CN100377400C - 燃料电池用催化剂、其制造方法和燃料电池 - Google Patents
燃料电池用催化剂、其制造方法和燃料电池 Download PDFInfo
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- CN100377400C CN100377400C CNB038220830A CN03822083A CN100377400C CN 100377400 C CN100377400 C CN 100377400C CN B038220830 A CNB038220830 A CN B038220830A CN 03822083 A CN03822083 A CN 03822083A CN 100377400 C CN100377400 C CN 100377400C
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- catalyst
- fuel cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002273176A JP4617053B2 (ja) | 2002-09-19 | 2002-09-19 | 燃料電池用触媒、その製造方法および燃料電池 |
JP273176/2002 | 2002-09-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1682395A CN1682395A (zh) | 2005-10-12 |
CN100377400C true CN100377400C (zh) | 2008-03-26 |
Family
ID=32024948
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038220830A Expired - Lifetime CN100377400C (zh) | 2002-09-19 | 2003-07-10 | 燃料电池用催化剂、其制造方法和燃料电池 |
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JP (1) | JP4617053B2 (de) |
CN (1) | CN100377400C (de) |
CA (1) | CA2498218C (de) |
DE (2) | DE10362173B4 (de) |
WO (1) | WO2004027904A1 (de) |
Families Citing this family (5)
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JP2008041498A (ja) * | 2006-08-08 | 2008-02-21 | Sharp Corp | 固体高分子形燃料電池用触媒担持体の製造方法および固体高分子形燃料電池 |
JP6818288B2 (ja) * | 2015-06-16 | 2021-01-20 | 国立大学法人東北大学 | 白金族担持触媒及びその製造方法 |
WO2019054722A1 (ko) * | 2017-09-12 | 2019-03-21 | 주식회사 엘지화학 | 담체-나노입자 복합체, 이를 포함하는 촉매 및 이의 제조방법 |
KR102110659B1 (ko) * | 2017-09-12 | 2020-05-14 | 주식회사 엘지화학 | 담체-나노입자 복합체, 이를 포함하는 촉매 및 이의 제조방법 |
KR102188587B1 (ko) * | 2019-04-01 | 2020-12-08 | 포항공과대학교 산학협력단 | 전이금속 단원자 촉매의 제조방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56155645A (en) * | 1980-05-06 | 1981-12-01 | Hitachi Ltd | Preparation of noble metal catalyst |
JP2000100448A (ja) * | 1998-09-24 | 2000-04-07 | Tanaka Kikinzoku Kogyo Kk | 高分子固体電解質型燃料電池用触媒 |
EP1164651A1 (de) * | 2000-06-12 | 2001-12-19 | Asahi Glass Co., Ltd. | Elektrodenkatalysator für Festpolymerelektrolytbrennstoffzelle und Verfahren zu dessen Herstellung |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6348752A (ja) * | 1986-08-14 | 1988-03-01 | Fuji Electric Co Ltd | 燃料電池用電極の製造方法 |
DE19534493A1 (de) * | 1995-09-18 | 1997-03-20 | Basf Ag | Verfahren zur Herstellung feinteiliger Schalenkatalysatoren und ihre Verwendung bei der Synthese von Aziridinen |
DE19721437A1 (de) * | 1997-05-21 | 1998-11-26 | Degussa | CO-toleranter Anodenkatalysator für PEM-Brennstoffzellen und Verfahren zu seiner Herstellung |
DE19745904A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen |
DE19756880A1 (de) * | 1997-12-19 | 1999-07-01 | Degussa | Anodenkatalysator für Brennstoffzellen mit Polymerelektrolyt-Membranen |
JP2001093531A (ja) * | 1999-09-28 | 2001-04-06 | Asahi Glass Co Ltd | 固体高分子型燃料電池及びそのための電極触媒の製造方法 |
JP2001357857A (ja) * | 2000-06-12 | 2001-12-26 | Asahi Glass Co Ltd | 固体高分子型燃料電池及びその製造方法 |
-
2002
- 2002-09-19 JP JP2002273176A patent/JP4617053B2/ja not_active Expired - Lifetime
-
2003
- 2003-07-10 CA CA2498218A patent/CA2498218C/en not_active Expired - Lifetime
- 2003-07-10 CN CNB038220830A patent/CN100377400C/zh not_active Expired - Lifetime
- 2003-07-10 DE DE10362173A patent/DE10362173B4/de not_active Expired - Lifetime
- 2003-07-10 WO PCT/JP2003/008802 patent/WO2004027904A1/ja active Application Filing
- 2003-07-10 DE DE10393310T patent/DE10393310B4/de not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56155645A (en) * | 1980-05-06 | 1981-12-01 | Hitachi Ltd | Preparation of noble metal catalyst |
JP2000100448A (ja) * | 1998-09-24 | 2000-04-07 | Tanaka Kikinzoku Kogyo Kk | 高分子固体電解質型燃料電池用触媒 |
EP1164651A1 (de) * | 2000-06-12 | 2001-12-19 | Asahi Glass Co., Ltd. | Elektrodenkatalysator für Festpolymerelektrolytbrennstoffzelle und Verfahren zu dessen Herstellung |
Also Published As
Publication number | Publication date |
---|---|
JP4617053B2 (ja) | 2011-01-19 |
DE10393310T5 (de) | 2005-11-03 |
DE10362173B4 (de) | 2010-04-22 |
JP2004111251A (ja) | 2004-04-08 |
CN1682395A (zh) | 2005-10-12 |
CA2498218A1 (en) | 2004-04-01 |
DE10393310B4 (de) | 2010-01-14 |
WO2004027904A1 (ja) | 2004-04-01 |
CA2498218C (en) | 2011-05-17 |
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