CN102616959B - 从含酚和碘离子废碱水中回收碘与酚类物质且无污染排放的方法 - Google Patents
从含酚和碘离子废碱水中回收碘与酚类物质且无污染排放的方法 Download PDFInfo
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- CN102616959B CN102616959B CN 201210098506 CN201210098506A CN102616959B CN 102616959 B CN102616959 B CN 102616959B CN 201210098506 CN201210098506 CN 201210098506 CN 201210098506 A CN201210098506 A CN 201210098506A CN 102616959 B CN102616959 B CN 102616959B
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- iodine
- aldehydes matter
- waste water
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- ions
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- 229910052740 iodine Inorganic materials 0.000 title claims abstract description 77
- 239000011630 iodine Substances 0.000 title claims abstract description 77
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000002699 waste material Substances 0.000 title abstract description 15
- 238000004064 recycling Methods 0.000 title abstract description 3
- -1 phenol ions Chemical class 0.000 title abstract 6
- 150000002989 phenols Chemical class 0.000 title abstract 2
- 239000003513 alkali Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000706 filtrate Substances 0.000 claims abstract description 7
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 7
- 230000001590 oxidative effect Effects 0.000 claims abstract description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims abstract description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 30
- 239000002351 wastewater Substances 0.000 claims description 30
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims description 16
- 229940006461 iodide ion Drugs 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 11
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000012074 organic phase Substances 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 10
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000020477 pH reduction Effects 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000005188 flotation Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 206010006895 Cachexia Diseases 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 208000016318 wasting Diseases 0.000 description 1
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CN 201210098506 CN102616959B (zh) | 2012-04-01 | 2012-04-01 | 从含酚和碘离子废碱水中回收碘与酚类物质且无污染排放的方法 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103508420A (zh) * | 2013-09-29 | 2014-01-15 | 辽宁师范大学 | 一种在实验室含碘废液中回收碘的方法 |
CN112028020B (zh) * | 2020-09-02 | 2021-06-22 | 山东博苑医药化学股份有限公司 | 一种含溴化碘医药有机废液回收碘的工艺 |
CN112079716A (zh) * | 2020-09-11 | 2020-12-15 | 浙江禾本科技股份有限公司 | 一种利用含碘废水制备2-碘丙酸甲酯的方法 |
CN112551760A (zh) * | 2020-12-22 | 2021-03-26 | 上海鲲谷环保科技有限公司 | 一种废水中碘的去除方法 |
CN113120925B (zh) * | 2021-04-16 | 2022-12-30 | 湖南瑞冠生物化工科技有限公司 | 一种从异佛尔酮裂解料中回收碘化物的方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1699143A (zh) * | 2005-05-09 | 2005-11-23 | 浙江大学 | 从坡缕石矿石中回收碘的方法 |
CN1803641A (zh) * | 2006-01-23 | 2006-07-19 | 南京大学 | 集成工艺处理对氨基苯酚生产废水和资源回收方法 |
CN101348236A (zh) * | 2008-09-12 | 2009-01-21 | 湖南利洁生物化工有限公司 | 碘代烷烃催化剂中碘素的回收方法 |
CN101955425A (zh) * | 2009-07-21 | 2011-01-26 | 常明 | 一种无废水生产2.4-d酸的工艺方法 |
CN102139976A (zh) * | 2011-02-22 | 2011-08-03 | 上海化学工业区中法水务发展有限公司 | Mdi生产过程中含盐废水的处理方法 |
-
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- 2012-04-01 CN CN 201210098506 patent/CN102616959B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1699143A (zh) * | 2005-05-09 | 2005-11-23 | 浙江大学 | 从坡缕石矿石中回收碘的方法 |
CN1803641A (zh) * | 2006-01-23 | 2006-07-19 | 南京大学 | 集成工艺处理对氨基苯酚生产废水和资源回收方法 |
CN101348236A (zh) * | 2008-09-12 | 2009-01-21 | 湖南利洁生物化工有限公司 | 碘代烷烃催化剂中碘素的回收方法 |
CN101955425A (zh) * | 2009-07-21 | 2011-01-26 | 常明 | 一种无废水生产2.4-d酸的工艺方法 |
CN102139976A (zh) * | 2011-02-22 | 2011-08-03 | 上海化学工业区中法水务发展有限公司 | Mdi生产过程中含盐废水的处理方法 |
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GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: JIANGSU HUANXIN NEW MATERIALS CO., LTD. Free format text: FORMER NAME: JIANGSU HUANXIN HIGH-TECH MATERIALS CO., LTD. |
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Address after: North latitude two South Industrial Park Marine Economic Development Zone Dafeng City, Jiangsu province Yancheng City 224100 Patentee after: JIANGSU HUANXIN HIGH-TECH MATERIALS CO.,LTD. Address before: North latitude two South Industrial Park Marine Economic Development Zone Dafeng City, Jiangsu province Yancheng City 224100 Patentee before: Jiangsu Huanxingao New Material Technology Co.,Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: Method for recycling iodine and phenolic compounds from waste alkaline water containing phenol ions and iodine ions and realizing pollution-free emission Effective date of registration: 20181015 Granted publication date: 20131106 Pledgee: Yancheng Cathay new industries Development Fund (L.P.) Pledgor: JIANGSU HUANXIN HIGH-TECH MATERIALS CO.,LTD. Registration number: 2018990000960 |
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Effective date of registration: 20191118 Granted publication date: 20131106 |
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Date of cancellation: 20221118 Granted publication date: 20131106 |