CN100377411C - 高度氟化主链聚合物电解质膜 - Google Patents

高度氟化主链聚合物电解质膜 Download PDF

Info

Publication number
CN100377411C
CN100377411C CNB2003801062787A CN200380106278A CN100377411C CN 100377411 C CN100377411 C CN 100377411C CN B2003801062787 A CNB2003801062787 A CN B2003801062787A CN 200380106278 A CN200380106278 A CN 200380106278A CN 100377411 C CN100377411 C CN 100377411C
Authority
CN
China
Prior art keywords
polymer
electrolyte membrane
polymer electrolyte
membrane
membrane according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB2003801062787A
Other languages
English (en)
Chinese (zh)
Other versions
CN1726611A (zh
Inventor
S·J·哈姆罗克
L·M·里瓦德
G·G·I·穆尔
T·H·弗里迈尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN1726611A publication Critical patent/CN1726611A/zh
Application granted granted Critical
Publication of CN100377411C publication Critical patent/CN100377411C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Development (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CNB2003801062787A 2002-12-19 2003-11-17 高度氟化主链聚合物电解质膜 Expired - Lifetime CN100377411C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/325,278 US7348088B2 (en) 2002-12-19 2002-12-19 Polymer electrolyte membrane
US10/325,278 2002-12-19

Publications (2)

Publication Number Publication Date
CN1726611A CN1726611A (zh) 2006-01-25
CN100377411C true CN100377411C (zh) 2008-03-26

Family

ID=32593719

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2003801062787A Expired - Lifetime CN100377411C (zh) 2002-12-19 2003-11-17 高度氟化主链聚合物电解质膜

Country Status (8)

Country Link
US (1) US7348088B2 (https=)
EP (1) EP1573850A1 (https=)
JP (1) JP5230898B2 (https=)
KR (1) KR20050092713A (https=)
CN (1) CN100377411C (https=)
AU (1) AU2003291542A1 (https=)
CA (1) CA2507541A1 (https=)
WO (1) WO2004062019A1 (https=)

Families Citing this family (126)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2005029624A1 (ja) * 2003-09-17 2007-11-15 旭化成株式会社 固体高分子型燃料電池用膜−電極接合体
US7285349B2 (en) * 2003-10-30 2007-10-23 3M Innovative Properties Company Polymer electrolyte membrane and method of making
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7255798B2 (en) * 2004-03-26 2007-08-14 Ion Power, Inc. Recycling of used perfluorosulfonic acid membranes
US7304101B2 (en) * 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US7572534B2 (en) * 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US20060078781A1 (en) * 2004-10-08 2006-04-13 3M Innovative Properties Company Curable subgasket for a membrane electrode assembly
US7850871B2 (en) * 2004-10-13 2010-12-14 Air Products And Chemicals, Inc. Resistivity stable electrically conductive films formed from polythiophenes
US7569158B2 (en) * 2004-10-13 2009-08-04 Air Products And Chemicals, Inc. Aqueous dispersions of polythienothiophenes with fluorinated ion exchange polymers as dopants
US20060105219A1 (en) * 2004-11-15 2006-05-18 Anderson Robert D Fuel cell component storage or shipment
US7608118B2 (en) * 2004-11-15 2009-10-27 3M Innovative Properties Company Preconditioning fuel cell membrane electrode assemblies
US7687176B2 (en) * 2004-12-10 2010-03-30 3M Innovative Properties Company Fuel cell
US7311990B2 (en) 2004-12-29 2007-12-25 3M Innovative Properties Company Form-in-place fastening for fuel cell assemblies
US7862956B2 (en) 2004-12-29 2011-01-04 3M Innovative Properties Company Z-axis electrically conducting flow field separator
US20060141138A1 (en) * 2004-12-29 2006-06-29 3M Innovative Properties Company Microwave annealing of membranes for use in fuel cell assemblies
US20060147791A1 (en) * 2004-12-30 2006-07-06 Debe Mark K Platinum recovery from fuel cell stacks
US20060144791A1 (en) * 2004-12-30 2006-07-06 Debe Mark K Platinum recovery from nanostructured fuel cell catalyst
CN101120467A (zh) * 2005-02-16 2008-02-06 3M创新有限公司 燃料电池催化剂
JP4916668B2 (ja) * 2005-03-01 2012-04-18 旭化成イーマテリアルズ株式会社 高安定性フッ素化スルホン酸ポリマー
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
US7517604B2 (en) 2005-09-19 2009-04-14 3M Innovative Properties Company Fuel cell electrolyte membrane with acidic polymer
US7838138B2 (en) * 2005-09-19 2010-11-23 3M Innovative Properties Company Fuel cell electrolyte membrane with basic polymer
US7622217B2 (en) * 2005-10-12 2009-11-24 3M Innovative Properties Company Fuel cell nanocatalyst
US20070082814A1 (en) * 2005-10-12 2007-04-12 3M Innovative Properties Company Ternary nanocatalyst and method of making
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US20070128425A1 (en) * 2005-12-07 2007-06-07 3M Innovative Properties Company Reinforced ion-conductive membranes
US7906251B2 (en) * 2006-04-20 2011-03-15 3M Innovative Properties Company Oxygen-reducing catalyst layer
US7740902B2 (en) * 2006-04-20 2010-06-22 3M Innovative Properties Company Method for making oxygen-reducing catalyst layers
US8058319B2 (en) * 2006-06-01 2011-11-15 E.I. Du Pont De Nemours And Company Process to prepare fluoropolymer dispersions and membranes
US20070282023A1 (en) * 2006-06-01 2007-12-06 Lousenberg Robert D Fluoropolymer dispersions and membranes
US20070281198A1 (en) * 2006-06-01 2007-12-06 Lousenberg Robert D Membranes electrode assemblies prepared from fluoropolymer dispersions
JP5431958B2 (ja) * 2006-12-29 2014-03-05 スリーエム イノベイティブ プロパティズ カンパニー 耐久性のあるポリマー電解質薄膜を製造する方法
US7875388B2 (en) * 2007-02-06 2011-01-25 3M Innovative Properties Company Electrodes including polyacrylate binders and methods of making and using the same
US20090068528A1 (en) * 2007-09-12 2009-03-12 Teasley Mark F Heat treatment of perfluorinated ionomeric membranes
US8183319B2 (en) 2007-10-31 2012-05-22 Air Products And Chemicals, Inc. Film forming additive formulations of conductive polymers
US20090110967A1 (en) * 2007-10-31 2009-04-30 Asahi Glass Company Limited Electrolyte membrane for polymer electrolyte fuel cell, process for its production, membrane/electrode assembly for polymer electrolyte fuel cell and method of operating polymer electrolyte fuel cell
CN101919100B (zh) * 2007-11-09 2014-10-01 3M创新有限公司 包含杂多酸的聚合物电解质
JP5196988B2 (ja) 2007-12-21 2013-05-15 スリーエム イノベイティブ プロパティズ カンパニー インク組成物、その製造方法、そのインク組成物を用いて形成した電極触媒層及びこれらの用途
CN101953012B (zh) 2007-12-27 2014-05-07 3M创新有限公司 具有组合添加剂的耐久性燃料电池膜电极组件
WO2009086364A1 (en) * 2007-12-27 2009-07-09 3M Innovative Properties Company Electrode inks containing coalescing solvents
US20090236979A1 (en) * 2008-03-24 2009-09-24 Air Products And Chemicals, Inc. Organic Electroluminescent Device and the Method of Making
EP2276728B1 (en) 2008-04-24 2013-07-17 3M Innovative Properties Company Proton conducting materials
EP2145916B1 (en) 2008-07-17 2013-06-19 W.L.Gore & Associates Gmbh Substrate coating comprising a complex of an ionic fluoropolymer and surface charged nanoparticles
ATE524513T1 (de) 2008-07-17 2011-09-15 Gore W L & Ass Gmbh Antimikrobielle beschichtungen mit einem komplex aus einem ionischen fluorpolymer und einem antimikrobiellen gegenion
WO2010025118A1 (en) * 2008-08-25 2010-03-04 3M Innovative Properties Company Fuel cell nanocatalyst with voltage reversal tolerance
US8268195B2 (en) * 2008-09-29 2012-09-18 Air Products And Chemicals, Inc. Electrically conductive films formed from dispersions comprising polythiophenes and ether containing polymers
WO2010075321A1 (en) * 2008-12-22 2010-07-01 3M Innovative Properties Company Fuel cell membrane electrode assembly with multilayer cathode
US20100270055A1 (en) 2009-04-27 2010-10-28 Air Products And Chemicals, Inc. Electrically Conductive Films Formed From Dispersions Comprising Conductive Polymers and Polyurethanes
US8470205B2 (en) * 2009-06-05 2013-06-25 Air Products And Chemicals, Inc. Electrically conductive films formed from dispersions comprising conductive polymers and hyperbranched polymers
WO2011087846A1 (en) * 2009-12-22 2011-07-21 3M Innovative Properties Company Membrane electrode assemblies including mixed carbon particles
CN102668201B (zh) * 2009-12-22 2015-05-20 3M创新有限公司 具有纳米结构化催化剂和分散催化剂亚层的燃料电池电极
CN102834374B (zh) 2010-04-16 2016-08-03 3M创新有限公司 质子传导材料
CN103004001B (zh) 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
CN103443210B (zh) * 2010-12-17 2016-04-06 3M创新有限公司 具有侧链含溴部分的氟化低聚物
WO2012082546A1 (en) 2010-12-17 2012-06-21 3M Innovative Properties Company Partially fluorinated polysulfinic acids and their salts
EP2500393B1 (en) 2011-03-15 2018-05-02 W.L.Gore & Associates Gmbh Use of an ionic fluoropolymer as antistatic coating
EP2718706B1 (en) 2011-06-08 2015-03-11 3M Innovative Properties Company Humidity sensor and sensor element therefor
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
CN103857831B (zh) 2011-10-10 2016-08-17 3M创新有限公司 催化剂电极及其制备和使用方法
EP2798690A1 (en) 2011-12-29 2014-11-05 3M Innovative Properties Company Electrochemical cell electrode
CN104583763B (zh) 2012-06-25 2017-03-08 3M创新有限公司 传感器元件及其制备和使用方法
US9692077B2 (en) 2012-07-27 2017-06-27 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries comprising matched ionomer membranes
US9865893B2 (en) 2012-07-27 2018-01-09 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring optimal membrane systems
US9559374B2 (en) 2012-07-27 2017-01-31 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring large negative half-cell potentials
US9768463B2 (en) 2012-07-27 2017-09-19 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries comprising metal ligand coordination compounds
US9382274B2 (en) 2012-07-27 2016-07-05 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries featuring improved cell design characteristics
US8753761B2 (en) 2012-07-27 2014-06-17 Sun Catalytix Corporation Aqueous redox flow batteries comprising metal ligand coordination compounds
US8691413B2 (en) 2012-07-27 2014-04-08 Sun Catalytix Corporation Aqueous redox flow batteries featuring improved cell design characteristics
US9899694B2 (en) 2012-07-27 2018-02-20 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring high open circuit potential
US10164284B2 (en) 2012-07-27 2018-12-25 Lockheed Martin Energy, Llc Aqueous redox flow batteries featuring improved cell design characteristics
JP6263179B2 (ja) 2012-08-02 2018-01-17 スリーエム イノベイティブ プロパティズ カンパニー 携帯用電子装置及び蒸気センサカード
WO2014105407A1 (en) 2012-12-28 2014-07-03 3M Innovative Properties Company Electrode and method of making the same
JP2017501544A (ja) 2013-12-17 2017-01-12 スリーエム イノベイティブ プロパティズ カンパニー 膜電極接合体及びその製造方法
WO2015095021A1 (en) 2013-12-17 2015-06-25 3M Innovative Properties Company Membrane electrode assembly and methods of making the same
WO2016086163A1 (en) 2014-11-26 2016-06-02 Lockheed Martin Advanced Energy Storage, Llc Metal complexes of substituted catecholates and redox flow batteries containing the same
EP3235039B1 (en) 2014-12-15 2019-04-17 3M Innovative Properties Company Membrane electrode assembly
US10253051B2 (en) 2015-03-16 2019-04-09 Lockheed Martin Energy, Llc Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride
WO2016154175A1 (en) 2015-03-24 2016-09-29 3M Innovative Properties Company Membrane assemblies, electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries therefrom
WO2016154197A1 (en) 2015-03-24 2016-09-29 3M Innovative Properties Company Porous electrodes, membrane-electrode assemblies, electrode assemblies, and electrochemical cells and liquid flow batteries therefrom
KR20170129884A (ko) 2015-03-24 2017-11-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 다공성 전극 및 이로부터 제조된 전기화학 전지 및 액체 흐름 배터리
KR20170129888A (ko) 2015-03-24 2017-11-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 다공성 전극 및 이로부터 제조된 전기화학 전지 및 액체 흐름 배터리
JP6846359B2 (ja) 2015-05-26 2021-03-24 スリーエム イノベイティブ プロパティズ カンパニー 酸素発生触媒電極並びにそれを製造及び使用する方法
WO2017004495A1 (en) * 2015-07-01 2017-01-05 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
WO2017004496A1 (en) * 2015-07-01 2017-01-05 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
US10737220B2 (en) 2015-07-01 2020-08-11 3M Innovative Properties Company PVP- and/or PVL-containing composite membranes and methods of use
US10316047B2 (en) 2016-03-03 2019-06-11 Lockheed Martin Energy, Llc Processes for forming coordination complexes containing monosulfonated catecholate ligands
US10644342B2 (en) 2016-03-03 2020-05-05 Lockheed Martin Energy, Llc Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same
EP3430664A1 (en) 2016-03-17 2019-01-23 3M Innovative Properties Company Electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries therefrom
WO2017160961A1 (en) 2016-03-17 2017-09-21 3M Innovative Properties Company Membrane assemblies, electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries therefrom
US20190051877A1 (en) 2016-03-17 2019-02-14 3M Innovative Properties Company Membrane assemblies, electrode assemblies, membrane-electrode assemblies and electrochemical cells and liquid flow batteries therefrom
US9938308B2 (en) 2016-04-07 2018-04-10 Lockheed Martin Energy, Llc Coordination compounds having redox non-innocent ligands and flow batteries containing the same
US10377687B2 (en) 2016-07-26 2019-08-13 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
US10343964B2 (en) 2016-07-26 2019-07-09 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
KR20190039971A (ko) 2016-08-11 2019-04-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 막-전극 조립체 및 그로부터의 전기화학 전지 및 액체 흐름 배터리
US10065977B2 (en) 2016-10-19 2018-09-04 Lockheed Martin Advanced Energy Storage, Llc Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone
US10930937B2 (en) 2016-11-23 2021-02-23 Lockheed Martin Energy, Llc Flow batteries incorporating active materials containing doubly bridged aromatic groups
US10497958B2 (en) 2016-12-14 2019-12-03 Lockheed Martin Energy, Llc Coordinatively unsaturated titanium catecholate complexes and processes associated therewith
US10741864B2 (en) 2016-12-30 2020-08-11 Lockheed Martin Energy, Llc Aqueous methods for forming titanium catecholate complexes and associated compositions
US10320023B2 (en) 2017-02-16 2019-06-11 Lockheed Martin Energy, Llc Neat methods for forming titanium catecholate complexes and associated compositions
WO2018185616A1 (en) 2017-04-03 2018-10-11 3M Innovative Properties Company Water electrolyzers
KR102543281B1 (ko) 2017-04-03 2023-06-16 쓰리엠 이노베이티브 프로퍼티즈 캄파니 물 전해 장치
EP3607114A1 (en) 2017-04-03 2020-02-12 3M Innovative Properties Company Water electrolyzers
WO2019034994A1 (en) 2017-08-16 2019-02-21 3M Innovative Properties Company POLYMER IONOMER SEPARATION MEMBRANES AND METHODS OF USE
EP3473659A1 (de) 2017-10-17 2019-04-24 Evonik Degussa GmbH Polymere anionen leitende membrane
WO2019193500A1 (en) 2018-04-03 2019-10-10 3M Innovative Properties Company Non-woven electrode integrated with transport protection layer for electrochemical devices
WO2019212926A1 (en) 2018-05-01 2019-11-07 3M Innovative Properties Company Platinum-coated polyimide particles and articles thereof
WO2020065455A1 (en) 2018-09-24 2020-04-02 3M Innovative Properties Company Porous electrode, membrane-electrode assembly, liquid flow battery and method of making a porous electrode
US11560632B2 (en) 2018-09-27 2023-01-24 3M Innovative Properties Company Membrane, membrane electrode assembly, and water electrolyzer including the same
CN112771212A (zh) 2018-09-28 2021-05-07 3M创新有限公司 氢燃料系统
WO2020128849A1 (en) 2018-12-19 2020-06-25 3M Innovative Properties Company Water electrolyzers
CN113228356B (zh) 2018-12-21 2025-03-25 3M创新有限公司 减少催化剂中毒的含氟聚合物离聚物及由其制得的制品
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
PL3770201T3 (pl) 2019-07-22 2023-09-25 Evonik Operations Gmbh Membrana polimerowa przewodząca aniony
JP2023504273A (ja) 2019-12-02 2023-02-02 スリーエム イノベイティブ プロパティズ カンパニー ペルフルオロスルホン酸アイオノマーの分散性粒子
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles
WO2022256669A1 (en) 2021-06-04 2022-12-08 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
WO2023007289A1 (en) 2021-07-28 2023-02-02 3M Innovative Properties Company Making an electrochemical membrane from low t(alpha) fluorinated ionomer salts
WO2026059608A2 (en) 2024-06-17 2026-03-19 The Chemours Company Fc, Llc Method for converting ionomers
WO2026050192A1 (en) 2024-08-27 2026-03-05 The Chemours Company Fc, Llc Method for recycling reinforced ionomer membranes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5893728A (ja) * 1981-12-01 1983-06-03 Tokuyama Soda Co Ltd イオン交換膜
WO1986006879A1 (en) * 1985-05-17 1986-11-20 The Dow Chemical Company Proton exchange polymer film fuel cells
CN86104292A (zh) * 1985-05-31 1987-01-21 陶氏化学公司 新的氟化高聚物溶液

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3114778A (en) 1963-12-17 Fluorinated vinyl ethers and their
US2732398A (en) 1953-01-29 1956-01-24 cafiicfzsojk
US3450684A (en) 1963-07-24 1969-06-17 Du Pont Fluorocarbon polyethers
US3301893A (en) 1963-08-05 1967-01-31 Du Pont Fluorocarbon ethers containing sulfonyl groups
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3250808A (en) 1963-10-31 1966-05-10 Du Pont Fluorocarbon ethers derived from hexafluoropropylene epoxide
US3250608A (en) 1963-11-07 1966-05-10 Electro Glass Lab Inc Method and apparatus for the vacuum purification of materials
US3311658A (en) 1966-08-01 1967-03-28 Du Pont Fluorocarbon ethers containing iodine
US3560568A (en) 1968-11-26 1971-02-02 Du Pont Preparation of sulfonic acid containing fluorocarbon vinyl ethers
US4275226A (en) 1978-08-25 1981-06-23 Asahi Glass Company, Ltd. Process for producing fluorovinyl ether
US4329435A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof
US4329434A (en) 1979-05-31 1982-05-11 Asahi Kasei Kogyo Kabushiki Kaisha Novel fluorinated cation exchange membrane and process for producing the same
US4417969A (en) 1980-06-11 1983-11-29 The Dow Chemical Co. Sulfonic acid electrolytic cell membranes
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4337137A (en) 1980-06-11 1982-06-29 The Dow Chemical Company Composite ion exchange membranes
US4330654A (en) 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
US4358412A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Preparation of vinyl ethers
US4554112A (en) 1980-10-16 1985-11-19 The Dow Chemical Company Method for the preparation of vinyl compounds
US4332954A (en) 1981-01-30 1982-06-01 Minnesota Mining And Manufacturing Company Cyclic sulfoperfluoroaliphaticcarboxylic acid anhydrides
JPS57164991A (en) 1981-04-02 1982-10-09 Asahi Chem Ind Co Ltd Production of (omega-fluorosulfonyl)haloaliphatic carboxylic acid fluoride
US4433082A (en) 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
US4834922A (en) 1982-02-04 1989-05-30 The Dow Chemical Company Process to produce novel fluorocarbon vinyl ethers and resulting polymers
US4784882A (en) * 1985-05-31 1988-11-15 The Dow Chemical Company Method for forming composite polymer films
HUT44053A (en) 1985-05-31 1988-01-28 Dow Chemical Co New fluoropolymer solutions
US4749526A (en) 1986-09-12 1988-06-07 Minnesota Mining And Manufacturing Co. Process for preparing fluoraliphatic ether-containing carbonyl fluoride compositions
US4940525A (en) * 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
US4997988A (en) 1988-08-19 1991-03-05 Phillips Petroleum Company Oxa-organic sulfur compounds, their preparation and use
IT1230138B (it) 1989-04-28 1991-10-14 Ausimont Srl Procedimento per preparare perfluoroalchenil solfonil fluoruri.
IT1246357B (it) 1990-07-12 1994-11-17 Ausimont Spa Processo per la preparazione di composti perfluoroalcossisolfonici
JP3360689B2 (ja) 1992-06-26 2002-12-24 ダイキン工業株式会社 フッ素化ビニルエーテルの製造方法
JPH08500374A (ja) * 1992-07-30 1996-01-16 インペリアル・ケミカル・インダストリーズ・ピーエルシー フッ素化ポリマー
US5281680A (en) 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
JP3382654B2 (ja) * 1993-02-03 2003-03-04 旭硝子株式会社 固体高分子電解質型燃料電池
US5318674A (en) 1993-06-30 1994-06-07 Minnesota Mining And Manufacturing Company Process for preparing perfluoroalkanesulfonyl fluorides
US5746954A (en) 1995-09-07 1998-05-05 The Dow Chemical Company Processes for forming thin, durable coatings of perfluorocarbon ionomers on various substrate materials
US6388139B1 (en) 1997-11-05 2002-05-14 E. I. Du Pont De Nemours And Company Production of perfluoro (alkyl vinyl) ethers
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
US6255536B1 (en) 1999-12-22 2001-07-03 Dyneon Llc Fluorine containing vinyl ethers
US7094851B2 (en) * 2001-12-06 2006-08-22 Gore Enterprise Holdings, Inc. Low equivalent weight ionomer
US7285349B2 (en) * 2003-10-30 2007-10-23 3M Innovative Properties Company Polymer electrolyte membrane and method of making
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5893728A (ja) * 1981-12-01 1983-06-03 Tokuyama Soda Co Ltd イオン交換膜
WO1986006879A1 (en) * 1985-05-17 1986-11-20 The Dow Chemical Company Proton exchange polymer film fuel cells
CN86104292A (zh) * 1985-05-31 1987-01-21 陶氏化学公司 新的氟化高聚物溶液

Also Published As

Publication number Publication date
CA2507541A1 (en) 2004-07-22
WO2004062019A8 (en) 2005-07-07
WO2004062019A1 (en) 2004-07-22
EP1573850A1 (en) 2005-09-14
CN1726611A (zh) 2006-01-25
KR20050092713A (ko) 2005-09-22
JP5230898B2 (ja) 2013-07-10
US20040121210A1 (en) 2004-06-24
AU2003291542A1 (en) 2004-07-29
US7348088B2 (en) 2008-03-25
JP2006511919A (ja) 2006-04-06

Similar Documents

Publication Publication Date Title
CN100377411C (zh) 高度氟化主链聚合物电解质膜
US7265162B2 (en) Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
EP2739682B1 (en) Low equivalent weight polymers
CN111094439B (zh) 氟化共聚物及其组合物以及包含氟化共聚物的制品
JP5319067B2 (ja) Ｅ−ビームにより架橋されたポリマー電解質
CN100448087C (zh) 聚合物电解质膜和制备方法
EP3426701B1 (en) Fluorinated copolymer having sulfonyl pendant groups and method of making an ionomer
JP2018528316A (ja) スルホニルペンダント基を有するテトラフルオロエチレンのコポリマーを作製する方法
US20100093878A1 (en) Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes
US12034193B2 (en) Fluorinated copolymer and compositions and articles including the same
US20250239638A1 (en) Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
CN115398684A (zh) 包含氟化聚合物和盐纳米粒子的复合材料以及包含其的制品

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20080326

CX01 Expiry of patent term