CN100352770C - 集成工艺处理对氨基苯酚生产废水和资源回收方法 - Google Patents
集成工艺处理对氨基苯酚生产废水和资源回收方法 Download PDFInfo
- Publication number
- CN100352770C CN100352770C CNB2006100379193A CN200610037919A CN100352770C CN 100352770 C CN100352770 C CN 100352770C CN B2006100379193 A CNB2006100379193 A CN B2006100379193A CN 200610037919 A CN200610037919 A CN 200610037919A CN 100352770 C CN100352770 C CN 100352770C
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- Prior art keywords
- aminophenol
- resin
- waste water
- wastewater
- desorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 239000002351 wastewater Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 238000011084 recovery Methods 0.000 title description 5
- 239000011347 resin Substances 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 238000003795 desorption Methods 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000001179 sorption measurement Methods 0.000 claims abstract description 21
- 230000003647 oxidation Effects 0.000 claims abstract description 16
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 13
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 3
- 238000010521 absorption reaction Methods 0.000 claims description 20
- 241001131796 Botaurus stellaris Species 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 239000012047 saturated solution Substances 0.000 claims description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 230000008929 regeneration Effects 0.000 claims description 2
- 238000011069 regeneration method Methods 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 5
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910001902 chlorine oxide Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 5
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- 230000000202 analgesic effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000005304 joining Methods 0.000 description 3
- 229960005489 paracetamol Drugs 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical group C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000003843 chloralkali process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- -1 photography Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100379193A CN100352770C (zh) | 2006-01-23 | 2006-01-23 | 集成工艺处理对氨基苯酚生产废水和资源回收方法 |
Applications Claiming Priority (1)
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CNB2006100379193A CN100352770C (zh) | 2006-01-23 | 2006-01-23 | 集成工艺处理对氨基苯酚生产废水和资源回收方法 |
Publications (2)
Publication Number | Publication Date |
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CN1803641A CN1803641A (zh) | 2006-07-19 |
CN100352770C true CN100352770C (zh) | 2007-12-05 |
Family
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Family Applications (1)
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CNB2006100379193A Active CN100352770C (zh) | 2006-01-23 | 2006-01-23 | 集成工艺处理对氨基苯酚生产废水和资源回收方法 |
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CN (1) | CN100352770C (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102616959B (zh) * | 2012-04-01 | 2013-11-06 | 江苏焕鑫高新材料科技有限公司 | 从含酚和碘离子废碱水中回收碘与酚类物质且无污染排放的方法 |
CN102815827A (zh) * | 2012-06-18 | 2012-12-12 | 江苏扬农锦湖化工有限公司 | 环氧树脂高盐废水处理方法 |
CN104086029A (zh) * | 2014-07-21 | 2014-10-08 | 上海伟业环保工程有限公司 | 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物及其衍生物的生产废水回收工艺 |
CN107043145A (zh) * | 2016-11-30 | 2017-08-15 | 南通波涛化工有限公司 | 一种树脂吸附法预处理含苯胺类废水工艺 |
CN107117749A (zh) * | 2017-05-17 | 2017-09-01 | 浙江奇彩环境科技股份有限公司 | 一种对氨基苯酚生产废水的资源化处理方法 |
CN115521014A (zh) * | 2022-10-28 | 2022-12-27 | 辽宁世星药化有限公司 | 硝基苯催化加氢生产对氨基苯酚产生废水的处理方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1562790A (zh) * | 2004-04-06 | 2005-01-12 | 南京大学 | 对硝基苯酚生产废水的治理与资源回收利用的方法 |
CN1600700A (zh) * | 2003-09-24 | 2005-03-30 | 浙江工业大学 | 一种含苯酚废水的电解氧化处理工艺 |
CN1636892A (zh) * | 2004-11-17 | 2005-07-13 | 杨云军 | 一种组合工艺处理扑热息痛高浓度、高色度废水的方法 |
CN1712365A (zh) * | 2005-05-18 | 2005-12-28 | 南京大学 | 对氨基苯酚生产废水的治理与资源化方法 |
-
2006
- 2006-01-23 CN CNB2006100379193A patent/CN100352770C/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1600700A (zh) * | 2003-09-24 | 2005-03-30 | 浙江工业大学 | 一种含苯酚废水的电解氧化处理工艺 |
CN1562790A (zh) * | 2004-04-06 | 2005-01-12 | 南京大学 | 对硝基苯酚生产废水的治理与资源回收利用的方法 |
CN1636892A (zh) * | 2004-11-17 | 2005-07-13 | 杨云军 | 一种组合工艺处理扑热息痛高浓度、高色度废水的方法 |
CN1712365A (zh) * | 2005-05-18 | 2005-12-28 | 南京大学 | 对氨基苯酚生产废水的治理与资源化方法 |
Non-Patent Citations (1)
Title |
---|
超临界水氧化处理对氨基苯酚废水研究 甄宝勤,葛红光,李星彩,郭小华.化工技术与开发,第34卷第5期 2005 * |
Also Published As
Publication number | Publication date |
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CN1803641A (zh) | 2006-07-19 |
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Assignee: Jiangsu Ruixiang Chemical Co., Ltd. Assignor: Jiangsu Yangnong Chemical Group Co., Ltd.|Nanjing University|Jiangsu NJU Gede Environmental Protection Technology Co., Ltd. Contract fulfillment period: 2009.3.10 to 2015.3.9 contract change Contract record no.: 2009320000424 Denomination of invention: Integrated process for treating waste water of p-aminophenol production and resource recovery method Granted publication date: 20071205 License type: Exclusive license Record date: 2009.3.18 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.3.10 TO 2015.3.9; CHANGE OF CONTRACT Name of requester: JIANGSU RUIXIANG CHEMICAL INDUSTRY CO., LTD. Effective date: 20090318 |