CN100479231C - 阳极和电池 - Google Patents
阳极和电池 Download PDFInfo
- Publication number
- CN100479231C CN100479231C CNB2005100656327A CN200510065632A CN100479231C CN 100479231 C CN100479231 C CN 100479231C CN B2005100656327 A CNB2005100656327 A CN B2005100656327A CN 200510065632 A CN200510065632 A CN 200510065632A CN 100479231 C CN100479231 C CN 100479231C
- Authority
- CN
- China
- Prior art keywords
- anode
- active material
- lithium
- material layers
- anode active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000006183 anode active material Substances 0.000 claims abstract description 130
- 239000011248 coating agent Substances 0.000 claims abstract description 42
- 238000000576 coating method Methods 0.000 claims abstract description 42
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 37
- 239000000956 alloy Substances 0.000 claims abstract description 37
- 239000000126 substance Substances 0.000 claims abstract description 30
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 28
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 20
- 239000010703 silicon Substances 0.000 claims abstract description 19
- 229910052744 lithium Inorganic materials 0.000 claims description 155
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 117
- 238000000034 method Methods 0.000 claims description 64
- 238000005229 chemical vapour deposition Methods 0.000 claims description 41
- 230000015572 biosynthetic process Effects 0.000 claims description 30
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 23
- 239000003792 electrolyte Substances 0.000 claims description 22
- 230000000694 effects Effects 0.000 claims description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 16
- 238000000151 deposition Methods 0.000 claims description 16
- 229910052732 germanium Inorganic materials 0.000 claims description 16
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 16
- 229910052718 tin Inorganic materials 0.000 claims description 16
- 238000005245 sintering Methods 0.000 claims description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 238000003860 storage Methods 0.000 abstract description 4
- 238000001947 vapour-phase growth Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 116
- 210000004027 cell Anatomy 0.000 description 58
- 239000000463 material Substances 0.000 description 42
- 208000028659 discharge Diseases 0.000 description 36
- 239000010408 film Substances 0.000 description 27
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 20
- 239000011149 active material Substances 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- 238000005516 engineering process Methods 0.000 description 13
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 12
- 230000004888 barrier function Effects 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- -1 lithium metals Chemical class 0.000 description 12
- 230000014759 maintenance of location Effects 0.000 description 12
- 239000011261 inert gas Substances 0.000 description 11
- 238000002161 passivation Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 238000005275 alloying Methods 0.000 description 9
- 239000006182 cathode active material Substances 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 230000008021 deposition Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000007850 degeneration Effects 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000001771 vacuum deposition Methods 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 6
- 239000007769 metal material Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000002033 PVDF binder Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 230000016507 interphase Effects 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 5
- 210000002966 serum Anatomy 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000011532 electronic conductor Substances 0.000 description 4
- 238000005538 encapsulation Methods 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- 229910001947 lithium oxide Inorganic materials 0.000 description 4
- 159000000002 lithium salts Chemical class 0.000 description 4
- 238000001465 metallisation Methods 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- 229910013870 LiPF 6 Inorganic materials 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011245 gel electrolyte Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910004706 CaSi2 Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910019001 CoSi Inorganic materials 0.000 description 1
- 229910019974 CrSi Inorganic materials 0.000 description 1
- 229910005329 FeSi 2 Inorganic materials 0.000 description 1
- 229910006115 GeF Inorganic materials 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- 229910005829 GeS Inorganic materials 0.000 description 1
- 229910005839 GeS 2 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- 229910013872 LiPF Inorganic materials 0.000 description 1
- 229910012573 LiSiO Inorganic materials 0.000 description 1
- 229910012404 LiSnO Inorganic materials 0.000 description 1
- 101150058243 Lipf gene Proteins 0.000 description 1
- 229910017028 MnSi Inorganic materials 0.000 description 1
- 229910016006 MoSi Inorganic materials 0.000 description 1
- 229910005881 NiSi 2 Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 229910006826 SnOw Inorganic materials 0.000 description 1
- 229910005790 SnSiO Inorganic materials 0.000 description 1
- 229910008484 TiSi Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910002065 alloy metal Inorganic materials 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- SIXOAUAWLZKQKX-UHFFFAOYSA-N carbonic acid;prop-1-ene Chemical compound CC=C.OC(O)=O SIXOAUAWLZKQKX-UHFFFAOYSA-N 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 150000001787 chalcogens Chemical class 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N germanium monoxide Inorganic materials [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000005289 physical deposition Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- BHZCMUVGYXEBMY-UHFFFAOYSA-N trilithium;azanide Chemical compound [Li+].[Li+].[Li+].[NH2-] BHZCMUVGYXEBMY-UHFFFAOYSA-N 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
- H01M10/446—Initial charging measures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0085—Immobilising or gelification of electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
Description
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004019795A JP4442235B2 (ja) | 2004-01-28 | 2004-01-28 | 二次電池用負極、二次電池およびそれらの製造方法 |
JP019795/2004 | 2004-01-28 | ||
JP019795/04 | 2004-01-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1665050A CN1665050A (zh) | 2005-09-07 |
CN100479231C true CN100479231C (zh) | 2009-04-15 |
Family
ID=34675458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2005100656327A Active CN100479231C (zh) | 2004-01-28 | 2005-01-28 | 阳极和电池 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9425441B2 (zh) |
EP (1) | EP1562250B1 (zh) |
JP (1) | JP4442235B2 (zh) |
KR (1) | KR20050077478A (zh) |
CN (1) | CN100479231C (zh) |
TW (1) | TWI274432B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109328413A (zh) * | 2016-06-21 | 2019-02-12 | 应用材料公司 | 用于改良的锂金属循环的界面层 |
WO2022052019A1 (zh) * | 2020-09-11 | 2022-03-17 | 宁德新能源科技有限公司 | 电化学装置和电子装置 |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100860341B1 (ko) * | 2004-06-15 | 2008-09-26 | 미쓰비시 가가꾸 가부시키가이샤 | 비수전해질 이차 전지와 그 음극 |
JP5103903B2 (ja) * | 2004-09-22 | 2012-12-19 | ソニー株式会社 | 二次電池用電解液および二次電池 |
JP4193141B2 (ja) * | 2005-03-25 | 2008-12-10 | ソニー株式会社 | リチウム二次電池用負極およびリチウム二次電池、並びにそれらの製造方法 |
US7923148B2 (en) * | 2005-03-31 | 2011-04-12 | Sanyo Electric Co., Ltd. | Nonaqueous electrolyte secondary battery including a negative electrode containing silicon and an additive which retards oxidation of silicon during battery operation |
WO2007010922A1 (ja) * | 2005-07-21 | 2007-01-25 | Matsushita Electric Industrial Co., Ltd. | リチウムイオン二次電池用負極、その製造方法、およびそれを用いたリチウムイオン二次電池 |
JP5119584B2 (ja) * | 2005-10-11 | 2013-01-16 | パナソニック株式会社 | 非水電解質二次電池およびその負極の製造法 |
JP4876531B2 (ja) * | 2005-10-27 | 2012-02-15 | パナソニック株式会社 | リチウム二次電池用負極およびリチウム二次電池の製造方法 |
JP5238195B2 (ja) * | 2006-07-24 | 2013-07-17 | パナソニック株式会社 | リチウムイオン二次電池用負極およびリチウムイオン二次電池 |
JPWO2008056791A1 (ja) * | 2006-11-10 | 2010-02-25 | 富士重工業株式会社 | リチウムイオン二次電池 |
JP2008234850A (ja) * | 2007-03-16 | 2008-10-02 | Matsushita Electric Ind Co Ltd | 電気化学素子とその電極の製造方法、製造装置 |
CN101675545B (zh) | 2007-07-19 | 2012-06-13 | 松下电器产业株式会社 | 锂离子二次电池 |
JP5400451B2 (ja) | 2008-04-18 | 2014-01-29 | パナソニック株式会社 | リチウム一次電池用負極およびリチウム一次電池 |
CN102144320A (zh) * | 2009-06-29 | 2011-08-03 | 松下电器产业株式会社 | 锂离子电池用负极、其制造方法以及锂离子电池 |
JP5461561B2 (ja) * | 2009-08-10 | 2014-04-02 | 株式会社アルバック | 薄膜リチウム二次電池の製造方法、薄膜リチウム二次電池 |
KR101028657B1 (ko) * | 2009-08-19 | 2011-04-11 | 고려대학교 산학협력단 | 리튬 분말과 실리콘 옥사이드 이중층 음극, 그 제조 방법 및 이를 이용한 리튬 이차 전지 |
US8580332B2 (en) * | 2009-09-22 | 2013-11-12 | Applied Materials, Inc. | Thin-film battery methods for complexity reduction |
JP5873971B2 (ja) * | 2009-11-13 | 2016-03-01 | パナソニックIpマネジメント株式会社 | 電気化学キャパシタおよびそれに用いられる電極 |
WO2011136028A1 (en) | 2010-04-28 | 2011-11-03 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for manufacturing the same |
WO2011152190A1 (en) | 2010-06-02 | 2011-12-08 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device and method for manufacturing the same |
JP2012017478A (ja) * | 2010-07-06 | 2012-01-26 | Honjo Metal Co Ltd | リチウム積層部材およびその製造方法 |
CN103918107B (zh) * | 2011-12-28 | 2016-09-07 | 松下知识产权经营株式会社 | 非水电解质二次电池用负极及使用其的非水电解质二次电池 |
JP6286829B2 (ja) * | 2013-01-28 | 2018-03-07 | 日本電気株式会社 | リチウムイオン二次電池 |
JP5888353B2 (ja) * | 2013-07-25 | 2016-03-22 | 株式会社デンソー | アルカリ金属含有活物質の製造方法および二次電池の製造方法 |
US10553854B2 (en) | 2013-09-26 | 2020-02-04 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery |
KR20150057730A (ko) | 2013-11-20 | 2015-05-28 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질층 조성물 및 이의 제조 방법, 그리고 이를 포함하는 음극 및 리튬 이차 전지 |
JP6181590B2 (ja) * | 2014-04-02 | 2017-08-16 | 信越化学工業株式会社 | 非水電解質二次電池用負極及び非水電解質二次電池 |
KR102214834B1 (ko) * | 2014-07-29 | 2021-02-10 | 삼성전자주식회사 | 엑스선 분석용 인-시츄 코인 셀과 그 제조방법 및 그에 대한 엑스선 분석방법 |
US20170194672A1 (en) * | 2015-12-30 | 2017-07-06 | Nissan North America, Inc. | High current treatment for lithium ion batteries having metal based anodes |
CN106206080A (zh) * | 2016-08-16 | 2016-12-07 | 肖丽芳 | 一种锂离子电容器预嵌锂正极片的制备方法 |
CN106158421A (zh) * | 2016-08-16 | 2016-11-23 | 肖丽芳 | 一种预嵌锂石墨烯正极片的制备方法 |
JP7057085B2 (ja) * | 2016-09-30 | 2022-04-19 | 旭化成株式会社 | 非水系アルカリ金属型蓄電素子 |
US10944128B2 (en) * | 2017-03-30 | 2021-03-09 | International Business Machines Corporation | Anode structure for solid-state lithium-based thin-film battery |
US10622680B2 (en) | 2017-04-06 | 2020-04-14 | International Business Machines Corporation | High charge rate, large capacity, solid-state battery |
KR102140128B1 (ko) * | 2017-06-20 | 2020-07-31 | 주식회사 엘지화학 | 리튬 전극 및 이를 포함하는 리튬 이차전지 |
KR102357946B1 (ko) | 2017-08-17 | 2022-02-08 | 어플라이드 머티어리얼스, 인코포레이티드 | 올레핀 분리기가 없는 Li-이온 배터리 |
KR102255537B1 (ko) * | 2018-01-12 | 2021-05-25 | 주식회사 엘지에너지솔루션 | 파우치 필름 및 그의 제조 방법 |
CN110911732B (zh) * | 2018-09-16 | 2021-12-14 | 深圳格林德能源集团有限公司 | 一种长寿命高容量硅负极锂离子电池 |
GB2584415A (en) * | 2019-05-22 | 2020-12-09 | Dyson Technology Ltd | An anode |
US20230268487A1 (en) * | 2020-03-26 | 2023-08-24 | Panasonic Intellectual Property Management Co., Ltd. | Negative electrode for electrochemical device, and electrochemical device |
US20220052307A1 (en) * | 2020-08-11 | 2022-02-17 | Applied Materials, Inc. | Inline contact pre-lithiation |
JPWO2022181608A1 (zh) * | 2021-02-25 | 2022-09-01 | ||
WO2023212229A1 (en) * | 2022-04-27 | 2023-11-02 | Board Of Trustees Of The University Of Arkansas | High-energy lithium metal batteries enabling extremely fast charge and discharge |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02168562A (ja) | 1988-12-20 | 1990-06-28 | Sanyo Electric Co Ltd | 有機電解質電池の製造方法 |
JP3232710B2 (ja) | 1992-10-08 | 2001-11-26 | 松下電器産業株式会社 | 非水電解液二次電池の製造方法 |
JP3566509B2 (ja) | 1997-08-13 | 2004-09-15 | 株式会社リコー | 二次電池用電極板及びその製造方法 |
US6096454A (en) * | 1998-08-31 | 2000-08-01 | The Regents Of The University Of California | Surface modifications for carbon lithium intercalation anodes |
US7247408B2 (en) * | 1999-11-23 | 2007-07-24 | Sion Power Corporation | Lithium anodes for electrochemical cells |
JP2002093411A (ja) | 2000-09-08 | 2002-03-29 | Sumitomo Metal Ind Ltd | 非水電解質二次電池用負極材料 |
JP2002151056A (ja) * | 2000-11-14 | 2002-05-24 | Sanyo Electric Co Ltd | リチウム二次電池用電極及びリチウム二次電池 |
JPWO2002091514A1 (ja) * | 2001-05-09 | 2004-08-26 | 日本電池株式会社 | 非水電解質電池およびその製造方法 |
US6991662B2 (en) | 2001-09-10 | 2006-01-31 | Polyplus Battery Company | Encapsulated alloy electrodes |
JP4144335B2 (ja) | 2002-11-19 | 2008-09-03 | ソニー株式会社 | 負極およびそれを用いた二次電池 |
JP3664253B2 (ja) * | 2002-12-26 | 2005-06-22 | ソニー株式会社 | 二次電池用負極およびそれを用いた二次電池 |
JP4497899B2 (ja) | 2003-11-19 | 2010-07-07 | 三洋電機株式会社 | リチウム二次電池 |
JP4338506B2 (ja) | 2003-12-03 | 2009-10-07 | 三洋電機株式会社 | リチウム二次電池およびその製造方法 |
-
2004
- 2004-01-28 JP JP2004019795A patent/JP4442235B2/ja not_active Expired - Lifetime
-
2005
- 2005-01-20 US US11/039,321 patent/US9425441B2/en active Active
- 2005-01-21 KR KR1020050005684A patent/KR20050077478A/ko not_active Application Discontinuation
- 2005-01-21 EP EP05001209.5A patent/EP1562250B1/en active Active
- 2005-01-28 CN CNB2005100656327A patent/CN100479231C/zh active Active
- 2005-01-28 TW TW094102751A patent/TWI274432B/zh not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109328413A (zh) * | 2016-06-21 | 2019-02-12 | 应用材料公司 | 用于改良的锂金属循环的界面层 |
WO2022052019A1 (zh) * | 2020-09-11 | 2022-03-17 | 宁德新能源科技有限公司 | 电化学装置和电子装置 |
Also Published As
Publication number | Publication date |
---|---|
JP2005216601A (ja) | 2005-08-11 |
JP4442235B2 (ja) | 2010-03-31 |
TW200603452A (en) | 2006-01-16 |
CN1665050A (zh) | 2005-09-07 |
KR20050077478A (ko) | 2005-08-02 |
US9425441B2 (en) | 2016-08-23 |
US20050191547A1 (en) | 2005-09-01 |
EP1562250B1 (en) | 2013-11-13 |
EP1562250A3 (en) | 2007-03-21 |
EP1562250A2 (en) | 2005-08-10 |
TWI274432B (en) | 2007-02-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100479231C (zh) | 阳极和电池 | |
EP3469648B1 (en) | High energy density, high power density, high capacity, and room temperature capable "anode-free" rechargeable batteries | |
US20160133941A1 (en) | Anode and battery | |
CN100409481C (zh) | 电池 | |
CN100570929C (zh) | 阳极和采用此阳极的电池 | |
CN102723460B (zh) | 电池及其充放电方法以及电池的充放电控制装置 | |
US6805999B2 (en) | Buried anode lithium thin film battery and process for forming the same | |
US11569533B2 (en) | Replenished negative electrodes for secondary batteries | |
CN101364645B (zh) | 集电体、阳极和电池 | |
CN100463281C (zh) | 电池 | |
CN101207192B (zh) | 负极、使用该负极的电池、以及制造负极的方法 | |
CN100566003C (zh) | 锂二次电池 | |
CN1964102A (zh) | 阳极和电池 | |
EP3545577A1 (en) | Li-ion based electrochemical energy storage cell | |
KR101308096B1 (ko) | 리튬 이차 박막 전지용 음극, 이의 제조방법 및 이를포함하는 리튬 이차 박막 전지 | |
JP2008243828A (ja) | 負極および二次電池の製造方法 | |
US7482095B2 (en) | Anode and battery using the same | |
JP2005085632A (ja) | 電池 | |
JP4919451B2 (ja) | 非水二次電池およびその製造方法 | |
EP4220750A1 (en) | Solid-state battery anode comprising polymer layer for preventing micro-short circuit, and solid-state battery comprising same | |
WO2003043108A1 (en) | Buried anode lithium thin film battery and process for forming the same | |
US20230268516A1 (en) | All-solid-state battery including thin film current collector and method of manufacturing the same | |
Lee et al. | Buried anode lithium thin film battery and process for forming the same | |
CN117795700A (zh) | 一种制造作为锂电池用阳极的硅电极的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180410 Address after: Kyoto Japan Patentee after: Murata Manufacturing Co.,Ltd. Address before: Fukushima Patentee before: Murata, Northeast China Effective date of registration: 20180410 Address after: Fukushima Patentee after: Murata, Northeast China Address before: Tokyo, Japan Patentee before: Sony Corp. |
|
TR01 | Transfer of patent right |