-三丁氧基二苯酮;2-羟基-4-丁氧基-4′,5′-二甲氧基二苯酮;2-羟基-4-乙氧基-2′,4′-二丁基二苯酮;2-羟基-4-丙氧基-4′,6′-二氯二苯酮;2-羟基-4-丙氧基-4′,6′-二溴二苯酮;2,4-二羟基二苯酮;2-羟基-4-甲氧基二苯酮;2-羟基-4-乙氧基二苯酮;2-羟基-4-丙氧基二苯酮;2-羟基-4-丁氧基二苯酮;2-羟基-4-甲氧基-4′-甲基二苯酮;2-羟基-4-甲氧基-4′-乙基二苯酮;2-羟基-4-甲氧基-4′-丙基二苯酮;2-羟基-4-甲氧基-4′-丁基二苯酮;2-羟基-4-甲氧基-4′-叔丁基二苯酮;2-羟基-4-甲氧基-4′-氯二苯酮;2-羟基-4-甲氧基-2′-氯二苯酮;2-羟基-4-甲氧基-4′-溴二苯酮;2-羟基-4,4′-二甲氧基二苯酮;2-羟基-4,4′-二甲氧基-3-甲基二苯酮;2-羟基-4,4′-二甲氧基-2′-乙基二苯酮;2-羟基-4,4′,5′-三甲氧基二苯酮;2-羟基-4-乙氧基-4′-甲基二苯酮;2-羟基-4-乙氧基-4′-乙基二苯酮;2-羟基-4-乙氧基-4′-丙基二苯酮;2-羟基-4-乙氧基-4′-丁基二苯酮;2-羟基-4-乙氧基-4′-甲氧基二苯酮;2-羟基-4,4′-二乙氧基二苯酮;2-羟基-4-乙氧基-4′-丙氧基二苯酮;2-羟基-4-乙氧基-4′-丁氧基二苯酮;2-羟基-4-乙氧基-4′-氯二苯酮;和2-羟基-4-乙氧基-4′-溴二苯酮。
组合物可包括含量为0.5~5重量%的紫外光吸收剂。在该范围内,紫外光吸收剂的存在量可大于或等于0.6重量%,或者更具体地,该量大于或等于0.7重量%,或者甚至更具体地,该量大于或等于0.8重量%。同样在该范围内,紫外光吸收剂的存在量可小于或等于4.9重量%,或者更具体地小于或等于4.8重量%,或者甚至更具体地小于或等于4.7重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
光致漂白性染料定义为在曝光时褪色的有机染料或颜料。在一实施方案中,光致漂白性染料包括紫色蒽吡啶酮(anthrapyridone)染料和/或具有以下结构主链的黄色醌酞酮(quinophtalone)染料:
它们可以携带取代基,除了在结构主链的3′位具有羟基取代基的这类黄色醌酞酮染料和/或紫色蒽吡啶酮染料之外。醌酞酮类染料本身是已知的;在Helvetia Chimica Acta,vol.52,fasc.5(1969)p.1259-1273中可以找到一系列合适的醌酞酮类染料,该文献列举了一些醌酞酮类染料,其中在3′位没有羟基取代基的黄色醌酞酮类染料可以用作光致漂白性染料。
光致漂白性染料的实例包括颜色索引(下文表示为C.I.)溶剂黄4,C.I.溶剂黄16,C.I.溶剂黄17,C.I.溶剂黄28,C.I.溶剂黄30,C.I.溶剂黄33,C.I.溶剂黄34,C.I.溶剂黄44,C.I.溶剂黄58,C.I.溶剂黄77,C.I.溶剂黄82,C.I.溶剂橙1,C.I.溶剂橙13,C.I.溶剂红52,C.I.溶剂橙45,C.I.溶剂绿5,C.I颜料黄13,C.I.颜料黄83,C.I.颜料黄97,C.I.颜料黄98,C.I.颜料黄108,C.I.颜料黄138,C.I.颜料橙4。C.I.溶剂黄33是购自American Color & Chemical Co.的Amaplast Yellow Y,是在醌酞酮主链上没有任何取代基的醌酞酮类染料。C.I.颜料黄138是购自BASF的Paliotol Yellow K0961 HD。C.I.溶剂红52是购自Messrs.Bayer Ag的Macrolex Red 5B,且被认为是被卤素原子和一个或多个芳香基团取代且3′位没有羟基的醌酞酮类染料。
组合物可包括含量为0.01~1.0重量%的光致漂白性染料。在该范围内,光致漂白性染料的存在量可大于或等于0.02重量%,或者更具体地,该量大于或等于0.03重量%。同样在该范围内,光致漂白性染料的存在量可小于或等于0.9重量%,或者更具体地小于或等于0.8重量%,或者甚至更具体地小于或等于0.7重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
抗氧化剂包括亚磷酸酯和亚膦酸酯。示例性的亚磷酸酯包括亚磷酸三苯酯、二苯基烷基亚磷酸酯、苯基二烷基亚磷酸酯、三(壬基苯基)亚磷酸酯、亚磷酸三月桂酯、亚磷酸三(十八烷)酯、二(十八烷基)季戊四醇二亚磷酸酯、三(2,4-二叔丁基苯基)亚磷酸酯、二异癸基季戊四醇二亚磷酸酯、双(2,4-二叔丁基苯基)季戊四醇二亚磷酸酯、双(2,6-二叔丁基-4-甲基苯基)-季戊四醇二亚磷酸酯、二异癸氧基季戊四醇二亚磷酸酯、双(2,4-二叔丁基-6-甲基苯基)季戊四醇二亚磷酸酯、双(2,4,6-三(叔丁基苯基)季戊四醇二亚磷酸酯、三(十八烷基)山梨糖醇三亚磷酸酯、四(2,4-二叔丁基苯基)4,4′-亚联苯基二亚膦酸酯、6-异辛氧基-2,4,8,10-四叔丁基-12H-二苯并[d,g]-1,3,2-二氧杂磷杂环辛烯(dioxaphosphocin),双(2,4-二叔丁基-6-甲基苯基)甲基亚磷酸盐,双(2,4-二叔丁基-6-甲基苯基)乙基亚磷酸酯,6-氟-2,4,8,10-四叔丁基-12-甲基-二苯并[d,g]-1,3,2-二氧杂磷杂环辛烯,2,2′,2″-次氮基[三乙基三(3,3′,5,5′-四叔丁基-1,1′-联苯基-2,2′-二基)亚磷酸酯],2-乙基己基(3,3′,5,5′-四叔丁基-1,1′-联苯基-2,2′-二基)亚磷酸酯,5-丁基-5-乙基-2-(2,4,6-三叔丁基苯氧基)-1,3,2-二氧杂磷杂环丙烷,三(2,4-二叔丁基苯基)亚磷酸酯和三(壬基苯基)亚磷酸酯。
组合物可包括含量为0.05~1.5重量%的抗氧化剂。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
环氧化合物是包含环氧基团的化合物。例如,合适的环氧化合物是下式表示的化合物:
其中R11、R12、R13和R14表示有机基团。示例性的环氧化合物包括3,4-环氧六氢苯甲基-3,4-环氧-六氢苯甲酸酯和三缩水甘油基异氰脲酸酯。
在一实施方案中,环氧化合物包括环状脂肪族环氧化合物(或者它们也可以称为脂环族环氧化物)。实例包括乙烯基环己烯二氧化物(vinylcyclohexene dioxide),3,4-环氧-环己基甲基-3,4-环氧环己烷羧酸酯,2-(3,4-环氧环己基)-5,5-螺(3,4-环氧)环己烷-间-二噁烷,双(3,4-环氧-6-甲基环己基甲基)己二酸酯,双(2,3-环氧环戊基)醚,二环戊二烯二氧化物,1,2-环氧-6-(2,3-环氧丙氧基)六氢-4,7-桥亚甲基茚满(1,2-epoxy-6-(2,3-epoxypropoxy)hexahydro-4,7-methanoindane),二-3,4-环氧-2,5-桥亚甲基环己基琥珀酸酯和双环氧二环戊基琥珀酸酯。另一实例是具有以下结构的3,4-环氧环己基-甲基-3,4-环氧环己烷羧酸酯:
具有该结构的一种商品是Ciba-Geigy Corporation制造的,商品名为ARALDITE CY179。
组合物可包括含量为0.5~5重量%的环氧化合物。在该范围内,环氧化合物存在的量可大于或等于0.6重量%,或者更具体地,该量大于或等于0.7重量%,或者甚至更具体地,该量大于或等于0.8重量%。同样在该范围内,环氧化合物存在的量可小于或等于4.9重量%,或者更具体地小于或等于4.8重量%,或者甚至更具体地小于或等于4.7重量%。所述重量%以聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为基准。
此外,组合物还任选包含各种添加剂,例如填料和增强剂,例如硅酸盐、TiO2、纤维、玻璃纤维(包括长纤和切断纤维)、碳黑、石墨、碳酸钙、滑石、云母和其他添加剂,例如脱模剂、润滑剂、增塑剂、颜料、染料、着色剂、抗静电剂、发泡剂和抗冲改性剂,等等。
在一实施方案中,组合物包括聚亚芳基醚、聚(链烯基芳香族)树脂、有机二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物。组合物还任选包括光致漂白性染料、抗氧化剂、环氧化合物或两种或多种上述添加剂的组合。组合物在3毫米厚度下可具有V1或更好的UL 94等级,或更具体地,具有V0等级。当如上述进行测量时,组合物的色移小于6,或者更具体地,小于5,或者甚至更具体地,小于4.5。
在一实施方案中,母料包括树脂、双酚A二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物。树脂可以是聚亚芳基醚、聚(链烯基芳香族)树脂或适用于聚亚芳基醚组合物的其他树脂。母料包含有机二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物,其含量高于在最终组合物中的含量。在母料中每种组分的确切含量将取决于最终组合物中需要的含量和可得的混合装置。母料可任选包括抗氧化剂、光致漂白性染料、环氧化合物,或上述物质的两种或多种的组合。在制备组合物时使用母料可以促进组分的分散。
组合物可以通过以下方法制备:用充足的能量将聚亚芳基醚、聚(链烯基芳香族)树脂、有机二磷酸酯、受阻胺光稳定剂、紫外光吸收化合物和其他需要的组分共混,形成共混物。可以在挤出机、辊炼机、料团混合机等中进行共混。聚合物树脂在最初可以为粉末、线料或粒料的形式,且可以与组合物的任何其他组分预混或干混。
通过以下非限制性实施例进一步说明所述组合物。
实施例
在表1中示出了以下实施例采用的物质。
表1
组分 | 规格/供应商 |
PPE I | 聚苯醚,在25℃氯仿中测量时特性粘度为0.31dl/g。 |
PPE II | 聚苯醚,在25℃氯仿中测量时特性粘度为0.46dl/g。 |
HIPS I | 市售的橡胶改性的聚苯乙烯,在200℃和5千克下的熔体流动指数为3克/10分钟。 |
HIPS II | 市售的高流动性橡胶改性的聚苯乙烯,在200℃和5千克下的熔体流动指数为7克/10分钟。 |
HALS | 受阻胺光稳定剂,购自Ciba SpecialtyChemicals,商品名为Tinuvin 770。 |
UV 1 | 羟基苯并三唑紫外光吸收剂,购自Cytec,商品名为Cyasorb UV5411。 |
UV 2 | 羟基苯并三唑紫外光吸收剂,购自CibaSpecialty Chemicals,商品名为Tinuvin 234。 |
UV 3 | 二苯酮紫外光吸收剂,购自Cytec,商品名为Cyasorb 531。 |
BPADP I | 双酚A四苯基二磷酸酯 |
BPADP I | 双酚A四苯基二磷酸酯 |
RDP I | 间苯二酚二磷酸酯 |
71B | 丁基化的磷酸三苯酯 |
TiO2 | 二氧化钛 |
环氧I | 环氧化合物,购自Dow Chemical,商品名为ERL-4221。CAS No.2386-87-0。 |
实施例1-17
通过熔融共混制备含有31.3wt%PPE I、45.4wt%HIPS I和19wt%RDP或BPADP的组合物,基于PPE I、HIPS I、添加剂和RDP或BPADP的总重量。组合物还包括总共4.3wt%的添加剂,例如颜料、光致漂白性染料和脱模剂,基于PPE I、HIPS I、添加剂和RDP或BPADP的总重量。如表2所示,改变UV光吸收化合物、TiO2和环氧化合物,且含量是以重量%计,基于PPE I、HIPS I、添加剂和BPADP或RDP的总重量。将PPE I和添加剂进行干混并在挤出机的进料口与UV I或UV II、HALS、TiO2、环氧化合物及HIPS一起加入。在下游添加RDP或BPADP。将组合物注塑为实验样片(plaque)(2英寸×3英寸)并依照ASTM D4459气候老化300小时。使用Gretag MacBeth分光光度计根据ASTM 2244由L*、a*和b*值确定色移(dE)。经校准的分光光度计采用反射模式测量颜色。结果示于表2。
表2
实施例 | UVA类型 | UVA含量 | TiO2含量 | HALS | 环氧化合物含量 | 阻燃剂类型 | dE |
1* | I | 1 | 4 | 1 | 0 | RDP | 9.99 |
2* | I | 3 | 4 | 1 | 2 | RDP | 4.02 |
3* | II | 1 | 4 | 1 | 2 | RDP | 8.24 |
4* | II | 3 | 4 | 1 | 0 | RDP | 7.48 |
1 | |||||||
5 | I | 1 | 4 | 1 | 2 | BPADP | 4.99 |
6 | I | 3 | 4 | 1 | 0 | BPADP | 4.22 |
7 | II | 1 | 4 | 1 | 0 | BPADP | 7.56 |
8 | II | 3 | 4 | 1 | 2 | BPADP | 2.96 |
9* | I | 1 | 12 | 1 | 2 | RDP | 7.71 |
10* | I | 3 | 12 | 1 | 0 | RDP | 8.14 |
11* | II | 1 | 12 | 1 | 0 | RDP | 11.09 |
12* | II | 3 | 12 | 1 | 2 | RDP | 6.68 |
1 | |||||||
13 | I | 1 | 12 | 1 | 0 | BPADP | 7.96 |
14 | I | 3 | 12 | 1 | 2 | BPADP | 3.8 |
15 | II | 1 | 12 | 1 | 2 | BPADP | 6.50 |
16 | II | 3 | 12 | 1 | 0 | BPADP | 6.61 |
*比较例
正如从上述实施例可以看到的,相比于含有间苯二酚二磷酸酯的组合物,当组合物含有双酚A二磷酸酯时,dE值令人惊讶地更低。当UV吸收化合物的含量基于PPE I、HIPS I、添加剂和RDP或BPADP的总重量大于1重量%且存在环氧化合物时,同样出现令人惊讶的改进。
实施例18-21
通过熔融共混制备含有31.3wt%PPE I、45.4wt%HIPS I和19wt%RDP或BPADP的组合物,基于PPE I、HIPS I、添加剂和RDP或BPADP的总重量。组合物还包括总共4.6wt%的添加剂,例如颜料、光致漂白性染料、抗氧化剂和脱模剂,基于PPE I、HIPS I和RDP或BPADP的总重量。如表3所示,改变UV光吸收化合物、TiO2和受阻胺光稳定剂,且含量是以重量%计,基于PPE I、HIPS I、添加剂和BPADP或RDP的总重量。将PPE和添加剂干混并在挤出机的进料口与UV吸收化合物、HALS、TiO2及HIPS一起加入。在下游添加RDP或BPADP。将组合物注塑为片(2英寸×3英寸)并依照ASTM D4459气候老化300小时。如上所述测定色移(dE)。经校准的分光光度计采用反射模式测量颜色。结果示于表3。
表3
实施例 | UV 1含量 | HALS I含量 | TiO2含量 | RDP | BPADP | dE |
18* | 0.5 | 1.0 | 4.0 | X | - | 8.6 |
19 | 0.5 | 1.0 | 4.0 | - | X | 4.6 |
20* | 1.5 | 1.0 | 12.0 | X | - | 6.0 |
21 | 1.5 | 1.0 | 12.0 | - | X | 3.9 |
*比较例
实施例18-21显示,含有双酚A二磷酸酯的组合物的dE显著小于含有间苯二酚二磷酸酯的对比组合物的dE,在双酚A二磷酸酯和间苯二酚二磷酸酯都是芳香族二磷酸酯的事实下,这是令人惊讶的。
实施例22-25
通过熔融共混制备含有28wt%PPE I、49-51wt%HIPS II和18.7wt%RDP或BPADP的组合物,基于PPE I、HIPS II、添加剂和RDP或BPADP的总重量。组合物还包括总共6.8-8.8wt%的添加剂,例如颜料、抗氧化剂和脱模剂,基于PPE I、HIPS II和RDP或BPADP的总重量。将PPE加上颜料和添加剂(包括UV吸收化合物和HALS,如果存在的话)进行干混,并在挤出机的进料口和HIPS一起加入。在下游添加RDP或BPADP。将组合物注塑为盘(直径为10cm,厚度为3.2mm)并依照ASTM D4459测试300小时。如上所述测定色移(dE)。结果示于表4。
表4
实施例 | HIPS含量 | UV 1含量 | HALS I含量 | RDP | BPADP | dE | |
22* | 51 | 0 | 0 | X | - | 17.1 | |
23* | 49 | 1.0 | 1.0 | X | - | 9.8 | |
24 | 51 | 0 | 0 | - | X | 12.9 | |
25 | 49 | 1.0 | 1.0 | - | X | 5.0 |
*比较例
实施例22-25显示,含有双酚A二磷酸酯的组合物的dE显著小于含有间苯二酚二磷酸酯的对比组合物的dE,在双酚A二磷酸酯和间苯二酚二磷酸酯都是芳香族二磷酸酯的事实下,这是令人惊讶的。
本文中使用“第一”、“第二”等词并不表示任何次序、数量或重要性,而是用来将一要素和其他要素区分开来,本文中的“一种”和“一个”并不表示对数量进行限制,而是表示存在至少一个所述对象。
虽然参考示例性实施方案描述了本发明,但本领域的技术人员应理解,在不偏离本发明的范围下可以进行各种变化,以及可以用等同物代替其要素。另外,根据本发明的教导在不偏离其基本范围下,可以进行许多改进以适用于特定的场合或材料。因此,其意指本发明不限定为用于实施本发明的作为预期的最好模式而公开的具体实施方案,而是意指本发明将包括落入所附权利要求书的范围内的所有实施方案。
Claims (26)
1.一种组合物,其包含聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物,其中组合物的色移(dE)小于6,阻燃性为V1或更好,该色移(dE)是根据ASTM D4459气候老化300小时之后依照ASTM D2244测定的,该阻燃性是在3毫米厚度下依照UL94测定的。
2.权利要求1的组合物,其中聚亚芳基醚包括聚亚芳基醚和官能化剂的反应产物。
3.权利要求2的组合物,其中官能化剂包含马来酸酐。
4.权利要求1的组合物,其中聚亚芳基醚存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为20~80重量%。
5.权利要求1的组合物,其中聚(链烯基芳香族)树脂包括橡胶改性的聚(链烯基芳香族)树脂。
6.权利要求1的组合物,其中聚(链烯基芳香族)树脂存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为20~80重量%。
7.权利要求1的组合物,其中双(羟基苯)二磷酸酯具有下式:
其中R3为具有1~5个碳的烷基,R5各自独立地为具有1~8个碳的烷基或具有6~12个碳的芳基;R4各自为具有1~12个碳的烷基、芳基、烷氧基或芳氧基;X2和X3独立地为卤素或甲基;h和r为0或1~4的整数,以及q为1~10。
8.权利要求1的组合物,其中双(羟基苯)二磷酸酯包括双酚A二磷酸酯。
9.权利要求1的组合物,其中双(羟基苯)二磷酸酯存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为5~30重量%。
10.权利要求1的组合物,其中受阻胺光稳定剂存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为0.5~3.0重量%。
11.权利要求1的组合物,其中紫外光吸收化合物包括苯并三唑、二苯酮或它们的组合。
12.权利要求1的组合物,其中紫外光吸收剂存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为0.5~5重量%。
13.权利要求1的组合物,其进一步包括光致漂白性染料。
14.权利要求13的组合物,其中光致漂白性染料存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为0.01~1.0重量%。
15.权利要求1的组合物,其进一步包括抗氧化剂。
16.权利要求1的组合物,其进一步包括环氧化合物。
17.权利要求16的组合物,其中环氧化合物存在的量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为0.5~5重量%。
18.权利要求1的组合物,其中组合物进一步包括填料、增强剂、碳黑、石墨、碳酸钙、滑石、云母、脱模剂、润滑剂、增塑剂、颜料、染料、着色剂、抗静电剂、发泡剂,或上述两种或多种物质的组合。
19.一种组合物,其包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物,其中受阻胺光稳定剂和紫外光吸收化合物存在的总量基于聚亚芳基醚和聚(链烯基芳香族)树脂的总重量为2.5~5重量%,该组合物的色移小于6且阻燃性为V1或更好,该色移是根据ASTM D4459气候老化300小时之后依照ASTM D2244测定的,该阻燃性是在3毫米厚度下依照UL94测定的。
20.一种组合物,其包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯,受阻胺光稳定剂、紫外光吸收化合物和环氧化合物。
21.权利要求20的组合物,其中该组合物的色移(dE)小于或等于5,该色移是根据ASTM D4459气候老化300小时之后依照ASTM D2244测定的。
22.权利要求20的组合物,其中该组合物的阻燃性根据UL 94为V1或更好。
23.一种组合物,其包括聚亚芳基醚、聚(链烯基芳香族)树脂、双(羟基苯)二磷酸酯、受阻胺光稳定剂、光致漂白性染料、紫外光吸收化合物、抗氧化剂和环氧化合物。
24.权利要求23的组合物,其中该组合物的色移(dE)小于或等于5,该色移是根据ASTM D4459气候老化300小时之后依照ASTM D2244测定的。
25.权利要求23的组合物,其中该组合物的阻燃性根据UL 94为V1或更好。
26.一种母料,其包括树脂、双酚A二磷酸酯、受阻胺光稳定剂和紫外光吸收化合物。
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CN112662162A (zh) * | 2020-12-17 | 2021-04-16 | 上海日之升科技有限公司 | 一种抗紫外黄变led用浅色聚苯醚组合物及其制备方法 |
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US7585906B2 (en) * | 2007-02-28 | 2009-09-08 | Sabic Innovative Plastics Ip B.V. | Poly(arylene ether) composition, method, and article |
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CN109071914A (zh) * | 2016-04-25 | 2018-12-21 | 沙特基础工业全球技术有限公司 | 聚(苯醚)组合物和制品 |
CN112662162A (zh) * | 2020-12-17 | 2021-04-16 | 上海日之升科技有限公司 | 一种抗紫外黄变led用浅色聚苯醚组合物及其制备方法 |
CN112662162B (zh) * | 2020-12-17 | 2022-09-16 | 上海日之升科技有限公司 | 一种抗紫外黄变led用浅色聚苯醚组合物及其制备方法 |
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