CN100554311C - 有机化合物的烷氧基化方法 - Google Patents

有机化合物的烷氧基化方法 Download PDF

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Publication number
CN100554311C
CN100554311C CNB028228987A CN02822898A CN100554311C CN 100554311 C CN100554311 C CN 100554311C CN B028228987 A CNB028228987 A CN B028228987A CN 02822898 A CN02822898 A CN 02822898A CN 100554311 C CN100554311 C CN 100554311C
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CN
China
Prior art keywords
initiator
alkylene oxide
hydrogen fluoride
dmc
product
Prior art date
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Expired - Fee Related
Application number
CNB028228987A
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English (en)
Chinese (zh)
Other versions
CN1589290A (zh
Inventor
M·B·埃利威尔德
J·H·H·穆尔司
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Shell Internationale Research Maatschappij BV
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Shell Internationale Research Maatschappij BV
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Publication of CN1589290A publication Critical patent/CN1589290A/zh
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Publication of CN100554311C publication Critical patent/CN100554311C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
CNB028228987A 2001-11-19 2002-11-18 有机化合物的烷氧基化方法 Expired - Fee Related CN100554311C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01309728 2001-11-19
EP01309728.2 2001-11-19

Publications (2)

Publication Number Publication Date
CN1589290A CN1589290A (zh) 2005-03-02
CN100554311C true CN100554311C (zh) 2009-10-28

Family

ID=8182473

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB028228987A Expired - Fee Related CN100554311C (zh) 2001-11-19 2002-11-18 有机化合物的烷氧基化方法
CNA028229606A Pending CN1589289A (zh) 2001-11-19 2002-11-18 环氧树脂的聚合方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA028229606A Pending CN1589289A (zh) 2001-11-19 2002-11-18 环氧树脂的聚合方法

Country Status (10)

Country Link
US (1) US20040254337A1 (https=)
EP (2) EP1448663B1 (https=)
JP (2) JP2005509707A (https=)
KR (2) KR20050044510A (https=)
CN (2) CN100554311C (https=)
AU (2) AU2002349039A1 (https=)
CA (1) CA2467488A1 (https=)
DE (1) DE60232988D1 (https=)
ES (1) ES2327722T3 (https=)
WO (2) WO2003044074A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060069220A1 (en) * 2004-09-28 2006-03-30 Meurs Jan Hermen H Process for preparing an alkoxylated alcohol or phenol
US8946486B2 (en) * 2007-12-03 2015-02-03 Tyco Fire & Security Gmbh Method of forming alkoxylated fluoroalcohols
CN101215367B (zh) * 2007-12-29 2010-08-11 海洋化工研究院 一种含全氟烷基侧链的环氧树脂及其制备方法和应用
JP5683115B2 (ja) * 2009-01-29 2015-03-11 花王株式会社 ポリグリセリルエーテル誘導体の製造方法
BR112013025054B1 (pt) * 2011-03-31 2020-03-17 Dow Global Technologies Llc Método para produzir um poliéter poliol de cadeia curta

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2293868A (en) * 1939-12-29 1942-08-25 Carbide & Carbon Chem Corp Polymerization products
US4456697A (en) * 1982-09-23 1984-06-26 Conoco Inc. Catalysts for alkoxylation reactions
EP0289159A2 (en) * 1987-04-28 1988-11-02 Vista Chemical Company Alkoxylation process using calcium based catalysts

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO120858B (https=) * 1964-06-29 1970-12-14 Stanislav Stary
US3576781A (en) * 1970-02-02 1971-04-27 Celanese Coatings Co Process for preparing fusible polyhydroxy-polyether resins
US5503937A (en) * 1984-07-17 1996-04-02 The Dow Chemical Company Curable composition which comprises adducts of heterocyclic compounds
CA1312040C (en) * 1985-12-19 1992-12-29 Joseph Victor Koleske Conformal coatings cured with actinic radiation
EP1276562B1 (en) * 2000-03-30 2003-09-17 Shell Internationale Researchmaatschappij B.V. Dmc complex catalyst and process for its preparation
US6331583B1 (en) * 2000-04-04 2001-12-18 Air Products And Chemicals, Inc. Acid catalyzed polymerization of aqueous epoxy resin emulsions and uses thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2293868A (en) * 1939-12-29 1942-08-25 Carbide & Carbon Chem Corp Polymerization products
US4456697A (en) * 1982-09-23 1984-06-26 Conoco Inc. Catalysts for alkoxylation reactions
EP0289159A2 (en) * 1987-04-28 1988-11-02 Vista Chemical Company Alkoxylation process using calcium based catalysts

Also Published As

Publication number Publication date
ES2327722T3 (es) 2009-11-03
DE60232988D1 (de) 2009-08-27
CA2467488A1 (en) 2003-05-30
AU2002349039A1 (en) 2003-06-10
JP2005509706A (ja) 2005-04-14
WO2003044074A1 (en) 2003-05-30
KR20050044510A (ko) 2005-05-12
CN1589289A (zh) 2005-03-02
KR100948010B1 (ko) 2010-03-18
JP2005509707A (ja) 2005-04-14
KR20040066823A (ko) 2004-07-27
EP1448663B1 (en) 2009-07-15
EP1448663A1 (en) 2004-08-25
US20040254337A1 (en) 2004-12-16
CN1589290A (zh) 2005-03-02
EP1448653A1 (en) 2004-08-25
WO2003044073A1 (en) 2003-05-30
AU2002366220A1 (en) 2003-06-10

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Granted publication date: 20091028

Termination date: 20121118