CN100540571C - 防水和防油的氟代丙烯酸酯 - Google Patents

防水和防油的氟代丙烯酸酯 Download PDF

Info

Publication number
CN100540571C
CN100540571C CNB2004800396766A CN200480039676A CN100540571C CN 100540571 C CN100540571 C CN 100540571C CN B2004800396766 A CNB2004800396766 A CN B2004800396766A CN 200480039676 A CN200480039676 A CN 200480039676A CN 100540571 C CN100540571 C CN 100540571C
Authority
CN
China
Prior art keywords
acrylic ester
fluoro acrylic
fluoro
ester
acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2004800396766A
Other languages
English (en)
Chinese (zh)
Other versions
CN1902244A (zh
Inventor
格雷格·A·考德威尔
约翰·C·克拉克
大卫·J·欣宁
艾伦·R·柯克
托马斯·P·克伦
拉梅什·C·库马尔
罗杰·A·马德
乔治·G·I·摩尔
裘再明
理查德·B·罗斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN1902244A publication Critical patent/CN1902244A/zh
Application granted granted Critical
Publication of CN100540571C publication Critical patent/CN100540571C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/22—Esters containing halogen
    • C08F20/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/20—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
    • C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/387—Esters containing sulfur and containing nitrogen and oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
    • Y10T442/2287—Fluorocarbon containing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
CNB2004800396766A 2003-12-31 2004-12-28 防水和防油的氟代丙烯酸酯 Expired - Fee Related CN100540571C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53420303P 2003-12-31 2003-12-31
US60/534,203 2003-12-31

Publications (2)

Publication Number Publication Date
CN1902244A CN1902244A (zh) 2007-01-24
CN100540571C true CN100540571C (zh) 2009-09-16

Family

ID=34748995

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800396766A Expired - Fee Related CN100540571C (zh) 2003-12-31 2004-12-28 防水和防油的氟代丙烯酸酯

Country Status (10)

Country Link
US (2) US7199197B2 (enExample)
EP (1) EP1709089B1 (enExample)
JP (1) JP2007523971A (enExample)
KR (1) KR20060117981A (enExample)
CN (1) CN100540571C (enExample)
AT (1) ATE388172T1 (enExample)
BR (1) BRPI0418241A (enExample)
CA (1) CA2551874A1 (enExample)
DE (1) DE602004012324T2 (enExample)
WO (1) WO2005066224A1 (enExample)

Families Citing this family (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0418241A (pt) 2003-12-31 2007-04-17 3M Innovative Properties Co fluoroacrilato, isocianato fluorado, polìmero acrìlico fluorado, composição de revestimento, e, artigo
US7081545B2 (en) * 2003-12-31 2006-07-25 3M Innovative Properties Company Process for preparing fluorochemical monoisocyanates
US7291688B2 (en) 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US20060142530A1 (en) * 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US7253241B2 (en) 2004-12-28 2007-08-07 3M Innovative Properties Company Fluorochemical containing low adhesion backsize
US7411020B2 (en) 2004-12-28 2008-08-12 3M Innovative Properties Company Water-based release coating containing fluorochemical
US7345123B2 (en) * 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US7495118B2 (en) * 2004-12-30 2009-02-24 3M Innovative Properties Company Compositions containing C4-swallow tail silanes
KR20080033306A (ko) 2005-06-29 2008-04-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 올리고머형 플루오로아크릴레이트로부터 유도된 폴리우레탄
US20070029085A1 (en) * 2005-08-05 2007-02-08 Panga Mohan K Prevention of Water and Condensate Blocks in Wells
US7279210B2 (en) * 2005-09-07 2007-10-09 3M Innovative Properties Company Curable compositions, methods of making and using the same, and articles therefrom
US7560166B2 (en) * 2005-12-28 2009-07-14 3M Innovative Properties Company Adhesive article, composite article, and methods of making the same
US7629298B2 (en) * 2006-02-21 2009-12-08 3M Innovative Properties Company Sandstone having a modified wettability and a method for modifying the surface energy of sandstone
WO2007102991A1 (en) * 2006-03-08 2007-09-13 3M Innovative Properties Company Controlled architecture materials
US7772162B2 (en) 2006-03-27 2010-08-10 Board Of Regents, The University Of Texas System Use of fluorocarbon surfactants to improve the productivity of gas and gas condensate wells
US20070225176A1 (en) * 2006-03-27 2007-09-27 Pope Gary A Use of fluorocarbon surfactants to improve the productivity of gas and gas condensate wells
US7569715B2 (en) * 2006-07-05 2009-08-04 3M Innovative Properties Company Compositions containing silanes
US7728098B2 (en) * 2006-07-27 2010-06-01 3M Innovative Properties Company Fluorochemical composition comprising fluorinated oligomeric silane
US20080047706A1 (en) * 2006-08-23 2008-02-28 Pope Gary A Method of obtaining a treatment composition for improving the productivity of hydrocarbon producing wells
US20080051300A1 (en) * 2006-08-23 2008-02-28 Pope Gary A Compositions and method for improving the productivity of hydrocarbon producing wells
US20080075951A1 (en) * 2006-09-27 2008-03-27 3M Innovative Properties Company Fluoroacrylates and hardcoat compositions including the same
US8530054B2 (en) * 2006-09-27 2013-09-10 3M Innovative Properties Company Solar control multilayer film
WO2008089391A1 (en) * 2007-01-19 2008-07-24 3M Innovative Properties Company Fluorinated surfactants and methods of using the same
US20100025038A1 (en) * 2007-01-19 2010-02-04 Savu Patricia M Methods of using stable hydrocarbon foams
US20100181068A1 (en) * 2007-03-23 2010-07-22 Board Of Regents, The University Of Texas System Method and System for Treating Hydrocarbon Formations
US8403050B2 (en) * 2007-03-23 2013-03-26 3M Innovative Properties Company Method for treating a hydrocarbon-bearing formation with a fluid followed by a nonionic fluorinated polymeric surfactant
EP2140103A4 (en) * 2007-03-23 2011-08-03 Univ Texas COMPOSITIONS AND METHOD FOR TREATING A WATER BLOCKED BOREOLE
EP2137280A4 (en) * 2007-03-23 2010-09-08 Univ Texas METHOD FOR TREATING A FRACTURED FORMATION
US20100224361A1 (en) * 2007-03-23 2010-09-09 Board Of Regents, The University Of Texas System Compositions and Methods for Treating a Water Blocked Well
RU2009138310A (ru) 2007-03-23 2011-04-27 Борд Оф Риджентс, Зе Юниверсити Оф Техас Систем (Us) Способ обработки формации растворителем
WO2008154421A1 (en) 2007-06-08 2008-12-18 3M Innovative Properties Company Blends of fluoroalkyl-containing ester oligomers with polydicarbodiimide(s)
US7897678B2 (en) * 2007-07-26 2011-03-01 3M Innovative Properties Company Fluorochemical urethane compounds having pendent silyl groups
US8015970B2 (en) * 2007-07-26 2011-09-13 3M Innovative Properties Company Respirator, welding helmet, or face shield that has low surface energy hard-coat lens
EP2238312A4 (en) * 2007-11-30 2011-08-17 Univ Texas METHOD FOR IMPROVING THE PRODUCTIVITY OF OIL EXTRACTION OILS
JP5485988B2 (ja) * 2008-06-12 2014-05-07 スリーエム イノベイティブ プロパティズ カンパニー メルトブローン微細繊維及び製造方法
EP2291285A4 (en) 2008-06-12 2011-11-02 3M Innovative Properties Co BIOCOMPATIBLE HYDROPHILIC COMPOSITIONS
KR101556810B1 (ko) * 2008-07-01 2015-10-01 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 기판에 그리스, 오일 및 수 반발성을 부여하는 방법
US20110232530A1 (en) * 2008-11-25 2011-09-29 Dams Rudolf J Fluorinated ether urethanes and methods of using the same
EP2370520B1 (en) 2008-12-17 2014-10-22 3M Innovative Properties Company Blended fluorosilicone release materials
JP5711211B2 (ja) 2009-03-31 2015-04-30 スリーエム イノベイティブ プロパティズ カンパニー 寸法安定性不織布繊維ウェブ並びにその製造及び使用方法
US8686179B2 (en) 2009-06-12 2014-04-01 3M Innovative Properties Company Fluorinated aromatic bis(acyl)-containing compounds and polyesters prepared therefrom
EP2497788B1 (en) * 2009-11-02 2014-09-24 Asahi Glass Company, Limited Fluorine-containing compound, fluorine-containing polymer and fluorine-containing copolymer
RU2539296C2 (ru) 2009-11-16 2015-01-20 Зм Инновейтив Пропертиз Компани Антиадгезионные материалы на основе фторсиликоновой смеси
MX347302B (es) * 2009-12-17 2017-04-21 3M Innovative Properties Company * Telas fibrosas no tejidas dimensionalmente estables y metodos para fabricar y utilizar las mismas.
EP2513365A4 (en) * 2009-12-17 2013-09-18 3M Innovative Properties Co DIMENSION-STABLE FIBER-NETS, MELT-BLOWN FIBER-FIBERS, AND METHOD FOR THEIR PRODUCTION AND USE
WO2011087717A1 (en) * 2009-12-22 2011-07-21 3M Innovative Properties Company Fluorinated arylene-containing compounds, methods, and polymers prepared therefrom
WO2011094342A1 (en) 2010-01-26 2011-08-04 3M Innovative Properties Company Low ghosting dry erase article and use thereof
KR20120125633A (ko) 2010-01-26 2012-11-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 소거가능한 필기 표면을 갖는 용품 및 그의 사용
AU2011218854B2 (en) 2010-02-23 2015-03-12 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
TW201221714A (en) 2010-10-14 2012-06-01 3M Innovative Properties Co Dimensionally stable nonwoven fibrous webs and methods of making and using the same
WO2012066084A1 (de) 2010-11-17 2012-05-24 Byk-Chemie Gmbh Aus urethan-basierten, polysiloxan enthaltenden makromonomeren erhältliche copolymere, verfahren zu deren herstellung und deren verwendung
US9508971B2 (en) 2011-02-28 2016-11-29 Nitto Denko Corporation Gas-permeable filter provided with oil repellency
KR102019408B1 (ko) 2012-03-12 2019-09-06 비와이케이-케미 게엠베하 방사선 경화성 코팅재 조성물용 첨가제로서의 폴리이소시아네이트 부가물
CN104204050B (zh) * 2012-04-06 2019-01-29 日东电工株式会社 赋予了拒油性的透气片
EP2692748B1 (de) * 2012-08-03 2015-01-21 Philipps-Universität Marburg Hydro- und oleophobe Polymerblends
JP6373363B2 (ja) 2013-05-31 2018-08-15 スリーエム イノベイティブ プロパティズ カンパニー フルオロアルキルシリコーン
US20150079865A1 (en) * 2013-09-17 2015-03-19 W.L. Gore & Associates, Inc. Conformable Microporous Fiber and Woven Fabrics Containing Same
WO2015050928A1 (en) 2013-10-04 2015-04-09 3M Innovative Properties Company Fluoroalkyl silicone compositions
US9938306B2 (en) 2013-10-04 2018-04-10 3M Innovative Properties Company Fluoroalkylsilanes and coatings therefrom
CN103666231B (zh) * 2013-12-11 2016-03-23 甘肃大禹节水集团股份有限公司 一种滴灌带抗太阳灼伤涂层材料及其使用方法
KR101515922B1 (ko) * 2013-12-12 2015-05-04 (주)제이엔티아이엔씨 발수성 향상용 조성물
JP2017517587A (ja) 2014-03-31 2017-06-29 スリーエム イノベイティブ プロパティズ カンパニー フルオロアルキルシリコーン
US20150361599A1 (en) * 2014-06-16 2015-12-17 W. L. Gore & Associates, Inc. Woven Fabrics Containing Expanded Polytetrafluoroethylene Fibers
SG11201703320QA (en) 2014-10-28 2017-05-30 3M Innovative Properties Co Spray application system components comprising a repellent surface & methods
JP6619008B2 (ja) * 2014-12-08 2019-12-11 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ コーティング材料組成物、およびそれらから生成されるコーティング、ならびにその使用方法
KR20170116113A (ko) * 2015-02-13 2017-10-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 아이소시아네이트-유도된 (메트)아크릴레이트-함유 중합체성 화합물을 포함하는 불소-무함유 조성물을 사용하여 섬유질 기재를 처리하는 방법
WO2017049185A1 (en) * 2015-09-17 2017-03-23 Ahmad Syed Taymur Process for protecting an electronic device by selective deposition of polymer coatings
CN113145341A (zh) 2015-10-28 2021-07-23 3M创新有限公司 包括拒液表面的喷雾施用系统部件和方法
US10584249B2 (en) 2015-10-28 2020-03-10 3M Innovative Properties Company Articles subject to ice formation comprising a repellent surface
EP3448944A4 (en) * 2016-04-26 2019-11-13 3M Innovative Properties Company ARTISTS SUBJECT TO ICE FORMATION WITH A REPELLENT SURFACE COMPRISING SILOXONE MATERIAL
US20180083662A1 (en) * 2016-09-16 2018-03-22 Syed Taymur Ahmad Process for protecting an electronic device by selective deposition of polymer coatings
JP6681520B1 (ja) 2017-02-15 2020-04-15 スリーエム イノベイティブ プロパティズ カンパニー 乾式消去物品
US10544260B2 (en) 2017-08-30 2020-01-28 Ppg Industries Ohio, Inc. Fluoropolymers, methods of preparing fluoropolymers, and coating compositions containing fluoropolymers
CN108211986B (zh) * 2017-12-29 2019-10-29 苏州昊通仪器科技有限公司 一种高分子表面活性剂、其制备方法及应用
CN110183918B (zh) * 2019-05-30 2021-07-23 温州澳南实业有限公司 一种长效型防粘贴涂料的制备方法
CN110746565A (zh) * 2019-10-14 2020-02-04 苏州联胜化学有限公司 一种耐水洗氟系防水剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4321404A (en) * 1980-05-20 1982-03-23 Minnesota Mining And Manufacturing Company Compositions for providing abherent coatings
CN1147811A (zh) * 1994-08-11 1997-04-16 W·L·戈尔及同仁股份有限公司 含氨基甲酸酯基的氟化丙烯酸单体及其聚合物
CN1149897A (zh) * 1995-03-31 1997-05-14 美国3M公司 防油和防水的水性组合物
EP0849392A2 (en) * 1996-12-20 1998-06-24 Nippon Mektron, Ltd. Fluoroalkylated allylurethane, its copolymer and water- and oil-repellent, anti-soiling processing agent containing the copolymer as an effective component

Family Cites Families (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2803615A (en) * 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbon acrylate and methacrylate esters and polymers
US3011988A (en) * 1957-05-21 1961-12-05 Minnesota Mining & Mfg Acrylic tetrapolymer, aqueous dispersion thereof and article coated therewith
GB870022A (en) 1959-06-23 1961-06-07 Minnesota Mining & Mfg Improvements in adhesive tapes
BE634770A (enExample) * 1961-05-03
US3282905A (en) * 1961-05-03 1966-11-01 Du Pont Fluorine containing esters and polymers thereof
US3398182A (en) * 1962-06-22 1968-08-20 Minnesota Mining & Mfg Fluorocarbon urethane compounds
US3278352A (en) * 1964-04-06 1966-10-11 Minnesota Mining & Mfg Composite propellants containing thioether elastomers
FR1468301A (fr) 1965-02-15 1967-02-03 American Cyanamid Co Mélange de polymères transparents plus particulièrement destinés aux enduits et produits stratifiés
GB1065780A (en) * 1965-02-15 1967-04-19 American Cyanamid Co Poly(vinylidene fluoride) compositions
US3318852A (en) * 1965-04-05 1967-05-09 Minnesota Mining & Mfg Fluorine-containing polymers
GB1120304A (en) 1966-02-23 1968-07-17 Minnesota Mining & Mfg Polycationically active polymers and their production
US3413226A (en) * 1966-05-09 1968-11-26 Lubrizol Corp Fluorine-containing copolymers
US3787351A (en) * 1972-02-28 1974-01-22 Minnesota Mining & Mfg Use of soluble fluoroaliphatic oligomers in resin composite articles
FR2483447A1 (fr) * 1980-06-03 1981-12-04 Ugine Kuhlmann Composition et procede pour la protection des materiaux contre les souillures
US4513059A (en) * 1982-02-02 1985-04-23 Permacel Release coating composition
JPS61148208A (ja) 1984-12-21 1986-07-05 Kuraray Co Ltd 含フツ素基を有するポリビニルエステル系重合体
US4792444A (en) * 1985-06-14 1988-12-20 Kao Corporation Cosmetic comprising fluoroalkyl (meth)acrylate copolymers
DE3531274A1 (de) * 1985-09-02 1987-03-12 Ant Nachrichtentech Schaltungsanordnung fuer eine rauscharme tonfrequenzquelle
FR2588555B1 (fr) * 1985-10-16 1987-12-11 Atochem Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers
FR2590895B1 (fr) * 1985-12-03 1988-01-15 Atochem Monomeres acryliques fluores, polymeres en derivant et leur application comme agents hydrophobes et oleophobes
US5144056A (en) * 1985-12-03 1992-09-01 Atochem Fluorinated acrylic monomers as hydrophobic and oleophobic agents
JPH01172416A (ja) * 1987-12-28 1989-07-07 Nippon Kayaku Co Ltd ウレタン（メタ）アクリレート混合物、それを用いた樹脂組成物及び光フアイバ用コーティング剤
US5115059A (en) * 1988-10-31 1992-05-19 Conoco Inc. Terpolymers of alkyl acrylates or methacrylates, an olefinically unsaturated homo or heterocyclic-nitrogen compound and an allyl acrylate or methacrylate
US5032460A (en) * 1989-08-14 1991-07-16 Minnesota Mining And Manufacturing Company Method of making vinyl-silicone copolymers using mercapto functional silicone chain-transfer agents and release coatings made therewith
DE3934543A1 (de) * 1989-10-17 1991-04-18 Bayer Ag Perfluoralkylgruppen enthaltende copolymerisate/ii
DE3935859A1 (de) * 1989-10-27 1991-05-02 Bayer Ag Dispersionen von perfluoralkylgruppen enthaltende copolymerisate
US6048952A (en) 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
JP3339873B2 (ja) * 1992-03-23 2002-10-28 大日本印刷株式会社 ホログラム形成材料
DE69310815T2 (de) 1992-07-03 1997-08-28 Asahi Glass Co Ltd Polyfluorkohlenwasserstoffgruppe enthaltende Monomere, ihre Polymere und die Anwendungen dieser Polymere
JP3399107B2 (ja) * 1994-09-05 2003-04-21 ダイキン工業株式会社 撥水撥油性を有する防汚加工剤組成物
US5635331A (en) 1994-10-13 1997-06-03 Minnesota Mining And Manufacturing Company Substrate and a color proofing article having release agent/adhesive mixture coated thereon
DE4441982A1 (de) * 1994-11-25 1996-05-30 Bayer Ag Öl-, wasser- und schmutzabweisend ausgerüstete Substrate und fluorhaltige Mittel hierzu
US6265060B1 (en) * 1995-03-15 2001-07-24 Imation Corp. Magnetic recording medium incorporating fluorine-containing, solvent-soluble vinyl copolymer having no vinyl chloride or vinylidene chloride components
US5725789A (en) * 1995-03-31 1998-03-10 Minnesota Mining And Manufacturing Company Aqueous oil and water repellent compositions
US5688884A (en) * 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5672651A (en) 1995-10-20 1997-09-30 Minnesota Mining And Manufacturing Company Durable repellent fluorochemical compositions
JP3982012B2 (ja) 1997-01-30 2007-09-26 ダイキン工業株式会社 新規組成物および処理剤
US5723630A (en) * 1997-02-18 1998-03-03 Minnesota Mining And Manufacturing Company Process for preparing fluorinated beta-sultones
US6001923A (en) * 1997-03-27 1999-12-14 Pilkington Aerospace Inc. Transparent fluorinated polyurethane coating compositions and methods of use thereof
US6197378B1 (en) * 1997-05-05 2001-03-06 3M Innovative Properties Company Treatment of fibrous substrates to impart repellency, stain resistance, and soil resistance
WO1998055078A1 (fr) * 1997-06-04 1998-12-10 Daikin Industries, Ltd. Copolymeres pour cosmetiques
EP0890621B1 (fr) * 1997-07-08 2005-12-21 Arkema Revêtement
US6121143A (en) 1997-09-19 2000-09-19 3M Innovative Properties Company Abrasive articles comprising a fluorochemical agent for wafer surface modification
US6238798B1 (en) 1999-02-22 2001-05-29 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
AU1440901A (en) * 1999-10-27 2001-05-08 3M Innovative Properties Company Fluorochemical sulfonamide surfactants
DE19962272A1 (de) * 1999-12-23 2001-06-28 Basf Ag Isocyanatgruppen aufweisende Bausteine sowie ihre Verwendung zur Funktionalisierung oder Modifizierung von Verbindungen oder Oberflächen
JP2001279578A (ja) * 2000-03-30 2001-10-10 Daikin Ind Ltd 繊維製品への撥水撥油処理
US6569521B1 (en) * 2000-07-06 2003-05-27 3M Innovative Properties Company Stretch releasing pressure sensitive adhesive tape and articles
JP5298399B2 (ja) 2000-09-21 2013-09-25 ダイキン工業株式会社 撥水撥油剤水性分散液組成物およびその製造方法
EP1225188B1 (en) 2001-01-19 2007-03-28 3M Innovative Properties Company Water soluble or water dispersible fluorochemical silanes for rendering substrates oil and water repellent.
ATE432298T1 (de) 2001-01-19 2009-06-15 3M Innovative Properties Co Fluorovinyloligomerkomponente mit silangruppen, flüssigzusammensetzungen daraus und beschichtungsverfahren
US7217760B2 (en) 2001-03-09 2007-05-15 Daikin Industries, Ltd. Water-and-oil repellant composition with improved suitability for cold cure
US6753380B2 (en) * 2001-03-09 2004-06-22 3M Innovative Properties Company Water-and oil-repellency imparting ester oligomers comprising perfluoroalkyl moieties
US6803109B2 (en) * 2001-03-09 2004-10-12 3M Innovative Properties Company Water-and oil-repellency imparting urethane oligomers comprising perfluoroalkyl moieties
WO2002083809A1 (en) * 2001-04-13 2002-10-24 Asahi Glass Company, Limited Water-and-oil repellant composition
US6482911B1 (en) * 2001-05-08 2002-11-19 3M Innovative Properties Company Fluoroalkyl polymers containing a cationogenic segment
US6689854B2 (en) * 2001-08-23 2004-02-10 3M Innovative Properties Company Water and oil repellent masonry treatments
US7056846B2 (en) 2001-12-04 2006-06-06 3M Innovative Properties Company Repellent fluorochemical compositions
US6890360B2 (en) 2001-12-17 2005-05-10 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
EP1329548A1 (en) 2002-01-21 2003-07-23 3M Innovative Properties Company Method of treatment of a textile or non-woven substrate to render same water and oil repellent
US20040147188A1 (en) * 2003-01-28 2004-07-29 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
US7247386B2 (en) * 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
BRPI0418241A (pt) 2003-12-31 2007-04-17 3M Innovative Properties Co fluoroacrilato, isocianato fluorado, polìmero acrìlico fluorado, composição de revestimento, e, artigo
US7081545B2 (en) * 2003-12-31 2006-07-25 3M Innovative Properties Company Process for preparing fluorochemical monoisocyanates
US20060142530A1 (en) 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US7291688B2 (en) 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US7345123B2 (en) 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US7253241B2 (en) 2004-12-28 2007-08-07 3M Innovative Properties Company Fluorochemical containing low adhesion backsize
US7411020B2 (en) 2004-12-28 2008-08-12 3M Innovative Properties Company Water-based release coating containing fluorochemical

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4321404A (en) * 1980-05-20 1982-03-23 Minnesota Mining And Manufacturing Company Compositions for providing abherent coatings
CN1147811A (zh) * 1994-08-11 1997-04-16 W·L·戈尔及同仁股份有限公司 含氨基甲酸酯基的氟化丙烯酸单体及其聚合物
CN1149897A (zh) * 1995-03-31 1997-05-14 美国3M公司 防油和防水的水性组合物
EP0849392A2 (en) * 1996-12-20 1998-06-24 Nippon Mektron, Ltd. Fluoroalkylated allylurethane, its copolymer and water- and oil-repellent, anti-soiling processing agent containing the copolymer as an effective component

Also Published As

Publication number Publication date
US20050143541A1 (en) 2005-06-30
EP1709089A1 (en) 2006-10-11
US7199197B2 (en) 2007-04-03
EP1709089B1 (en) 2008-03-05
DE602004012324T2 (de) 2009-03-19
WO2005066224A1 (en) 2005-07-21
US7659351B2 (en) 2010-02-09
DE602004012324D1 (de) 2008-04-17
CA2551874A1 (en) 2005-07-21
JP2007523971A (ja) 2007-08-23
ATE388172T1 (de) 2008-03-15
KR20060117981A (ko) 2006-11-17
BRPI0418241A (pt) 2007-04-17
CN1902244A (zh) 2007-01-24
US20070173149A1 (en) 2007-07-26

Similar Documents

Publication Publication Date Title
CN100540571C (zh) 防水和防油的氟代丙烯酸酯
CN101146834B (zh) 含氟丙烯酸酯-巯基官能性共聚物
JP3623511B2 (ja) ウレタン基を含むフッ素化アクリルモノマー及びそれらのポリマー
US7851387B2 (en) Fluoroacrylate-multifunctional acrylate copolymer compositions
US7682771B2 (en) Compositions containing photosensitive fluorochemical and uses thereof
JPS62132850A (ja) フッ素化アクリルモノマーとその製造方法
WO2004096939A1 (ja) 含フッ素重合体を含んでなる表面処理剤
JP2004026688A (ja) ポリフルオロアルキル基含有重合性化合物およびその重合体
JP2008525618A (ja) 撥水撥油性のフルオロウレタンおよびフルオロウレア
JP2012233059A (ja) 新規ポリマー
JP2022084379A (ja) 接着剤
MXPA06007540A (en) Water-and oil-repellent fluoroacrylates
JPS6214590B2 (enExample)
TW202530175A (zh) 含氟化合物、含氟聚合物及使用其之表面處理劑
JPH0681811B2 (ja) エマルジョン型被覆組成物
JP2003327650A (ja) 三級アミノ基を有するポリウレタン鎖骨格とフッ化アルキル側鎖基を有するポリウレタンを含有するコーティング組成物
JPH0967334A (ja) フロロアルキルアルコールとその誘導体

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090916

Termination date: 20121228