CN100412106C - 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法 - Google Patents

由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法 Download PDF

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Publication number
CN100412106C
CN100412106C CNB2005800076283A CN200580007628A CN100412106C CN 100412106 C CN100412106 C CN 100412106C CN B2005800076283 A CNB2005800076283 A CN B2005800076283A CN 200580007628 A CN200580007628 A CN 200580007628A CN 100412106 C CN100412106 C CN 100412106C
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CN
China
Prior art keywords
antimony
comparative example
catalyst composition
catalyst
polycondensation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB2005800076283A
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English (en)
Chinese (zh)
Other versions
CN1930210A (zh
Inventor
Z·巴施尔
J·斯蒂奎
V·萨姆帕斯
K·阿鲁海丹
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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Publication date
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Publication of CN1930210A publication Critical patent/CN1930210A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • C08G63/866—Antimony or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/80—Solid-state polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CNB2005800076283A 2004-03-11 2005-02-10 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法 Expired - Fee Related CN100412106C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04005822A EP1574539B1 (en) 2004-03-11 2004-03-11 Catalyst composition for producing polyethylene terephthalate from terephthalic acid and ethylene glycol, and process therefore
EP04005822.4 2004-03-11

Publications (2)

Publication Number Publication Date
CN1930210A CN1930210A (zh) 2007-03-14
CN100412106C true CN100412106C (zh) 2008-08-20

Family

ID=34814301

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005800076283A Expired - Fee Related CN100412106C (zh) 2004-03-11 2005-02-10 由对苯二甲酸和乙二醇制备聚对苯二甲酸乙二醇酯的催化剂组合物，及其制备方法

Country Status (9)

Country Link
US (1) US7608652B2 (enExample)
EP (1) EP1574539B1 (enExample)
JP (1) JP2007528433A (enExample)
KR (1) KR101152510B1 (enExample)
CN (1) CN100412106C (enExample)
AT (1) ATE360658T1 (enExample)
DE (1) DE602004006076T2 (enExample)
ES (1) ES2286525T3 (enExample)
WO (1) WO2005087839A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI473832B (zh) * 2009-03-13 2015-02-21 Saudi Basic Ind Corp 聚對酞酸乙二酯的製造方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287225A1 (en) * 2009-08-20 2011-02-23 Saudi Basic Industries Corporation Process for making polyethylene terephthalate
US8362189B2 (en) * 2010-10-05 2013-01-29 Uhde Inventa-Fischer Gmbh Catalyst mixture and method for the production of polyesters with high viscosity
EP2791202B1 (en) * 2011-12-16 2019-05-08 Saudi Basic Industries Corporation Process for synthesizing a new catalyst complex for the production of polyethylene terephthlate
TW201602077A (zh) * 2013-11-20 2016-01-16 英威達技術有限公司 整合純化對苯二甲酸製造及聚酯聚合反應之工廠中之汙染防治
CN105463614B (zh) * 2014-09-12 2020-01-24 东丽纤维研究所（中国）有限公司 吸放湿性聚酯纤维的制造方法
CN107849292B (zh) 2015-03-17 2021-03-12 尼亚加拉装瓶有限责任公司 石墨烯增强的聚对苯二甲酸乙二醇酯
JP2018521207A (ja) 2015-07-08 2018-08-02 ナイアガラ・ボトリング・リミテツド・ライアビリテイー・カンパニー グラフェン強化ポリエチレンテレフタレート
MX2020011750A (es) * 2018-05-09 2021-02-15 Niagara Bottling Llc Nanocompuestos de poli (tereftalato de etileno)-grafeno a partir de una dispersión mejorada.
CN109734889B (zh) * 2018-12-27 2021-01-05 江苏恒力化纤股份有限公司 一种聚酯合成过程中Sb2O3的添加方法
AU2020256188B2 (en) 2019-04-01 2025-08-14 Niagara Bottling, Llc Graphene polyethylene terephthalate composite for improving reheat energy consumption
KR102915059B1 (ko) 2020-11-17 2026-01-19 주식회사 엘지화학 디에스터계 물질의 제조방법
CN115197408A (zh) * 2022-08-30 2022-10-18 科泽新材料股份有限公司 一种锌系催化剂及其制备方法与在无锑聚酯合成中的应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5608031A (en) * 1995-11-30 1997-03-04 Eastman Chemical Company Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system
US5623047A (en) * 1995-03-28 1997-04-22 Industrial Technology Research Institute Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color
JPH1121338A (ja) * 1997-05-09 1999-01-26 Teijin Ltd 結晶化抑制型ポリエステル

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55115426A (en) * 1979-02-27 1980-09-05 Toyobo Co Ltd Manufacture of polyester
JPS55116722A (en) * 1979-03-05 1980-09-08 Toyobo Co Ltd Preparation of polyester
US5166311A (en) * 1989-05-22 1992-11-24 Hoechst Celanese Corporation Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate
JPH05222180A (ja) * 1992-02-17 1993-08-31 Fuji Photo Film Co Ltd ポリエステルの製造法
US6160085A (en) * 1998-05-06 2000-12-12 Mitsubishi Chemical Corporation Polyester and process for its production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5623047A (en) * 1995-03-28 1997-04-22 Industrial Technology Research Institute Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color
US5608031A (en) * 1995-11-30 1997-03-04 Eastman Chemical Company Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system
JPH1121338A (ja) * 1997-05-09 1999-01-26 Teijin Ltd 結晶化抑制型ポリエステル

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI473832B (zh) * 2009-03-13 2015-02-21 Saudi Basic Ind Corp 聚對酞酸乙二酯的製造方法

Also Published As

Publication number Publication date
EP1574539A1 (en) 2005-09-14
KR101152510B1 (ko) 2012-06-01
JP2007528433A (ja) 2007-10-11
DE602004006076D1 (de) 2007-06-06
ES2286525T3 (es) 2007-12-01
WO2005087839A3 (en) 2006-02-16
WO2005087839A2 (en) 2005-09-22
EP1574539B1 (en) 2007-04-25
US7608652B2 (en) 2009-10-27
US20080033084A1 (en) 2008-02-07
DE602004006076T2 (de) 2007-12-27
KR20070012363A (ko) 2007-01-25
ATE360658T1 (de) 2007-05-15
CN1930210A (zh) 2007-03-14

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