CN100497477C - 韧性聚(乳酸)组合物 - Google Patents
韧性聚(乳酸)组合物 Download PDFInfo
- Publication number
- CN100497477C CN100497477C CNB2004800365876A CN200480036587A CN100497477C CN 100497477 C CN100497477 C CN 100497477C CN B2004800365876 A CNB2004800365876 A CN B2004800365876A CN 200480036587 A CN200480036587 A CN 200480036587A CN 100497477 C CN100497477 C CN 100497477C
- Authority
- CN
- China
- Prior art keywords
- weight
- composition
- lactic acid
- impact modifier
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0884—Epoxide-containing esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52920803P | 2003-12-12 | 2003-12-12 | |
| US60/529,208 | 2003-12-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1894338A CN1894338A (zh) | 2007-01-10 |
| CN100497477C true CN100497477C (zh) | 2009-06-10 |
Family
ID=34699954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800365876A Expired - Fee Related CN100497477C (zh) | 2003-12-12 | 2004-12-08 | 韧性聚(乳酸)组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7354973B2 (enExample) |
| EP (1) | EP1697463A1 (enExample) |
| JP (1) | JP2007514042A (enExample) |
| KR (1) | KR101105949B1 (enExample) |
| CN (1) | CN100497477C (enExample) |
| WO (1) | WO2005059031A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265798A (zh) * | 2013-06-03 | 2013-08-28 | 山东昊达化学有限公司 | 聚乳酸(pla)与乙烯-醋酸乙烯酯共聚物(eva)共混组合物及其成型制品 |
Families Citing this family (95)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20080027178A1 (en) * | 2006-07-27 | 2008-01-31 | Julius Uradnisheck | Article comprising poly(hydroxyalkanoic acid) |
| US7834092B2 (en) * | 2003-12-12 | 2010-11-16 | E. I. Du Pont De Nemours And Company | Article comprising poly(hydroxyalkanoic acid) |
| US7595363B2 (en) * | 2003-12-12 | 2009-09-29 | E.I. Du Pont De Nemours And Company | Toughened poly(hydroxyalkanoic acid) compositions |
| DE602005027814D1 (de) * | 2004-02-16 | 2011-06-16 | Mitsui Chemicals Inc | Copolymer enthaltende zusammensetzung auf basis von aliphatischem polyesterharz |
| AU2005258271B2 (en) * | 2004-06-23 | 2010-02-18 | Natureworks Llc | Branched polylactic acid polymers and method of preparing same |
| JP2006328117A (ja) * | 2005-05-23 | 2006-12-07 | National Institute Of Advanced Industrial & Technology | 耐衝撃性環境素材とその製造方法及び成形体 |
| EP1911807B1 (en) | 2005-08-04 | 2015-03-04 | Toray Industries, Inc. | Resin composition and molded article comprising the same |
| US7365128B2 (en) * | 2005-08-31 | 2008-04-29 | Acushnet Company | Highly-neutralized acid polymers and their use in golf balls |
| JP2007070379A (ja) * | 2005-09-02 | 2007-03-22 | National Institute Of Advanced Industrial & Technology | 環境素材マテリアルとその製造方法 |
| EP1953191B1 (en) * | 2005-11-25 | 2013-05-22 | Kuraray Co., Ltd. | Polylactic acid composition |
| JP2012136715A (ja) * | 2005-12-22 | 2012-07-19 | Toray Ind Inc | 樹脂組成物およびそれからなる成形品 |
| JP5140988B2 (ja) * | 2005-12-22 | 2013-02-13 | 東レ株式会社 | 樹脂組成物およびそれからなる成形品 |
| JP2007191695A (ja) * | 2005-12-22 | 2007-08-02 | Toray Ind Inc | 樹脂組成物およびそれからなる成形品 |
| US7666946B2 (en) * | 2006-01-27 | 2010-02-23 | Arkema Inc. | Blends of biopolymers with acrylic copolymers |
| JP4700545B2 (ja) * | 2006-04-10 | 2011-06-15 | 住江織物株式会社 | 布帛の裏打層形成用樹脂組成物及びこれを用いた布帛並びに自動車用内装材 |
| US9163141B2 (en) * | 2006-04-27 | 2015-10-20 | Cryovac, Inc. | Polymeric blend comprising polylactic acid |
| US8206796B2 (en) * | 2006-04-27 | 2012-06-26 | Cryovac, Inc. | Multilayer film comprising polylactic acid |
| DE102006024568A1 (de) * | 2006-05-23 | 2007-12-06 | Huhtamaki Forchheim Zweigniederlassung Der Huhtamaki Deutschland Gmbh & Co. Kg | Verfahren zur Herstellung einer biologisch abbaubaren Kunststofffolie und Folie |
| FR2902433A1 (fr) * | 2006-06-16 | 2007-12-21 | Arkema France | Materiau composite a base d'acide polylactique et de polyamide presentant une resistance aux chocs amelioree, son procede de fabrication et utilisation |
| FR2902434B1 (fr) * | 2006-06-16 | 2008-08-01 | Arkema France | Composition d'acide polylactique presentant une resistance aux chocs amelioree |
| US8399101B2 (en) * | 2006-09-19 | 2013-03-19 | E I Du Pont De Nemours And Company | Toughened poly(hydroxyalkanoic acid) compositions |
| EP2064287A2 (en) * | 2006-09-19 | 2009-06-03 | E.I. Du Pont De Nemours And Company | Toughened poly(hydroxyalkanoic acid) compositions |
| FR2911879B1 (fr) * | 2007-01-29 | 2009-05-15 | Arkema France | Materiau composite a base de polyamide et de polyacide lactique, procede de fabrication et utilisation |
| CN101275011B (zh) * | 2007-03-29 | 2011-06-15 | 东丽纤维研究所(中国)有限公司 | 高抗冲击聚乳酸复合材料及其制备方法和用途 |
| JP5399894B2 (ja) * | 2007-03-29 | 2014-01-29 | 三菱樹脂株式会社 | 脂肪族ポリエステル系フィルム |
| JP2010529284A (ja) | 2007-06-11 | 2010-08-26 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリ(ヒドロキシアルカン酸)及びそれを使った物品 |
| US20090005514A1 (en) * | 2007-06-29 | 2009-01-01 | E. I. Du Pont De Nemours And Company | Toughened polyester and articles therefrom |
| US8182734B1 (en) | 2007-08-20 | 2012-05-22 | E. I. Du Pont De Nemours And Company | Thermoformed articles and compositions of poly(hydroxyalkanoic acid) and polyoxymethylene |
| US7642301B2 (en) * | 2007-09-07 | 2010-01-05 | E.I. Du Pont De Nemours And Company | Poly (hydroxyalkanoic acid) compositions with improved toughness, dimensional stability and stretchability |
| US20090099313A1 (en) * | 2007-10-10 | 2009-04-16 | E. I. Du Pont De Nemours And Company | Poly(hydroxyalkanoic acid) and thermoformed articles |
| JP2011505433A (ja) * | 2007-10-31 | 2011-02-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリ(ヒドロキシアルカン酸)組成物 |
| US7786210B2 (en) | 2007-11-15 | 2010-08-31 | E.I. Du Pont De Nemours And Company | Plasticized poly(hydroxyalkanoic acid) composition |
| WO2009076458A1 (en) * | 2007-12-10 | 2009-06-18 | Toray Plastics (America) , Inc. | Biaxially oriented polylactic acid film with high barrier |
| US20110244257A1 (en) * | 2007-12-11 | 2011-10-06 | Toray Plastics (America), Inc. | Method to reprocess polylactic acid resin and articles |
| WO2009076541A1 (en) * | 2007-12-11 | 2009-06-18 | Toray Plastics (America), Inc. | Process to produce biaxially oriented polylactic acid film at high transverse orientation rates |
| US8697804B1 (en) | 2008-01-24 | 2014-04-15 | E I Du Pont De Nemours And Company | Nucleated poly(trimethylene terephthalate) |
| WO2009094362A1 (en) * | 2008-01-24 | 2009-07-30 | E. I. Du Pont De Nemours And Company | Toughened poly(trimethylene terephthalate) composition with reduced melt viscosity |
| US8716404B1 (en) | 2008-01-24 | 2014-05-06 | E I Du Pont De Nemours And Company | Polyesters modified by a combination of ionomer and fatty acid salts |
| EP2110407A1 (en) * | 2008-04-16 | 2009-10-21 | Total Petrochemicals Research Feluy | Blends of polar low density ethylene copolymers and poly(hydroxy carboxylic acid)s |
| CN102007182B (zh) * | 2008-04-16 | 2013-03-27 | 纳幕尔杜邦公司 | 由乙烯丙烯酸烷基酯韧化的聚(羟基链烷酸)组合物 |
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| CN101445606B (zh) * | 2008-12-29 | 2012-09-05 | 南京林业大学 | 一种蚕丝蛋白与聚l-乳酸的共聚物及其熔融聚合制备方法和应用 |
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| JP6856970B2 (ja) * | 2017-05-10 | 2021-04-14 | 三国紙工株式会社 | 脂肪族ポリエステル樹脂組成物およびそれを用いた包装材料 |
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Citations (4)
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| WO2000023520A1 (en) * | 1998-10-20 | 2000-04-27 | Eastman Chemical Company | Polyester articles having improved impact strength |
| JP2003138119A (ja) * | 2001-11-06 | 2003-05-14 | Toray Ind Inc | 樹脂組成物ならびにそれからなる成形品、フィルムおよび繊維 |
| WO2003082980A1 (en) * | 2002-03-29 | 2003-10-09 | Mitsui Chemicals, Inc. | Lactic acid-based resin composition |
| CN1701082A (zh) * | 2003-05-13 | 2005-11-23 | 纳幕尔杜邦公司 | 增韧聚甲醛-聚乳酸组合物 |
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| US4912167A (en) * | 1987-12-14 | 1990-03-27 | E. I. Du Pont De Nemours And Company | Polyester compositions for blow molding |
| US5252642A (en) * | 1989-03-01 | 1993-10-12 | Biopak Technology, Ltd. | Degradable impact modified polyactic acid |
| JP3693756B2 (ja) | 1996-05-27 | 2005-09-07 | カネボウ株式会社 | ポリ乳酸樹脂組成物 |
| JP2000336259A (ja) * | 1999-03-24 | 2000-12-05 | Polyplastics Co | 難燃性ポリエステル樹脂組成物 |
| JP2001123055A (ja) * | 1999-10-27 | 2001-05-08 | Shimadzu Corp | ポリ乳酸系樹脂組成物 |
| CN1307259C (zh) | 2001-08-03 | 2007-03-28 | 东丽株式会社 | 树脂组合物和由该树脂组合物制成的成型制品、薄膜和纤维 |
| US6943214B2 (en) * | 2003-05-13 | 2005-09-13 | E. I. Du Pont De Nemours And Company | Toughened polyoxymethylene-poly(lactic acid) compositions |
| EP1622962B1 (en) | 2003-05-13 | 2006-07-05 | E.I. Dupont De Nemours And Company | Toughened polyoxymethylene-poly(lactic acid) compositions |
-
2004
- 2004-11-23 US US10/996,899 patent/US7354973B2/en not_active Expired - Lifetime
- 2004-12-08 KR KR1020067011336A patent/KR101105949B1/ko not_active Expired - Fee Related
- 2004-12-08 WO PCT/US2004/041695 patent/WO2005059031A1/en not_active Ceased
- 2004-12-08 JP JP2006544079A patent/JP2007514042A/ja active Pending
- 2004-12-08 EP EP04813942A patent/EP1697463A1/en not_active Withdrawn
- 2004-12-08 CN CNB2004800365876A patent/CN100497477C/zh not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000023520A1 (en) * | 1998-10-20 | 2000-04-27 | Eastman Chemical Company | Polyester articles having improved impact strength |
| JP2003138119A (ja) * | 2001-11-06 | 2003-05-14 | Toray Ind Inc | 樹脂組成物ならびにそれからなる成形品、フィルムおよび繊維 |
| WO2003082980A1 (en) * | 2002-03-29 | 2003-10-09 | Mitsui Chemicals, Inc. | Lactic acid-based resin composition |
| CN1701082A (zh) * | 2003-05-13 | 2005-11-23 | 纳幕尔杜邦公司 | 增韧聚甲醛-聚乳酸组合物 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265798A (zh) * | 2013-06-03 | 2013-08-28 | 山东昊达化学有限公司 | 聚乳酸(pla)与乙烯-醋酸乙烯酯共聚物(eva)共混组合物及其成型制品 |
| CN103265798B (zh) * | 2013-06-03 | 2015-11-25 | 山东昊达化学有限公司 | 聚乳酸(pla)与乙烯-醋酸乙烯酯共聚物(eva)共混组合物及其成型制品 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20050131120A1 (en) | 2005-06-16 |
| KR20060134948A (ko) | 2006-12-28 |
| US7354973B2 (en) | 2008-04-08 |
| WO2005059031A1 (en) | 2005-06-30 |
| CN1894338A (zh) | 2007-01-10 |
| EP1697463A1 (en) | 2006-09-06 |
| HK1095350A1 (zh) | 2007-05-04 |
| JP2007514042A (ja) | 2007-05-31 |
| KR101105949B1 (ko) | 2012-01-18 |
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