KR101152510B1 - 테레프탈산 및 에틸렌 글리콜로부터 폴리에틸렌테레프탈레이트를 제조하기 위한 촉매조성물 및 이의제조방법 - Google Patents

테레프탈산 및 에틸렌 글리콜로부터 폴리에틸렌테레프탈레이트를 제조하기 위한 촉매조성물 및 이의제조방법 Download PDF

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Publication number
KR101152510B1
KR101152510B1 KR1020067018574A KR20067018574A KR101152510B1 KR 101152510 B1 KR101152510 B1 KR 101152510B1 KR 1020067018574 A KR1020067018574 A KR 1020067018574A KR 20067018574 A KR20067018574 A KR 20067018574A KR 101152510 B1 KR101152510 B1 KR 101152510B1
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South Korea
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ppm
antimony
condensation polymerization
comparative example
polymer
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Expired - Fee Related
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KR1020067018574A
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English (en)
Korean (ko)
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KR20070012363A (ko
Inventor
자히르 바쉬
자밀 시디큐이
벤카타나단 샘패스
칼리드 알우하이단
Original Assignee
사우디 베이식 인더스트리즈 코포레이션
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Publication of KR20070012363A publication Critical patent/KR20070012363A/ko
Application granted granted Critical
Publication of KR101152510B1 publication Critical patent/KR101152510B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • C08G63/866—Antimony or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/80—Solid-state polycondensation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020067018574A 2004-03-11 2005-02-10 테레프탈산 및 에틸렌 글리콜로부터 폴리에틸렌테레프탈레이트를 제조하기 위한 촉매조성물 및 이의제조방법 Expired - Fee Related KR101152510B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04005822A EP1574539B1 (en) 2004-03-11 2004-03-11 Catalyst composition for producing polyethylene terephthalate from terephthalic acid and ethylene glycol, and process therefore
EU04005822.4 2004-03-11
PCT/IB2005/001249 WO2005087839A2 (en) 2004-03-11 2005-02-10 Catalyst composition for producing polyethylene terephthalate from terephthalic acid and ethylene glycol, and process therefore

Publications (2)

Publication Number Publication Date
KR20070012363A KR20070012363A (ko) 2007-01-25
KR101152510B1 true KR101152510B1 (ko) 2012-06-01

Family

ID=34814301

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020067018574A Expired - Fee Related KR101152510B1 (ko) 2004-03-11 2005-02-10 테레프탈산 및 에틸렌 글리콜로부터 폴리에틸렌테레프탈레이트를 제조하기 위한 촉매조성물 및 이의제조방법

Country Status (9)

Country Link
US (1) US7608652B2 (enExample)
EP (1) EP1574539B1 (enExample)
JP (1) JP2007528433A (enExample)
KR (1) KR101152510B1 (enExample)
CN (1) CN100412106C (enExample)
AT (1) ATE360658T1 (enExample)
DE (1) DE602004006076T2 (enExample)
ES (1) ES2286525T3 (enExample)
WO (1) WO2005087839A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12275698B2 (en) 2020-11-17 2025-04-15 Lg Chem, Ltd. Method of preparing diester-based material

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI473832B (zh) 2009-03-13 2015-02-21 Saudi Basic Ind Corp 聚對酞酸乙二酯的製造方法
EP2287225A1 (en) * 2009-08-20 2011-02-23 Saudi Basic Industries Corporation Process for making polyethylene terephthalate
US8362189B2 (en) * 2010-10-05 2013-01-29 Uhde Inventa-Fischer Gmbh Catalyst mixture and method for the production of polyesters with high viscosity
EP2791202B1 (en) * 2011-12-16 2019-05-08 Saudi Basic Industries Corporation Process for synthesizing a new catalyst complex for the production of polyethylene terephthlate
TW201602077A (zh) * 2013-11-20 2016-01-16 英威達技術有限公司 整合純化對苯二甲酸製造及聚酯聚合反應之工廠中之汙染防治
CN105463614B (zh) * 2014-09-12 2020-01-24 东丽纤维研究所（中国）有限公司 吸放湿性聚酯纤维的制造方法
CN107849292B (zh) 2015-03-17 2021-03-12 尼亚加拉装瓶有限责任公司 石墨烯增强的聚对苯二甲酸乙二醇酯
JP2018521207A (ja) 2015-07-08 2018-08-02 ナイアガラ・ボトリング・リミテツド・ライアビリテイー・カンパニー グラフェン強化ポリエチレンテレフタレート
MX2020011750A (es) * 2018-05-09 2021-02-15 Niagara Bottling Llc Nanocompuestos de poli (tereftalato de etileno)-grafeno a partir de una dispersión mejorada.
CN109734889B (zh) * 2018-12-27 2021-01-05 江苏恒力化纤股份有限公司 一种聚酯合成过程中Sb2O3的添加方法
AU2020256188B2 (en) 2019-04-01 2025-08-14 Niagara Bottling, Llc Graphene polyethylene terephthalate composite for improving reheat energy consumption
CN115197408A (zh) * 2022-08-30 2022-10-18 科泽新材料股份有限公司 一种锌系催化剂及其制备方法与在无锑聚酯合成中的应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55115426A (en) * 1979-02-27 1980-09-05 Toyobo Co Ltd Manufacture of polyester
JPS55116722A (en) * 1979-03-05 1980-09-08 Toyobo Co Ltd Preparation of polyester
US5166311A (en) * 1989-05-22 1992-11-24 Hoechst Celanese Corporation Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate
JPH05222180A (ja) * 1992-02-17 1993-08-31 Fuji Photo Film Co Ltd ポリエステルの製造法
US5623047A (en) * 1995-03-28 1997-04-22 Industrial Technology Research Institute Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color
US5608031A (en) * 1995-11-30 1997-03-04 Eastman Chemical Company Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system
JP3727145B2 (ja) * 1997-05-09 2005-12-14 帝人株式会社 結晶化抑制型ポリエステル
US6160085A (en) * 1998-05-06 2000-12-12 Mitsubishi Chemical Corporation Polyester and process for its production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12275698B2 (en) 2020-11-17 2025-04-15 Lg Chem, Ltd. Method of preparing diester-based material

Also Published As

Publication number Publication date
EP1574539A1 (en) 2005-09-14
JP2007528433A (ja) 2007-10-11
DE602004006076D1 (de) 2007-06-06
ES2286525T3 (es) 2007-12-01
WO2005087839A3 (en) 2006-02-16
WO2005087839A2 (en) 2005-09-22
EP1574539B1 (en) 2007-04-25
US7608652B2 (en) 2009-10-27
US20080033084A1 (en) 2008-02-07
DE602004006076T2 (de) 2007-12-27
CN100412106C (zh) 2008-08-20
KR20070012363A (ko) 2007-01-25
ATE360658T1 (de) 2007-05-15
CN1930210A (zh) 2007-03-14

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